Download or read book Contemporary Problems in Carbonium Ion Chemistry I II written by C. Rees and published by Springer. This book was released on 2013-11-27 with total page 351 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1965 a book by P. Bartlett appeared under the title "The Nonclassical Ions" 1). The book is a collection of papers reprinted from various journals. The many reviews that have appeared since 2-22) are either antiquated (the book published in 1972 12) covers the literature mainly before 1968) or relatively biased (e.g., 3.4,10» on brief 2, 7,11). This review attempts to discuss the various points of view on the "nonclassical" carbocations. The main point is to establish the relative role of "nonclassical" and "classical" ions in various chemical processes. The author has followed P. Bartlett's advice 1) that when setting forth the achievements of the human mind one should see how we came to the modern understanding of a given problem (" ... how we know what we know"). The theory of "nonclassical" ions offers an explanation of many unique chemical, stereochemical and kinetic peculiarities of bicyclic compounds. It has expanded our knowledge on chemical bonds in carbocations by introducing electron-deficient bonds (as in boron hydrides). It has accounted for many rearrangements of stable cations. As a "side" result our knowledge has been extended about ionization processes in a solution, as well as about stereochemical methods. 2 Main Terms of Nonclassical Carbocations In 1939 Hevell, Salas and Wilson 23) assumed an intermediate, "bridge" ion 2 to be formed when camphene hydrochloride 1 is rearranged into isobornyl chloride 3. This happened 17 years after Meerwein first postulated the intermediate formation of "carbonium" ions in chemical reactions.

Download or read book Contemporary Problems in Carbonium Ion Chemistry III written by V. A. Koptyug and published by Walter de Gruyter GmbH & Co KG. This book was released on 1985-12-31 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: No detailed description available for "Contemporary Problems in Carbonium Ion Chemistry III".

Download or read book Biomimetic and Bioorganic Chemistry II written by F. Vögtle and published by Springer. This book was released on 1986-04-01 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt:

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Download or read book Inorganic Chemistry written by and published by Walter de Gruyter GmbH & Co KG. This book was released on 1984-12-31 with total page 148 pages. Available in PDF, EPUB and Kindle. Book excerpt: No detailed description available for "Inorganic Chemistry".

Download or read book Rearrangements in Ground and Excited States written by Paul de Mayo and published by Academic Press. This book was released on 2013-10-22 with total page 497 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rearrangement in ground and excited states, Volume 1 covers essays on the rearrangements of carbocations; gas-phase ion rearrangements; and rearrangements of carbenes and nitrenes. The book also includes essays on the free-radical rearrangements; hypothetical biradical pathways in thermal unimolecular rearrangements; and rearrangements in carbanions. Chemists and people involved in the study of rearrangements will find the book invaluable.

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