Download or read book A Critical Review of Equilibrium Data for Proton and Metal Complexes of 1 10 Phenanthroline 2 2 Bipyridyl and Related Compounds written by W.A.E. McBryde and published by Elsevier. This book was released on 2013-10-22 with total page 85 pages. Available in PDF, EPUB and Kindle. Book excerpt: A Critical Review of Equilibrium Data for Proton- and Metal Complexes of 1,10-Phenanthroline, 2,2'-Bipyridyl and Related Compounds is a compilation of acidity constants for the 1,10-phenanthrolinium and 2,2'-bipyridinium ions and their derivatives, as well as stability constants for metal complexes formed by the conjugate bases of these. These equilibrium data are critically examined. This monograph includes values determined in non-aqueous or mixed solvents, as well as those for a large number of ""mixed"" metal complexes incorporating these bases and a second ligand. The survey also contains known values for the enthalpies and entropies of formation for the proton- and metal-ion complexes. The compilation indicates the conditions under which the equilibrium constants apply and the methods by which they were determined. The acid-base properties of the compounds are represented by the acidity constant of the phenanthrolinium or bipyridinium ion expressed as a pK value. Nearly all the values listed were obtained either potentiometrically or spectrophotometrically, both of which depend fundamentally on measurements of pH or hydrogen-ion concentration. This book will be of value to chemists.
Download or read book Bulletin of the Chemical Society of Japan written by Nihon Kagakkai and published by . This book was released on 1996 with total page 660 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Metal Complexes in Aqueous Solutions written by Arthur E. Martell and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 259 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stability constants are fundamental to understanding the behavior of metal ions in aqueous solution. Such understanding is important in a wide variety of areas, such as metal ions in biology, biomedical applications, metal ions in the environment, extraction metallurgy, food chemistry, and metal ions in many industrial processes. In spite of this importance, it appears that many inorganic chemists have lost an appreciation for the importance of stability constants, and the thermodynamic aspects of complex formation, with attention focused over the last thirty years on newer areas, such as organometallic chemistry. This book is an attempt to show the richness of chemistry that can be revealed by stability constants, when measured as part of an overall strategy aimed at understanding the complexing properties of a particular ligand or metal ion. Thus, for example, there are numerous crystal structures of the Li+ ion with crown ethers. What do these indicate to us about the chemistry of Li+ with crown ethers? In fact, most of these crystal structures are in a sense misleading, in that the Li+ ion forms no complexes, or at best very weak complexes, with familiar crown ethers such as l2-crown-4, in any known solvent. Thus, without the stability constants, our understanding of the chemistry of a metal ion with any particular ligand must be regarded as incomplete. In this book we attempt to show how stability constants can reveal factors in ligand design which could not readily be deduced from any other physical technique.
Download or read book The Environmental Chemistry of Aluminum written by Garrison Sposito and published by CRC Press. This book was released on 2020-04-08 with total page 477 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Environmental Chemistry of Aluminum provides a comprehensive, fundamental account of the aqueous chemistry of aluminum within an environmental context. An excellent reference for environmental chemists and scientific administrators of environmental programs, this book contains material reflecting the many recent changes in this rapidly developing discipline. The first three chapters discuss the most fundamental aspects of aluminum chemistry: its quantitation in soils and natural waters, including speciation measurements, and its stable chemical forms, both as a dissolved solute and in a solid phase. These chapters emphasize both critical assessments of and definitive recommendations for laboratory methodologies and measured thermodynamic properties relating to aluminum chemistry. The next four chapters in The Environmental Chemistry of Aluminum build on this foundation to provide details of the polymeric chemistry of aluminum: its polynuclear and colloidal hydrolytic species in aqueous solution, its complexes with natural organic ligands, including humic substances, and its role as an adsorptive and adsorbent in surface reactions. These chapters are grounded in experimental results rather than conceptual modeling. The final three chapters describe the chemistry of aluminum in soils, waters, and watersheds. These chapters illustrate the problems of spatial and temporal variability, metastability, and scale that continue to make aluminum geochemistry one of the great challenges in modern environmental science.
Download or read book Electron Paramagnetic Resonance written by John A. Weil and published by John Wiley & Sons. This book was released on 2007-01-09 with total page 690 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an introduction to the underlying theory, fundamentals, and applications of EPR spectroscopy, as well as new developments in the area. Knowledge of the topics presented will allow the reader to interpret of a wide range of EPR spectra, as well as help them to apply EPR techniques to problem solving in a wide range of areas: organic, inorganic, biological, and analytical chemistry; chemical physics, geophysics, and minerology. Includes updated information on high frequency and multi-frequency EPR, pulsed microwave techniques and spectra analysis, dynamic effects, relaxation phenomena, computer-based spectra simulation, biomedical aspects of EPR, and more Equips readers with sufficient knowledge of EPR techniques to go on in their specialized area of interest Provides problem sets and concise bibliographies at the end of each chapter, plus several tutorial appendices on topics like mathematical operations, quantum mechanics of angular momentum, experimental considerations.
Download or read book Perchloric Acid and Perchlorates written by Alfred Ayars Schilt and published by . This book was released on 1979 with total page 189 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Electrochemical Methods written by Allen J. Bard and published by Wiley Global Education. This book was released on 2012-04-13 with total page 862 pages. Available in PDF, EPUB and Kindle. Book excerpt: Das führende Werk auf seinem Gebiet - jetzt durchgängig auf den neuesten Stand gebracht! Die theoretischen Grundlagen der Elektrochemie, erweitert um die aktuellsten Erkenntnisse in der Theorie des Elektronentransfers, werden hier ebenso besprochen wie alle wichtigen Anwendungen, darunter modernste Verfahren (Ultramikroelektroden, modifizierte Elektroden, LCEC, Impedanzspektrometrie, neue Varianten der Pulsvoltammetrie und andere). In erster Linie als Lehrbuch gedacht, läßt sich das Werk aber auch hervorragend zum Selbststudium und zur Auffrischung des Wissensstandes verwenden. Lediglich elementare Grundkenntnisse der physikalischen Chemie werden vorausgesetzt.
Download or read book Optoelectronic Properties of Inorganic Compounds written by D. Max Roundhill and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 422 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is intended to offer the reader a snapshot of the field of optoelectronic materials from the viewpoint of inorganic chemists. The field of inorganic chemistry is transforming from one focused on the synthesis of compounds having interesting coordination numbers, structures, and stereochemistries, to one focused on preparing compounds that have potentially useful practical applica tions. Two such applications are in the area of optics and electronics. These are fields where the use of inorganic materials has a long history. As the field of microelectronics develops the demands on the performance of such materials increases, and it becomes necessary to discover compounds that will meet these demands. The field of optoelectronics represents a merging of the two disciplines. Its emergence is a natural one because many of the applications involve both of these properties, and also because the electronic structure of a metal compound that confers novel optical properties is often one that also influences its electron transfer and conductivity characteristics. Two of the more important growth areas that have led to these developments are communications and medicine. Within the communications field there is the microelectronics that is involved in information storage and transmittal, some of which will be transferred into the optical regime. Within the medical field there are chemical probes that transmit analytical information from an in vivo environment. This information needs to be readily accessible from an external site, and then quickly converted into images or data that yield accurate and inexpensive diagnoses.
Download or read book Inorganic Syntheses Volume 32 written by and published by John Wiley & Sons. This book was released on 2009-09-22 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Inorganic Synthesis Series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds. This new volume includes information on water-solubilizing ligands for organometallics, labile ligand complexes, and the syntheses of cluster compounds and hydrides.
Download or read book Macromolecular Metal Carboxylates and Their Nanocomposites written by Anatolii D. Pomogailo and published by Springer Science & Business Media. This book was released on 2010-09-02 with total page 311 pages. Available in PDF, EPUB and Kindle. Book excerpt: Data on the synthesis and physicochemical studies of salts of mono- or dibasic unsaturated carboxylic acids and macromolecular metal carboxylates are generalised and described systematically in this monograph. The structures and properties of the COO group in various compounds and characteristic features of the structures of carboxylate are analysed. The main routes and kinetics of polymerisation transformations of unsaturated metal carboxylates are considered. The attention is focused on the effect of the metal ion on the monomer reactivity and the polymer morphology and structure. The possibility of stereochemical control of radical polymerisation of unsaturated metal carboxylates is demonstrated. The electronic, magnetic, optical, absorption and thermal properties of metal (co)polymers and nanocomposites and their main applications are also considered.
Download or read book Inorganic and Organometallic Reaction Mechanisms written by Jim D. Atwood and published by John Wiley & Sons. This book was released on 1997-02-18 with total page 327 pages. Available in PDF, EPUB and Kindle. Book excerpt: Jetzt in neuer Auflage: Das erfolgreiche Lehrwerk über Kinetik und Mechanismen anorganischer und organometallischer Reaktionen für fortgeschrittene Studenten! Hervorragend geeignet als Begleiter eines Vorlesungssemesters. Mit zahlreichen Übungsaufgaben; für eine bessere Übersicht sorgen Zusammenfassungen am Ende jedes Kapitels.
Download or read book Hydrogen Transfer Reactions written by Gabriela Guillena and published by Springer. This book was released on 2016-09-27 with total page 393 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
Download or read book Bioinorganic Chemistry of Copper written by K.D. Karlin and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 510 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioinorganic Chemistry of Copper focuses on the vital role of copper ions in biology, especially as an essential metalloenzyme cofactor. The book is highly interdisciplinary in its approach--the outstanding list of contributors includes coordination chemists, biochemists, biophysicists, and molecular biologists. Chapters are grouped into major areas of research interest in inorganic copper chemistry, spectroscopy, oxygen chemistry, biochemistry, and molecular biology. The book also discusses basic research of great potential importance to pharmaceutical scientists. This book is based on the first Johns Hopkins University Copper Symposium, held in August 1992. Researchers in chemistry, biochemistry, molecular biology, and medicinal chemistry will find it to be an essential reference on its subject.
Download or read book Magnetism written by Joel S. Miller and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 395 pages. Available in PDF, EPUB and Kindle. Book excerpt: Combining the contemporary knowledge from widely scattered sources, this is a much-needed and comprehensive overview of the field. In maintaining a balance between theory and experiment, the book guides both advanced students and specialists to this research area. Topical reviews written by the foremost scientists explain recent trends and advances, focusing on the correlations between electronic structure and magnetic properties. The book spans recent trends in magnetism for molecules -- as well as inorganic-based materials, with an emphasis on new phenomena being explored from both experimental and theoretical viewpoints with the aim of understanding magnetism on the atomic scale. The volume helps readers evaluate their own experimental observations and serves as a basis for the design of new magnetic materials. Topics covered include: * Metallocenium Salts of Radical Anion Bis-(dichalcogenate) metalates * Chiral Molecule-Based Magnets * Cooperative Magnetic Behavior in Metal-Dicyanamide Complexes * Lanthanide Ions in Molecular Exchange Coupled Systems * Monte Carlo Simulation * Metallocene-Based Magnets * Magnetic Nanoporous Molecular Materials A unique reference work, indispensable for everyone concerned with the phenomena of magnetism.
Download or read book The Chemistry of Organic Derivatives of Gold and Silver written by Saul Patai and published by Wiley-Blackwell. This book was released on 1999-10-18 with total page 768 pages. Available in PDF, EPUB and Kindle. Book excerpt: The 100th volume in this highly successful and renowned Patai andRappoport series 'The Chemistry of Functional Groups' is fittinglydevoted to the precious metals, gold and silver. Gold is a soft metal occurring naturally as particles in quartz oras nuggets. Gold was initially used extensively in coinage andjewellery and has recently found applications in biochemistry,medicine and material science. Gold readily forms organometalliccompounds (R-Au-L with L = sulphide, phosphine and isocyanide),oxides and halides. Silver is a ductile metal which was used incoinage and for mirrors. It is now used for jewellery, electricalconductors, dental and surgical components. Silver forms stablesilver halides for use in Photography and i.r. spectroscopy as asupport material. Other silver compounds are also used incatalysis. This volume contains 16 chapters dealing with calculations onorganogold compounds, physical and spectroscopic properties (NMR,ESR, PES, Mossbauer spectra), thermochemical and analyticalproperties, the synthesis and uses of the title compounds and theirreactions such as rearrangements, pyrolysis and photochemicalreactions. The medicinal use of organogold compounds and theincreased use of gold-thiol monolayers are also summarized. Each of the chapters has been prepared by leading scientists inthis field making this volume invaluable for researchers inacademia and industry working with gold and silver, inbiochemistry, pharmaceutical and materials chemistry. Organic compunds containg Nitrogen are of outstanding importnce inbiochemistry and in environmental systems. This volume gives asound introduction into physical chemistry of amino, nitriso, nitroand related functional groups. This volume is now available in electronic format from BooksOnline.
Download or read book The Chemistry of Ruthenium written by E.A. Seddon and published by Elsevier. This book was released on 2013-10-22 with total page 1414 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Ruthenium is concerned with the chemistry of ruthenium, with emphasis on synthesis and structure. The discussion spans a wide range of fields, from coordination chemistry and organometallic chemistry to structural chemistry (of both molecular and extended lattices), electrochemistry and photochemistry, as well as kinetics and spectroscopy. Comprised of 15 chapters, this book begins with an introduction to the discovery and early history of ruthenium, along with its extraction and purification, isotopes, physical and chemical properties, and applications. The discussion then turns to the concept of oxidation state and a scheme for systematizing descriptive inorganic chemistry together with its applicability to ruthenium chemistry. Subsequent chapters focus on the chemistry of ruthenium(VIII), ruthenium(VII), ruthenium(VI), ruthenium(V), ruthenium(IV), ruthenium(III), ruthenium(II), ruthenium(I), and ruthenium(0). The book also considers ruthenium carbonyl clusters and nitrosyls before concluding with a review of the photophysics and photochemistry of tris(diimine)ruthenium(II) complexes. This monograph will be useful to students, practitioners, and researchers in the field of inorganic chemistry, as well as those who are interested in the chemistry of ruthenium.
Download or read book Exchange Reactions written by and published by . This book was released on 1965 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt:
