Download or read book Well to wheels Analysis of Fast Pyrolysis Pathways with the GREET Model written by and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The pyrolysis of biomass can help produce liquid transportation fuels with properties similar to those of petroleum gasoline and diesel fuel. Argonne National Laboratory conducted a life-cycle (i.e., well-to-wheels [WTW]) analysis of various pyrolysis pathways by expanding and employing the Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model. The WTW energy use and greenhouse gas (GHG) emissions from the pyrolysis pathways were compared with those from the baseline petroleum gasoline and diesel pathways. Various pyrolysis pathway scenarios with a wide variety of possible hydrogen sources, liquid fuel yields, and co-product application and treatment methods were considered. At one extreme, when hydrogen is produced from natural gas and when bio-char is used for process energy needs, the pyrolysis-based liquid fuel yield is high (32% of the dry mass of biomass input). The reductions in WTW fossil energy use and GHG emissions relative to those that occur when baseline petroleum fuels are used, however, is modest, at 50% and 51%, respectively, on a per unit of fuel energy basis. At the other extreme, when hydrogen is produced internally via reforming of pyrolysis oil and when bio-char is sequestered in soil applications, the pyrolysis-based liquid fuel yield is low (15% of the dry mass of biomass input), but the reductions in WTW fossil energy use and GHG emissions are large, at 79% and 96%, respectively, relative to those that occur when baseline petroleum fuels are used. The petroleum energy use in all scenarios was restricted to biomass collection and transportation activities, which resulted in a reduction in WTW petroleum energy use of 92-95% relative to that found when baseline petroleum fuels are used. Internal hydrogen production (i.e., via reforming of pyrolysis oil) significantly reduces fossil fuel use and GHG emissions because the hydrogen from fuel gas or pyrolysis oil (renewable sources) displaces that from fossil fuel natural gas and the amount of fossil natural gas used for hydrogen production is reduced; however, internal hydrogen production also reduces the potential petroleum energy savings (per unit of biomass input basis) because the fuel yield declines dramatically. Typically, a process that has a greater liquid fuel yield results in larger petroleum savings per unit of biomass input but a smaller reduction in life-cycle GHG emissions. Sequestration of the large amount of bio-char co-product (e.g., in soil applications) provides a significant carbon dioxide credit, while electricity generation from bio-char combustion provides a large energy credit. The WTW energy and GHG emissions benefits observed when a pyrolysis oil refinery was integrated with a pyrolysis reactor were small when compared with those that occur when pyrolysis oil is distributed to a distant refinery, since the activities associated with transporting the oil between the pyrolysis reactors and refineries have a smaller energy and emissions footprint than do other activities in the pyrolysis pathway.

Download or read book Fuel Production from Non Food Biomass written by Barnabas Gikonyo and published by CRC Press. This book was released on 2015-05-05 with total page 345 pages. Available in PDF, EPUB and Kindle. Book excerpt: This title includes a number of Open Access chapters.The practice of converting corn to ethanol is controversial, with debates currently being raged in both public policy and science. While biofuels from corn have important implications in alleviating some of the global energy crisis, critics argue that it takes away from vital agricultural pr

Download or read book Efficiency and Sustainability in Biofuel Production written by Barnabas Gikonyo and published by CRC Press. This book was released on 2015-05-08 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: This title includes a number of Open Access chapters.The world's interest in reducing petroleum use has led to the rapid development of the biofuel industry over the past decade or so. However, there is increasing concern over how current food-based biofuels affect both food security and the environment. Second-generation biofuels, however, use wid

Download or read book Biofuels from Lignocellulosic Biomass written by Michael Boot and published by John Wiley & Sons. This book was released on 2016-08-01 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by experts in combustion technology, this is a unique and refreshing perspective on the current biofuel discussion, presenting the latest research in this important field. The emphasis throughout this reference is on applications, industrial perspectives and economics, focusing on new classes of biofuels such as butanols, levulinates, benzenoids and others. Clearly structured, each chapter presents a new class of biofuel and discusses such topics as production pathways, fuel properties and its impact on engines. The result is a fascinating, user-oriented overview of new classes of biofuels beyond bioethanol.

Download or read book Lignocellulose Conversion written by Vincenza Faraco and published by Springer Science & Business Media. This book was released on 2013-06-12 with total page 207 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioethanol has been recognized as a potential alternative to petroleum-derived transportation fuels. Even if cellulosic biomass is less expensive than corn and sugarcane, the higher costs for its conversion make the near-term price of cellulosic ethanol higher than that of corn ethanol and even more than that of sugarcane ethanol. Conventional process for bioethanol production from lignocellulose includes a chemical/physical pre-treatment of lignocellulose for lignin removal, mostly based on auto hydrolysis and acid hydrolysis, followed by saccharification of the free accessible cellulose portions of the biomass. The highest yields of fermentable sugars from cellulose portion are achieved by means of enzymatic hydrolysis, currently carried out using a mix of cellulases from the fungus Trichoderma reesei. Reduction of (hemi)cellulases production costs is strongly required to increase competitiveness of second generation bioethanol production. The final step is the fermentation of sugars obtained from saccharification, typically performed by the yeast Saccharomyces cerevisiae. The current process is optimized for 6-carbon sugars fermentation, since most of yeasts cannot ferment 5-carbon sugars. Thus, research is aimed at exploring new engineered yeasts abilities to co-ferment 5- and 6-carbon sugars. Among the main routes to advance cellulosic ethanol, consolidate bio-processing, namely direct conversion of biomass into ethanol by a genetically modified microbes, holds tremendous potential to reduce ethanol production costs. Finally, the use of all the components of lignocellulose to produce a large spectra of biobased products is another challenge for further improving competitiveness of second generation bioethanol production, developing a biorefinery.

Download or read book Life Cycle Assessment written by Aiduan Borrion and published by Royal Society of Chemistry. This book was released on 2021-03-19 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: Life cycle assessment (LCA) is an established methodology used to quantify the environmental impacts of products, processes and services. Circular economy (CE) thinking is conceptual way of considering the impacts of consuming resources. By taking a closed loop approach, CE provides a framework for influencing behaviours and practices to minimise this impact. Development of the circular economy is a crucial component in the progression towards future sustainability. This book provides a robust systematic approach to the circular economy concept, using the established methodology of LCA. Including chapters on circular economic thinking, the use of LCA as a metric and linking LCA to the wider circular economy, this book utilises case studies to illustrate the approaches to LCA. With contributions from researchers worldwide, Life Cycle Assessment provides a practical, global guide for those who wish to use LCA as a research tool or to inform policy, process, and product improvement.

Download or read book Fast Pyrolysis of Biomass written by Robert C Brown and published by Royal Society of Chemistry. This book was released on 2017-06-30 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fast pyrolysis and related catalytic pyrolysis are of increasing interest as pathways to advanced biofuels that closely mimic traditional petroleum products. Research has moved from empirical investigations to more fundamental studies of pyrolysis mechanisms. Theories on the chemical and physical pathways from plant polymers to pyrolysis products have proliferated as a result. This book brings together the latest developments in pyrolysis science and technology. It examines, reviews and challenges the unresolved and sometimes controversial questions about pyrolysis, helping advance the understanding of this important technology and stimulating discussion on the various competing theories of thermal deconstruction of plant polymers. Beginning with an introduction to the biomass-to-biofuels process via fast pyrolysis and catalytic pyrolysis, chapters address prominent questions such as whether free radicals or concerted reactions dominate deconstruction reactions. Finally, the book concludes with an economic analysis of fast pyrolysis versus catalytic pyrolysis. This book will be of interest to advanced students and researchers interested in the science behind renewable fuel technology, and particularly the thermochemical processing of biomass.

Download or read book Transportation Biofuels written by Alwin Hoogendoorn and published by Royal Society of Chemistry. This book was released on 2011 with total page 203 pages. Available in PDF, EPUB and Kindle. Book excerpt: Current world fossil oil production is struggling to meet demand and may even show a decline after 2010. It is therefore necessary to develop new energy-efficient production pathways for transportation biofuels. This book offers an insight into three promising and innovative pathways for the biological production of ethanol, biogas and biodiesel. These unconventional methods should provide higher product yields, less stringent feedstock specifications, lower chemical additive demand, reduced waste production and much better energy balances when compared to more traditional methods. One pathway concerns the enzymatic production of a new kind of biodiesel where no glycerol waste is produced and an up to twenty percent higher product yield is obtained. The other two pathways are based on the biological conversion of syngas into ethanol or methane using various kinds of lignocellulosic biomass as the starting point. For each of the three pathways a comparison will be made with competing production methods. The contents reflect extended desktop research and show practical experimental results. Government scientists, academics and biofuel producers with an interest in novel transportation fuels will all find this book to be essential reading.

Download or read book Ex Situ Catalytic Fast Pyrolysis Technology Pathway written by and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline, diesel and jet range blendstocks . Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Download or read book Biofuels for Aviation written by Christopher Chuck and published by Academic Press. This book was released on 2016-06-02 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biofuels for Aviation: Feedstocks, Technology and Implementation presents the issues surrounding the research and use of biofuels for aviation, such as policy, markets, certification and performance requirements, life cycle assessment, and the economic and technical barriers to their full implementation. Readers involved in bioenergy and aviation sectors—research, planning, or policy making activities—will benefit from this thorough overview. The aviation industry's commitment to reducing GHG emissions along with increasing oil prices have sparked the need for renewable and affordable energy sources tailored to this sector's very specific needs. As jet engines cannot be readily electrified, turning to biofuels is the most viable option. However, aviation is a type of transportation for which traditional biofuels, such as bioethanol and biodiesel, do not fulfill key fuel requirements. Therefore, different solutions to this situation are being researched and tested around the globe, which makes navigating this scenario particularly challenging. This book guides readers through this intricate subject, bringing them up to speed with its current status and future prospects both from the academic and the industry point of view. Science and technology chapters delve into the technical aspects of the currently tested and the most promising technology in development, as well as their respective feedstocks and the use of additives as a way of adapting them to meet certain specifications. Conversion processes such as hydrotreatment, synthetic biology, pyrolysis, hydrothermal liquefaction and Fisher-Tropsch are explored and their results are assessed for current and future viability. - Presents the current status of biofuels for the aviation sector, including technologies that are currently in use and the most promising future technologies, their production processes and viability - Explains the requirements for certification and performance of aviation fuels and how that can be achieved by biofuels - Explores the economic and policy issues, as well as life cycle assessment, a comparative techno-economic analysis of promising technologies and a roadmap to the future - Explores conversion processes such as hydrotreatment, synthetic biology, pyrolysis, hydrothermal liquefaction and Fisher-Tropsch

Download or read book Sustainable Development of Algal Biofuels in the United States written by National Research Council and published by National Academies Press. This book was released on 2013-01-18 with total page 247 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biofuels made from algae are gaining attention as a domestic source of renewable fuel. However, with current technologies, scaling up production of algal biofuels to meet even 5 percent of U.S. transportation fuel needs could create unsustainable demands for energy, water, and nutrient resources. Continued research and development could yield innovations to address these challenges, but determining if algal biofuel is a viable fuel alternative will involve comparing the environmental, economic and social impacts of algal biofuel production and use to those associated with petroleum-based fuels and other fuel sources. Sustainable Development of Algal Biofuels was produced at the request of the U.S. Department of Energy.

Download or read book In Situ Catalytic Fast Pyrolysis Technology Pathway written by and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline, diesel, and jet range blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Download or read book Biofuels for Transport written by International Energy Agency and published by OECD. This book was released on 2004 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the absence of strong government policies, the IEA projects that the worldwide use of oil in transport will nearly double between 2000 and 2030, leading to a similar increase in greenhouse gas emissions. Bio fuels, such as ethanol, bio diese

Download or read book Introduction to Biomass Energy Conversions written by Sergio Capareda and published by CRC Press. This book was released on 2013-07-09 with total page 649 pages. Available in PDF, EPUB and Kindle. Book excerpt: The potential that biomass energy has to supplement traditional fuels and reduce greenhouse gas emissions has put it front and center in the plan to replace fossil-based fuels with renewable fuels. While much has been written about biomass conversions, no single textbook contains all the information needed to teach a biomass conversion course—until now. Introduction to Biomass Energy Conversions presents a comprehensive review of biomass resources available for conversion into heat, power, and biofuels. The textbook covers biomass characterization and discusses facilities, equipment, and standards (e.g. ASTM or NREL) used for analysis. It examines the range of biomass resources available for conversion and presents traditional biomass conversion processes along with extensive biomass characterization data tables, illustrations, and graphical presentations of the various biomass energy conversion processes. The author also describes how to set up a laboratory for biomass energy conversion, and presents economics and sustainability issues. Loaded with real-world examples, the text includes numerous worked examples and problems in each chapter. No one knows what the price of oil will be next year or in future decades. It is governed by many factors other than supply and demand (politics, wars, etc.), however, whatever the future of energy is, bio-fuels will play an important role. This technical guide prepares students for managing bio-refineries, no matter what type of bio-fuel is produced. It also provides practicing engineers with a resource for starting a small bio-fuel business.

Download or read book Hydrogen Technology written by Aline Léon and published by Springer Science & Business Media. This book was released on 2008-07-18 with total page 680 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aline Leon ́ In the last years, public attention was increasingly shifted by the media and world governmentsto the conceptsof saving energy,reducingpollution,protectingthe - vironment, and developing long-term energy supply solutions. In parallel, research funding relating to alternative fuels and energy carriers is increasing on both - tional and international levels. Why has future energy supply become such a matter of concern? The reasons are the problems created by the world’s current energy supply s- tem which is mainly based on fossil fuels. In fact, the energystored in hydrocarb- based solid, liquid, and gaseous fuels was, is, and will be widely consumed for internal combustion engine-based transportation, for electricity and heat generation in residential and industrial sectors, and for the production of fertilizers in agric- ture, as it is convenient, abundant, and cheap. However, such a widespread use of fossil fuels by a constantly growing world population (from 2. 3 billion in 1939 to 6. 5 billion in 2006) gives rise to the two problems of oil supply and environmental degradation. The problemrelated to oil supply is caused by the fact that fossil fuels are not - newable primary energy sources: This means that since the rst barrel of petroleum has been pumped out from the ground, we have been exhausting a heritage given by nature.

Download or read book Microbial Technologies in Advanced Biofuels Production written by Patrick C. Hallenbeck and published by Springer Science & Business Media. This book was released on 2011-12-16 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: Concerns over dwindling fossil fuel reserves and impending climate changes have focused attention worldwide on the need to discover alternative, sustainable energy sources and fuels. Biofuels, already produced on a massive industrial scale, are seen as one answer to these problems. However, very real concerns over the effects of biofuel production on food supplies, with some of ht recent increases in worldwide food costs attributable to biofuel production, have lead to the realization that new, non-food substrates for biofuel production must be bought online. This book is an authoritative, comprehensive, up-to-date review of the various options under development for the production of advanced biofuels as alternative energy sources. A general overview and introductory chapters for each section place the field in the context as well as provide essential basic notions for the more general reader. Accomplished, internationally recognized experts carrying out research on individual focus areas contribute specific technical chapters detailing present progress and future prospects.

Download or read book Hydrogen and Fuel Cells written by International Energy Agency and published by Simon and Schuster. This book was released on 2004 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrogen and fuel cells are vital technologies to ensure a secure and CO2-free energy future. Their development will take decades of extensive public and private effort to achieve technology breakthroughs and commercial maturity. Government research programs are indispensable for catalyzing the development process. This report maps the IEA countries' current efforts to research, develop and deploy the interlocking elements that constitute a "hydrogen economy", including CO2 capture and storage when hydrogen is produced out of fossil fuels. It provides an overview of what is being done, and by whom, covering an extensive complexity of national government R & D programs. The survey highlights the potential for exploiting the benefits of the international cooperation. This book draws primarily upon information contributed by IEA governments. In virtually all the IEA countries, important R & D and policy efforts on hydrogen and fuel cells are in place and expanding. Some are fully-integrated, government-funded programs, some are a key element in an overall strategy spread among multiple public and private efforts. The large amount of information provided in this publication reflects the vast array of technologies and logistics required to build the "hydrogen economy."--Publisher description.