Download or read book Electrochemical Reactions and Mechanisms in Organic Chemistry written by J. Grimshaw and published by Elsevier. This book was released on 2000-12-01 with total page 415 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemical reactions make significant contributions to organic synthesis either in the laboratory or on an industrial scale. These methods have the potential for developing more "green" chemical synthesis. Over recent years, modern investigations have clarified the mechanisms of important organic electrochemical reactions. Progress has also been made in controlling the reactivity of intermediates through either radical or ionic pathways. Now is the time to gather all the electrochemical work into a textbook. As an essential addition to the armory of synthetic organic chemists, electrochemical reactions give results not easily achieved by many other chemical routes. This book presents a logical development of reactions and mechanisms in organic electrochemistry at a level suited to research scientists and final year graduate students. It forms an excellent starting point from which synthetic organic chemists, in both academia and industry, can appreciate uses for electrochemical methods in their own work. The book is also a reference guide to the literature.

Download or read book The Investigation of Organic Reactions and Their Mechanisms written by Howard Maskill and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: A range of alternative mechanisms can usually be postulated for most organic chemical reactions, and identification of the most likely requires detailed investigation. Investigation of Organic Reactions and their Mechanisms will serve as a guide for the trained chemist who needs to characterise an organic chemical reaction and investigate its mechanism, but who is not an expert in physical organic chemistry. Such an investigation will lead to an understanding of which bonds are broken, which are made, and the order in which these processes happen. This information and knowledge of the associated kinetic and thermodynamic parameters are central to the development of safe, efficient, and profitable industrial chemical processes, and to extending the synthetic utility of new chemical reactions in chemical and pharmaceutical manufacturing, and academic environments. Written as a coherent account of the principal methods currently used in mechanistic investigations, at a level accessible to academic researchers and graduate chemists in industry, the book is highly practical in approach. The contributing authors, an international group of expert practitioners of the techniques covered, illustrate their contributions by examples from their own research and from the relevant wider chemical literature. The book covers basic aspects such as product analysis, kinetics, catalysis, and investigation of reactive intermediates. It also includes material on significant recent developments, e.g. computational chemistry, calorimetry, and electrochemistry, in addition to topics of high current industrial relevance, e.g. reactions in multiphase systems, and synthetically useful reactions involving free radicals and catalysis by organometallic compounds.

Download or read book Fundamentals and Applications of Organic Electrochemistry written by Toshio Fuchigami and published by John Wiley & Sons. This book was released on 2014-11-10 with total page 238 pages. Available in PDF, EPUB and Kindle. Book excerpt: This textbook is an accessible overview of the broad field of organic electrochemistry, covering the fundamentals and applications of contemporary organic electrochemistry. The book begins with an introduction to the fundamental aspects of electrode electron transfer and methods for the electrochemical measurement of organic molecules. It then goes on to discuss organic electrosynthesis of molecules and macromolecules, including detailed experimental information for the electrochemical synthesis of organic compounds and conducting polymers. Later chapters highlight new methodology for organic electrochemical synthesis, for example electrolysis in ionic liquids, the application to organic electronic devices such as solar cells and LEDs, and examples of commercialized organic electrode processes. Appendices present useful supplementary information including experimental examples of organic electrosynthesis, and tables of physical data (redox potentials of various organic solvents and organic compounds and physical properties of various organic solvents).

Download or read book The Mechanisms of the Electrochemical Reactions of Simple Organic Compounds in Aqueous Solutions written by S. B. Brummer and published by . This book was released on 1970 with total page 25 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research to further the understanding of the anode of a hydrocarbon fuel cell is reported. Studies of simple organic reactions, e.g., the reduction of CO2, the oxidation of HCOOH, and the effects of adsorbed layers on their reactions in acid solutions are reported. Methods of determining the properties of adsorbate layers are experimentally and theoretically explored. Methods to allow determination of double layer charging effects and electrode oxidation corrections are developed. Studies of the Pt electrocatalytic surface show it to be markedly heterogeneous. Studies of the formation of 'reduced CO2', the main intermediate in hydrocarbon oxidation, have been carried out. The mechanism of HCOOH oxidation has been explored. It has been shown that the product of a side reaction blocks the electrode and inhibits the desired reaction. The electroactive species is apparently HCOO( - ). The effects of adsorbed inorganic layers on HCOOH oxidation have been studied with a view to developing a non-noble metal catalyst stabilized by adsorption. Experiments with Cu, Ag, Pb, Hg, S, and Cl( - ) are reported. The most reactive layers are Pb, Hg, and S. (Author).

Download or read book Organic Redox Chemistry written by Jun-Ichi Yoshida and published by John Wiley & Sons. This book was released on 2022-03-07 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Redox Chemistry Explore the most recent advancements and synthesis applications in redox chemistry Redox chemistry has emerged as a crucial research topic in synthetic method development. In Organic Redox Chemistry: Chemical, Photochemical and Electrochemical Syntheses, some key researchers in this field, including editors Dr. Frédéric W. Patureau and the late Dr. Jun-Ichi Yoshida, deliver an insightful exploration of this rapidly developing topic. This book highlights electron transfer processes in synthesis by using different techniques to initiate them, allowing for a multi-directional perspective in organic redox chemistry. Covering a wide array of the important and recent developments in the field, Organic Redox Chemistry will earn a place in the libraries of chemists seeking a one-stop resource that compares chemical, photochemical, and electrochemical methods in organic synthesis.

Download or read book Progress in Electrochemistry of Organic Compounds 1 written by A. N. Frumkin and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 442 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the Soviet Union, investigations of electrochemical changes in organic substances are being conducted on a comparatively large scale and a large number of specialists are involved. This arises to a large extent from the necessity to solve problems in the applied fields, e.g. in the development of new improved methods for the analysis and synthesis of organic compounds or in the work on fuel cells. The attainment of substantial successes in this field has been linked inseparably with a deeper understanding of the mechanism and kinetics of electrolytic organic reactions and the utilization of modem research methods based on the latest achievements in instrumentation. The theory of organic electrode processes is therefore now developing rapidly. However, the propagation of information on this work has been relatively slow. The Series of reports on Progress in Electrochemistry of Organic Compounds should stimulate systematic treatment and propagation of information in this field of science. It is proposed that each volume of the series will be compiled on the same lines as the book Advances in Electrochemistry of Organic Compounds published by Nauka in 1966. They will form collections of original review articles on the most important aspects of the subject, prepared by competent authorities.

Download or read book Electroorganic Chemistry as a New Tool in Organic Synthesis written by Tatsuya Shono and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: Although the first electroorganic reaction used in organic synthesis is probably the famous Kolbe electrolysis published in 1849, no other remarkable reactions have been found until the reductive dimerization of acrylonitrile to adipo nitrile was developed by Dr. M. M. Baizer of Monsanto Co. in 1964. Since then, the electro organic chemistry has been studied extensively with the expectation that it is a new useful tool for finding novel reactions in organic synthesis. The purpose of this book is not to give a comprehensive survey of studies on electrochemical reactions of organic compounds but to show that the electro organic chemistry is indeed useful in organic synthesis. Thus, this book has been written under the following policies. (1) Since this monograph is mainly concerned with organic synthesis, only few studies carried out from the view point of electrochemical, theoretical, or analytical chemistry are mentioned. (2) Since electroorganic chemistry covers a great variety of reactions, the types of reactions described in this book are selected mainly with regard to their application in organic synthesis. Simple transformations of functional groups are only described in particular cases, and also some well established processes such as the Kolbe electrolysis, pinacolic coupling, and hydrodimerization are only briefly mentioned. (3) Since many reports have already been published for each type of these reactions, only a limited number of the relevant papers are cited in this book.

Download or read book Handbook of Electrochemistry written by Cynthia G. Zoski and published by Elsevier. This book was released on 2007-02-07 with total page 935 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)

Download or read book Electrochemistry in Organic Synthesis written by Jiri Volke and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 161 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book has been written as an introduction to the electro synthesis of organic compounds, in particular for organic chemists. Both authors assume that the knowledge of electro chemistry of these specialists is rather poor and is usually based only on the remnants of the teaching in the courses on physical and analytical chemistry during their university stud ies. Even with Czech chemists one cannot expect - as it was in the past - the experience obtained in the courses on polaro graphy. This is the reason why it was deemed necessary to write an introductory text to the electro synthesis of organics both as regards the theoretical and the methodological point of view, i. e. the fundamentals, the experimental setup, the application of various working and reference electrodes, the shape and con struction of electrolysis cells, the use of suitable pro tic and aprotic solvents, the experience obtained with various sup porting electrolytes, the separation and isolation of products, as well as the use of inert gases which prevent the interaction of intermediates and of final products with, for example, oxygen or traces of water. - The second part of the book contains a systematic description of preparative organic electrochemical processes, the interpretation of their mechanisms and several prescriptions for synthesizing characteristical groups of com pounds. As a whole the book is not written in an exhaustive way.

Download or read book Electrochemical Reactions and Mechanisms of Organic and Organometallic Compounds in Aprotic Solvents written by Duane Keith Root and published by . This book was released on 1980 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Organic Electrochemistry written by Ole Hammerich and published by CRC Press. This book was released on 2015-09-22 with total page 1706 pages. Available in PDF, EPUB and Kindle. Book excerpt: Praise for the Fourth Edition"Outstanding praise for previous editions.the single best general reference for the organic chemist."-Journal of the Electrochemical Society"The cast of editors and authors is excellent, the text is, in general, easily readable and understandable, well documented, and well indexed those who purchase the book will be sa

Download or read book Trends in Molecular Electrochemistry written by Armando J.L. Pombeiro and published by CRC Press. This book was released on 2004-09-13 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemists increasingly apply electrochemical methods to the investigation of their systems, in particular towards a better understanding of molecular properties, the exploration of chemical reactions involving electron-transfer (ET), the initiation of further reactions by ET, the kinetic measurements, and the establishment of the reaction mechanisms

Download or read book Anodic Oxidation written by Sidney D. Ross and published by Elsevier. This book was released on 2013-10-22 with total page 353 pages. Available in PDF, EPUB and Kindle. Book excerpt: Anodic Oxidation covers the application of the concept, principles, and methods of electrochemistry to organic reactions. This book is composed of two parts encompassing 12 chapters that consider the mechanism of anodic oxidation. Part I surveys the theory and methods of electrochemistry as applied to organic reactions. These parts also present the mathematical equations to describe the kinetics of electrode reactions using both polarographic and steady-state conditions. Part II examines the anodic oxidation of organic substrates by the functional group initially attacked. This part particularly emphasizes the kinds of intermediates generated and the mechanisms leading to final products. This book is intended primarily to organic chemists and physical electrochemists.

Download or read book Basics of Electroorganic Synthesis written by Demetrios K. Kyriacou and published by John Wiley & Sons. This book was released on 1981 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Organic Electrochemistry written by Manuel M. Baizer and published by . This book was released on 1983 with total page 1192 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book CO2 as a Building Block in Organic Synthesis written by Shoubhik Das and published by John Wiley & Sons. This book was released on 2020-09-16 with total page 623 pages. Available in PDF, EPUB and Kindle. Book excerpt: A guide to the fascinating application of CO2 as a building block in organic synthesis This important book explores modern organic synthesis’ use of the cheap, non-toxic and abundant chemical CO2as an attractive C1 building block. With contributions from an international panel of experts, CO2 as a Building Block in Organic Synthesis offers a review of the most important reactions which use CO2 as a building block in organic synthesis. The contributors examine a wide-range of CO2 reactions including methylation reactions, CH bond functionalization, carboxylation, cyclic carbonate synthesis, multicomponent reactions, and many more. The book reviews the most recent developments in the field and also: Presents the most important reactions like CH-bond functionalization, carboxylation, carbonate synthesis and many more Contains contributions from an international panel of experts Offers a comprehensive resource for academics and professionals in the field Written for organic chemists, chemists working with or on organometallics, catalytic chemists, pharmaceutical chemists, and chemists in industry, CO2 as Building Block in Organic Synthesis contains an analysis of the most important reactions which use CO2 as an effective building block in organic synthesis.

Download or read book Electrochemical Reactions in Nonaqueous Systems written by Charles Kenneth Mann and published by . This book was released on 1970 with total page 584 pages. Available in PDF, EPUB and Kindle. Book excerpt: