Download or read book Contribution to Performance Characterization and Kinetic Modelling of Micropollutants Abatement in Water and Wastewater by Ozone based Oxidation Processes written by Alberto Cruz Alcalde and published by . This book was released on 2019 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Ozonation is nowadays a competent technology for micropollutant oxidation in wastewater effluents. The combination of ozone with hydroxyl radical formed through ozone decomposition is effective in the abatement of a number of organic compounds. However, there are still some points to be addressed for a more efficient application of ozone-based processes to wastewater treatment and reclamation. There are, for instance, several organic compounds that react very slowly with ozone. They are known as ozone-resistant micropollutants. If a high quality water is wanted to be obtained, these substances should be also removed from the effluent. In addition, modelling the abatement of micropollutants during wastewater ozonation is essential for process simulation, optimization and real-time control. To make this possible, performance characterization in terms of oxidation efficiency is required, as well as some kinetic information regarding the abatement of micropollutants. The first can be addressed by using normalizing parameters allowing the estimation, for instance, of hydroxyl radical availability as a function of the consumed ozone, or any other parameter whose measurement during the process is simple. The most accurate way of obtaining kinetic data of micropollutants oxidation is conducting individual studies on this chemicals degradation by ozone and hydroxyl radicals. Some complementary tests, in addition, may be useful to obtain valuable data regarding the mechanisms of degradation and the potential ecotoxicological effects of formed transformation products. This thesis was divided in two parts: first, individual batch ozonation studies of selected concerning micropollutants were conducted. Particularly, the pesticides methiocarb, acetamiprid and dichlorvos were selected for that work. The second part consisted of the application of single ozonation and the combination O3/H2O2 was tested in the removal of ozone-refractory micropollutants from actual wastewater effluents. The latter was done through semi-batch ozonation experiments. The objectives were, on one hand, obtaining kinetic, mechanistic and toxicological data of some priority/emerging concern chemicals. On the other, ozonation studies with real effluent samples were performed with the aim of exploring the removal of ozone-recalcitrant chemicals and potential strategies for the modelling and real-time control of this process. In addition, improvement strategies for O3/H2O2 process application were investigated. Different kinetics were observed for pesticides reaction with ozone, being acetamiprid the most recalcitrant compound. In addition, toxicity of some of the pesticides transformation products was revealed, especially in the case of methiocarb degradation. Regarding ozone-based processes application to actual wastewater effluents, the removal of model ozone-recalcitrant compounds was found difficult, concluding that ozone doses higher than the immediate ozone demand (IOD) value are required for a more effective abatement of these substances regardless of the process employed. In the case of the O3/H2O2 process application, dosing hydrogen peroxide simultaneously to ozone bubbling was found to potentially entail important energy savings related to oxidants use. The oxidation performance of ozone-based processes and thus the abatement of ozone-refractory compounds could be effectively modelled using kinetic parameters, the monitoring of water quality parameters and empirical relationships obtained for each effluent. Furthermore, side reactions of involved oxidants with effluent organic compounds was found to increase the content in small and oxidized organic compounds in all cases. In the case of effluents containing suspended solids, ozone application also caused a net increase in the dissolved organic load." -- TDX.

Download or read book Experimental Investigation and Kinetic Modelling of Micropollutant Abatement and Byproduct Formation in a Novel UVA ClO2 Advanced Oxidation Process written by Jiadong Peng and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Ozone Reaction Kinetics for Water and Wastewater Systems written by Fernando J. Beltran and published by CRC Press. This book was released on 2003-12-29 with total page 385 pages. Available in PDF, EPUB and Kindle. Book excerpt: Interest in ozonation for drinking water and wastewater treatment has soared in recent years due to ozone's potency as a disinfectant, and the increasing need to control disinfection byproducts that arise from the chlorination of water and wastewater. Ozone Reaction Kinetics for Water and Wastewater Systems is a comprehensive reference that

Download or read book Chemistry of Ozone in Water and Wastewater Treatment written by Clemens von Sonntag and published by IWA Publishing. This book was released on 2012-08-31 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: Even though ozone has been applied for a long time for disinfection and oxidation in water treatment, there is lack of critical information related to transformation of organic compounds. This has become more important in recent years, because there is considerable concern about the formation of potentially harmful degradation products as well as oxidation products from the reaction with the matrix components. In recent years, a wealth of information on the products that are formed has accumulated, and substantial progress in understanding mechanistic details of ozone reactions in aqueous solution has been made. Based on the latter, this may allow us to predict the products of as yet not studied systems and assist in evaluating toxic potentials in case certain classes are known to show such effects. Keeping this in mind, Chemistry of Ozone in Water and Wastewater Treatment: From Basic Principles to Applications discusses mechanistic details of ozone reactions as much as they are known to date and applies them to the large body of studies on micropollutant degradation (such as pharmaceuticals and endocrine disruptors) that is already available. Extensively quoting the literature and updating the available compilation of ozone rate constants gives the reader a text at hand on which his research can be based. Moreover, those that are responsible for planning or operation of ozonation steps in drinking water and wastewater treatment plants will find salient information in a compact form that otherwise is quite disperse. A critical compilation of rate constants for the various classes of compounds is given in each chapter, including all the recent publications. This is a very useful source of information for researchers and practitioners who need kinetic information on emerging contaminants. Furthermore, each chapter contains a large selection of examples of reaction mechanisms for the transformation of micropollutants such as pharmaceuticals, pesticides, fuel additives, solvents, taste and odor compounds, cyanotoxins. Authors: Prof. Dr. Clemens von Sonntag, Max-Planck-Institut für Bioanorganische Chemie, Mülheim an der Ruhr, and Instrumentelle Analytische Chemie, Universität Duisburg-Essen, Essen, Germany and Prof. Dr. Urs von Gunten, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Dübendorf, and Ecole Polytechnique Federal de Lausanne, Lausanne, Switzerland.

Download or read book Advanced Oxidation Processes for Water Treatment written by Mihaela I. Stefan and published by IWA Publishing. This book was released on 2017-09-15 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Oxidation Processes (AOPs) rely on the efficient generation of reactive radical species and are increasingly attractive options for water remediation from a wide variety of organic micropollutants of human health and/or environmental concern. Advanced Oxidation Processes for Water Treatment covers the key advanced oxidation processes developed for chemical contaminant destruction in polluted water sources, some of which have been implemented successfully at water treatment plants around the world. The book is structured in two sections; the first part is dedicated to the most relevant AOPs, whereas the topics covered in the second section include the photochemistry of chemical contaminants in the aquatic environment, advanced water treatment for water reuse, implementation of advanced treatment processes for drinking water production at a state-of-the art water treatment plant in Europe, advanced treatment of municipal and industrial wastewater, and green technologies for water remediation. The advanced oxidation processes discussed in the book cover the following aspects: - Process principles including the most recent scientific findings and interpretation. - Classes of compounds suitable to AOP treatment and examples of reaction mechanisms. - Chemical and photochemical degradation kinetics and modelling. - Water quality impact on process performance and practical considerations on process parameter selection criteria. - Process limitations and byproduct formation and strategies to mitigate any potential adverse effects on the treated water quality. - AOP equipment design and economics considerations. - Research studies and outcomes. - Case studies relevant to process implementation to water treatment. - Commercial applications. - Future research needs. Advanced Oxidation Processes for Water Treatment presents the most recent scientific and technological achievements in process understanding and implementation, and addresses to anyone interested in water remediation, including water industry professionals, consulting engineers, regulators, academics, students. Editor: Mihaela I. Stefan - Trojan Technologies - Canada

Download or read book Advanced Oxidation Processes for Micropollutant Remediation written by Mohammad Khalid and published by CRC Press. This book was released on 2023-08-17 with total page 253 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Oxidation Processes for Micropollutant Remediation covers current state-of-the-art in advanced oxidation processes (AOP) for removal of micropollutants from industrial and pharmaceutical wastewater. It covers various AOP-based techniques like Fenton process, ozonation, hydrogen peroxide, ultraviolet radiation, electrochemical oxidation, ultrasonic irradiation, and other hybrid technologies. It focuses on aspects like impact of micropollutants on the ecosystems, different types of AOPs, their principles, applications, and challenges in implementing these techniques and their future perspectives. Features: Presents state-of-the-art in advanced oxidation processes (AOP) techniques along with hybrid technologies Covers latest advances in technological know-how for remediation of wastewater soiled with micropollutants Discusses pressing environmental pollution issues associated with AOPs needed for wastewater remediation Presents future perspective as well as techno-economic analysis in implementing various AOPs Reviews strategies to limit the micropollutants in water bodies This book is aimed at graduate students and researchers in chemical and industrial engineering, environmental science, and wastewater treatment.

Download or read book Advanced Oxidation Processes for Water and Wastewater Treatment written by Simon Parsons and published by IWA Publishing. This book was released on 2004-03-01 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: The suitability of Advanced Oxidation Processes (AOPs) for pollutant degradation was recognised in the early 1970s and much research and development work has been undertaken to commercialise some of these processes. AOPs have shown great potential in treating pollutants at both low and high concentrations and have found applications as diverse as ground water treatment, municipal wastewater sludge destruction and VOCs control. Advanced Oxidation Processes for Water and Wastewater Treatment is an overview of the advanced oxidation processes currently used or proposed for the remediation of water, wastewater, odours and sludge. The book contains two opening chapters which present introductions to advanced oxidation processes and a background to UV photolysis, seven chapters focusing on individual advanced oxidation processes and, finally, three chapters concentrating on selected applications of advanced oxidation processes. Advanced Oxidation Processes for Water and Wastewater Treatment will be invaluable to readers interested in water and wastewater treatment processes, including professionals and suppliers, as well as students and academics studying in this area. Dr Simon Parsons is a Senior Lecturer in Water Sciences at Cranfield University with ten years' experience of industrial and academic research and development.

Download or read book Physico Chemical Wastewater Treatment and Resource Recovery written by Robina Farooq and published by BoD – Books on Demand. This book was released on 2017-05-03 with total page 280 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book on Physico-Chemical Treatment of Wastewater and Resource Recovery provides an efficient and low-cost solution for remediation of wastewater. This book focuses on physico-chemical treatment via advanced oxidation process, adsorption, its management and recovery of valuable chemicals. It discusses treatment and recovery process for the range of pollutants including BTX, PCB, PCDDs, proteins, phenols, antibiotics, complex organic compounds and metals. The occurrence of persistent pollutants poses deleterious effects on human and environmental health. Simple solutions for recovery of valuable chemicals and water during physico-chemical treatment of wastewater are discussed extensively. This book provides necessary knowledge and experimental studies on emerging physico-chemical processes for reducing water pollution and resource recovery.

Download or read book Ozone based advanced oxidation processes for trace organic contaminants removal in waste water written by Ze Liu (Doctor of Bioscience Engineering) and published by . This book was released on 2020 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Advanced Oxidation Processes for Emerging Contaminant Removal written by Dionysios (Dion) Demetriou Dionysiou and published by Mdpi AG. This book was released on 2023-02-07 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Special Issue includes manuscripts on mechanistic understanding, development, and implementation of advanced oxidation processes (AOPs) for the removal of contaminants of emerging concern in water and wastewater treatment. The main goal was successfully achieved under the joint effort of authors, anonymous reviewers, and editorial managers. In total, one review and 15 research papers are included in the Special Issue. These are mainly focused on catalyst synthesis, reactor design, treatment performance, kinetic modeling, reaction mechanisms, and by-product formation during electrochemical, photocatalytic, plasma, persulfate, chlorine, ozone-based, and Fenton-related AOPs at different scales. This Special Issue has received attention from researchers from different parts of the world such as Argentina, Brazil, Canada, China, Germany, India, Mexico, and the USA. The guest editors are happy to see that all papers presented are innovative and meaningful, and hope that this Special Issue can promote mechanistic understanding and engineering applications of AOPs for the removal of contaminants of emerging concern in water.

Download or read book Advanced Oxidation Processes for Wastewater Treatment written by Suresh C. Ameta and published by Academic Press. This book was released on 2018-02-19 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Oxidation Processes for Waste Water Treatment: Emerging Green Chemical Technology is a complete resource covering the fundamentals and applications of all Advanced Oxidation Processes (AOPs). This book presents the most up-to-date research on AOPs and makes the argument that AOPs offer an eco-friendly method of wastewater treatment. In addition to an overview of the fundamentals and applications, it details the reactive species involved, along with sections on reactor designs, thus helping readers understand and implement these methods. - Presents in-depth coverage of all types of Advanced Oxidation Processes, including Super Critical Water Oxidation, Photo-Fenton and Like Processes - Includes a fundamental review, applications, reactive species and reactor designs - Reviews applications across waste types, including industrial waste, domestic and municipal sewage, and hospital wastes

Download or read book Advanced Oxidation Processes AOPs in Water and Wastewater Treatment written by Aziz, Hamidi Abdul and published by IGI Global. This book was released on 2018-08-03 with total page 519 pages. Available in PDF, EPUB and Kindle. Book excerpt: Population growth and industrial development have increased the amount of wastewater generated by urban areas, and one of the major problems facing industrialized nations is the contamination of the environment by hazardous chemicals. Therefore, to meet the standards, suitable treatment alternatives should be established. Advanced Oxidation Processes (AOPs) in Water and Wastewater Treatment is a pivotal reference source that provides vital research on the current, green, and advanced technologies for wastewater treatment. While highlighting topics such as groundwater treatment, environmental legislation, and oxidation processes, this publication explores the contamination of environments by hazardous chemicals as well as the methods of decontamination and the reduction of negative effects on the environment. This book is a vital reference source for environmental engineers, waste authorities, solid waste management companies, landfill operators, legislators, environmentalists, and academicians seeking current research on achieving sustainable management for wastewater treatment.

Download or read book Advanced Oxidation Process Models for Optimisation and Decision Making Support in Water Management written by Francesca Audino and published by . This book was released on 2020 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of this thesis is contributing to the development of a systematic modelling approach for a more efficient and sustainable water management.The main aim is introducing Chemical and Process System Engineering methods and tools to provide a contribution to the AOPs (Advanced Oxidation Processes) investigation field by proposing process models that can be exploited to progress towards efficient management strategies for practical AOPs operation and inclusion in wastewater treatment networks. First, different advanced oxidation processes, namely Fenton, photo-Fenton and VUV photo-oxidation, were investigated and compared for the treatment of paracetamol (PCT) aqueous solution, by evaluating a series of performance indicators. Among the selected AOPs, VUV photo-oxidation and photo-Fenton showed the most promising results. Both processes allowed attaining total removal of the target compound and high mineralization levels.The second and main part of the thesis was focused on transforming "data into knowledge" by proposing different modelling approaches. The modelling effort focused on Fenton/photo-Fenton processes that showed the need of improving operating conditions.Accordingly, two practical kinetic models for Fenton and photo-Fenton degradation of organic compounds have been proposed and validated:•A conventional First Principles Model, based on a line source radiation model with spherical and isotropic emission, developed for the prediction of Fenton and photo-Fenton degradation of PCT and the oxidant (H2O2) consumption;•A general non-conventional First Principles Model, based on a wide-ranging contaminant degradation mechanism considering a variable number of carbon atoms for the characterization of the intermediates.Both models were experimentally validated and showed that were able to satisfactorily reproduce the system behavior. Particularly, the non-conventional First Principles Model showed to be a successful modelling approach for the Fenton/photo-Fenton degradation of different wastewater systems composed by single or multiple organic contaminants by means of lumped parameters (e.g. Total Organic Carbon-TOC). Thus, the approach proved to offer practical characterization of complex mixtures of chemicals. Once process models are proposed and validated, they can be systematically exploited to determine efficient operation modes or design alternatives. Accordingly, the thesis addressed two cases of practical interest: the optimization of a control recipe and the design of a treatment network.Particularly, a dynamic optimization framework for taking advantage of available kinetic models and determining the best hydrogen peroxide dosage profile, was proposed. Economic and environmental objectives and constraints were included to develop a dynamic optimization problem that was implemented in JModelica and solved using a direct simultaneous optimization method (IPOPT). Finally, the combination of cheaper conventional biological processes with more expensive AOPs was explored. A Mixed-Integer Non Linear Programming (MINLP) model for the optimization of a general wastewater network was proposed based on a superstructure of alternative designs, which was implemented and solved in GAMS. The novel formulation includes the BOD5/COD ratio method, describing the removal efficiency of BOD5 and COD of a treatment for modelling the variation of the biodegradability of the influents. This novel formulation allows determining the extent of the AOP treatments when combined with biological treatments, and paves the way for more complex models aimed at solving the trade-off between cost and treatment efficiency.

Download or read book Ozonation of Water and Waste Water written by Christiane Gottschalk and published by John Wiley & Sons. This book was released on 2009-12-09 with total page 378 pages. Available in PDF, EPUB and Kindle. Book excerpt: The leading resource on ozone technology, this book contains everything from chemical basics to technical and economic concerns. The text has been updated to include the latest developments in water treatment and industrial processes. Following an introduction, the first part looks at toxicology, reaction mechanisms and full-scale applications, while Part B covers experimental design, equipment and analytical methods, mass transfer, reaction kinetics and the application of ozone in combined processes.

Download or read book Advanced Oxidation Processes for Emerging Contaminant Removal written by Gaya Herrington and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Special Issue includes manuscripts on mechanistic understanding, development, and implementation of advanced oxidation processes (AOPs) for the removal of contaminants of emerging concern in water and wastewater treatment. The main goal was successfully achieved under the joint effort of authors, anonymous reviewers, and editorial managers. In total, one review and 15 research papers are included in the Special Issue. These are mainly focused on catalyst synthesis, reactor design, treatment performance, kinetic modeling, reaction mechanisms, and by-product formation during electrochemical, photocatalytic, plasma, persulfate, chlorine, ozone-based, and Fenton-related AOPs at different scales. This Special Issue has received attention from researchers from different parts of the world such as Argentina, Brazil, Canada, China, Germany, India, Mexico, and the USA. The guest editors are happy to see that all papers presented are innovative and meaningful, and hope that this Special Issue can promote mechanistic understanding and engineering applications of AOPs for the removal of contaminants of emerging concern in water.

Download or read book Empirically Based Models for Predicting Chlorination and Ozonation By products written by and published by . This book was released on 1998 with total page 174 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Current Developments in Biotechnology and Bioengineering written by R. D. Tyagi and published by Elsevier. This book was released on 2020-04-15 with total page 668 pages. Available in PDF, EPUB and Kindle. Book excerpt: Current Developments in Biotechnology and Bioengineering: Environmental and Health Impact of Hospital Wastewater narrates the origin (history) of pharmaceuticals discoveries, hospital wastewater and its environmental and health impacts. It covers microbiology of hospital wastewater (pathogens, multi-drug resistance development, microbial evolution and impacts on humans, animals, fish), advanced treatment options (including biological, physical and chemical methods), and highlights aspects required during hospital wastewater treatment processes. This book provides an amalgamation of all recent scientific information on hospital wastewater which is not available in the current literature. Introduces physical, chemical and molecular testing methods for the analysis and characterization of hospital wastewater Discusses the environmental impact and health hazards of hospital wastewater Describes the microbiological aspects of the hospital wastewater, like microbial community, metagenomics, pathogens, VBNC and mechanism of antibiotic resistance development Explains hospital wastewater and its role in microbial evolution Highlights future treatment options, guidelines and drug disposal tactics