Download or read book An Investigation of the Rheology of Reactive and Nonreactive Highly Filled Polymer Systems written by J. Andrew Walberer and published by . This book was released on 2000 with total page 226 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Rheology of Filled Polymer Systems written by A.V. Shenoy and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymerie materials have been replacing other conventional materials like metals, glass and wood in a number of applications. The use of various types of fillers incorporated into the polymer has become quite common as a means of reducing cost and to impart certain desirable mechanieal, thermal, electrieal and magnetic properties to the polymers. Oue to the energy crisis and high priees of petrochemieals, there has been a greater demand to use more and more fillers to cheapen the polymerie materials while maintaining and/or improving their properties. The advantages that filled polymer systems have to offer are normally offset to some extent by the increased complexity in the rheological behavior that is introduced by the inclusion of the fillers. Usually when the use of fillers is considered, a compromise has to be made between the improved mechanieal properties in the solid state, the increased difficulty in melt processing, the problem of achieving uniform dispersion of the filler in the polymer matrix and the economics of the process due to the added step of compounding. It has been recognized that addition of filler to the polymer brings a change in processing behavior. The presence of the filler increases the melt viscosity leading to increases in the pressure drop across the die but gives rise to less die swell due to decreased melt elasticity.
Download or read book Polymer Rheology Theory and Practice written by Y.G. Yanovsky and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 309 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present book is devoted to a rapidly developing field of science which studies the behavior of viscoelastic materials under the influence of deformation~the rheology of polymers. Rheology has long been treated as the theoretical foundation of polymer processing, and from this standpoint it is difficult to overesti mate its importance in practice. Rheology plays an important role in developing our ideas on the nature of viscoelastic behavior in connection with the structural features of polymers and composites based on them. This expands the possibilities of employing rheological methods to characterize a variety of materials and greatly magnifies the interest in this field of research. The rheological properties of polymer systems are studied experimen tally, chiefly under conditions of shear and tensile strains. One explana tion is that many aspects of polymer material processing are associated with the stretching of melts or a combination of shear and tensile strains. In scientific investigations, either periodic or continuous conditions of shear deformation are employed. Each mode provides widespread infor mation. In periodic deformation, most attention is generally given to conditions with low deformation amplitudes that do not alter the structure of the polymer system during an experiment (the region of linear deformation conditions). Here the viscoelastic parameters are generally determined with respect to the frequency. Continuous deforma tion involves considerable strains, and may be attended by significant reversible and irreversible changes in the structure of a polymer.
Download or read book Rheology Applied in Polymer Processing written by B.R. Gupta and published by CRC Press. This book was released on 2022-11-17 with total page 463 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers a wide range of topics in polymer rheology. These are: Basic Principles, parameters, systems and applied mathematical models used in the rheological studies Melt flow analysis of different non-Newtonian fluids in laminar flow, transition between laminar and turbulent flow and modified Reynolds number The effects of different physical and molecular parameters on purely viscous rheological response of polymer melts and solutions Principles of rheometery and different types of viscometers and on-line rheometers The static and dynamic viscoelastic response of the polymer melts and solutions, viscoelasticity, mechanical models and Boltzmann superposition principle Molecular structure – viscoelasticity relationship and linear and non-linear viscoelasticity Effects of different processes, materials parameters like temperature, fillers (micro and nano-fillers) and molecular parameters like MW, MWD The role of rheology in polymer processing in different equipment Modified power law constants and two range power law constants for a large number of polymers, rheology software program in Java, comparison of different polymer rheological models using the rheology software and answers to the problems The book will be very useful to both undergraduate and postgraduate students, as well as teachers and practicing rheologists.
Download or read book Polymer Rheology written by Jose Luis Rivera Armenta and published by BoD – Books on Demand. This book was released on 2018-10-03 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rheology is the science that studies the behavior of the flow of matter in a liquid state or soft solids under the application of stress or deformation to obtain a response to an applied force. In polymers, rheology is an important tool to understand behavior under processing conditions and to design equipment. Another application for rheology in the polymer field is to understand structure-property relationships by means of molecular weight, molecular weight distribution, stereochemistry, morphology, melt degradation, and performance under processing. This book covers the essential criteria for selecting the best test types for various applications and new developments, for accurately interpreting results, and for determining other areas where rheology and rheological phenomena may be useful in your work.
Download or read book Dissertation Abstracts International written by and published by . This book was released on 2001 with total page 820 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Rheology for Chemists written by James William Goodwin and published by Royal Society of Chemistry. This book was released on 2008 with total page 277 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rheology is primarily concerned with materials: scientific, engineering and everyday products whose mechanical behaviour cannot be described using classical theories. From biological to geological systems, the key to understanding the viscous and elastic behaviour firmly rests in the relationship between the interactions between atoms and molecules and how this controls the structure, and ultimately the physical and mechanical properties. Rheology for Chemists An Introduction takes the reader through the range of rheological ideas without the use of the complex mathematics. The book gives particular emphasis on the temporal behaviour and microstructural aspects of materials, and is detailed in scope of reference. An excellent introduction to the newer scientific areas of soft matter and complex fluid research, the second edition also refers to system dimension and the maturing of the instrumentation market. This book is a valuable resource for practitioners working in the field, and offers a comprehensive introduction for graduate and post graduates. Extracts from reviews of 1st Edition: "... well-suited for self-study by research workers and technologists, who, confronted with technical problems in this area, would like a straightforward introduction to the subject of rheology." Chemical Educator, "... full of valuable insights and up-to-date information." Chemistry World
Download or read book Studies Concerning the Rheology of Polymer Systems from the Solution to the Melt written by Maria Aranzazu Odriozola and published by . This book was released on 1996 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Interfacial Rheology of Polymers in the Molten State Experimental and Fundamental Aspects written by Younes El Omari and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The work of this thesis deals with the interfacial rheology in shear and in extension of polymeric systems. Initially, we chose to study model systems based on PIB poly (isobutylene) and PDMS poly (dimethylsiloxane). These polymers have the advantage of being liquid at room temperature. For this purpose, a cell for measuring interfacial properties has been developed in our laboratory. It allows to study the surface and interface properties at high temperatures up to 200 °C. Thus, we were able to study the interfacial properties according to the steady and oscillatory regime of these model systems by highlighting the influence of the molar mass and the temperature. These studies were then transposed to semi-crystalline molten polymers such as PEG poly (ethylene glycol) and PCL poly (caprolactone). In a second step, we studied and analyzed the interfacial elongational rheological properties of the model systems, by means of interfacial dilational rheology via the oscillating pendant drop method. In addition, the relaxation of surfaces / interfaces was studied by the "pulse" method and using the capillary breakup extensional rheometer (CaBER). The interfacial rheological quantities in elongation of model systems of different molar masses and under different temperatures were obtained. They were then compared with those measured in shear and analyzed according to the interfacial Trouton ratio. In the last part of the thesis, we have shown that the interfacial shear rheology allows to probe the chemical reaction at the interfaces of a polymeric melt system : PEgMA Poly (Ethylene Grafted Maleic Anhydride) / PDMS-(PropNH2)2, Poly (Dimethyl Siloxane Amino Propyl terminated). In addition, the study of the dynamic interfacial tension allowed the monitoring of the kinetics of the interfacial reaction of the reactive systems of different molar masses and at different temperatures. Finally, the studies of interfacial rheology are very relevant to probe in-situ the interfaces and/or interphases of molten polymer systems. The methodologies thus established and used are very innovative and overcome major scientific and technological barriers.
Download or read book The Entanglement Concept in Polymer Rheology written by W.W. Graessley and published by Springer. This book was released on 2013-10-03 with total page 182 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Rheology of Polymer Systems written by and published by Wiley-VCH. This book was released on 2000-12-07 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This conference on the Rheology of Polymer Systems was held at the Institute of Macromolecular Chemistry of the Academy of Sciences of the Czech Republic in Prague from 19-22nd July 1999, as part of the Prague Meetings on Macromolecules sponsored, as usual, by IUPAC. The topics covered included relations between rheological properties and structure of molten polymer systems, advanced rheometry and rheological characterization, interrelations between rheological data measured in various flow fields and progress in the description of complex flow of molten polymer systems. The papers within this volume of Macromolecular Symposia cover a broad range of topics typical of the symposium.
Download or read book Polymer Systems written by British Society of Rheology and published by . This book was released on 1968 with total page 362 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Rheology in Polymer Processing written by Krzysztof Wilczynski and published by Carl Hanser Verlag GmbH Co KG. This book was released on 2020-12-07 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: “Rheology in Polymer Processing” introduces the fundamentals of rheology and rheometry as the basis for modeling and computer-aided design in plastics processing. The logically structured content enables the reader to intelligently use the tools of computer-aided design and modeling of plastics processing, with correct interpretation of the results. The book presents difficult and complex issues of rheology and modeling in an accessible way, with particular emphasis on the practical engineering aspects. The software described in the book allows modeling all the important problems of plastics processing. Particular attention is paid to the extrusion process, which is fundamentally important as a processing technology in mass manufacture of plastic parts, and the basis of compounding processes (blending, filling, granulation, and reinforcement). This book is aimed equally at engineers, researchers, and scientists, as well as intermediate students, for whom it will serve as an ideal course book.
Download or read book Directory of Graduate Research written by and published by . This book was released on 2001 with total page 1850 pages. Available in PDF, EPUB and Kindle. Book excerpt: Faculties, publications and doctoral theses in departments or divisions of chemistry, chemical engineering, biochemistry and pharmaceutical and/or medicinal chemistry at universities in the United States and Canada.
Download or read book Applied Rheology In Polymer Processing written by B. R. Gupta and published by . This book was released on 2006-01-01 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Book Covers Wide Range Of Topics In The Polymer Rheology. These Include -The Basic Principles, Parameters, Systems And Applied Mathematical Models Used In The Rheological Studies. The Melt Flow Analysis Of Different Non-Newtonian Fluids In Laminar Flow, Transition Between Laminar And Turbulent Flow And Modified Reynolds Etc. The Effects Of Different Physical And Molecular Parameters On Purely Viscous Rheological Response Of Polymer Melts And Solutions. Principles Of Rheometery And Different Types Viscometers And On-Line Rheometers. The Static And Dynamic Viscoelastic Response Of The Polymer Melts And Solutions, Linear Viscoelasticity. Mechanical Models And Boltzmann Superposition Principle. Molecular Structure - Viscoelasticity Relationship And Linear And Non-Linear Viscoelasticity. A Good Number Of Solved Examples And Exercise Problems.The Book Will Be Of Immense Help To Both Under Graduate And Post-Graduate Students, Teachers, Polymer Engineers And Practicing Rheologists. Content Highlights : - # Preface # Introduction # Rheological Principles # Melt Flow Analysis # Parameters Influencing The Polymer Rheology # Rheometry # Viscoelastic Behaviour # Viscoelastic Functions : Effect Of Various Parameters # Rheology In Polymer And Rubber Processing # References
Download or read book Rheology of Highly Filled Polymers written by Christian Kukla and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In many applications and/or manufacturing processes, highly filled polymers are necessary. One of these fields is powder metallurgy, where polymers or polymer mixtures are used to enable the shaping process within the production of the parts. Metal and also ceramic powders are mixed with different polymeric substances with a powder content of more than 50 vol%. Within the production, this mixture, called feedstock, has to flow into the final shape. Thus, for a proper understanding of the production processes, fundamental knowledge on the flow behavior of the feedstocks is required. For the rheology of polymers, several techniques together with the proper equipment are available. In the case of high viscosities, rotational and high-pressure capillary rheometers (HPCRs) are used. To gain reliable data, a proper measurement procedure is essential, which means that the operator has to have a deeper physical understanding of the material and the effects arising during the measurements. Therefore, this chapter gives an insight into rotational and high-pressure capillary rheometry with special emphasis on the behavior of polymers highly filled with stiff particles. Based thereon important remarks on the measurement equipment, procedure and evaluation of the measured data are provided.
Download or read book Chemorheology of Polymers written by Peter J. Halley and published by Cambridge University Press. This book was released on 2009-05-28 with total page 445 pages. Available in PDF, EPUB and Kindle. Book excerpt: Understanding the dynamics of reactive polymer processes allows scientists to create new, high-value, high-performance polymers. This book is an indispensable resource for researchers and practitioners working in this area. It includes coverage of thermoplastics, thermoset and reactive polymers, together with practical industrial processes and modern chemorheological models and tools.
