Download or read book Evaluation of Silicone based Passive Samplers for Monitoring Organic Aquatic Pollutants written by Ulrike Bauer and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Evaluation of Passive Samplers for the Monitoring of Contaminants in Sediment and Water written by Martin Larsen and published by Nordic Council of Ministers. This book was released on 2009 with total page 103 pages. Available in PDF, EPUB and Kindle. Book excerpt: Passive samplers spiked with performance reference compounds (PRC) were prepared in Holland, and deployed at 9 sites in the Nordic countries and Greenland. Mussels were collected at the same sites to compare passive sampler results with the mussel-watch approach usually applied in national monitoring. Sediments were sampled from 6 sites, and analysed both by total methods and passive samplers for pore water concentration. From the spiked PRCs, sampling rates was calculated, and used to determine water phase concentration of PAHs and other organic compounds with a high octanol-water partitioning coefficient. The project has shown that silicone passive samplers can be used for monitoring programmes, and development of guidelines and quality assurance of analysis are underway. Within the next 2-3 years it could become part of the monitoring strategy of OSPAR, EU and the Nordic Countries.

Download or read book Passive Sampling Techniques in Environmental Monitoring written by Richard Greenwood and published by Elsevier. This book was released on 2007-07-03 with total page 487 pages. Available in PDF, EPUB and Kindle. Book excerpt: Monitoring pollutants in air, soil and water is a routine requirement in the workplace, and in the wider environment. Passive samplers can provide a representative picture of levels of pollutants over a period of time from days to months by measuring the average concentrations to which they have been exposed. Air monitors are widely used, for instance to measure the exposure of workers to volatile compounds, but also for monitoring the fate of pollutants in the atmosphere. Passive sampling devices are now becomining increasingly used to monitor pollutants in rivers, coastal waters and ground water where contamination results from sources such as domestic and industrial discharges, and the use of agrochemicals. Passive Sampling Techniques in Environmental Monitoring provides a timely collection of information on a set of techniques that help monitor the quality of air, surface and ground waters. Passive sampling can provide an inexpensive means of obtaining a representative picture of quality over a period of time, even where levels of pollutants fluctuate due to discontinuous discharges or seasonal application of chemicals such as pesticides. Recent changes in legislation have increased the pressure to obtain better information than that provided by classical infrequent spot sampling.Brought together in one source, this book looks at the performance of a range of devices for the passive sampling of metals, and of non-polar and polar organic chemicals in air and in water. The strengths and weaknesses and the range of applicability of the technology are considered.* Comprehensive review of passive sampling - covering air, water and majority of available technologies in one volume* Chapters written by international specialist experts * Covers theory and applications, providing background information and guidelines for use in the field

Download or read book Evaluation of Passive Samplers for the Monitoring of Contaminants in Sediment and Water written by Martin Larsen and published by . This book was released on 2009 with total page 81 pages. Available in PDF, EPUB and Kindle. Book excerpt: Passive samplers spiked with performance reference compounds (PRC) were prepared in Holland, and deployed at 9 sites in the Nordic countries and Greenland. Mussels were collected at the same sites to compare passive sampler results with the mussel-watch approach usually applied in national monitoring. Sediments were sampled from 6 sites, and analysed both by total methods and passive samplers for pore water concentration. From the spiked PRCs, sampling rates was calculated, and used to determine water phase concentration of PAHs and other organic compounds with a high octanol-water partitioning coefficient. The project has shown that silicone passive samplers can be used for monitoring programmes, and development of guidelines and quality assurance of analysis are underway. Within the next 2-3 years it could become part of the monitoring strategy of OSPAR, EU and the Nordic Countries.

Download or read book NORMAN Interlaboratory Study ILS on Passive Sampling of Emerging Pollutants written by and published by . This book was released on 2016 with total page 237 pages. Available in PDF, EPUB and Kindle. Book excerpt: Passive samplers can play a valuable role in monitoring water quality within a legislative framework such as the European Union's Water Framework Directive (WFD). The time-integrated data from these devices can be used to complement chemical monitoring of priority and emerging contaminants which are difficult to analyse by spot or bottle sampling methods, and to improve risk assessment of chemical pollution. In order to increase the acceptance of passive sampling technology amongst end users and to gain further information about the robustness of the calibration and analytical steps, several inter-laboratory field studies have recently been performed in Europe. Such trials are essential to further validate this sampling method and to increase the confidence of the technological approach for end users.^An inter-laboratory study on the use of passive samplers for the monitoring of emerging pollutants was organised in 2011 by the NORMAN association (Network of reference laboratories for monitoring emerging environmental pollutants; www.norman-network.net) together with the European DG Joint Research Centre to support the Common Implementation Strategy of the WFD. Thirty academic, commercial and regulatory laboratories participated in the passive sampler comparison exercise and each was allowed to select their own sampler design. All the different devices were exposed at a single sampling site to treated waste water from a large municipal treatment plant. In addition, the organisers deployed in parallel for each target analyte class multiple samplers of a single type which were subsequently distributed to the participants for analysis. This allowed an evaluation of the contribution of the different analytical laboratory procedures to the data variability.^The results obtained allow an evaluation of the potential of different passive sampling methods for monitoring selected emerging organic contaminants (pharmaceuticals, polar pesticides, steroid hormones, fluorinated surfactants, triclosan, bisphenol A and brominated flame retardants). In most cases, between laboratory variation of results from passive samplers was roughly a factor 5 larger than within laboratory variability. Similar results obtained for different passive samplers analysed by individual laboratories and also low within laboratory variability of sampler analysis indicate that the passive sampling process is causing less variability than the analysis. This points at difficulties that laboratories experienced with analysis in complex environmental matrices. Where a direct comparison was possible (not in case of brominated flame retardants) analysis of composite water samples provided results that were within the concentration range obtained by passive samplers.^However, in the future a significant improvement of the overall precision of passive sampling is needed. The results will be used to inform EU Member States about the potential application of passive sampling methods for monitoring organic chemicals within the framework of the WFD.

Download or read book Monitors of Organic Chemicals in the Environment written by James N. Huckins and published by Springer Science & Business Media. This book was released on 2006-11-30 with total page 229 pages. Available in PDF, EPUB and Kindle. Book excerpt: The authors of this book are pioneers of the passive, integrative sampling approach and developers of globally applied semipermeable membrane devices (SPMDs). The book will boost understanding of how passive samplers such as SPMD function by examining basic exchange processes that mediate the concentration of SVOCs in a sampling matrix. The book delineates fundamental theory and modeling techniques, while providing a practical guide for its proper application.

Download or read book Development and Evaluation of Passive Sampling Devices to Characterize the Sources Occurrence and Fate of Polar Organic Contaminants in Aquatic Systems written by Jonathan K. Challis and published by . This book was released on 2018 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The primary goal of this dissertation was to develop and evaluate an improved aquatic passive sampling device (PSD) for measurement of polar organic contaminants. Chemical uptake of current polar-PSDs (e.g., POCIS - polar organic chemical integrative sampler) is dependent on the specific environmental conditions in which the sampler is deployed (flow-rate, temperature), leading to large uncertainties when applying laboratory-derived sampling rates in-situ. A novel configuration of the diffusive gradients in thin-films (DGT) passive sampler was developed to overcome these challenges. The organic-DGT (o-DGT) configuration comprised a hydrophilic-lipophilic balance® sorbent binding phase and an outer agarose diffusive gel (thickness = 0.5-1.5 mm), notably excluding a polyethersulfone protective membrane which is used with all other polar-PSDs. Sampler calibration exhibited linear uptake and sufficient capacity for 34 pharmaceuticals and pesticides over typical environmental deployment times, with measured sampling rates ranging from 9-16 mL/d. Measured and modelled diffusion coefficients (D) through the outer agarose gel provided temperature-specific estimates of o-DGT sampling rates within 20% (measured-D) and 30% (modelled-D) compared to rates determined through full-sampler calibration. Boundary layer experiments in lab and field demonstrated that inclusion of the agarose diffusive gel negated boundary layer effects, suggesting that o-DGT uptake is largely insensitive to hydrodynamic conditions. The utility of o-DGT was evaluated under a variety of field conditions and performance was assessed in comparison to POCIS and grab samples. o-DGT was effective at measuring pharmaceuticals and pesticides in raw wastewater effluents, small creeks, large fast-flowing rivers, open-water lakes, and under ice at near-zero water temperatures. Concentrations measured by o-DGT were more accurate than POCIS when compared to grab samples, likely resulting from the influence in-situ conditions have on POCIS. Modelled sampling rates were successfully used to estimate semi-quantitative water concentrations of suspect wastewater contaminants using high-resolution mass spectrometry, demonstrating the unique utility of this o-DGT technique. This dissertation establishes o-DGT as a more accurate, user-friendly, and widely applicable passive sampler compared to current-use polar-PSDs. The o-DGT tool will help facilitate more accurate and efficient monitoring efforts and ultimately lead to more appropriate exposure data and environmental risk assessment.

Download or read book New Applications and Emerging Contaminants written by Steven G. O'Connell and published by . This book was released on 2014 with total page 156 pages. Available in PDF, EPUB and Kindle. Book excerpt: Passive sampling is a popular technology for environmental monitoring, and silicone is an ideal choice for a variety of passive sampling applications. The silicone work described here encompasses laboratory and field studies that demonstrate the use of this polymer in novel environments, for new applications, and for emerging compounds. Unique attributes of silicone polymers make them advantageous for targeting semi-polar contaminants not typically targeted in environmental research. Oxygenated polycyclic hydrocarbons (OPAHs) represent an emerging class of contaminants with chemical properties well suited to silicone passive sampling. The first challenge was to create a robust OPAH analytical method to examine these compounds in silicone, and two independent methods (liquid as well as gas chromatography) were optimized and demonstrated for 24 ketone-containing aromatic hydrocarbons, more than other methods published at that time. An isotopically labeled OPAH was used as an internal standard in contrast to previous methods which used only labeled polycyclic aromatic hydrocarbons (PAHs). The efficacy of each method was further demonstrated by comparing standard addition to internal standard quantitation. Next, OPAHs, PAHs and pesticides were used to compare several silicone materials with low density polyethylene (LDPE) at Portland Harbor Superfund field sites. Target analyte detection, precision, and practical considerations in the field and laboratory were used to evaluate silicone materials. Individual differences between LDPE and the most optimal silicone polymer for OPAHs highlighted the importance of using optimized methods or polymer choice for a particular analyte class. Biggest differences were found for 9-fluorenone, benzanthrone, and 5,12-naphtacenequinone. After this successful polymer comparison, the next study involved a novel application of silicone wristbands as personal passive samplers. Commercially available silicone was modified to serve as personal samplers and tested in both an ambient and occupational settings. Silicone wristbands provided a valuable tool to monitor individual exposures that were time weighted averages of personalized exposure. The ambient study captured 49 individual compounds including PAHs, personal and consumer products, pesticides, phthalates, and as well as other industrial compounds. In the occupational study, roofers working with hot asphalt wore silicone samplers and evidence of both temporal (day versus week deployment, p

Download or read book Monitoring for Gaseous Pollutants in Museum Environments written by Cecily M. Grzywacz and published by Getty Publications. This book was released on 2006-09-01 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt: With an emphasis on passive sampling, this volume focuses on the environmental monitoring for common gaseous pollutants. It offers an overview of the history and nature of pollutants of concern to museums and the challenges facing scientists, conservators, and managers seeking to develop target pollutant guidelines to protect cultural property.

Download or read book Evaluation of Passive Samplers for Long term Monitoring of Organic Compounds in the Untreated Drinking Water Supply for the City of Eugene Oregon September October 2007 written by and published by . This book was released on 2009 with total page 20 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Advancing Passive Sampling for Monitoring Organic Contaminants in the Aquatic Environment written by Yoonah Jeong and published by . This book was released on 2018* with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Guidelines for Passive Sampling of Hydrophobic Contaminants in Water Using Silicone Rubber Samplers written by Foppe Smedes and published by . This book was released on 2012 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Ecological Risk Assessment written by Glenn W. Suter II and published by CRC Press. This book was released on 1992-10-23 with total page 564 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recently, environmental scientists have been required to perform a new type of assessment-ecological risk assessment. This is the first book that explains how to perform ecological risk assessments and gives assessors access to the full range of useful data, models, and conceptual approaches they need to perform an accurate assessment. It explains how ecological risk assessment relates to more familiar types of assessments. It also shows how to organize and conduct an ecological risk assessment, including defining the source, selecting endpoints, describing the relevant features of the receiving environment, estimating exposure, estimating effects, characterizing the risks, and interacting with the risk manager. Specific technical topics include finding and selecting toxicity data; statistical and mathematical models of effects on organisms, populations, and ecosystems; estimation of chemical fate parameters; modeling of chemical transport and fate; estimation of chemical uptake by organisms; and estimation, propagation, and presentation of uncertainty. Ecological Risk Assessment also covers conventional risk assessments, risk assessments for existing contamination, large scale problems, exotic organisms, and risk assessments based on environmental monitoring. Environmental assessors at regulatory agencies, consulting firms, industry, and government labs need this book for its approaches and methods for ecological risk assessment. Professors in ecology and other environmental sciences will find the book's practical preparation useful for classroom instruction. Environmental toxicologists and chemists will appreciate the discussion of the utility for risk assessment of particular toxicity tests and chemical determinations.

Download or read book Bioanalytical Tools in Water Quality Assessment written by Beate Escher and published by IWA Publishing. This book was released on 2011-12-15 with total page 273 pages. Available in PDF, EPUB and Kindle. Book excerpt: Part of Water Quality Set - Buy all four books and save over 30% on buying separately! Bioanalytical Tools in Water Quality Assessment reviews the application of bioanalytical tools to the assessment of water quality including surveillance monitoring. The types of water included range from wastewater to drinking water, including recycled water, as well as treatment processes and advanced water treatment. Bioanalytical Tools in Water Quality Assessment not only demonstrates applications but also fills in the background knowledge in toxicology/ecotoxicology needed to appreciate these applications. Each chapter summarises fundamental material in a targeted way so that information can be applied to better understand the use of bioanalytical tools in water quality assessment. Bioanalytical tools in Water Quality Assessment can be used by lecturers teaching academic and professional courses and also by risk assessors, regulators, experts, consultants, researchers and managers working in the water sector. It can also be a reference manual for environmental engineers, analytical chemists, and toxicologists. Authors: Beate Escher, National Research Centre for Environmental Toxicology (EnTox), The University of Queensland, Australia, Frederic Leusch, Smart Water Research Facility (G51), Griffith University Gold Coast Campus, Australia. With contributions by Heather Chapman and Anita Poulsen

Download or read book Implementation of Passive Samplers for Monitoring Volatile Organic Compounds in Ground Water at the Kansas City Plant written by and published by . This book was released on 1998 with total page 23 pages. Available in PDF, EPUB and Kindle. Book excerpt: Passive sampling for monitoring volatile organic compounds (VOCs) has been suggested as a possible replacement to the traditional bailer method used at the Department of Energy Kansas City Plant (KCP) for routine groundwater monitoring. To compare methods, groundwater samples were collected from 19 KCP wells with VOC concentrations ranging from non-detectable to> 100,000 [mu]g/L. Analysis of the data was conducted using means and medians of multiple measurements of TCE, 1,2-DCE, 1,1-DCE and VC. All 95% confidence intervals of these VOCs overlap, providing evidence that the two methods are similar. The study also suggests that elimination of purging and decontamination of sampling equipment reduces the labor required to sample by approximately 32%. Also, because the passive method generates no waste water, there are no associated disposal costs. The results suggest evidence to continue studies and efforts to replace traditional bailer methods with passive sampling at KCP based on cost and the similarity of the methods.

Download or read book Species Sensitivity Distributions in Ecotoxicology written by Leo Posthuma and published by CRC Press. This book was released on 2001-12-20 with total page 617 pages. Available in PDF, EPUB and Kindle. Book excerpt: In spite of the growing importance of Species Sensitivity Distribution models (SSDs) in ecological risk assessments, the conceptual basis, strengths, and weaknesses of using them have not been comprehensively reviewed. This book fills that need. Written by a panel of international experts, Species Sensitivity Distributions in Ecotoxicology reviews

Download or read book Microbial Degradation of Xenobiotics written by Shree Nath Singh and published by Springer Science & Business Media. This book was released on 2011-10-07 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt: Our interest in the microbial biodegradation of xenobiotics has increased many folds in recent years to find out sustainable ways for environmental cleanup. Bioremediation and biotransformation processes harness the naturally occurring ability of microbes to degrade, transform or accumulate a wide range of organic pollutants. Major methodological breakthroughs in recent years through detailed genomic, metagenomic, proteomic, bioinformatic and other high-throughput analyses of environmentally relevant microorganisms have provided us unprecedented insights into key biodegradative pathways and the ability of organisms to adapt to changing environmental conditions. The degradation of a wide spectrum of organic pollutants and wastes discharged into the environment by anthropogenic activities is an emerging need today to promote sustainable development of our society with low environmental impact. Microbial processes play a major role in the removal of recalcitrant compounds taking advantage of the astonishing catabolic versatility of microorganisms to degrade or transform such compounds. New breakthroughs in sequencing, genomics, proteomics, bioinformatics and imaging are generating vital information which opens a new era providing new insights of metabolic and regulatory networks, as well as clues to the evolution of degradation pathways and to the molecular adaptation strategies to changing environmental conditions. Functional genomic and metagenomic approaches are increasing our understanding of the relative importance of different pathways and regulatory networks to carbon flux in particular environments and for particular compounds. New approaches will certainly accelerate the development of bioremediation technologies and biotransformation processes in coming years for natural attenuation of contaminated environments