Download or read book A Textbook of Inorganic Chemistry Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.

Download or read book Descriptive Catalogue of Books Contained in the Lending Library written by Bishopsgate Institute, London and published by . This book was released on 1901 with total page 662 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Monthly Record of Scientific Literature written by and published by . This book was released on 1897 with total page 212 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book A Classified Catalogue of Educational Works written by Anonymous and published by BoD – Books on Demand. This book was released on 2023-03-31 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reprint of the original, first published in 1871. The publishing house Anatiposi publishes historical books as reprints. Due to their age, these books may have missing pages or inferior quality. Our aim is to preserve these books and make them available to the public so that they do not get lost.

Download or read book A Classified Catalogue of School College Classical Training and General Educational Works in Use in Great Britain Etc written by Walter LOW and published by . This book was released on 1871 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book A Classified Catalogue of School College Classical Technical and General Educational Works in Use in Great Britain in 1871 written by and published by . This book was released on 1871 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book A classified catalogue of Educational Works written by Walter Low and published by BoD – Books on Demand. This book was released on 2022-07-29 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reprint of the original, first published in 1871.

Download or read book Classified Catalogue of the Library of the Royal Geographical Society to December 1870 written by Royal Geographical Society (Great Britain). Library and published by London : J. Murray. This book was released on 1871 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Physical and Chemical Apparatus written by and published by . This book was released on 1909 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Practice and Theory of the Injector written by Strickland Landis Kneass and published by . This book was released on 1910 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book The Theory of Numbers written by Robert Daniel Carmichael and published by . This book was released on 1914 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Nature written by Sir Norman Lockyer and published by . This book was released on 1926 with total page 1100 pages. Available in PDF, EPUB and Kindle. Book excerpt:

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Download or read book Report of the Commissioner of Education Made to the Secretary of the Interior for the Year with Accompanying Papers written by United States. Bureau of Education and published by . This book was released on 1879 with total page 864 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book The Theory and Practice of Modern Framed Structures Statically indeterminate structures and secondary stresses written by John Butler Johnson and published by . This book was released on 1910 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book The Standard Medical Directory of North America 1902 written by and published by . This book was released on 1901 with total page 860 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book House Documents Otherwise Publ as Executive Documents written by United States. Congress. House and published by . This book was released on 1878 with total page 890 pages. Available in PDF, EPUB and Kindle. Book excerpt: