Download or read book Experimental and Theoretical Studies Toward a Characterization of Conceivable Intermediates Involved in the Gas phase Oxidation of Methane by Bare FeO written by Helmut Schwarz and published by . This book was released on 1992 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Proceedings of the Robert A Welch Foundation Conferences on Chemical Research written by and published by . This book was released on 1994 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Mass Spectrometry Bulletin written by and published by . This book was released on 1992 with total page 924 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Direct Hydroxylation of Methane written by Kazunari Yoshizawa and published by Springer Nature. This book was released on 2020-10-29 with total page 167 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on theoretical and computational studies by the editor’s group on the direct hydroxylation of methane, which is one of the most challenging subjects in catalyst chemistry. These studies of more than 20 years include gas-phase reactions by transition-metal oxide ions, enzymatic reactions by two types of methane monooxygenase (soluble and particulate MMO), catalytic reactions by metal-exchanged zeolites, and methane C–H activation by metal oxide surfaces. Catalyst chemistry has been mostly empirical and based on enormous experimental efforts. The subject of the title has been tackled using the orbital interaction and computations based on extended Hückel, DFT, and band structure calculations. The strength of the theoretical studies is in the synergy between theory and experiment. Therefore, the group has close contacts with experimentalists in physical chemistry, catalyst chemistry, bioinorganic chemistry, inorganic chemistry, and surface chemistry. This resulting book will be useful for the theoretical analysis and design of catalysts.
Download or read book Methane Conversion by Oxidative Processes written by Wolf and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: A reasonable case could be made that the scientific interest in catalytic oxidation was the basis for the recognition of the phenomenon of catalysis. Davy, in his attempt in 1817 to understand the science associated with the safety lamp he had invented a few years earlier, undertook a series of studies that led him to make the observation that a jet of gas, primarily methane, would cause a platinum wire to continue to glow even though the flame was extinguished and there was no visible flame. Dobereiner reported in 1823 the results of a similar investigation and observed that spongy platina would cause the ignition of a stream of hydrogen in air. Based on this observation Dobereiner invented the first lighter. His lighter employed hydrogen (generated from zinc and sulfuric acid) which passed over finely divided platinum and which ignited the gas. Thousands of these lighters were used over a number of years. Dobereiner refused to file a patent for his lighter, commenting that "I love science more than money." Davy thought the action of platinum was the result of heat while Dobereiner believed the ~ffect ~as a manifestation of electricity. Faraday became interested in the subject and published a paper on it in 1834; he concluded that the cause for this reaction was similar to other reactions.
Download or read book Theoretical Insights Into the Selective Oxidation of Methane to Methanol written by Allegra Latimer and published by . This book was released on 2019 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: While the search for catalysts capable of directly converting methane to higher value commodity chemicals and liquid fuels has been active for over a century, a viable industrial process for selective methane activation has yet to be developed. Generally, this failure has been attributed to two primary difficulties: (1) the high barriers required to activate methane (activity), and (2) the higher activity of the C-H bonds in methanol compared to methane (selectivity). In this thesis, we delve into both of these problems and identify general frameworks and strategies that can be used in future research to identify promising catalyst materials. First, we show that, for the wide range of catalysts that proceed via a radical intermediate, a unifying framework for predicting C-H activation barriers using a single universal descriptor can be established. We combine this scaling approach with a thermodynamic analysis of active site formation to provide a map of methane activation rates, and successfully rationalize the available empirical data across catalyst classes. We then extend this analysis to catalysts that proceeed via a surface-stabilized transition state for methane activation. We present a framework for predicting the transition state's geometry (radical or surface-stabilized) and its approximate energy on a given active site. We then shift our attention to understanding and optimizing selectivity. First, we determine the principles guiding the selectivity of a related reaction, direct methanol to formaldehyde on ruthenium oxide catalysts, and find that limiting electrophilic surface oxygen coverage for this reaction is key to obtaining high selectivity. Next, recognizing that a precise and general quantification of the limitations of catalytic direct methane to methanol has not yet been established, we present a simple kinetic model to explain the selectivity-conversion tradeoff that hampers continuous partial oxidation of methane to methanol. Stemming from this analysis, we suggest several design strategies for increasing methanol yields under the constraint of the selectivity-conversion tradeoff. These strategies include (1) "collectors, " materials with strong methanol adsorption potential that can help to lower the partial pressure of methanol in the gas phase, (2) aqueous reaction conditions, and/or (3) diffusion-limited systems. Having identified these strategies, we work towards realizing a system capitalizing on (2), aqueous reaction conditions, by collaborating with experimental colleagues to develop a low-temperature electrochemical approach for methane oxidation. It is the general aim of this thesis to develop straightforward, accessible models with the help of Density Functional Theory that yield generalizable insights. We are hopeful that the models presented herein may provide a reliable framework for future researchers working to understand and evaluate new catalysts and processes for the direct oxidation of methane to methanol.
Download or read book Microwave Infrared and Laser Transitions of Methanol Atlas of Assigned Lines from 0 to 1258 cm 1 written by Giovanni Moruzzi and published by CRC Press. This book was released on 2018-01-10 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt: This unique atlas presents the recorded spectrum of CH3OH, the main isotopic species of methanol, in the range 28-1258 cm-1. The spectral plot is accompanied by a list of all currently assigned rotation-torsion-vibration lines in the absorption spectrum of methanol. The list of nearly 35,000 transitions spans all of the known microwave transitions, as well as the region of coincidence with CO2 laser emissions.
Download or read book Nanoscale Materials written by Luis M. Liz-Marzán and published by Springer Science & Business Media. This book was released on 2007-05-08 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organized nanoassemblies of inorganic nanoparticles and organic molecules are building blocks of nanodevices, whether they are designed to perform molecular level computing, sense the environment or improve the catalytic properties of a material. The key to creation of these hybrid nanostructures lies in understanding the chemistry at a fundamental level. This book serves as a reference book for researchers by providing fundamental understanding of many nanoscopic materials.
Download or read book Chemisorption and Reactivity on Supported Clusters and Thin Films written by R.M. Lambert and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 534 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous catalysis provides the backbone of the world's chemical and oil industries. The innate complexity of practical catalytic systems suggests that useful progress should be achievable by investigating key aspects of catalysis by experimental studies on idealised model systems. Thin films and supported clusters are two promising types of model system that can be used for this purpose, since they mimic important aspects of the properties of practical dispersed catalysts. Similarly, appropriate theoretical studies of chemisorption and surface reaction clusters or extended slab systems can provide valuable information on the factors that underlie bonding and catalytic activity. This volume describes such experimental and theoretical approaches to the surface chemistry and catalytic behaviour of metals, metal oxides and metal/metal oxide systems. An introduction to the principles and main themes of heterogeneous catalysis is followed by detailed accounts of the application of modern experimental and theoretical techniques to fundamental problems. The application of advanced experimental methods is complemented by a full description of theoretical procedures, including Hartree-Fock, density functional and similar techniques. The relative merits of the various approaches are considered and directions for future progress are indicated.
Download or read book One Hundred Years at the Intersection of Chemistry and Physics written by Jeremiah James and published by Walter de Gruyter. This book was released on 2011-10-27 with total page 325 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume, occasioned by the centenary of the Fritz Haber Institute, formerly the Institute for Physical Chemistry and Electrochemistry, covers the institute's scientific and institutional history from its founding until the present. The institute was among the earliest established by the Kaiser Wilhelm Society, and its inauguration was one of the first steps in the development of Berlin-Dahlem into a center for scientific research. Its establishment was made possible by an endowment from Leopold Koppel, granted on the condition that Fritz Haber, well-known for his discovery of a method to synthesize ammonia from its elements, be made its director. The history of the institute has largely paralleled that of 20th-century Germany. It undertook controversial weapons research during World War I, followed by a "Golden Era" during the 1920s, in spite of financial hardships. Under the National Socialists it experienced a purge of its scientific staff and a diversion of its research into the service of the new regime, accompanied by a breakdown in its international relations. In the immediate aftermath of World War II it suffered crippling material losses, from which it recovered slowly in the post-war era. In 1953, shortly after taking the name of its founding director, the institute joined the fledgling Max Planck Society. During the 1950s and 60s, the institute supported diverse researches into the structure of matter and electron microscopy in a territorially insular and politically precarious West-Berlin. In subsequent decades, as both Berlin and the Max Planck Society underwent significant changes, the institute reorganized around a board of coequal scientific directors and a renewed focus on the investigation of elementary processes on surfaces and interfaces, topics of research that had been central to the work of Fritz Haber and the first "Golden Era" of the institute.
Download or read book The Principles of Chemical Equilibrium written by Kenneth George Denbigh and published by Cambridge University Press. This book was released on 1981-03-26 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sample Text
Download or read book Chemical Equilibria in the Earth written by Wallace S. Broecker and published by . This book was released on 1971 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Mangrove Ecosystems A Global Biogeographic Perspective written by Victor H. Rivera-Monroy and published by Springer. This book was released on 2017-11-03 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a comprehensive overview and analysis of mangrove ecological processes, structure, and function at the local, biogeographic, and global scales and how these properties interact to provide key ecosystem services to society. The analysis is based on an international collaborative effort that focuses on regions and countries holding the largest mangrove resources and encompasses the major biogeographic and socio-economic settings of mangrove distribution. Given the economic and ecological importance of mangrove wetlands at the global scale, the chapters aim to integrate ecological and socio-economic perspectives on mangrove function and management using a system-level hierarchical analysis framework. The book explores the nexus between mangrove ecology and the capacity for ecosystem services, with an emphasis on thresholds, multiple stressors, and local conditions that determine this capacity. The interdisciplinary approach and illustrative study cases included in the book will provide valuable resources in data, information, and knowledge about the current status of one of the most productive coastal ecosystem in the world.
Download or read book Hydrogen in Intermetallic Compounds II written by Louis Schlapbach and published by Springer Science & Business Media. This book was released on 2006-01-21 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: The topic of hydrogen in an on metals and alloys is important in a number ofdisciplines including solid-state physics, materials science, physical chemistry, and energy technology. This volume treats the dynamics of hydrogen in intermetallic compounds, surface properties, kinetics, and applications of metal hydrides in energy technology. In addition, selected experimental methods are described. The introductory chapter will enable non-specialists to gain an overall picture of the field and to appreciate the relevant scientific issue. The companion volume, Hydrogene in Intermetallic Compounds I, was published as Vol. 63 of Topics in Applied Physics.
Download or read book Molten Salt Technology written by David G. Lovering and published by Springer. This book was released on 2014-11-14 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Physics and Chemistry of the Solar System written by John S. Lewis and published by Academic Press. This book was released on 2013-10-22 with total page 567 pages. Available in PDF, EPUB and Kindle. Book excerpt: Physics and Chemistry of the Solar System is a broad survey of the Solar System. The book discusses the general properties and environment of our planetary system, including the astronomical perspective, the general description of the solar system and of the sun and the solar nebula). The text also describes the solar system beyond mars, including the major planets; pluto and the icy satellites of the outer planets; the comets and meteors; and the meteorites and asteroids. The inner solar system, including the airless rocky bodies; mars, venus, and earth; and planets and life about other stars, is also encompassed. Mathematicians, chemists, physicists, geologists, astronomers, meteorologists, and biologists will find the book useful.
Download or read book Thermodynamics for the Practicing Engineer written by Louis Theodore and published by John Wiley & Sons. This book was released on 2011-11-30 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: Enables you to easily advance from thermodynamics principles to applications Thermodynamics for the Practicing Engineer, as the title suggests, is written for all practicing engineers and anyone studying to become one. Its focus therefore is on applications of thermodynamics, addressing both technical and pragmatic problems in the field. Readers are provided a solid base in thermodynamics theory; however, the text is mostly dedicated to demonstrating how theory is applied to solve real-world problems. This text's four parts enable readers to easily gain a foundation in basic principles and then learn how to apply them in practice: Part One: Introduction. Sets forth the basic principles of thermodynamics, reviewing such topics as units and dimensions, conservation laws, gas laws, and the second law of thermodynamics. Part Two: Enthalpy Effects. Examines sensible, latent, chemical reaction, and mixing enthalpy effects. Part Three: Equilibrium Thermodynamics. Addresses both principles and calculations for phase, vapor-liquid, and chemical reaction equilibrium. Part Four: Other Topics. Reviews such important issues as economics, numerical methods, open-ended problems, environmental concerns, health and safety management, ethics, and exergy. Throughout the text, detailed illustrative examples demonstrate how all the principles, procedures, and equations are put into practice. Additional practice problems enable readers to solve real-world problems similar to the ones that they will encounter on the job. Readers will gain a solid working knowledge of thermodynamics principles and applications upon successful completion of this text. Moreover, they will be better prepared when approaching/addressing advanced material and more complex problems.
