Download or read book Investigation of Volatile Organic Compounds VOCs Detected at Vapor Intrusion Sites written by Mohammadyousef Roghani and published by . This book was released on 2018 with total page 217 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Vapor Intrusion of VOCs written by Environmental & Occupational Health Assessment Program (Conn.) and published by . This book was released on 2012 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Vapor Intrusion of Contamination from Soil and Groundwater Into Indoor Air written by and published by . This book was released on 2005 with total page 40 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Vapor Intrusion Simulations and Risk Assessments written by Yijun Yao and published by Springer Nature. This book was released on 2022-07-25 with total page 133 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book introduces key concepts in modeling and risk assessments of vapor intrusion, a process by which the subsurface volatile contaminants migrate into the building of concern. Soil vapor intrusion is the major exposure pathway for building occupants to chemicals from the subsurface, and its risk assessments determine the criteria of volatile contaminants in soil/groundwater in brownfield redevelopment. The chapters feature the recent advances in vapor intrusion studies and practices, including analytical and numerical modeling of vapor intrusion, statistical findings of United States Environmental Protection Agency’s Vapor Intrusion Database and Petroleum Vapor Intrusion Databases, the challenges of preferential pathways, and the application of building pressure cycling methods, and field practices of vapor intrusion risk assessments at developed contaminated sites and in brownfield redevelopment. This volume also summarizes the advantages and limits of current applications in vapor intrusion risk assessment, laying the groundwork for future research of better understanding in risk characterization of soil vapor intrusion using models. Written by experts in this field, Vapor Intrusion Simulations and Risk Assessments will serve as an invaluable reference for researchers, regulators, and practitioners, who are interested in perceiving the basic knowledge and current advances in risk assessments of soil vapor intrusion.
Download or read book Vapor Intrusion Modeling written by Jessica Marie Friscia and published by . This book was released on 2014 with total page 127 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vapor intrusion is the migration of volatile organic compounds (VOCs) from a subsurface source into the indoor air of an overlying building. Vapor intrusion models, including the Johnson and Ettinger (J&E) model, can be used to predict the concentration of VOCs in the indoor air of a building based on a measured subsurface soil gas concentration or contaminant source concentrations, either in non-aqueous phase liquid (NAPL), groundwater, or soil. An analysis of two of the EPA-implemented J&E spreadsheet models, one that considers subsurface soil gas data and one that considers groundwater data, was conducted. The governing equations, assumptions, and limitations of these spreadsheet models were investigated. A value of information (Vol) worksheet was developed that can assist practitioners in deciding what additional data to collect as part of a remedial investigation. The Vol worksheet calculates how varying values of model input parameters affect the model-predicted indoor air carcinogenic risk. The worksheet then compares the user-defined target risk to the range of potential risk values for different combinations of varying parameters. The results of this analysis allow the user to determine which groups of parameters have the most impact on the model results. This information can assist the practitioner in deciding whether or not to collect additional data to reduce the uncertainty in the input parameters. The EPA J&E soil gas and groundwater spreadsheet models, as well as the Vol worksheet developed for each model, were applied to case study data for a trichloroethylene-impacted site in Rhode Island. The results of the J&E model and Vol worksheet analyses for this case study predicted incremental carcinogenic risk values for trichloroethylene (TCE) below the risk value calculated based on measured indoor air data. This comparison suggests the potential for other sources of TCE within the building. Groups of parameters were identified for each model that impacted the model-predicted carcinogenic risk. The development of a cost-benefit analysis, which would be used to quantify the value of obtaining additional data for these critical parameters, is recommended for future research.
Download or read book Analysis of Vapor Intrusion of Volatile Organic Compounds from the Subsurface Into Buildings written by Michael A. Lesakowski (Jr) and published by . This book was released on 2008 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Accuracy of Three Screening level Vapor Intrusion Models for Indoor Air written by and published by . This book was released on 2016 with total page 117 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vapor intrusion models were developed to predict indoor air concentrations from subsurface sources and then calculate an associated risk using toxicological data and exposure scenarios for the building occupants. Prior to the issuance of final guidance documents in 2015, the United States Environmental Protection Agency (USEPA) guidance on vapor intrusion was in draft form since November 2002. This delay between the draft version and the final guidelines resulted in the utilization of varying methodologies for assessing vapor intrusion by the regulated community and as well as the regulators at both state and local levels. The purpose of this study was to evaluate the accuracy of screening-level vapor intrusion models, using soil vapor samples collected from three sites with known or suspected contamination, and to compare the predicted indoor air results with measured indoor air results. The models evaluated were the County of San Diego Department of Environmental Health Vapor Risk 2000 Model, the Department of Toxic Substances Control (DTSC) version of the Johnson and Ettinger Model (J&E Model), and the USEPA, Office of Solid Waste and Emergency Response (OSWER), Vapor Intrusion Screening Level Calculator (VISLC). The results of this study found that the Vapor Risk 2000 Model more accurately predicts indoor air concentrations, followed by the J&E Model and VISLC. While the Vapor Risk 2000 Model more closely predicts the indoor air concentration, it does have a tendency to underpredict. Due to the underpredictions, there is more potential for false negatives (i.e., screening out sites that do have a potential for vapor intrusion. Similar to previous studies, this study found the Vapor Risk 2000 and J&E Models both over and under predict the indoor air concentrations. This may not necessarily be a reflection on the model’s prediction ability, but rather the complexity of vapor intrusion and the confounders of indoor air. Combined with additional lines of evidence (e.g., indoor air sampling), these screening-level vapor intrusion models can assist decision makers in screening in or out sites that are susceptible to vapor intrusion.
Download or read book Contaminated Water Supplies at Camp Lejeune written by National Research Council and published by National Academies Press. This book was released on 2009-09-06 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the early 1980s, two water-supply systems on the Marine Corps Base Camp Lejeune in North Carolina were found to be contaminated with the industrial solvents trichloroethylene (TCE) and perchloroethylene (PCE). The water systems were supplied by the Tarawa Terrace and Hadnot Point watertreatment plants, which served enlisted-family housing, barracks for unmarried service personnel, base administrative offices, schools, and recreational areas. The Hadnot Point water system also served the base hospital and an industrial area and supplied water to housing on the Holcomb Boulevard water system (full-time until 1972 and periodically thereafter). This book examines what is known about the contamination of the water supplies at Camp Lejeune and whether the contamination can be linked to any adverse health outcomes in former residents and workers at the base.
Download or read book Brownfields Technology Primer written by and published by . This book was released on 2008 with total page 52 pages. Available in PDF, EPUB and Kindle. Book excerpt: "This primer is designed for land revitalization stakeholders concerned about vapor intrusion, including property owners, municipalities, and real estate developers. It provides an overview of the vapor intrusion issue and how it can affect redevelopment. It also summarizes techniques for quickly and cost effectively assessing the potential for vapor intrusion, as well as techniques for mitigating it. The topics covered will familiarize stakeholders with options for addressing vapor intrusion to help them communicate with their project contractors and consultants."--Page 1.
Download or read book Natural Attenuation of Fuels and Chlorinated Solvents in the Subsurface written by Todd H. Wiedemeier and published by John Wiley & Sons. This book was released on 1999-03-08 with total page 634 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first comprehensive guide to one of today's most innovative approaches to environmental contamination Natural attenuation is gaining increasing attention as a nonintrusive, cost-effective alternative to standard remediation techniques for environmental contamination. This landmark work presents the first in-depth examination of the theory, mechanisms, and application of natural attenuation. Written by four internationally recognized leaders in this approach, the book describes both biotic and abiotic natural attenuation processes, focusing on two of the environmental contaminants most frequently encountered in groundwater--fuels and chlorinated solvents. The authors draw on a wealth of combined experience to detail successful techniques for simulating natural attenuation processes and predicting their effectiveness in the field. They also show how natural attenuation works in the real world, using numerous examples and case studies from a wide range of leading-edge projects nationwide involving fuel hydrocarbons and chlorinated solvents. Finally, they discuss the evaluation and assessment of natural attenuation and explore the design of long-term monitoring programs. An indispensable reference for anyone working in environmental remediation, Natural Attenuation of Fuels and Chlorinated Solvents in the Subsurface is essential reading for scientists and engineers in a range of industries, as well as state and federal environmental regulators, and professors and graduate students in environmental or chemical engineering.
Download or read book EPA s Vapor Intrusion Database written by Helen E. Dawson and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book In Situ Chemical Oxidation for Groundwater Remediation written by Robert L. Siegrist and published by Springer Science & Business Media. This book was released on 2011-02-25 with total page 715 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume provides comprehensive up-to-date descriptions of the principles and practices of in situ chemical oxidation (ISCO) for groundwater remediation based on a decade of intensive research, development, and demonstrations, and lessons learned from commercial field applications.
Download or read book Volatile Organic Compounds VOCs In Indoor Air written by Todd A. Wetzel and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Indoor air concentrations of volatile organic compounds (VOCs), including many with documented adverse health effects, vary widely but are generally higher than found outdoors. Volatile organic compounds can enter indoor environments via internal (e.g. paints, paint strippers, fuels, cleaning supplies, pesticides, building materials, adhesives) and external sources (e.g. vapor intrusion (VI) from contaminated soil and/or groundwater and ambient air from automobiles and industrial facilities). Since many consumer products contain volatile organic compounds (VOCs) that are also the focus of soil and groundwater cleanup projects, emissions of these VOCs can lead to false source identifications during VI investigations. Laboratory-measured emissions of VOCs from several consumer products were used with a standard box model to predict indoor air concentrations. The predicted concentrations were compared to measured values generated by introducing the same consumer products into an actual residence. The screening level agreement between measured and estimated air concentrations suggests that a standard box model can be used with laboratory measured emission rates to show if an emission source can cause a potential health risk or lead to false assumption during VI investigations. The use of plant leaves as a simple, cost-effective and sustainable approach to sampling indoor air concentrations of VOCs was also investigated in three studies: 1) a headspace approach; 2) a flow-through glass and stainless steel plant growth chamber, and 3) a house-scale study where plant leaf and air concentrations of VOC were simultaneously measured. Similar relationships between the leaf and air concentrations observed in the three studies suggest that plant leaf concentrations can be used as a surrogate for indoor air concentrations of VOCs.
Download or read book Fate and Transport of Subsurface Pollutants written by Pankaj Kumar Gupta and published by Springer Nature. This book was released on 2020-10-20 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume offers detailed information on the behaviour of various water pollutants, and on the principles and concepts of groundwater flow and transport. It will help readers to understand and execute the planning, supervision, and review of solute transport and groundwater modeling projects. The book also discusses the role and fate of elements that have been identified as major contaminants in surface and subsurface waters, and their adverse effects on ecology and human health. The book explores this theme throughout four sections – a. Understanding Soil-Water Systems, b. Fate and Transport of Pollutants, c. Physico-Chemical Treatment of Wastewater and d. Microbial Techniques Used to Decontaminate Soil-Water Systems. Introducing readers to a range of recent advances concerning the fundamentals of subsurface water treatment, it offers a valuable guide for teachers, researchers, policymakers, and undergraduate and graduate students of hydrology, environmental microbiology, biotechnology and the environmental sciences. It also provides field engineers and industrial practitioners with essential support in the effective remediation and management of polluted sites.
Download or read book EPA 402 R written by and published by . This book was released on 1993 with total page 58 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Dealing with Contaminated Sites written by Frank A. Swartjes and published by Springer Science & Business Media. This book was released on 2011-01-12 with total page 1121 pages. Available in PDF, EPUB and Kindle. Book excerpt: This standard work on contaminated site management covers the whole chain of steps involved in dealing with contaminated sites, from site investigation to remediation. An important focus throughout the book is on Risk Assessment. In addition, the book includes chapters on characterisation of natural and urban soils, bioavailability, natural attenuation, policy and stakeholder viewpoints and Brownfields. Typically, the book includes in-depth theories on soil contamination, along with offering possibilities for practical applications. More than sixty of the world’s top experts from Europe, the USA, Australia and Canada have contributed to this book. The twenty-five chapters in this book offer relevant information for experienced scientists, students, consultants and regulators, as well as for ‘new players’ in contaminated site management
Download or read book Demonstration and Validation of the Use of Passive Samplers for Monitoring Soil Vapor Intrusion to Indoor Air written by Todd Arthur McAlary and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis documents a demonstration/validation of passive diffusive samplers for assessing soil vapor, indoor air and outdoor air concentrations of volatile organic compounds (VOCs) at sites with potential human health risks attributable to subsurface vapor intrusion to indoor air. The study was funded by the United States (U.S.) Department of Defense (DoD) and the U.S. Department of the Navy (DoN). The passive samplers tested included: SKC Ultra and Ultra II, Radiello®, Waterloo Membrane Sampler (WMS), Automated Thermal Desorption (ATD) tubes, and 3M OVM 3500. The program included laboratory testing under controlled conditions for 10 VOCs (including chlorinated ethenes, ethanes, and methanes, as well as aromatic and aliphatic hydrocarbons), spanning a range of properties and including some compounds expected to pose challenges (naphthalene, methyl ethyl ketone). Laboratory tests were performed under conditions of different temperature (17 to 30 oC), relative humidity (30 to 90 % RH), face velocity (0.014 to 0.41 m/s), concentration (1 to 100 parts per billion by volume [ppbv]) and sample duration (1 to 7 days). These conditions were selected to challenge the samplers across a range of conditions likely to be encountered in indoor and outdoor air field sampling programs. A second set of laboratory tests were also conducted at 1, 10 and 100 parts per million by volume (ppmv) to evaluate concentrations of interest for soil vapor monitoring using the same 10 VOCs and constant conditions (80% RH, 30 min exposure, 22 oC). Inter-laboratory testing was performed to assess the variability attributable to the differences between several laboratories used in this study. The program also included field testing of indoor air, outdoor air, sub-slab vapor and deeper soil vapor at several DoD facilities. Indoor and outdoor air samples were collected over durations of 3 to 7 days, and Summa canister samples were collected over the same durations as the passive samples for comparison. Subslab and soil vapor samples were collected with durations ranging from 10 min to 12 days, at depths of about 15 cm (immediately below floor slabs), 1.2 m and 3.7 m. Passive samplers were employed with uptake rates ranging from about 0.05 to almost 100 mL/min and analysis by both thermal desorption and solvent extraction. Mathematical modeling was performed to provide theoretical insight into the potential behavior of passive samplers in the subsurface, and to help select those with uptake rates that would minimize the risk of a negative bias from the starvation effect (which occurs when a passive sampler with a high uptake rate removes VOC vapors from the surroundings faster than they are replenished, resulting in biased concentrations). A flow-through cell apparatus was tested as an option for sampling existing sub-surface probes that are too small to accommodate a passive sampler or sampling a slip-stream of a high-velocity gas (e.g., vent-pipes of mitigation systems). The results of this demonstration show that all of the passive samplers provided data that met the performance criteria for accuracy and precision (relative percent difference less than 45 % for indoor air or 50% for soil vapor compared to conventional active samples and a coefficient of variation less than 30%) under some or most conditions. Exceptions were generally attributable to one or more of five possible causes: poor retention of analytes by the sorbent in the sampler; poor recovery of the analytes from the sorbent; starvation effects, uncertainty in the uptake rate for the specific combination of sampler/compound/conditions, or blank contamination. High (or positive) biases were less common than low biases, and attributed either to blank contamination, or to uncertainty in the uptake rates. Most of the passive samplers provided highly reproducible results throughout the demonstrations. This is encouraging because the accuracy can be established using occasional inter-method verification samples (e.g., conventional samples collected beside the passive samples for the same duration), and the field-calibrated uptake rates will be appropriate for other passive samples collected under similar conditions. Furthermore, this research demonstrated for the first time that passive samplers can be used to quantify soil vapor concentrations with accuracy and precision comparable to conventional methods. Passive samplers are generally easier to use than conventional methods (Summa canisters and active ATD tubes) and minimal training is required for most applications. A modest increase in effort is needed to select the appropriate sampler, sorbent and sample duration for the site-specific chemicals of concern and desired reporting limits compared to Summa canisters and EPA Method TO-15. As the number of samples in a given program increases, the initial cost of sampling design becomes a smaller fraction of the overall total cost, and the passive samplers gain a significant cost advantage because of the simplicity of the sampling protocols and reduced shipping charges.
