Download or read book Chemistry of Transition Metal Carbonyls and Their Derivatives written by Walter Mark Douglas and published by . This book was released on 1970 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Transition Metal Organometallic Chemistry written by R. Bruce King and published by Elsevier. This book was released on 2012-12-02 with total page 217 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition-Metal Organometallic Chemistry: An Introduction presents the basic facts and principles of transition-metal organometallic chemistry. The book discusses the general principles of transition-metal organometallic chemistry; the organometallic derivatives of the early transition metals; and the organometallic derivatives of chromium, molybdenum, and tungsten. The text also describes the organometallic derivatives of manganese, technetium, and rhenium; the organometallic derivatives of iron, ruthenium, and osmium; and the organometallic derivatives of cobalt, rhodium, and iridium. The organometallic derivatives of nickel, palladium, platinum, copper, silver, and gold are also considered. Chemists and chemistry students will find the book invaluable.
Download or read book Transition Metal Carbonyl Cluster Chemistry written by Paul J. Dyson and published by CRC Press. This book was released on 2000-11-17 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.
Download or read book Transition Metal Carbonyl Cluster Chemistry written by Paul J. Dyson and published by CRC Press. This book was released on 2018-10-03 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.
Download or read book The Interaction of Group III Lewis Acids with Transition Metal Carbonyls and Their Derivatives written by Jeffrey Steven Kristoff and published by . This book was released on 1973 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organometallic Chemistry of the Transition Elements written by Florian P. Pruchnik and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 767 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry belongs to the most rapidly developing area of chemistry today. This is due to the fact that research dealing with the structure of compounds and chemical bonding has been greatly intensified in recent years. Additionally, organometallic compounds have been widely utilized in catalysis, organic synthesis, electronics, etc. This book is based on my lectures concerning basic organometallic chemistry for fourth and fifth year chemistry students and on my lectures concerning advanced organometallic chemistry and homogeneous catalysis for Ph.D. graduate students. Many recent developments in the area of organometallic chemistry as weIl as homogeneous catalysis are presented. Essential research results dealing with a given class of organometallic compounds are discussed briefly. Results of physicochemical research methods of various organometallic compounds as weIl as their synthesis, properties, structures, reactivities, and applications are discussed more thoroughly. The selection of tabulated data is arbitrary because, often, it has been impossible to avoid omissions. Nevertheless, these data can be very helpful in understanding properties of organometaIlic compounds and their reactivities. All physical data are given in SI units; the interatomic distances are given in pm units in figures and tables. I am indebted to Professor S. A. Duraj for translating and editing this book. His remarks, discussions, and suggestions are greatly appreciated. I also express gratitude to Virginia E. Duraj for editing and proofreading.
Download or read book New Aspects of the Chemistry of Metal Carbonyls and Derivatives written by and published by . This book was released on 1969 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Chemistry of Carbonyl Compounds and Derivatives written by Paulo Costa and published by Royal Society of Chemistry. This book was released on 2022-06-15 with total page 841 pages. Available in PDF, EPUB and Kindle. Book excerpt: Originally published in Portuguese, this book is divided into three sections which merge aspects of valence bond and molecular orbital theories in order to discuss structural and physico-chemical properties.
Download or read book A Textbook of Inorganic Chemistry Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Download or read book Organo Transition Metal Compounds and Related Aspects of Homogeneous Catalysis written by B. L. Shaw and published by Elsevier. This book was released on 2016-06-06 with total page 231 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis covers compounds that possess carbon atoms bonded to metal and to other carbon atoms. The order in which the substances appear in the book is based on the number of carbon atoms it have. The first section is about the alkyl, aryl, ethynyl, acyl, and carbene complexes. The second section deals with olefin and chelating diolefin complexes and complexes formed from acetylene. The following section covers the p-allylic complexes. The structures, stability, and bonding of alkyl and aryl complexes are fully covered. The magnetic moments and electronic spectra are discussed in detail.The fourth section discusses the conjugated diolefinic complexes that contain butadiene or cyclobutadiene. The rest of the book focuses on cyclopentadienyls, arene complexes, tropylium complexes, and complexes formed from cyclo-octatetraene or azulene. The book will be a useful tool for chemists, chemical engineers, and students and researchers in the field of chemistry.
Download or read book NEW ASPECTS OF THE CHEMISTRY OF METAL CARBONYLS AND DERIVATIVES PROCEEDINGS OF THE 1ST INTERNATIONAL SYMPOSIUM written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Inorganic Chemistry of the Transition Elements written by B F G Johnson and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 542 pages. Available in PDF, EPUB and Kindle. Book excerpt: Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Download or read book Compounds of Transition Metals written by Michael Dub and published by Springer. This book was released on 2013-12-01 with total page 845 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this Compilation has been to provide a comprehensive, non critical source of information concerning organometallic compounds. The scope is limited to the compounds containing at least one carbon-metal bond. The information includes methods of preparation, properties, chemical reactions and applications. The First Edition comprised the literature from 1937 to 1958. The Second Edition is completely revised and extended through 1964. The literature prior to 1937 was thoroughly covered by E. Krause and A. von Grosse in 11 11 Die Chemie der metall-organischen Verbindungen, Verlag von Gebrueder Borntraeger, Berlin, 1937. Our work consists of three volumes. Volume I contains derivatives of the transition metals of Groups III through VIII of the Periodic Table. Volume II contains derivatives of germanium, tin and lead. Volume Ill contains derivatives of arsenic, antimony and bismuth. The Compilation is based on searches through Chemical Abstracts. The collection of references for 1964 was completed before the Subject Indexes to Volumes 60 and 61 of the Abstracts were available; thus some omissions in the coverage of that year are possible. We have attempted to make the coverage of the literature complete in order that the Compilation may have best utility to the chemist, chemical engineer, patent attorney and editor. In the interest of brevity, certain numerical data are omitted, but references to the original literature are given. Yield data are rounded to two significant figures. Wherever possible, tables have been used. The entries in the Bibliography section include references to Chemical Abstracts.
Download or read book Advances in Metal Carbene Chemistry written by U. Schubert and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 405 pages. Available in PDF, EPUB and Kindle. Book excerpt: There are only few topics in organometallic chemistry, which have stimulated research activities in as many areas, as transition-metal carbene (alkylidene) complexes. About 25 years after the first planned synthesis of a carbene complex in E.O. Fischer's laboratory in Munich the NATO Advanced Research Workshop on Transition-Metal Carbene Complexes was the first meeting which,brought together scientists from different disciplines to discuss inorganic, organic, theoretical structural catalysis-related aspects of metal carbene chemistry. The 70th birthday of Professor E.O. Fischer was a good occasion for this enterprise. The organizers of the meeting (K.D. Dotz, Marburg; F.R. KreiBl, Munchen; U. Schubert, Wurzburg) were encouraged by the fact that most of the leading scientists in this area were able to participate in the workshop. The very high standard of the contributions is reflected in this book, which contains papers from the majority of the participants. The Proceedings show the state of the art in metal carbene chemistry and will hopefully be a landmark in the development of this area of chemistry. Generous financial support for the workshop and for the preparation of this book was provided by the Scientific Affairs Division of NATO and some companies. The organizers also acknowledge the efforts of the staff of the Bildungs zentrum der Hans-Seidel-Stiftung in Wild bad Kreuth for creating a pleasant and stimulating atmosphere during the conference.
Download or read book Some Aspects of the Organometallic Chemistry of the Group VI Transition Metals written by Ezra Eddy Isaacs and published by . This book was released on 1974 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The reaction of cycloheptatrienyltricarbonyl molybdenum cation with various main group V donor ligands (L) yielded, in general, mono-substituted complexes, [C[subscript 7]H[subscript 7]Mo(CO)[subscript 2]L][superscript +]. [superscript 31]P nmr studies on some related di-tertiary phosphine complexes provided a convenient and unequivocal determination of the stereochemistry. The reduction of the cationic cycloheptatrienyl complexes with sodium borohydride provided a suitable synthetic route to the group V derivatives of cyclo- heptatrienetricarbonylmolybdenum. The infrared, [superscript l]H and [superscript 13]C nmr, and mass spectral properties of these complexes were studied. Some main group IV ligands bonded to cycloheptatrienyldicarbonylmolybdenum were also prepared and studied by spectral means. A number of main group IV - group VI metal penta- carbonyl anionic derivatives have been prepared by the reaction of the chloropentacarbonyl anions with the organolithium compounds of the group IV elements. These compounds have the general formula, [R[subscript 3]M' -M(CO)[subscript 5]][superscript -] (where R = Me, Ph or halogen; M' = Si, Ge, Sn or Pb; M = Cr, Mo or W). Approximate carbonyl force constants were calculated from the infrared carbonyl stretching vibrations and these provided some insight into the nature of the metal-metal bonds. Transition metal nitrosyl derivatives have also been prepared by the reaction of some anionic complexes with nitrosonium hexafluorophosphate. These compounds have the general formula LM(CO)[subscript 4]NO (where L is a main group IV ligand or a halogen group and M is Mo or W). The carbonyl and nitrosyl force constants were calculated and are discussed in terms of the relative bonding properties of CO and NO ligands. Finally, the oxidation reaction of some dinuclear metal carbonyls with AgNO[subscript 2] led to the formation of metal carbonyls containing nitro ligands. Linkage isomerism involving nitro and nitrito species was encountered in solution. The [(CH[subscript 3]CN)[subscript 3]Re(CO)[subscript 3]] + cation was formed 2 - from the oxidation reaction of [Re[subscript 4](CO)[subscript 16]][superscript 2-] in acetonitrile.
Download or read book Organometallic Compounds written by M. L. Green and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 389 pages. Available in PDF, EPUB and Kindle. Book excerpt: to thank Messrs J. R. Sanders, W. E. Lindsell and M. G. Swanwick for helping to check the text and references and prepare indexes. Finally, I should like to thank my wife for the very considerable assis tance she has given me in the writing and production of this book. M. L. H. G. Contents Preface to the Third Edition, Volume Two Page v INTRODUCTION TO VOLUME TWO I Oassification I The IS-electron rule 2 (i) The basis of the I8-electron rule p. 4, (ii) Exceptions to the I8-electron rule p. 5 1. TWO-ELECTRON LIGANDS 7 A. Classification 7 B. The preparation of olefin-transition metal complexes 7 (a) Displacement of solvent ligands p. 9, (b) Preparations from metal carbonyls p. 9, (c) Less common preparative routes p. 11, Reductive olefination method p. 12 C. A molecular orbital description of the bonding in orga- metallic complexes 13 (a) General comments p. 13, (b) Symmetry considerations p. 13, (c) Energies of the molecular orbitals p. 14 D. A description of the bonding of 2-electron ligands to transition metals 14 E. General comments of 2-electron ligands 19 (a) Infrared studies p. 20, (b) Effect of olefin substituents p. 21, (c) The rotation of ethylene about the ligand-metal bond p. 22, (d) Chemical properties p. 23 F. Particular complexes of metals with 2-electron ligands 25 (a) Copper, silver and gold p. 25, Complexes with benzene p. 28, (b) Nickel, palladium and platinum p.
Download or read book Transition Metals in the Synthesis of Complex Organic Molecules written by Louis S. Hegedus and published by University Science Books. This book was released on 1999 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.
