Download or read book Geochemical Partitioning of Trace Metals in Sediments and Factors Affecting Bioaccumulation in Benthic Organisms written by Kuldip Singh Bindra and published by . This book was released on 1977 with total page 118 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Aquatic Ecotoxicology written by Alain Boudou and published by CRC Press. This book was released on 2018-01-18 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research into ecotoxicology can be classified into three fundamental concerns: abiotic factors, which characterize the physicochemistry of environments; biotic factors, relating to biological structures and functions; and contamination factors, which define the modes of pollution of ecosystems. The most significant research methodologies currently being developed in aquatic ecotoxicology are presented, specifically experimental approaches in the laboratory
Download or read book Biologically Available Metals in Sediments written by P. G. C. Campbell and published by . This book was released on 1988 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Trace Metals in a Tropical Mangrove Wetland written by Santosh Kumar Sarkar and published by Springer. This book was released on 2017-08-09 with total page 261 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive and accessible guide covering various aspects of trace metal contamination in abiotic and biotic matrices of an iconic Indian tropical mangrove wetland – Sundarban. Divided into nine chapters, the book begins by discussing the fundamental concepts of sources, accumulation rate and significance of trace metal speciation, along with the impact of multiple stressors on trace metal accumulation, taking into account both tourist activities and the exacerbating role of climate change. The second chapter presents a detailed account of the sampling strategy and preservation of research samples, followed by exhaustive information on sediment quality assessment and ecological risk, instrumental techniques in environmental chemical analyses, quality assurance and quality control, along with the Sediment Quality Guidelines (SQGs). Using raw data, the sediment quality assessment indices (e.g., pollution load index, index of geoaccumulation, Nemerow Pollution Load Index etc.) and conventional statistical analyses are worked out and interpreted precisely, allowing students to readily evaluate and interpret them. This is followed by chapters devoted to trace metal accumulation in sediments and benthic organisms, as well as acid-leachable and geochemical fractionation of trace metals in sediments. The book then focuses on chemical speciation of butylin and arsenic in sediments as well as macrozoobenthos (polychaetous annelids). Finally, potential positive role of the dominant mangrove Avicennia in sequestering trace metals from rhizosediments of Sundarban Wetland is elaborately discussed. This timely reference book provides a versatile and in-depth account for understanding the emerging problems of trace metal contamination – issues that are relevant for many countries around the globe.
Download or read book Distribution and Partitioning of Trace Metals and Tributyltin in Estuarine Sediments written by Edward D. Burton and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: An improved understanding of the geochemical partitioning of trace metals and tributyltin (TBT) in sediments is of great importance in risk assessment and remedial investigation. The aim of this thesis was to examine the distribution and partitioning behaviour of trace metals and TBT in benthic, estuarine sediments. This was achieved by a series of field- and laboratory-based studies investigating factors controlling the geochemical behaviour of trace metals and TBT in sediments from south-east Queensland, Australia. The distribution and enrichment of selected trace metals in benthic sediments of the Southport Broadwater (a semi-enclosed coastal body of water adjacent to the Gold Coast city, south-eastern Queensland, Australia) was studied. Sediment contamination for Cd, Cr, Cu, Ni, Pb, Sn and Zn was assessed by (1) comparison with Australian sediment quality guidelines, (2) calculation of the index of geoaccumulation based on regional background values, and (3) geochemical noi-malisation against Al (i.e. the abundance of alumino-silicate clay minerals). Based on this approach, several sites were found to be strongly enriched with Cu, Pb, Sn and Zn, arising from sources related to either urban runoff or vessel maintenance activities. The geochemical partitioning of Cu, Pb and Zn was examined in sediments collected from three of these sites of sediment contamination. Total Cu, Pb and Zn concentrations in coarse-textured (65 to 90 % sand sized particles), sub-oxic sediments (Eh + 120 to +260 mV) ranged from 8.3 to 194 mg/kg for Cu, 16.3 to 74.8 mg/kg for Pb and 30.1 to 220 mg/kg for Zn, and were related to vertical trends in sediment texture. The association of Cu, Pb and Zn with amorphous oxides, crystalline oxides and organic matter was linearly dependent on the abundance of each phase. For retention by amorphous oxide minerals, the trace metal retention ranged from 5.2 to 23.7 mgcjgFe oxide as Fe for Cu, 1 2.8 to 21 .5 mgpb/gFe oxide as Fe for Pb, and 23. I to 85.7 mgm/gFe oxide as Fe for Zn. Corresponding values for association with crystalline oxides were an order of magnitude less than those for amorphous oxides, indicating a weaker affinity of trace metals for crystalline oxides. The relationships describing association with organic matter ranged from 17.6 to 54.0 mgcu/gorg c for Cu, 6.1 to 9.6 mgpb/gorg c for Pb and 6.4 to 16.4 mgzn/gorg c for Zn. The in-situ solid/pore-water partitioning of TBT and the degradation products, dibutyltin (DBT) and monobutyltin (MBT), was determined for an estuarine sediment profile with previously identified elevated Sn concentrations. Total butyltin levels were (depending on depth) 220 to 8750 jig/kg for TBT, 150 to 5450 jig/kg for DBT and 130 to 4250 jig/kg for MBT. Pore-water butyltin concentrations ranged from 0.05 to 2.35 jig/L for TBT, 0.07 to 3.25 jiglL for DBT, and 0.05 to 0.53 J.tgIL for MBT. The organic carbon normalised distribution ratios (Doc) were similar for TBT, DBT and MBT, and were io to 106 L/kg. Values for the Butyltin Degradation Index (BDI) were larger than I at depths greater than 10 cm below the sediment/water-column interface, indicating that substantial TBT degradation has occurred in the sediments. This suggests that natural attenuation may be a viable sediment remediation strategy. Factors controlling the partitioning behaviour of Cu, Pb and Zn in nonsulfidic, estuarine sediments were examined in controlled laboratory-based studies with the use of combined sorption curve - sequential extraction analysis. This allowed determination of sorption parameters for Cu, Pb and Zn partitioning to individual geochemical fractions. Partitioning behaviour in sulfidic sediments was also determined by sequentially extracting Cu, Pb and Zn from synthetic sulfide minerals, and from natural sediment and pure quartz sand after spiking with acid-volatile sulfide (AVS). Trace metal sorption to the 'carbonate' fraction (pH 5, NaOAc extraction) increased with metal loading due to saturation of sorption sites associated with the 'Fe-oxide' (NH2OH. HCI extraction) and 'organic' (H202 extraction) fractions in non-sulfidic sediments. Freundlich isotherm parameters describing sorption to the 'Fe-oxide' and 'organic' fractions were dependent on the sediment Fe-oxide and organic carbon content, respectively. Sequential extraction of Cu from pure CuS, AVS-spiked sediment and AVS-spiked quartz sand showed that AVS-bound Cu was quantitatively recovered in association with the 'organic' fraction. However, some AVS-bound Pb and Zn were recovered by the NH2OH. HCI step (which has been previously interpreted as 'Fe-oxide' bound metals) in the sequential extraction procedure used in this study. This indicates that the sequential extraction of Pb and Zn in sulfidic sediments may lead to AVS-bound metals being mistaken as Fe-oxide bound species. Caution should therefore be exercised when interpreting sequential extraction results for Pb and Zn in anoxic sediments. Tributyltin (TBT) sorption to four natural sediment samples in artificial seawater was also examined under a range of modified pH and salinity conditions in controlled laboratory-based studies. Three of the sediment samples were relatively pristine with regard to TBT contamination, but the fourth was a TBT-contaminated sediment from a commercial marina. Sorption of TBT was described well by linear sorption isotherms, with distribution coefficients ranging from 6.1 to 5210 L/kg depending on pH and salinity. Sediment organic C content and particle size distribution were important determinants of sorption behaviour. The presence of resident TBT in the contaminated marina sediment caused a substantial reduction in TBT sorption due to satuaration of high selectivity sites. Desorption of TBT from the marina sediment was described by relatively large observed distribution coefficients ranging from 5100 to 9400 L/kg, suggesting that aging effects may reduce sorption reversibility. Increased artificial seawater salinity generally reduced TBT sorption at pH 4 and pH 6, but enhanced TBT sorption at pH 8. Regardless of salinity, maximum sorption of TBT was observed at pH 6, which is attributed to an optimal balance between abundance of the cationic TBT species and deprotonated surface ligands. Consideration of aqueous TBT speciation along with octanol-water partitioning behaviour suggest that hydrophobic partitioning of TBTCI to non-polar organic matter was important for pH (up to) 6, whilst partitioning of TBTOH was important at higher pH. The effect of aging on the solid/pore-water partitioning and desorption behaviour of TBT in sediments was examined. Three sediment samples with contrasting physical and chemical properties were spiked with 10 mg/kg TBT and aged under sterile conditions for periods of time ranging from I to 84 days. Aging had a negligible effect in a sandy sample with very low organic carbon content (0.2 % w/w). In contrast, for samples with larger amounts of organic carbon (2.6 and 4.8 % w/w), the effect of aging on the solid/pore-water partitioning behaviour was significant. For these samples, the apparent distribution coefficients (Ks) obtained from sequential two hour desorption experiments exhibited a two-fold increase between spiked sediments subjected to aging for 1 day and 84 days. This study demonstrates that aging effects may be an important aspect of TBT fate in contaminated sediments. Overall, the results described in this thesis demonstrate that environmental factors (i.e. pH, salinity, Eh, aging) and sediment composition (i.e. abundance of fine alumino-silicate minerals, organic matter, Fe-oxides, reactive sulfides) exert substantial effects on trace metal and TBT partitioning. The current reliance on measurement of total trace metal and TBT concentrations in contaminated sediment management may consequently lead to inaccurate estimates of environmental risk and inappropriate remediation measures if other factors regulating contaminant distribution and partitioning are ignored.
Download or read book Metal Biogeochemistry in Surface water Systems written by John F. Elder and published by . This book was released on 1988 with total page 43 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Ecological Effects of In Situ Sediment Contaminants written by R. Thomas and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 273 pages. Available in PDF, EPUB and Kindle. Book excerpt: The International Joint Commission (IJC) was established between Canada and the United States under the Boundary Water Agreement in 1909. The Great Lakes Water Quality Agreement between the two countries (signed in 1972, revised and renewed in 1978) expresses the determination of each country to restore and en hance the water quality of the largest freshwater system in the world. The Agreement provides for two inter national boards to assist the IJC: the Great Lakes Water Quality Board and the Great Lakes Science Advisory Board. In 1982, the Dredging Subcommittee of the Great Lakes Water Quality Board was asked to investigate and provide an assessment of the environmental impacts of sediment-bound contaminants and to recom mend alternate strategies for solving ecological problems associated with the presence and removal of pollu tants. This issue however, was beyond the scope of the Dredging Subcommittee. It was then referred to the Great Lakes Science Advisory Board with a specific request that the Board focus on whether contaminated sediments located in areas with water quality problems and impaired uses should be removed and if so, under what conditions. The Science Advisory Board established a Task Force to address these issues with specific reference to: - provide the IJC with an assessment of the effects of sediment-bound contaminants on biota and water quality; - recommend appropriate remedies for possible application by the parties for remedial activities in the Great Lakes; and - identify gaps in knowledge and suggest appropriate investigations to provide this knowledge.
Download or read book The Geochemical Partitioning and Bioavailability of Trace Metals in Marine Sediments written by Stewart M. Oakley and published by . This book was released on 1980* with total page 84 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Technical Report written by and published by . This book was released on 1979 with total page 812 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Aquatic Oligochaete Biology written by Ralph O. Brinkhurst and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt: After some conversations with Professor Dr. H. Caspers and other participants at the triennial congress of the International Association of Theoretical and Applied Limnology (S. I. L. ) held in Copenhagen, Denmark (1977), the senior editor approached the international delegates at the business meeting for approval of the concept of holding the First International Symposium on Aquatic Oligochaete Biology at Sidney (near Victoria) British Columbia on May 1-4, 1979. The S. I. L. agreed to sponsor such a meeting, and this sponsorship in turn led to the provision of space and technical facilities at the Institute of Ocean Sciences Patricia Bay, the Pacific Regional headquarters of the Ocean and Aquatic Sciences component of the federal Fisheri~s and Oceans Department. The National Research Council of Canada provided travel support for a number of non-Canadian participants. Invitations were sent to as many active workers in the field as the senior editor could name, and in addition two representatives of closely allied fields were invited - Dr. V. Standen who works with closely related but terrestrial species, and Dr. J. Grassle who works with polychaetes but especially with Capitella capitata which is much like an oligochaete in some aspects of its biolog- so much so that the senior editor in his salad days succumbed to some ill-founded advice and described Capitella as a new marine tubificid! The addition of these "outside" influences prevented the group from making a number of unfounded assumptions during discussions, and provided valuable cross-linkages.
Download or read book Thegeochemical Partitioning and Bioavailability of Trace Metals in Marine Sediments written by Stewart M. Oakley and published by . This book was released on 1981 with total page 92 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Mobilisation of Sedimentary Trace Metals Following Improved Oxygen Conditions written by and published by Nordic Council of Ministers. This book was released on 1999 with total page 72 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Technical Report Fisheries and Marine Service written by and published by . This book was released on 1979 with total page 940 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Metal Contaminated Aquatic Sediments written by HerbertE. Allen and published by Routledge. This book was released on 2018-04-27 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the past decade the sediments of many rivers, lakes, and estuaries have been contaminated by inorganic and organic materials. Contaminants from sediments, under certain conditions, can be released into overlying waters. Thus, sediments may be an important source of contaminants to waters in which littoral and atmospheric contaminants have been reduced or eliminated. Often found in aquatic sediments, metals are exposed to many reactions, such as sorption and precipitation, and are greatly influenced by the redox conditions in the sediment. The reactions - usually over a period of time - reflect biotic processing as well as chemical transformations. This book describes these important processes. Metal Contaminated Aquatic Sediments outlines advances in environmental chemistry, effective new modeling techniques, applications for biological treatment, and cycling and transport of trace metals in sedimentary environments. Each chapter contains a detailed reference section that draws upon a stunning array of sources. The book includes many figures and tables that illustrate the process under discussion. Features
Download or read book Trace Elements in Waterlogged Soils and Sediments written by Jörg Rinklebe and published by CRC Press. This book was released on 2016-08-19 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: Many wetlands around the world act as sinks for pollutants, in particular for trace elements. In comparison to terrestrial environments, wetlands are still far less studied. A collaborative effort among world experts, this book brings the current knowledge concerning trace elements in temporary waterlogged soils and sediments together. It discusses factors controlling the dynamics and release kinetics of trace elements and their underlying biogeochemical processes. It also discusses current technologies for remediating sites contaminated with trace metals, and the role of bioavailability in risk assessment and regulatory decision making. This book is intended for professionals around the world in disciplines related to contaminant bioavailability in aquatic organisms, contaminant fate and transport, remediation technologies, and risk assessment of aquatic and wetland ecosystems.
Download or read book Methods for Measuring the Toxicity and Bioaccumulation of Sediment associated Contaminants with Freshwater Invertebrates written by and published by . This book was released on 1994 with total page 150 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sediment contamination is a widespread environmental problem that can potentially pose a threat to a variety of aquatic ecosystems. The sediment test methods in this manual will be used by The United States Environmental Protection Agency (USEPA) to make decisions under a range of statutory authorities concerning such issues as: dredged material disposal, registration of pesticides and toxic substances, superfound site assessment, and assessment and cleanup of hazardous waste treatment, storage, and disposal facilities. The use of uniform sediment testing procedures by USEPA programs is expected to increase data accuracy and precision, facilitate test replication, increase the comparative value of test results, and ultimately, increase the efficiency of regulatory processes requiring sediment tests.
Download or read book Bioavailability of Contaminants in Soils and Sediments written by National Research Council and published by National Academies Press. This book was released on 2003-05-03 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioavailability refers to the extent to which humans and ecological receptors are exposed to contaminants in soil or sediment. The concept of bioavailability has recently piqued the interest of the hazardous waste industry as an important consideration in deciding how much waste to clean up. The rationale is that if contaminants in soil and sediment are not bioavailable, then more contaminant mass can be left in place without creating additional risk. A new NRC report notes that the potential for the consideration of bioavailability to influence decision-making is greatest where certain chemical, environmental, and regulatory factors align. The current use of bioavailability in risk assessment and hazardous waste cleanup regulations is demystified, and acceptable tools and models for bioavailability assessment are discussed and ranked according to seven criteria. Finally, the intimate link between bioavailability and bioremediation is explored. The report concludes with suggestions for moving bioavailability forward in the regulatory arena for both soil and sediment cleanup.
