Download or read book Sunscreens written by Nadim Shaath and published by CRC Press. This book was released on 2005-03-17 with total page 976 pages. Available in PDF, EPUB and Kindle. Book excerpt: The increasing number of individuals affected by sun damage has inspired cosmetic chemists to research new vehicles for improved protection against UVA and UVB rays. This volume collects the latest research and perspectives on sunscreen development, assessment, formulation, and quality control from leading authorities in academia, industry, and the regulatory and medical communities-describing the evolution, chemistry, evaluation, and regulation of sunscreens in the 21st century for improved skin protection.
Download or read book Deuterium and Shift Calculation written by U Fleischer and published by . This book was released on 1990-12-19 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Deuterium and Shift Calculation written by and published by Springer. This book was released on 1990-12-19 with total page 263 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1931 Vrey, Brickwedde, and Murphy discovered the hydrogen isotope deuterium. The isotopic enrichment was found to arise from the fact that the electrolysis oflight water is faster than of heavy water [1,2]. This success showed that although different isotopes of an element behave identically from a chemical standpoint the different isotopic masses nevertheless lead to both isotope effects on equilibrium as well as on rate constants of chemical reactions. Soon, ratios of equilibrium constants of isotopic reactions were called "equilibrium isotope effects" (EIE), ratios of isotopic rate constants "kinetic isotope effects" (KIE). Isotope effects have been found to be especially large for those elements which are directly involved in bond breaking and bond formation during the reaction studied [3]. Such effects are, therefore, referred to as "primary". Isotopic substitution in atomic sites which maintain all chemical bonds with their neighbors during the reaction of interest leads then only to smaller "secondary" isotope effects. Because of the unique mass relation between the different hydrogen isotopes hydrogen/deuterium isotope effects are particularly large and have attracted most attention. The largest contributions to these effects arise from changes in the vibrational frequencies of the reactants. The theory of equilibrium isotope effects has been founded by Vrey [4] and Bigeleisen [5,6] and has widely been accepted [3].