Download or read book Organic Sulfur Compounds written by N. Kharasch and published by Elsevier. This book was released on 2013-10-22 with total page 637 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Sulfur Compounds, Volume I deals with the chemistry of organic sulfur compounds such as disulfides, polysulfides, olefins, acetylenes, and chloroethylenes. Topics covered range from the inorganic acids of sulfur and the thermodynamics of organic sulfur compounds to some applications of isotopic sulfur and the stereochemistry of disulfides and polysulfides. The mechanism of oxidation of thiols to disulfides is also discussed. Comprised of 40 chapters, this volume first considers the precise structures of elemental sulfur in relation to the reactions of sulfur compounds, followed by an analysis of the inorganic acids of sulfur. The reader is then introduced to the thermodynamics of organic sulfur compounds and the bonding characteristics of the sulfur atom, as well as the infrared spectra of organosulfur compounds. Subsequent chapters focus on the ionic scission of the sulfur-sulfur bond; nucleophilic reactions of thiols with acetylene and chloroethylene; reactions of sulfur with olefins; and the chemistry of isothiocyanates. This book should prove useful to advanced students, practitioners, and research workers in the field of organic chemistry.
Download or read book Elemental Sulfur and Sulfur Rich Compounds I written by Ralf Steudel and published by Springer Science & Business Media. This book was released on 2003-10-23 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt: R. Steudel, B. Eckert: Solid Sulfur Allotropes.- R. Steudel: Liquid Sulfur.- R. Steudel, Y. Steudel, M.W. Wong: Speciation and Thermodynamics of Sulfur Vapor.- I. Krossing: Homoatomic Sulfur Cations.- R. Steudel: Aqueous Sulfur Sols.- W.E. Kleinjan, A. de Keizer, A. J. H. Janssen: Biologically Produced Sulfur.
Download or read book Elemental Sulfur and Sulfur Rich Compounds I written by Ralf Steudel and published by Springer. This book was released on 2004-01-26 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: R. Steudel, B. Eckert: Solid Sulfur Allotropes.- R. Steudel: Liquid Sulfur.- R. Steudel, Y. Steudel, M.W. Wong: Speciation and Thermodynamics of Sulfur Vapor.- I. Krossing: Homoatomic Sulfur Cations.- R. Steudel: Aqueous Sulfur Sols.- W.E. Kleinjan, A. de Keizer, A. J. H. Janssen: Biologically Produced Sulfur.
Download or read book The Chemistry of Organic Sulfur Compounds written by Norman Kharasch and published by Elsevier. This book was released on 2013-10-22 with total page 475 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Organic Sulfur Compounds deals with the chemistry of organic sulfur compounds such as thiocyanates, 1-alkynyl thioethers, thiols, and olefins. Topics covered range from the mechanisms of Raney nickel desulfuration to olefin sulfide chemistry, desulfonylation reactions, and alkaline decomposition of aliphatic disulfides. The reaction of cyanide with cystine and cystine peptides is also discussed. This volume is comprised of 15 chapters and begins with an introduction to electron correlation and bond properties in some selected sulfur compounds including thionyl and sulfuryl fluoride. The following chapters explore the mechanisms of Raney nickel desulfuration; isomerization of organic thiocyanates; polyfluoroalkyl derivatives of sulfur; anionic oxidation of thiols and co-oxidation of thiols with olefins; and the chemistry of the 1,2-sithiole ring. Thiohydantoins, thiophosgene, and the alkaline decomposition of aliphatic disulfides are also considered. The final chapter is devoted to oxidation of disulfides, with special reference to cystine. This book will be a useful resource for organic chemists.
Download or read book Organic Chemistry of Sulfur written by S. Oae and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 714 pages. Available in PDF, EPUB and Kindle. Book excerpt: In recent years organic sulfur chemistry has been growing at an even faster pace than the very rapid development in other fields of chemistry. This phenomenal growth is undoubtedly a reflection of industrial and public demands: not only was sulfur recently in overall surplus for the first time in the history of the chemical industry but it has now become a prin cipal environmental hazard in the form of sulfur dioxide, sulfuric acid and hydrogen sulfide. Another reason, discernible in the last fifteen years, has been the desire, on the part of individual chemists and all types of research managers, to move away from the established chemistry of carbon into the less well understood and sometimes virgin chemistries of the other elements which form covalent bonds. As a result of this movement the last decade has seen the development of sulfur chemistry into a well-organized and now much better understood branch of organic chemistry. Enough of the detail has become clear to see mechanistic interrelationships between previously unconnected reactions and with this clarification the whole subject has in tum become systema tized and subdivided. The divalent sulfur chemistry of thiols, monosulfides, disulfides and polysulfides is a large area in itself, much of it devoted to oxidation-reduction and the breakage and formation of sulfur-sulfur bonds, although interesting discoveries are now being made about the reac tivity of certain sulfur-carbon bonds. Of course, this area has its own mas sive biochemical branch involving enzymes and proteins.
Download or read book Elemental Sulfur and Sulfur Rich Compounds II written by Ralf Steudel and published by Springer. This book was released on 2004-01-26 with total page 267 pages. Available in PDF, EPUB and Kindle. Book excerpt: Despite more than 200 years of sulfur research the chemistry of elemental sulfur and sulfur-rich compounds is still full of “white spots” which have to be filled in with solid knowledge and reliable data. This situation is parti- larly regrettable since elemental sulfur is one of the most important raw - terials of the chemical industry produced in record-breaking quantities of ca. 35 million tons annually worldwide and mainly used for the production of sulfuric acid. Fortunately, enormous progress has been made during the last 30 years in the understanding of the “yellow element”. As the result of extensive inter- tional research activities sulfur has now become the element with the largest number of allotropes, the element with the largest number of binary oxides, and also the element with the largest number of binary nitrides. Sulfur, a typical non-metal, has been found to become a metal at high pressure and is even superconducting at 10 K under a pressure of 93 GPa and at 17 K at 260 GPa, respectively. This is the highest critical temperature of all chemical elements. Actually, the pressure-temperature phase diagram of sulfur is one of the most complicated of all elements and still needs further investigation.
Download or read book Sulfur Compounds Advances in Research and Application 2012 Edition written by and published by ScholarlyEditions. This book was released on 2012-12-26 with total page 337 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sulfur Compounds—Advances in Research and Application: 2012 Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about Sulfur Compounds. The editors have built Sulfur Compounds—Advances in Research and Application: 2012 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Sulfur Compounds in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Sulfur Compounds—Advances in Research and Application: 2012 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.
Download or read book Biological Interactions Of Sulfur Compounds written by Stephen C. Mitchell and published by CRC Press. This book was released on 1996-02-07 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text focuses on the biological interactions of sulphur compounds which arise specifically from the presence of the sulphur atom within the molecule. The book opens with introductory chapters on the chemistry and biology of sulphur, before tackling the field by introducing compounds which share a common chemical combination. In general, followi
Download or read book The Organic Chemistry of Sulfur Tetracovalent Sulfur Compounds written by Chester Merle Suter and published by . This book was released on 1944 with total page 858 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organic Sulfur Chemistry written by Shigeru Oae and published by CRC Press. This book was released on 2018-05-04 with total page 521 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains fundamental knowledge regarding the structure and mechanisms of organic sulfur chemistry. Topics include sulfur bondings, effects of sulfur groups, stereochemistry around sulfur, substitution, ligand coupling within s-sulfurane, oxidation, reduction and rearrangement. References in this work total over 2,300. Anyone with an interest in organic sulfur chemistry will find this book to be fascinating reading.
Download or read book TRANSITION METALS AND SULFUR written by and published by . This book was released on 2020 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Analytical Chemistry of Sulfur and Its Compounds written by Jean Herschel Karchmer and published by . This book was released on 1972 with total page 872 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Natural Sulfur Compounds written by Doriano Cavallini and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 550 pages. Available in PDF, EPUB and Kindle. Book excerpt: The third International Meeting on "Low Molecular Weight Sulfur Containing Natural Products,"sponsored by the International Union of Pure and Applied Chemistry, was held in the historical building of the Accademia Nazionale dei Lincei, Rome, Italy, June 18-21, 1979. The symposium was held in order to exchange knowledge in the intriguing and complex field of sulfur biochemistry. This theme brought together scientists from many speciali zed areas from organic and physical chemistry to biology and medicine. The interdisciplinary nature of the meeting gave to the participants the opportunity to discuss pro blems of common interest approached from different scienti fic standpoints. This volume contains 47 contributions presented at the meeting which mainly deal with new structural and metabolic aspects of sulfur biochemistry. An important aspect of such a scientific meeting is the rapid publication of the proceedings. Through the cooperation of the authors in providing "camera ready" copies of their manuscripts, the good efforts of the Orga nizing Committee, and the Plenum Press Publishing Co., it has been possible to publish this book within a few months of the meeting.
Download or read book Sulfur Compounds Advances in Research and Application 2011 Edition written by and published by ScholarlyEditions. This book was released on 2012-01-09 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sulfur Compounds: Advances in Research and Application: 2011 Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about Sulfur Compounds. The editors have built Sulfur Compounds: Advances in Research and Application: 2011 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Sulfur Compounds in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Sulfur Compounds: Advances in Research and Application: 2011 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.
Download or read book Reactions of Organosulfur Compounds written by Eric Block and published by Academic Press. This book was released on 2013-10-22 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Chemistry, Volume 37: Reactions of Organosulfur Compounds covers the basics of organosulfur chemistry and the characteristics of organically bound sulfur, with an emphasis on reactions, particularly those of synthetic utility. The book discusses the preparation, nature, stereochemical aspects, reactions, and the kinetic and thermodynamic assessment of the stability of sulfur-containing carbanions; the preparation and reactions of sulfur ylides; and the preparation, assessment of stability, and reactions of sulfur-containing carbocations. The text also describes preparation, assessment of stability, nature, and reactions of sulfur-containing radicals, organosulfur carbenes, and carbenoids; as well as the the pericyclic reactions of organosulfur compounds. Chemists, biochemists, and students taking related courses will find the book useful.
Download or read book S Sulfur Nitrogen Compounds written by Hans-Jürgen Fachmann and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume is the first of a series describing acyclic sulfur-nitrogen compounds with sulfur of oxidation number IV. The acyclic sw-N compounds are arranged according to the coordination number of the sulfur. Neutral compounds are described before ions and complex compounds. The preceding series "Sulfur-Nitrogen Compounds" Parts 2, 3, and 4 covers the cyclic sw-N compounds. In this volume, the first section deals with sulfur-nitrogen compounds with 1-coordinate sulfur and begins with the sulfur nitride {thiazyl) radical, SN. This transient molecule was observed in its electronic ground state and several electronically excited states. The descrip tions of the sulfur nitride (thiazyl) ions SN+ and SW follow. The SN+ ionwas studied in the gas phase as weil as in the solid state where it forms salts. Thionitrosyl complexes containing the SN Iigand as a terminal linear unit are described at the end of the first section. The second section concerns Sulfur-nitrogen compounds with 2-coordinate sulfur and starts with the description of poly(sulfur nitride), (SNlx· The preparation, crystal structure, and metallic and superconducting properties of (SN)x, which were extensively studied, fill a !arge part of the volume. Halogen-modified poly(sulfur nitride) such as the widely studied (SNBr )x 04 and Na-modified poly(sulfur nitride) are dealt with in the following chapters.
Download or read book Chemistry of Organic Sulfur Compounds written by and published by . This book was released on 1966 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
