Download or read book A Textbook of Inorganic Chemistry Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Download or read book Chemistry and Structures of Some Polynuclear Metal Carbonyl Complexes written by Glenn Richard Wilkes and published by . This book was released on 1965 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemistry for Degree Students B Sc Elective Semester V VI Elective I As per CBCS written by Madan R.L. and published by S. Chand Publishing. This book was released on with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: The subject matter has been divided into twelve chapters written in lucid language. Great care has been taken to explain the topics in such a simple way that it should be possible for the students to understand the various topics easily.
Download or read book The Crystal and Molecular Structures of Some Polynuclear Metal Carbonyls written by Eugene R. Corey and published by . This book was released on 1963 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemistry and Structures of Some Polynuclear Metal Carbonyl Complexes written by Glenn Richard Wilkes and published by . This book was released on 1965 with total page 362 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Metal Complexes Organic Chemistry written by Houghton and published by Cambridge University Press. This book was released on 1979-07-12 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemistry for Degree Students B Sc Third Year written by Madan R.L. and published by S. Chand Publishing. This book was released on 2022 with total page 939 pages. Available in PDF, EPUB and Kindle. Book excerpt: For B.Sc 3rd year students of all Indian Universities. The book has been prepared keeping view the syllabi prepared by different universities on the basis of Model UGC Curriculum. A large number of illustrations, pictures and interesting examples have been provided to make the reading interesting and understandable. The question that have been provided in the Exercise are in tune with the latest pattern of examination.
Download or read book Comprehensive Chemistry XII written by and published by Laxmi Publications. This book was released on with total page 1820 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Quarterly Journal of the Chemical Society of London written by Chemical Society (Great Britain) and published by . This book was released on 1969 with total page 970 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Organic Chemistry of Nickel written by P.W. Jolly and published by Elsevier. This book was released on 2012-12-02 with total page 533 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Organic Chemistry of Nickel, Volume I: Organonickel Complexes is devoted to a description of the organonickel complexes. The major goal is to provide a reference work, and for this reason a conventional layout has been adopted with separate chapters devoted to each type of organic ligand. In the interest of readability, known compounds have been assembled in tables at the end of each chapter, thereby allowing the text to be used for discussions of the general chemistry involved and to highlight the special reactions associated with nickel. Conscious of the needs of organometallic chemists, the authors included systems in which no nickel-carbon bond is involved. Among these is a chapter on the tetrakisligand nickel complexes and sections on dioxygen and azobenzene complexes. The nitrosyl complexes and complexes containing a metal-metal bond—topics frequently considered to be part of the domain of the organometallic chemist—have not received individual attention. Tables of the observed bond distances in organonickel complexes are provided as an Appendix; a short list of the more important review articles relevant to each organic ligand can be found at the end of each chapter.
Download or read book Lanthanide Based Multifunctional Materials written by and published by Elsevier. This book was released on 2018-06-26 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lanthanide-Based Multifunctional Materials: From OLEDs to SIMs serves as a comprehensive and state-of the art review on these promising compounds, delivering a panorama of their extensive and rapidly growing applications. After an introductory chapter on the theoretical description of the optical and magnetic behaviour of lanthanides and on the prediction of their properties by ab-initio methods, four chapters are devoted to lanthanide-based OLEDs, including the latest trends in visible emitters, the emerging field of near infrared emitters and the first achievements attained in the field of chiral OLEDs. The use of lanthanide complexes as molecular magnets spreads over another two chapters, which explain the evolution of 4f-elements-based SIMs and the most recent advances in heterometallic 3d–4f SMMs. Other very active research areas are covered in the remaining five chapters, dedicated to lanthanide-doped germanate and tellurite glasses, luminescent materials for up-conversion, luminescent thermosensors, multimodal imaging and therapeutic agents, and chemosensors. The book is aimed at academic and industrial researchers, undergraduates and postgraduates alike, and is of particular interest for the Materials Science, Applied Physics and Applied Chemistry communities. - Includes the latest progress on lanthanide-based materials and their applications (in OLEDs, SIMs, doped matrices, up-conversion, thermosensors, theragnostics and chemosensors) - Presents basic and applied aspects of the Physics and Chemistry of lanthanide compounds, as well as future lines of action - Covers successful examples of devices and proofs-of-concept and provides guidelines for the rational design of new materials
Download or read book Organometallics and Catalysis written by Manfred Bochmann and published by Oxford University Press, USA. This book was released on 2015 with total page 429 pages. Available in PDF, EPUB and Kindle. Book excerpt: A succinct review of the essential concepts of organometallic chemistry, enriched throughout with examples that demonstrate how our understanding of organometallic chemistry has led to new applications in research and industry - not least in relation to catalysis.
Download or read book Cluster Chemistry written by Guillermo Gonzalez-Moraga and published by Springer Science & Business Media. This book was released on 2013-11-09 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.
Download or read book Landmarks in Organo Transition Metal Chemistry written by Helmut Werner and published by Springer Science & Business Media. This book was released on 2008-12-16 with total page 361 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the discovery of ferrocene and the sandwich-type complexes, the development of organometallic chemistry took its course like an avalanche and became one of the scientific success stories of the second half of the twentieth century. Based on this development, the traditional boundaries between inorganic and organic chemistry gradually disappeared and a rebirth of the nowadays highly important field of homogeneous catalysis occurred. It is fair to say that despite the fact that the key discovery, which sparked it all off, was made more than 50 years ago, organometallic chemistry remains a young and lively discipline.
Download or read book Summaries of Projects Completed in Fiscal Year written by National Science Foundation (U.S.) and published by . This book was released on 1978 with total page 1092 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energy Research Abstracts written by and published by . This book was released on 1992-03 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book ERDA Energy Research Abstracts written by and published by . This book was released on 1983 with total page 1028 pages. Available in PDF, EPUB and Kindle. Book excerpt:
