Download or read book Fabrication and Characterization of Novel Environmentally Friendly Thin Film Nanocomposite Membranes for Water Desalination written by Farhad Asempour and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Thin film Nanocomposite (TFN) membranes are a relatively new class of high-performance semipermeable membranes for Reverse Osmosis (RO) applications. Large scale applications of TFN membranes have not been achieved yet due to the high production cost of the nanoparticles, agglomeration of the nanoparticles in the thin polyamide matrix of the membrane, and leaching out of typically toxic inorganic nanoparticles into the downstream. In this work, these challenges are addressed by incorporation of two different nanofillers: Cellulose NanoCrystals (CNC), and surface functionalized Halloysite NanoTubes (HNT). Amine groups, carboxylic acid groups, and the first generation of poly(amidoamine) (PAMAM) dendrimers were used for functionalization of the HNT. CNC and HNT are environmentally friendly, low/non-toxic, abundant, and inexpensive nanoparticles with a unique size, and chemical properties. TFN membranes were synthesized via in situ interfacial polymerization of m-phenylenediamine (MPD) with trimesoyl chloride (TMC) and the nanoparticles. The control Thin Film Composite (TFC) membranes, and CNC and HNT based TFN membranes were characterized by Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), X-Ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Fourier Transform Infrared spectroscopy (FTIR) and contact angle measurements. The antifouling capacity of CNC based membranes was investigated with a solution of Bovine Serum Albumin (BSA) as the fouling agent. Also, the leachability of the HNT from the membranes was examined by shaking the membranes in a batch incubator for 48 h, and then tracing the leached out HNT using Inductively Coupled Plasma Mass Spectrometry (ICP-MS). Separation characteristics of the membranes were studied by desalination of synthetic brackish water with a cross flow RO filtration system. It was revealed that incorporation of functionalized HNT enhanced the permeate flux without sacrificing the salt rejection (99.1 % ± 0.1 %). Also, incorporation of 0.1% (w/v) CNC doubled the permeate flux (from 30 to 63 L/m2.h at 20 bar) without compromising the salt rejection (97.8%). At the same time, leaching out of HNT from the TFN membranes was decreased as a result of the HNT functionalization and formation of covalent bonds with the TMC. Also, antifouling properties of the CNC-TFN membranes were 11% improved in comparison with control TFC membrane.

Download or read book Nanofiltration Membranes written by Lau Woei Jye and published by CRC Press. This book was released on 2016-12-19 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covering fabrication, characterization, and applications nanofiltration (NF) membranes, this book provides a comprehensive overview of the development of NF membrane technology over the past decade. It uniquely covers a variety of fabrication techniques, comparing the procedures of each technique to produce polymeric membranes of different morphologies. The book also discusses advances in the materials used in thin film composite (TFC) polyamide membrane fabrication and their influences on properties with respect to structural and separation characteristics. A comprehensive review on NF characterization methods and techniques is provided, assessing physical and chemical properties and separation characteristics and stability. Technical challenges in fabricating a new generation of NF membranes are also reviewed and the possible approaches to overcome the challenges are provided. The book concludes with relevant case studies on the use of NF membranes in industrial implementation of both aqueous and nonaqueous media. Details the latest progress on the fabrication techniques of asymmetric and composite NF membranes. Discusses characterization methods used in assessing membrane physical/chemical properties, separation characteristics, and performance stability. Describes the potential of advanced materials in improving properties of polyamide selective layer as well as microporous substrate. Reviews the technical challenges in fabricating a new generation of composite membrane—thin film nanocomposite (TFN) membrane—possible approaches to overcome challenges. Offers case studies on the applications of NF membranes for both aqueous and nonaqueous media.

Download or read book Nanocomposite Membranes for Water and Gas Separation written by Mohtada Sadrzadeh and published by Elsevier. This book was released on 2019-11-13 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanocomposite Membranes for Water and Gas Separation presents an introduction to the application of nanocomposite membranes in both water and gas separation processes. This in-depth literature review and discussion focuses on state-of-the-art nanocomposite membranes, current challenges and future progress, including helpful guidelines for the further improvement of these materials for water and gas separation processes. Chapters address material development, synthesis protocols, and the numerical simulation of nanocomposite membranes, along with current challenges and future trends in the areas of water and gas separation. Explains the development of nanocomposite membranes through bio-mimicking nanomaterials Discusses the surface modification of nanomaterials to fabricate robust nanocomposite membranes Outlines the environmental and operational challenges for the application of nanocomposite membranes

Download or read book Sustainable Nanoscale Engineering written by Gyorgy Szekely and published by Elsevier. This book was released on 2019-09-18 with total page 474 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sustainable Nanoscale Engineering: From Materials Design to Chemical Processing presents the latest on the design of nanoscale materials and their applications in sustainable chemical production processes. The newest achievements of materials science, in particular nanomaterials, opened new opportunities for chemical engineers to design more efficient, safe, compact and environmentally benign processes. These materials include metal-organic frameworks, graphene, membranes, imprinted polymers, polymers of intrinsic microporosity, nanoparticles, and nanofilms, to name a few. Topics discussed include gas separation, CO2 sequestration, continuous processes, waste valorization, catalytic processes, bioengineering, pharmaceutical manufacturing, supercritical CO2 technology, sustainable energy, molecular imprinting, graphene, nature inspired chemical engineering, desalination, and more. Describes new, efficient and environmentally accepted processes for nanomaterials design Includes a large array of materials, such as metal-organic frameworks, graphene, imprinted polymers, and more Explores the contribution of these materials in the development of sustainable chemical processes

Download or read book Nanotechnology for Environmental Management written by Jayanta Kumar Biswas and published by CRC Press. This book was released on 2024-09-20 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Nanotechnology for Environmental Management" is your gateway to the latest advancements in environmental science and technology. Edited by leading international scientists, this book delves into the diverse approaches and applications of nanomaterials and nanotechnologies, offering insights into their potential for environmental remediation, energy management, and sustainable development. Each chapter showcases cutting-edge innovations, making this book an essential reference for students, researchers, scientists, technicians, and professionals in environmental management and regulation. Explore the promises and challenges of nanotechnology in addressing environmental issues, and gain valuable perspectives on the future of sustainable development. With its thorough examination of state-of-the-art nanotechnological solutions, "Nanotechnology for Environmental Management" is your indispensable guide to navigating the complexities of environmental science and technology.

Download or read book Membranes for Environmental Applications written by Zhien Zhang and published by Springer Nature. This book was released on 2020-02-29 with total page 533 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book introduces recent developments of membrane technologies applied to gas and water treatments, energy processes and environmental issues. Novel knowledge and mechanisms on membrane fabrication and usage in energy, chemical, and environmental engineering are detailed in 12 book chapters from France, UK, Spain, China, Nigeria, Iran and Pakistan. The information in this book will be useful for engineers, students, and experts in these fields.

Download or read book Membrane Fabrication written by Nidal Hilal and published by CRC Press. This book was released on 2015-03-02 with total page 740 pages. Available in PDF, EPUB and Kindle. Book excerpt: Membranes play a crucial role in ensuring the optimum use and recovery of materials in manufacturing. In the process industries, they are required for efficient production and minimization of environmental impact. They are also essential for the efficient production of clean water, a significant global issue. Membrane Fabrication brings together ex

Download or read book Synthesis and Characterization of Efficient Polyamide Thin Film Nanocomposite Membranes written by Mohamed M. A. Elleithy and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: The availability of fresh water is directly associated with accessible natural resources. However, 2.5 billion of the world's population (around 40%) does not have access to proper sanitation systems, with 6 to 8 million annual deaths related to inadequate water supply, sanitation and hygiene in 2013. Currently, sea water desalination offers a feasible strategy to face global water challenge. Different water desalination techniques were developed and membrane desalination is currently the highest cost effective technique. Reverse osmosis (RO) system is by far considered the least expensive membrane process. Typically, RO system uses the thin film composite (TFC) membranes. A typical TFC membrane consists of two layers: a top dense polyamide (PA) skin layer (responsible for salt rejection) applied on an underlying support layer (responsible for mechanical support of the thin PA layer). Recently, a new category of membranes has emerged known as thin film nanocomposite membranes (TFNC) where nanoparticles (NPs) are incorporated into the support layer to enhance its properties. The support layer surface pore diameters are quite crucial in supporting and preserving the integrity of the PA layer. Thus, the ideal support layer shall comprise a non-porous to slightly porous top surface. However, a support layer with non-porous surface would resist the water flow. Consequently, the main target of the work represented was to fabricate a highly porous membrane that could still support a PA layer on top of it. Membranes with symmetric cross section have high permeability due to the highly interconnected porous structure. Yet, the surface of the symmetric membranes is also highly porous; and hence, serving as a TFNC support is challenging. Thus, this study focuses on tailoring symmetric TFNC support membranes to effectively support the PA layer. Firstly, we investigated the influence of different fabrication parameters on the support membrane properties. This entailed the understanding of the thermodynamic behavior of the cast solution during fabrication till the final precipitation of the support membrane. TFNC support membranes were prepared using cast solution of Polyethersulfone (PES) polymer in N-methyl-2-pyrrolidone (NMP) as a solvent. Afterwards, the effect of non-solvent addition was investigated using Triethylene Glycol (TEG). Furthermore, Pluronic® (Plu) and Titanium dioxide (TiO2) NPs were incorporated in two different sets of experiments to compare the enhancement of support membrane hydrophilicity and mechanical stability. Support membranes were fabricated using two consecutive phase separation processes, namely: Vapor-Induced Phase Separation (VIPS) followed by Liquid-Induced Phase Separation (LIPS). Various conditions were tested during the VIPS process, including relative humidity degree (RH) at exposure, exposure time and the effect of air convection during the exposure period. The cast solutions were prepared under 30% and 80% RH for exposure time ranging from 1 to 5 minutes. Forced convection condition was applied to the cast solutions whereas compressed dry air was introduced to the cast solution during the exposure period. On the other hand, free convection condition was defined in terms of the absence of compressed dry air introduction during VIPS process. Solution composition was systematically changed to further understand its influence on the thermodynamic behavior under VIPS process. This entailed studying the change in PES content ranging from 10 to 15 wt%, as well as the TEG (0 to 60 wt%), Plu (0 to 5 wt%) and TiO2 (0 to 1 wt%). This variability in cast solution composition clarified the influences of the solution viscosity and hygroscopicity on the thermodynamic behavior of the cast solution, which in turns, reflected on the support membrane final morphology. Afterwards, support membranes were characterized for their cross-sectional morphology using scanning electron microscopy, pore size distribution using the capillary flow porometer, hydrophilicity using contact angle method, surface charge using surface charge analyzer and chemical composition using Fourier transform infrared spectroscopy and proton nuclear magnetic resonance. Also, membranes hydraulic permeability and wettability were tested. Membranes fabricated under different conditions showed various structures including asymmetric and symmetric cross section morphologies. The effect of air convection was significantly important and in some cases even switched the cross section structure from asymmetric to completely symmetric. Interestingly, at low RH value (30%) and under free convection condition, membranes with semi-symmetric structure were successfully produced. This novel structure holds the privileges of both symmetric and asymmetric membranes. It showed high water permeability and mechanical stability due to the highly interconnected pores structure, as well as, having a very thin skin surface to support the PA layer on top of it. Furthermore, the semi-symmetric membrane showed higher compaction resistance (91.3%) and recovery (94%) as compared to the asymmetric membrane. As a consequence, the semi-symmetric morphology was considered as the structure of our interest as a TFNC support membrane. Support membrane hydrophilicity, water permeability, mechanical stability and morphology are known to have high contribution to the overall TFNC membrane performance. Thus, the developed semi-symmetric structure was then reproduced using cast solutions containing the hydrophilic additives Plu and TiO2. Results showed that the addition of TiO2 had increased both the membrane hydrophilicity and compaction resistance. However, semi-symmetric supports were only achievable with 0.05 and 0.1 wt% TiO2 concentrations. As a concluding step, polyamide (PA) top skin layer was fabricated on semi-symmetric support membranes of different compositions. The final TFNC showed the higher permeability values when semi-symmetric supports were compared to asymmetric support of same composition. Furthermore, the highest TFC permeability was for support membrane containing 1 wt% Plu and that containing 0.1 wt% TiO2.

Download or read book Reviews in Chemistry written by Omotayo Ademola Arotiba and published by Frontiers Media SA. This book was released on 2024-01-03 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Polyamide Thin Film Composite Membranes for Water Applications written by Shirley Ying Siew Khoo and published by . This book was released on 2024-04-26 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph presents the latest trends in characterization techniques for PA TFC (polyamide thin film composite) membranes and provides the most current and relevant information on these techniques tailored specifically for TFC nanofiltration and reverse osmosis membranes.

Download or read book Antibiofouling Membranes for Water and Wastewater Treatment written by Zhiwei Wang and published by Elsevier. This book was released on 2024-10-01 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt: Antibiofouling Membranes for Water and Wastewater Treatment: Principles and Applications covers most recent advances, challenges, and industrial applications of antibiofouling membranes to help in reducing cost and increasing sustainability of long term-filtration performance of membranes in water and wastewater treatment. This book will provide a compact source of relevant and timely information on antibiofouling membranes and will be of great interest to scientists, engineers, industry R&D personnel, and graduate students engaged in the development, engineering scale-up, and applications of antibiofouling membranes, as well as other readers who are interested in microfiltration, membrane bioreactor, ultrafiltration, nanofiltration, reverse osmosis, and related topics. Covers scientific and engineering principles of antibiofouling membranes for water and wastewater treatment Unravels the structure-preparation-property-application relationship of antibiofouling membranes Provides advanced design strategies of antibiofouling membrane materials Summarizes and critically discusses antibiofouling membrane materials based on biocidal nanomaterials and quaternary ammonium compounds Focuses on the state-of-the-art applications of antibiofouling membranes for water and wastewater treatment

Download or read book Sustainable Energy Water Environment Nexus in Deserts written by Essam Heggy and published by Springer Nature. This book was released on 2022-04-25 with total page 811 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses challenges and opportunities in the Energy-Water-Environment (EWE) nexus, with a particular focus on research and technology development requirements in harsh desert climates. Its chapters include selected contributions presented during the 1st international conference on sustainable Energy-Water-Environment nexus in desert climates (ICSEWEN-19) held at the Qatar Environment and Energy Research Institute (QEERI) in Doha, Qatar in December 2019. This volume is comprised of three main chapters, each describing important case studies and progress on water, energy and environmental questions. A fourth chapter on policies and community outreach on these three areas is also included. This compilation aims to bridge the gap between research and industry to address the socioeconomic impacts of the nexus imbalance as perceived by scientists, industrial partners, and policymakers. The content of this book is of particular importance to graduate students, researchers and decision makers interested in understanding water, energy and environmental challenges in arid areas. Re searchers in environmental and civil engineering, chemistry, hydrology and environmental science can also find unique in-situ observations of the current nexus imbalance in deserts climate to validate their investigations. It is also an invaluable guide for industry professionals working in water, energy, environment and food sectors to understand the rapidly evolving landscape of the EWE nexus in arid areas. The analyses, observations and lessons-learned summarized herein are applicable to other arid areas outside North Africa and the Arabian Peninsula as well, such as central Australia, the southwest of the United States and deserts in central Asia.

Download or read book Nanofiltration Membrane for Water Purification written by Akil Ahmad and published by Springer Nature. This book was released on 2023-02-04 with total page 273 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the basic and sustainable approach of nanofiltration membrane techniques along with their fabrication, characterization, separation mechanisms, and broad applications in the field of wastewater treatment. It provides a wide knowledge of nanofiltration technique to water purification audience concerning the recent development with various illustrations, methods and results for graduate students, scientists, academicians, researchers, and industrialists. Readers from wastewater and water purification will have a quick reference by exploring the research literature on the subject field with commercial value-added research applications of nanofiltration membrane.

Download or read book Membrane Based Salinity Gradient Processes for Water Treatment and Power Generation written by Sarper Sarp and published by Elsevier. This book was released on 2018-07-25 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt: Membrane-Based Salinity Gradient Processes for Water Treatment and Power Generation focuses on the various types of membrane- based salinity gradient processes that can be applied for desalination. Topics cover salinity gradient processes for desalination, such as Forward Osmosis (FO) and Pressure Retarded Osmosis (PRO), with chapters selected exclusively from a number of world-leading experts in various disciplines and from different continents. Sections include discussions on the theoretical and fundamental approaches to salinity gradient processes, various types of membrane materials and development, i.e., flat sheet and hollow fiber, various salinity water sources for an economically feasible process, and large-scale applications. Finally, the book focuses on economically feasible process optimization when both operational and capital costs are considered. Features specific details on salinity gradient techniques for various desalination applications of industrial and academic interest Contains unique discussions on membrane development and process optimization that normally only appear briefly in research articles Includes examples of internationally best practices for the evaluation of several system parameters, including thermodynamic optimization, high power density membrane development, and more Discusses large-scale applications and provides examples of such implementations, such as Statkraft, Japanese Megaton, and Korean GMVP

Download or read book Membrane Desalination written by Andreas Sapalidis and published by CRC Press. This book was released on 2020-09-13 with total page 401 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book aims to provide details about membrane desalination processes, starting from basic concepts leading to real world implementation. Chapters cover novel research topics such as biomimetic and nanocomposite membranes, nanostructured fillers for mixed matrix membranes, advanced characterization techniques and molecular modeling. Additionally, engineering and economical aspects of desalination as well as the exploitation of green energy sources are thoroughly presented. This books targets bridging the gap between the everyday research laboratory practices with practical application demands, so that the readers gain a global perspective of all desalination challenges.

Download or read book Engineering Nanocomposite Membranes written by Saif Al-Aani and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Membrane Technology written by Sundergopal Sridhar and published by CRC Press. This book was released on 2018-09-03 with total page 541 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contributed by multiple experts, the book covers the scientific and engineering aspects of membrane processes and systems. It aims to cover basic concepts of novel membrane processes including membrane bioreactors, microbial fuel cell, forward osmosis, electro-dialysis and membrane contactors. Maintains a pragmatic approach involving design, operation and cost analysis of pilot plants as well as scaled-up counterparts