Download or read book Coupled Multicomponent NAPL Dissolution and Transport in the Subsurface Analytic Solutions and Forensic Aspects written by Scott Kalev Hansen and published by . This book was released on 2012 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dissolving multicomponent NAPL as a source of contamination in subsurface water is considered. In particular, two processes are analyzed with regard to how they alter inter-species concentration ratios at remote monitoring locations relative to inter-species molar ratios in the NAPL: nonlinear dissolution governed by Raoult's Law and differential sorption during subsurface transport. An analytic solution for Raoult's Law-governed dissolution is presented. Separately, it is shown how a variety of 1D analytic transport models for simple boundary conditions may be adapted to use arbitrary time-varying concentrations by use of some properties of Laguerre series. This is combined with the analytic solution so that Raoult's Law-governed multicomponent NAPL dissolution may be employed as the boundary condition for analytic transport models. A new computer model implementing this technique in an environment of discrete, parallel fractures is presented, and its accuracy verified for specific conditions against an existing code. The new code is applied to a parametric study on the plume separation of PAH and phenolic compounds from the dissolution of creosote. Narrow fracture spacing as well as significant values of matrix organic carbon are seen as particularly conducive to separation of these types of plumes, which in some circumstances may be entirely disjoint. Concentration ratios downgradient are shown largely unrelated to concentration ratios at the source. Finally, a study of PCB speciation is undertaken in fractured rock with known parameters, for which a rigorous, least squares speciation approach is developed. Even at distances of 5 m from the source, given perfect information about the subsurface, it is found not possible to chemically fingerprint a source PCB mixture from a list of three absent a model of the weathering of the NAPL. Both the PCB and creosote studies demonstrate that forensic inference of source compositions from field data is unreliable and the need for coupled dissolution and transport models like the one developed here.
Download or read book Applications of Environmental Aquatic Chemistry written by Eugene R. Weiner and published by CRC Press. This book was released on 2012-12-07 with total page 625 pages. Available in PDF, EPUB and Kindle. Book excerpt: Professionals and students who come from disciplines other than chemistry need a concise yet reliable guide that explains key concepts in environmental chemistry, from the fundamental science to the necessary calculations for applying them. Updated and reorganized, Applications of Environmental Aquatic Chemistry: A Practical Guide, Third Edition provides the essential background for understanding and solving the most frequent environmental chemistry problems. Diverse and self-contained chapters offer a centralized and easily navigable framework for finding useful data tables that are ordinarily scattered throughout the literature. Worked examples provide step-by-step details for frequently used calculations, drawing on case histories from real-world environmental applications. Chapters also offer tools for calculating quick estimates of important quantities and practice problems that apply the principles to different conditions. This practical guide provides an ideal basis for self-study, as well as short courses involving the movement and fate of contaminants in the environment. In addition to extensive reorganization and updating, the Third Edition includes a new chapter, Nutrients and Odors: Nitrogen, Phosphorus, and Sulfur, two new appendices, Solubility of Slightly Soluble Metal Salts and Glossary of Acronyms and Abbreviations Used in this Book, and new material and case studies on remediation, stormwater management, algae growth and treatment, odor control, and radioisotopes.
Download or read book Natural Attenuation of Fuels and Chlorinated Solvents in the Subsurface written by Todd H. Wiedemeier and published by John Wiley & Sons. This book was released on 1999-03-08 with total page 634 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first comprehensive guide to one of today's most innovative approaches to environmental contamination Natural attenuation is gaining increasing attention as a nonintrusive, cost-effective alternative to standard remediation techniques for environmental contamination. This landmark work presents the first in-depth examination of the theory, mechanisms, and application of natural attenuation. Written by four internationally recognized leaders in this approach, the book describes both biotic and abiotic natural attenuation processes, focusing on two of the environmental contaminants most frequently encountered in groundwater--fuels and chlorinated solvents. The authors draw on a wealth of combined experience to detail successful techniques for simulating natural attenuation processes and predicting their effectiveness in the field. They also show how natural attenuation works in the real world, using numerous examples and case studies from a wide range of leading-edge projects nationwide involving fuel hydrocarbons and chlorinated solvents. Finally, they discuss the evaluation and assessment of natural attenuation and explore the design of long-term monitoring programs. An indispensable reference for anyone working in environmental remediation, Natural Attenuation of Fuels and Chlorinated Solvents in the Subsurface is essential reading for scientists and engineers in a range of industries, as well as state and federal environmental regulators, and professors and graduate students in environmental or chemical engineering.
Download or read book Transformations of Halogenated Hydrocarbons written by N. Lee Wolfe and published by . This book was released on 1990 with total page 12 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Remediation Engineering written by Suthan S. Suthersan and published by CRC Press. This book was released on 2016-11-25 with total page 628 pages. Available in PDF, EPUB and Kindle. Book excerpt: "This second edition of Remediation Engineering will continue to be the seminal handbook that regulators must have on-hand to address any of the remediation issues they are grappling with daily. The book is wide-ranging, but specific enough to address any environmental remediation challenge." —Patricia Reyes, Interstate Technology Regulatory Council, Washington, DC, USA "This book offers the researcher, teacher, practitioner, student, and regulator with state-of-the-art advances in conducting site investigations and remediation for common and emerging contaminants. It is revolutionary in its approach to conducting subsurface investigation, which greatly influences a successful and appropriate response in assessing and addressing environmental risk. This book is a giant leap forward in understanding how contaminates behave and how to reduce risk to acceptable levels in the natural world." —Daniel T. Rogers, Amsted Industries Incorporated, Chicago, Illinois, USA "This text is a superb reference and a good tool for learning about state-of-the-art techniques in remediation of soil and groundwater. [It] will become a ready reference at many companies as the engineering community creates increased value from remediation efforts around the world." —John Waites, AVX Corporation, Fountain Inn, South Carolina, USA Remediation Engineering was first published in 1996 and quickly became the go-to reference for a relatively young industry, offering the first comprehensive look at the state-of-the-science in treatment technologies of the time and the contaminants they applied to. This fully updated Second Edition will capture the fundamental advancements that have taken place during the last two decades within all the subdisciplines that form the foundation of the remediation engineering platform. It covers the entire spectrum of current technologies that are employed in the industry and also discusses future trends and how practitioners should anticipate and adapt to those needs. Features: Shares the latest paradigms in remediation design approach and contaminant hydrogeology Presents the landscape of new and emerging contaminants Details the current state of the practice for both conventional technologies, such as sparging and venting Examines newer technologies such as dynamic groundwater recirculation and injection-based remedies to address both organic and inorganic contaminants. Describes the advances in site characterization concepts such as smart investigations and digital conceptual site models. Includes all-new color photographs and figures.
Download or read book Advances in Porous Media written by M.Y. Corapcioglu and published by Elsevier. This book was released on 1996-12-06 with total page 455 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Porous Media, Volume 3 presents in-depth review papers that give a comprehensive coverage of the field of transport in porous media. This is the third volume in the series which treats transport phenomena in porous media as an interdisciplinary topic. The objective of each chapter is to review the work done on a specific topic including theoretical, numerical as well as experimental studies. All contributors are from a variety of backgrounds, such as civil and environmental engineering, earth and environmental sciences. The articles are aimed at scientists and engineers from various fields who are concerned with the fundamentals and applications of processes in porous media. Advances in Porous Media, Volume 3 is a valuable source of information for both researchers in the field and those working in other related disciplines.
Download or read book Oil Spill Environmental Forensics written by Zhendi Wang and published by Elsevier. This book was released on 2010-07-26 with total page 617 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oil Spill Environmental Forensics provides a complete view of the various forensic techniques used to identify the source of an oil spill into the environment. The forensic procedures described within represent various methods from scientists throughout the world. The authors explore which analytical and interpretative techniques are best suited for a particular oil spill project. This handy reference also explores the use of these techniques in actual environmental oil spills. Famous incidents discussed include the Exxon Valdez incident in 1989 and the Guanabara Bay, Brazil 2000. The authors chronicle both the successes and failures of the techniques used for each of these events. Dr. Zhendi Wang is a senior research scientist and Head of Oil Spill Research of Environment Canada, working in the oil and toxic chemical spill research field. He has authored over 270 academic publications and won a number of national and international scientific honors and awards. Dr. Wang is a member of American Chemical Society (ACS), the Canadian Society for Chemistry (CSC), and the International Society of Environmental Forensics (ISEF). International experts show readers the forensic techniques used in oil spill investigations Provides the theoretical basis and practical applications for investigative techniques Contains numerous case studies demonstrating proven technique
Download or read book Analytical Chemistry for Cultural Heritage written by Rocco Mazzeo and published by Springer. This book was released on 2017-01-25 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience.Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
Download or read book Contaminant Geochemistry written by Brian Berkowitz and published by Springer Science & Business. This book was released on 2014-04-22 with total page 582 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this updated and expanded second edition, new literature has been added on contaminant fate in the soil-subsurface environment. In particular, more data on the behavior of inorganic contaminants and on engineered nanomaterials were included, the latter comprising a group of “emerging contaminants” that may reach the soil and subsurface zones. New chapters are devoted to a new perspective of contaminant geochemistry, namely irreversible changes in pristine land and subsurface systems following chemical contamination. Two chapters were added on this topic, focusing attention on the impact of chemical contaminants on the matrix and properties of both liquid and solid phases of soil and subsurface domains. Contaminant impacts on irreversible changes occurring in groundwater are discussed and their irreversible changes on the porous medium solid phase are surveyed. In contrast to the geological time scale controlling natural changes of porous media liquid and solid phases, the time scale associated with chemical pollutant induced changes is far shorter and extends over a “human lifetime scale”.
Download or read book Chlorinated Solvent Source Zone Remediation written by Bernard H. Kueper and published by Springer Science & Business. This book was released on 2014-04-22 with total page 759 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this book is to help engineers and scientists better understand dense nonaqueous phase liquid (DNAPL) contamination of groundwater and the methods and technology used for characterization and remediation. Remediation of DNAPL source zones is very difficult and controversial and must be based on state-of-the-art knowledge of the behavior (transport and fate) of nonaqueous phase liquids in the subsurface and site specific geology, chemistry and hydrology. This volume is focused on the characterization and remediation of nonaqueous phase chlorinated solvents and it is hoped that mid-level engineers and scientists will find this book helpful in understanding the current state-of-practice of DNAPL source zone management and remediation.
Download or read book Chlorinated Solvents written by Robert D Morrison and published by Royal Society of Chemistry. This book was released on 2015-11-09 with total page 437 pages. Available in PDF, EPUB and Kindle. Book excerpt: Environmental forensics is emerging and evolving into a recognized scientific discipline with numerous applications, especially regarding chlorinated solvents. This unique book provides the reader with a concise compilation of information regarding the use of environmental forensic techniques for age dating and identification of the source of a chlorinated solvent release. Concentrating on the five commonly encountered chlorinated solvents (perchloroethylene, trichloroethylene, methyl chloroform, carbon tetrachloride and CFC-113), forensic opportunities applicable to each are presented including the use of stabilizers, manufacturing impurities, surrogate chemicals and physical measurements and degradation products as diagnostic indicators. Detailed historical chronology of the applications of the solvents and specific chapters devoted to dry cleaning and vapor degreasing equipment are included as are generic forensic approaches. Forming a basis for further ideas in the evolution of environmental forensic techniques, Chlorinated Solvents will be an indispensable reference tool for researchers, regulators and analysts in the field.
Download or read book Environmental Soil Remediation and Rehabilitation written by Eric D. van Hullebusch and published by Springer Nature. This book was released on 2020-04-22 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive overview of innovative remediation techniques and strategies for soils contaminated by heavy metals or organic compounds (e.g. petroleum hydrocarbons, NAPLs and chlorinated organic compounds). It discusses various novel chemical remediation approaches (in-situ and ex-situ) used alone and in combination with physical and/or thermal treatment. Further, it addresses the recovery of NAPLs, reuse of leaching solutions, and in-situ chemical reduction and oxidation, and explores the chemical enhancement of physical NAPLs recovery from both practical and theoretical perspectives. Also presenting the state-of-the-art in waste-assisted bioremediation to improve soil quality and the remediation of petroleum hydrocarbons, the book is a valuable resource for students, researchers and R&D professionals in industry engaged in the treatment of contaminated soils.
Download or read book Handbook of Chemical Mass Transport in the Environment written by Louis J. Thibodeaux and published by CRC Press. This book was released on 2010-10-21 with total page 631 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive account of the state of the science of environmental mass transportEdited by Louis J. Thibodeaux and Donald Mackay, renowned experts in this field, the Handbook of Chemical Mass Transport in the Environment covers those processes which are critically important for assessing chemical fate, exposure, and risk. In a comprehensive and a
Download or read book Atlas of Plastics Additives written by Dietrich O. Hummel and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 538 pages. Available in PDF, EPUB and Kindle. Book excerpt: A must for experts in industry, this book describes the application of vibrational (FTIR, UV, Raman) and mass spectrometries and other instrumental techniques for identification and structure elucidation of plastics additives. Numerous tables and figures compress the state of the art.
Download or read book Volcanic Unrest written by Joachim Gottsmann and published by Springer. This book was released on 2018-12-18 with total page 313 pages. Available in PDF, EPUB and Kindle. Book excerpt: This open access book summarizes the findings of the VUELCO project, a multi-disciplinary and cross-boundary research funded by the European Commission's 7th framework program. It comprises four broad topics: 1. The global significance of volcanic unrest 2. Geophysical and geochemical fingerprints of unrest and precursory activity 3. Magma dynamics leading to unrest phenomena 4. Bridging the gap between science and decision-making Volcanic unrest is a complex multi-hazard phenomenon. The fact that unrest may, or may not lead to an imminent eruption contributes significant uncertainty to short-term volcanic hazard and risk assessment. Although it is reasonable to assume that all eruptions are associated with precursory activity of some sort, the understanding of the causative links between subsurface processes, resulting unrest signals and imminent eruption is incomplete. When a volcano evolves from dormancy into a phase of unrest, important scientific, political and social questions need to be addressed. This book is aimed at graduate students, researchers of volcanic phenomena, professionals in volcanic hazard and risk assessment, observatory personnel, as well as emergency managers who wish to learn about the complex nature of volcanic unrest and how to utilize new findings to deal with unrest phenomena at scientific and emergency managing levels. This book is open access under a CC BY license.
Download or read book Toxic Chemical and Biological Agents written by Giovanni Sindona and published by Springer Nature. This book was released on 2020-10-19 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book critically assesses the current state of knowledge on new and important detection technologies, e.g. mass spectrometry, tandem mass spectrometry, biosensor detection and tissue imaging, in connection with toxic chemical and biological agents. In general, the main topics discussed concern the risks and consequences of chemical and biological agents for human health in general, with special emphasis on all biochemical and metabolic pathways including the reproductive system. The exposome, genetic risks and the environment, various health hazard agents, risk assessment, environmental assessment and preparedness, and analysis of sub-lethal effects at the molecular level are also discussed. In closing, the book provides comprehensive information on the diagnosis of exposure, and on health concerns related to toxic chemical and biological agents.
Download or read book Science and Technology in Historic Preservation written by Ray A. Williamson and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: Technology transfer has played an increasingly important role in historic preservation during the latter half of the twentieth century, a situation attested to by the undertaking of an important congressional study in 1986 that assessed the role of federal agencies in the field. In this book leading researchers update the earlier findings and contribute state-of-the-art reviews and evaluations of technological progress in their areas of expertise.
