Download or read book Experimental and Computer Modeling Studies of Isotopically Selective Two step Laser Photodissociation of Small Molecules Final Report written by and published by . This book was released on 1992 with total page 25 pages. Available in PDF, EPUB and Kindle. Book excerpt: The approach to laser isotope separation taken in this study is based on isotopically selective, two-step, laser photodissociation of small molecules. A primary goal of this study is the measurement of fundamental molecular processes which control the two-step, photodissociative isotope enrichment process. This objective has led to experimental measurements of uv photodissociation cross sections for vibrationally excited states of several small molecules, including the first cross section reported for any neutral molecule in a specific, excited vibrational state. A second goal of this study has been the laboratory demonstration of isotope enrichment for isotopes of practical interest and for processes with a potential for larger scale production. Where possible, efforts have focussed on the separation of middle isotopes, such as 17O and 33S, which are expensive and difficult to separate using other techniques. Considerable success has been achieved in demonstrating the enrichment of isotopes of bromine, carbon, oxygen and a third goal of this study has been the application of computer modeling to the two-step enrichment process. Experimental measurements define as many as possible of the critical photophysical and chemical parameters required by an ab initio computer model of the enrichment process. Progress toward these goals has been documented in detail in a variety of journal articles and technical reports. It is not the objective of this final report to discuss each aspect of the work done under this contract/grant in detail. A general overview of the program, touches briefly on each of the problems addressed by the study and provides references to more detailed discussions. 19 refs.
Download or read book Experimental and Computer Modeling Studies of Isotopically Selective Two step Laser Photodissociation of Small Molecules written by and published by . This book was released on 1992 with total page 25 pages. Available in PDF, EPUB and Kindle. Book excerpt: The approach to laser isotope separation taken in this study is based on isotopically selective, two-step, laser photodissociation of small molecules. A primary goal of this study is the measurement of fundamental molecular processes which control the two-step, photodissociative isotope enrichment process. This objective has led to experimental measurements of uv photodissociation cross sections for vibrationally excited states of several small molecules, including the first cross section reported for any neutral molecule in a specific, excited vibrational state. A second goal of this study has been the laboratory demonstration of isotope enrichment for isotopes of practical interest and for processes with a potential for larger scale production. Where possible, efforts have focussed on the separation of middle isotopes, such as 17O and 33S, which are expensive and difficult to separate using other techniques. Considerable success has been achieved in demonstrating the enrichment of isotopes of bromine, carbon, oxygen and a third goal of this study has been the application of computer modeling to the two-step enrichment process. Experimental measurements define as many as possible of the critical photophysical and chemical parameters required by an ab initio computer model of the enrichment process. Progress toward these goals has been documented in detail in a variety of journal articles and technical reports. It is not the objective of this final report to discuss each aspect of the work done under this contract/grant in detail. A general overview of the program, touches briefly on each of the problems addressed by the study and provides references to more detailed discussions. 19 refs.
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1992 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energy Research Abstracts written by and published by . This book was released on 1992 with total page 886 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Government Reports Announcements Index written by and published by . This book was released on 1992 with total page 1496 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Government Reports Annual Index written by and published by . This book was released on 1992 with total page 1400 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Winter Waterfront Year round Use in Metropolitan Toronto written by Xenia Klinger and published by . This book was released on 1991 with total page 79 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book INIS Atomindex written by and published by . This book was released on 1983 with total page 888 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book ERDA Energy Research Abstracts written by United States. Energy Research and Development Administration and published by . This book was released on 1976 with total page 1314 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Computer Modeling Study of Isotopically Selective Laser Photodissociation of OCS in Cryogenic Solutions written by and published by . This book was released on 1991 with total page 30 pages. Available in PDF, EPUB and Kindle. Book excerpt: Computer model calculations are presented for enrichments of carbon, oxygen, and sulfur isotopes by two-step, IR/UV, laser photodissociation of OCS in rare gas liquid solutions. The model calculations are based on previously measured fundamental physical properties, including spectroscopic parameters of the IR absorption bands of OCS in cryogenic solution, UV photodissociation cross sections for specific vibrational levels of OCS, and rates for vibrational relaxation of OCS by cryogenic solvents. Results are presented for both pulsed and continuous wave laser sources. Photodissociation through both the 2?2 and?1 intermediate vibrational levels of OCS is investigated. The laser characteristics required to obtain optimum enrichments are determined by modeling the dependence of enrichment on laser wavelength and intensity, as well as pulse width and timing for pulsed sources. Optimum carbon and oxygen isotope enrichment factors of 9--14 are found for two-step photodissociation through the OCS(2?2) vibrational level, using pulsed CO2 and KrF excimer laser sources. Optimum sulfur isotope enrichment factors of 5--6 are found for photodissociation through the OCS(?1) level, using a pulsed 12?m laser and a KrF excimer laser. The enrichments found for continuous wave laser sources are smaller than those for pulsed sources. 19 figs., 4 tabs.
Download or read book ERDA Energy Research Abstracts written by United States. Energy Research and Development Administration. Technical Information Center and published by . This book was released on 1976 with total page 1118 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book NBS Special Publication written by and published by . This book was released on 1968 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Publications written by United States. National Bureau of Standards and published by . This book was released on 1986 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Publications of the National Bureau of Standards Catalog written by United States. National Bureau of Standards and published by . This book was released on 1986 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Publications of the National Institute of Standards and Technology Catalog written by National Institute of Standards and Technology (U.S.) and published by . This book was released on 1986 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Laser Photodissociation and Spectroscopy of Mass separated Biomolecular Ions written by Nicolas C. Polfer and published by Springer Science & Business Media. This book was released on 2013-09-03 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt: This lecture notes book presents how enhanced structural information of biomolecular ions can be obtained from interaction with photons of specific frequency - laser light. The methods described in the book "Laser photodissociation and spectroscopy of mass-separated biomolecular ions" make use of the fact that the discrete energy and fast time scale of photoexcitation can provide more control in ion activation. This activation is the crucial process producing structure-informative product ions that cannot be generated with more conventional heating methods, such as collisional activation. The book describes how the powerful separation capabilities and sensitivity of mass spectrometry (MS) can be combined with the structural insights from spectroscopy by measuring vibrational and electronic spectra of trapped analytes. The implementation of laser-based photodissociation techniques in MS requires basic knowledge of tunable light sources and ion trapping devices. This book introduces the reader to key concepts and approaches in molecular spectroscopy, and the light sources and ion traps employed in such experiments. The power of the methods is demonstrated by spectroscopic interrogation of a range of important biomolecular systems, including peptides, proteins, and saccharides, with laser light in the ultraviolet-visible, and infrared range. The book "Laser photodissociation and spectroscopy of mass-separated biomolecular ions" is an indispensable resource for students and researchers engaged or interested in this emerging field. It provides the solid background of key concepts and technologies for the measurements, discusses state-of-the-art experiments, and provides an outlook on future developments and applications.
Download or read book ERDA Energy Research Abstracts written by United States. Energy Research and Development Administration and published by . This book was released on 1976-10 with total page 770 pages. Available in PDF, EPUB and Kindle. Book excerpt:
