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Book Conversion of Plutonium Containing Materials Into Borosilicate Glass Using the Glass Material Oxidation and Dissolution System

Download or read book Conversion of Plutonium Containing Materials Into Borosilicate Glass Using the Glass Material Oxidation and Dissolution System written by C. W. Forsberg and published by . This book was released on 1996 with total page 37 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Direct Conversion of Plutonium containing Materials to Borosilicate Glass for Storage Or Disposal

Download or read book Direct Conversion of Plutonium containing Materials to Borosilicate Glass for Storage Or Disposal written by and published by . This book was released on 1995 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A new process, the Glass Material Oxidation and Dissolution System (GMODS), has been invented for the direct conversion of plutonium metal, scrap, and residue into borosilicate glass. The glass should be acceptable for either the long-term storage or disposition of plutonium. Conversion of plutonium from complex chemical mixtures and variable geometries into homogeneous glass (1) simplifies safeguards and security; (2) creates a stable chemical form that meets health, safety, and environmental concerns; (3) provides an easy storage form; (4) may lower storage costs; and (5) allows for future disposition options. In the GMODS process, mixtures of metals, ceramics, organics, and amorphous solids containing plutonium are fed directly into a glass melter where they are directly converted to glass. Conventional glass melters can accept materials only in oxide form; thus, it is its ability to accept materials in multiple chemical forms that makes GMODS a unique glass making process. Initial proof-of-principle experiments have converted cerium (plutonium surrogate), uranium, stainless steel, aluminum, and other materials to glass. Significant technical uncertainties remain because of the early nature of process development.

Book Direct Vitrification of Plutonium containing Materials  PCM s  with the Glass Material Oxidation and Dissolution System  GMODS

Download or read book Direct Vitrification of Plutonium containing Materials PCM s with the Glass Material Oxidation and Dissolution System GMODS written by and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The end of the cold war has resulted in excess PCMs from nuclear weapons and associated production facilities. Consequently, the US government has undertaken studies to determine how best to manage and dispose of this excess material. The issues include (a) ensurance of domestic health, environment, and safety in handling, storage, and disposition, (b) international arms control agreements with Russia and other countries, and (c) economics. One major set of options is to convert the PCMs into glass for storage or disposal. The chemically inert characteristics of glasses make them a desirable chemical form for storage or disposal of radioactive materials. A glass may contain only plutonium, or it may contain plutonium along with other radioactive materials and nonradioactive materials. GMODS is a new process for the direct conversion of PCMs (i.e., plutonium metal, scrap, and residues) to glass. The plutonium content of these materials varies from a fraction of a percent to pure plutonium. GMODS has the capability to also convert other metals, ceramics, and amorphous solids to glass, destroy organics, and convert chloride-containing materials into a low-chloride glass and a secondary clean chloride salt strewn. This report is the initial study of GMODS for vitrification of PCMs as input to ongoing studies of plutonium management options. Several tasks were completed: initial analysis of process thermodynamics, initial flowsheet analysis, identification of equipment options, proof-of-principle experiments, and identification of uncertainties.

Book Glass Material Oxidation and Dissolution System

Download or read book Glass Material Oxidation and Dissolution System written by and published by . This book was released on 1996 with total page 10 pages. Available in PDF, EPUB and Kindle. Book excerpt: The cold war and the development of nuclear energy have resulted in significant inventories of miscellaneous fissile materials (MFMs). MFMs include (1) plutonium scrap and residue, (2) miscellaneous spent nuclear fuel (SNF), (3) certain hot cell wastes, and (4) many one-of-a-kind materials. Major concerns associated with the long-term management of these materials include: safeguards and nonproliferation issues; health, environment, and safety concerns. waste management requirements; and high storage costs. These issues can be addressed by converting the MFMs to glass for secure, long-term storage or repository disposal; however, conventional glass-making processes require oxide-like feed materials. Converting MFMs to oxide-like materials with subsequent vitrification is a complex and expensive process. A new vitrification process has been invented, the Glass Material Oxidation and Dissolution System (GMODS), which directly converts metals, ceramics, and amorphous solids to glass; oxidizes organics with the residue converted to glass; and converts chlorides to borosilicate glass and a secondary sodium chloride (NaCl) stream. Laboratory work has demonstrated the conversion of cerium (a plutonium surrogate), uranium, Zircaloy, stainless steel, multiple oxides, and other materials to glass. However, significant work is required to develop GMODS further for applications at an industrial scale. If implemented, GMODS will provide a new approach to manage these materials.

Book Conversion of Plutonium Scrap and Residue to Boroilicate Glass Using the GMODS Process

Download or read book Conversion of Plutonium Scrap and Residue to Boroilicate Glass Using the GMODS Process written by and published by . This book was released on 1995 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt: Plutonium scrap and residue represent major national and international concerns because (1) significant environmental, safety, and health (ES & H) problems have been identified with their storage; (2) all plutonium recovered from the black market in Europe has been from this category; (3) storage costs are high; and (4) safeguards are difficult. It is proposed to address these problems by conversion of plutonium scrap and residue to a CRACHIP (CRiticality, Aerosol, and CHemically Inert Plutonium) glass using the Glass Material Oxidation and Dissolution System (GMODS). CRACHIP refers to a set of requirements for plutonium storage forms that minimize ES & H concerns. The concept is several decades old. Conversion of plutonium from complex chemical mixtures and variable geometries into a certified, qualified, homogeneous CRACHIP glass creates a stable chemical form that minimizes ES & H risks, simplifies safeguards and security, provides an easy-to-store form, decreases storage costs, and allows for future disposition options. GMODS is a new process to directly convert metals, ceramics, and amorphous solids to glass; oxidize organics with the residue converted to glass; and convert chlorides to borosilicate glass and a secondary sodium chloride stream. Laboratory work has demonstrated the conversion of cerium (a plutonium surrogate), uranium (a plutonium surrogate), Zircaloy, stainless steel, and other materials to glass. GMODS is an enabling technology that creates new options. Conventional glassmaking processes require conversion of feeds to oxide-like forms before final conversion to glass. Such chemical conversion and separation processes are often complex and expensive.

Book Direct Vitrification of Plutonium containing Materials  PCMs    with the Glass Material Oxidation and Dissolution System  GMODS

Download or read book Direct Vitrification of Plutonium containing Materials PCMs with the Glass Material Oxidation and Dissolution System GMODS written by and published by . This book was released on 1995 with total page 175 pages. Available in PDF, EPUB and Kindle. Book excerpt: The end of the cold war has resulted in excess PCMs from nuclear weapons and associated production facilities. Consequently, the US government has undertaken studies to determine how best to manage and dispose of this excess material. The issues include (a) ensurance of domestic health, environment, and safety in handling, storage, and disposition, (b) international arms control agreements with Russia and other countries, and (c) economics. One major set of options is to convert the PCMs into glass for storage or disposal. The chemically inert characteristics of glasses make them a desirable chemical form for storage or disposal of radioactive materials. A glass may contain only plutonium, or it may contain plutonium along with other radioactive materials and nonradioactive materials. GMODS is a new process for the direct conversion of PCMs (i.e., plutonium metal, scrap, and residues) to glass. The plutonium content of these materials varies from a fraction of a percent to pure plutonium. GMODS has the capability to also convert other metals, ceramics, and amorphous solids to glass, destroy organics, and convert chloride-containing materials into a low-chloride glass and a secondary clean chloride salt strewn. This report is the initial study of GMODS for vitrification of PCMs as input to ongoing studies of plutonium management options. Several tasks were completed: initial analysis of process thermodynamics, initial flowsheet analysis, identification of equipment options, proof-of-principle experiments, and identification of uncertainties.

Book Radioactive Waste Management

Download or read book Radioactive Waste Management written by and published by . This book was released on 1995-08 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Waste Immobilization in Glass and Ceramic Based Hosts

Download or read book Waste Immobilization in Glass and Ceramic Based Hosts written by Ian W. Donald and published by John Wiley & Sons. This book was released on 2010-04-01 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt: The safe storage in glass-based materials of both radioactiveand non-radioactive hazardous wastes is covered in a single book,making it unique Provides a comprehensive and timely reference source at thiscritical time in waste management, including an extensive andup-to-date bibliography in all areas outlined to waste conversionand related technologies, both radioactive and non-radioactive Brings together all aspects of waste vitrification, drawscomparisons between the different types of wastes and treatments,and outlines where lessons learnt in the radioactive waste fieldcan be of benefit in the treatment of non-radioactive wastes

Book Direct Conversion of Halogen containing Wastes to Borosilicate Glass

Download or read book Direct Conversion of Halogen containing Wastes to Borosilicate Glass written by and published by . This book was released on 1996 with total page 10 pages. Available in PDF, EPUB and Kindle. Book excerpt: Glass has become a preferred waste form worldwide for radioactive wastes: however, there are limitations. Halogen-containing wastes can not be converted to glass because halogens form poor-quality waste glasses. Furthermore, halides in glass melters often form second phases that create operating problems. A new waste vitrification process, the Glass Material Oxidation and dissolution System (GMODS), removes these limitations by converting halogen-containing wastes into borosilicate glass and a secondary, clean, sodium-halide stream.

Book Proceedings of the Embedded Topical Meeting on DOE Spent Nuclear Fuel   Fissile Material Management  Reno  Nevada  June 16 20  1996

Download or read book Proceedings of the Embedded Topical Meeting on DOE Spent Nuclear Fuel Fissile Material Management Reno Nevada June 16 20 1996 written by and published by . This book was released on 1996 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Scientific Basis for Nuclear Waste Management XX  Volume 465

Download or read book Scientific Basis for Nuclear Waste Management XX Volume 465 written by Walter J. Gray and published by . This book was released on 1997-07 with total page 1398 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book features scientific research that supports the safe and effective disposal of radioactive waste in a geological repository. One highlight of the volume is the opening talk by Rustum Roy, who was instrumental in establishing the first symposium on this topic in 1978. Professor Roy summarizes his views of the past 19 years of progress in the field. A second highlight is the participation by several Russian and Ukrainian scientists who authored papers on nuclear waste disposal aspects of the Chernobyl Unit 4 reactor that exploded in April 1986. Additional topics include: glass formulations and properties; glass/water interactions; cements in radioactive waste management; ceramic and crystalline waste forms; spent nuclear fuel; waste processing and treatment; radiation effects in ceramics, glasses and nuclear waste materials; waste package materials; radionuclide solubility and speciation; radionuclide sorption; radionuclide transport; repository backfill; performance assessment; natural analogues and excess plutonium dispositioning.

Book Direct Conversion of Ion exchange Resins and Other Organics to Borosilicate Glass Using the Glass Material Oxidation and Dissolution System

Download or read book Direct Conversion of Ion exchange Resins and Other Organics to Borosilicate Glass Using the Glass Material Oxidation and Dissolution System written by C. W. Forsberg and published by . This book was released on 1996 with total page 11 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Radioactive Waste Management and Contaminated Site Clean Up

Download or read book Radioactive Waste Management and Contaminated Site Clean Up written by William E Lee and published by Elsevier. This book was released on 2013-10-31 with total page 925 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radioactive waste management and contaminated site clean-up reviews radioactive waste management processes, technologies, and international experiences. Part one explores the fundamentals of radioactive waste including sources, characterisation, and processing strategies. International safety standards, risk assessment of radioactive wastes and remediation of contaminated sites and irradiated nuclear fuel management are also reviewed. Part two highlights the current international situation across Africa, Asia, Europe, and North America. The experience in Japan, with a specific chapter on Fukushima, is also covered. Finally, part three explores the clean-up of sites contaminated by weapons programmes including the USA and former USSR.Radioactive waste management and contaminated site clean-up is a comprehensive resource for professionals, researchers, scientists and academics in radioactive waste management, governmental and other regulatory bodies and the nuclear power industry. - Explores the fundamentals of radioactive waste including sources, characterisation, and processing strategies - Reviews international safety standards, risk assessment of radioactive wastes and remediation of contaminated sites and irradiated nuclear fuel management - Highlights the current international situation across Africa, Asia, Europe, and North America specifically including a chapter on the experience in Fukushima, Japan

Book Treatment and Management of Sodium bonded Spent Nuclear Fuel

Download or read book Treatment and Management of Sodium bonded Spent Nuclear Fuel written by and published by . This book was released on 2000 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: