Download or read book Thermodynamics of Phase Equilibria in Food Engineering written by Camila Gambini Pereira and published by Academic Press. This book was released on 2018-10-17 with total page 682 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermodynamics of Phase Equilibria in Food Engineering is the definitive book on thermodynamics of equilibrium applied to food engineering. Food is a complex matrix consisting of different groups of compounds divided into macronutrients (lipids, carbohydrates, and proteins), and micronutrients (vitamins, minerals, and phytochemicals). The quality characteristics of food products associated with the sensorial, physical and microbiological attributes are directly related to the thermodynamic properties of specific compounds and complexes that are formed during processing or by the action of diverse interventions, such as the environment, biochemical reactions, and others. In addition, in obtaining bioactive substances using separation processes, the knowledge of phase equilibria of food systems is essential to provide an efficient separation, with a low cost in the process and high selectivity in the recovery of the desired component. This book combines theory and application of phase equilibria data of systems containing food compounds to help food engineers and researchers to solve complex problems found in food processing. It provides support to researchers from academia and industry to better understand the behavior of food materials in the face of processing effects, and to develop ways to improve the quality of the food products. Presents the fundamentals of phase equilibria in the food industry Describes both classic and advanced models, including cubic equations of state and activity coefficient Encompasses distillation, solid-liquid extraction, liquid-liquid extraction, adsorption, crystallization and supercritical fluid extraction Explores equilibrium in advanced systems, including colloidal, electrolyte and protein systems
Download or read book Phase Equilibria in Chemical Engineering written by Stanley M. Walas and published by Butterworth-Heinemann. This book was released on 2013-10-22 with total page 689 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phase Equilibria in Chemical Engineering is devoted to the thermodynamic basis and practical aspects of the calculation of equilibrium conditions of multiple phases that are pertinent to chemical engineering processes. Efforts have been made throughout the book to provide guidance to adequate theory and practice. The book begins with a long chapter on equations of state, since it is intimately bound up with the development of thermodynamics. Following material on basic thermodynamics and nonidealities in terms of fugacities and activities, individual chapters are devoted to equilibria primarily between pairs of phases. A few topics that do not fit into these categories and for which the state of the art is not yet developed quantitatively have been relegated to a separate chapter. The chapter on chemical equilibria is pertinent since many processes involve simultaneous chemical and phase equilibria. Also included are chapters on the evaluation of enthalpy and entropy changes of nonideal substances and mixtures, and on experimental methods. This book is intended as a reference and self-study as well as a textbook either for full courses in phase equilibria or as a supplement to related courses in the chemical engineering curriculum. Practicing engineers concerned with separation technology and process design also may find the book useful.
Download or read book Phase Equilibrium in Mixtures written by M. B. King and published by Elsevier. This book was released on 2013-10-22 with total page 604 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phase Equilibrium in Mixtures deals with phase equilibrium and the methods of correlating, checking, and predicting phase data. Topics covered range from latent heat and vapor pressure to dilute solutions, ideal and near-ideal solutions, and consistency tests. Molecular considerations and their use for the prediction and correlation of data are also discussed. Comprised of nine chapters, this volume begins with an introduction to the role of thermodynamics and the criteria for equilibrium between phases, along with fugacity and the thermodynamic functions of mixing. The discussion then turns to some of the phase phenomena which may be encountered in chemical engineering practice; methods of correlating and extending vapor pressure data and practical techniques for calculating latent heats from these data; the behavior of dilute solutions both at low and high pressures for reacting and non-reacting systems; and the behavior of ideal and near-ideal solutions. The remaining chapters explore non-ideal solutions at normal pressures; practical methods for testing the thermodynamic consistency of phase data; and the extent to which the broad aspects of phase behavior may be interpreted in the light of simple molecular considerations. This book is intended primarily for graduate chemical engineers but should also be of interest to those graduates in physics or chemistry who need to use phase equilibrium data.
Download or read book The Thermodynamics of Phase and Reaction Equilibria written by Ismail Tosun and published by Newnes. This book was released on 2012-10-17 with total page 736 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides you with a sound foundation for understanding abstract concepts (eg physical properties such as fugacity, etc or chemical processes, ie distillation, etc) of phase and reaction equilibria and shows you how to apply these concepts to solve practical problems using numerous and clear examples.
Download or read book Phase Equilibria written by Andre Muhlbauer and published by CRC Press. This book was released on 1997-09-01 with total page 490 pages. Available in PDF, EPUB and Kindle. Book excerpt: This new book provides, for the first time, a thorough survey of the techniques and equipment for both high- and low-pressure phase equilibrium measurement and addresses the equally challenging task of accurately modeling or predicting the equilibria. The book is unique because it combines in depth and authoritative coverage of both experimental and theoretical procedures in a single volume. Written as a reference for practicing engineers and scientists in the chemical engineering field, this book will also be useful as an advanced graduate-level text.
Download or read book Modelling Phase Equilibria written by Stanislaw Malanowski and published by John Wiley & Sons. This book was released on 1992-05-29 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents a rigorous development of thermodynamic laws of phase equilibria beginning with fundamental principles, accompanied by a short description of the mathematics vital to a clear understanding of basic concepts as well as the practical methods used to calculate phase equilibria. Offers excellent explanations of well-established thermodynamic tools and novel, state-of-the-art techniques representing real fluid behavior. Models covered are relevant to the modeling of nonelectrolyte mixtures over wide ranges of pressure, temperature, composition and molecular diversity.
Download or read book Phase Equilibrium Engineering written by Esteban Brignole and published by Elsevier Inc. Chapters. This book was released on 2013-04-02 with total page 19 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume on phase equilibrium engineering (PEE) aims to fill the gap between the books on reactors and separation process design and the textbooks on chemical engineering thermodynamics. The goal is to change the focus from the use of thermodynamic relationships to compute phase equilibria to the design and control of the phase conditions that a process needs. In this way, phase equilibrium thermodynamics is put to work. The main goal of PEE is the design of the system conditions to achieve the desired phase equilibrium scenario that the process at hand requires. In this chapter, the philosophy of phase equilibrium thermodynamic modeling is discussed in the context of process development and chemical plant operation. Typical phase scenarios that are encountered in separation, materials, and chemical process are presented as well as the problem of phase design and the PEE tools.
Download or read book Phase Equilibrium Engineering written by Esteban Brignole and published by Elsevier Inc. Chapters. This book was released on 2013-04-02 with total page 50 pages. Available in PDF, EPUB and Kindle. Book excerpt: In previous chapters, we have seen the fundamental criteria for phase equilibria and how the phenomenological phase behavior and separation technology of real mixtures are determined by their constituent molecular interactions. Our purpose in this chapter is to present the properties of fluids and the models for the prediction of thermodynamic properties and phase equilibria. These models are classified as predictive models using only pure component properties and semiempirical models based on a molecular thermodynamic approach. Finally, the chapter highlights the importance of the class of mixture and molecular interactions of its components in the selection of thermodynamic models for phase equilibrium calculations.
Download or read book Phase Equilibrium Engineering written by Esteban Brignole and published by Elsevier Inc. Chapters. This book was released on 2013-04-02 with total page 42 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this chapter, the basic methodologies of phase equilibrium engineering are introduced through the systematic analysis of several case studies. Some of the thermodynamic tools that have been presented in the previous chapters are applied to illustrate how the phase and conceptual process design of complex engineering problems can be tackled from a phase equilibrium engineering approach. In all the case studies, the first step is to consider in great detail the properties of the process feed, the components, their physical properties, concentrations, and molecular interactions. This information is then used for the selection of thermodynamic models, a suitable technology, pressure, temperature, and compositional operating boundaries. It is shown how the mixture composition and the process goals and specifications determine the process scheme and the unit thermodynamic sensitivity. In addition, the importance of the mixture composition is highlighted in combination with the energy and material balance in the case study for the selection of the desirable natural gas cryogenic technologies. The use of a pressure versus temperature drawing board is used to plot the process trajectory and the mixture phase envelopes from the initial conditions to the key phase engineering design problem. Moreover, the phase design provides also a sound basis for the process initial specification and computer simulation. As another example of phase equilibrium engineering, the heat integration in a complex process is solved by the application of the Gibbs phase rule to the LLV equilibria of a ternary mixture.
Download or read book Phase Equilibrium Engineering written by Esteban Alberto Brignole and published by Newnes. This book was released on 2013-04-02 with total page 347 pages. Available in PDF, EPUB and Kindle. Book excerpt: Traditionally, the teaching of phase equilibria emphasizes the relationships between the thermodynamic variables of each phase in equilibrium rather than its engineering applications. This book changes the focus from the use of thermodynamics relationships to compute phase equilibria to the design and control of the phase conditions that a process needs. Phase Equilibrium Engineering presents a systematic study and application of phase equilibrium tools to the development of chemical processes. The thermodynamic modeling of mixtures for process development, synthesis, simulation, design and optimization is analyzed. The relation between the mixture molecular properties, the selection of the thermodynamic model and the process technology that could be applied are discussed. A classification of mixtures, separation process, thermodynamic models and technologies is presented to guide the engineer in the world of separation processes. The phase condition required for a given reacting system is studied at subcritical and supercritical conditions. The four cardinal points of phase equilibrium engineering are: the chemical plant or process, the laboratory, the modeling of phase equilibria and the simulator. The harmonization of all these components to obtain a better design or operation is the ultimate goal of phase equilibrium engineering. Methodologies are discussed using relevant industrial examples The molecular nature and composition of the process mixture is given a key role in process decisions Phase equilibrium diagrams are used as a drawing board for process implementation
Download or read book Phase Equilibria Phase Diagrams and Phase Transformations written by Mats Hillert and published by Cambridge University Press. This book was released on 1998-03-12 with total page 560 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced undergraduate/ graduate level textbook which treats the theoretical basis of chemical equilibria and chemical changes.
Download or read book Chemical Thermodynamics for Process Simulation written by Jürgen Gmehling and published by John Wiley & Sons. This book was released on 2019-06-10 with total page 819 pages. Available in PDF, EPUB and Kindle. Book excerpt: The only textbook that applies thermodynamics to real-world process engineering problems This must-read for advanced students and professionals alike is the first book to demonstrate how chemical thermodynamics work in the real world by applying them to actual engineering examples. It also discusses the advantages and disadvantages of the particular models and procedures, and explains the most important models that are applied in process industry. All the topics are illustrated with examples that are closely related to practical process simulation problems. At the end of each chapter, additional calculation examples are given to enable readers to extend their comprehension. Chemical Thermodynamics for Process Simulation instructs on the behavior of fluids for pure fluids, describing the main types of equations of state and their abilities. It discusses the various quantities of interest in process simulation, their correlation, and prediction in detail. Chapters look at the important terms for the description of the thermodynamics of mixtures; the most important models and routes for phase equilibrium calculation; models which are applicable to a wide variety of non-electrolyte systems; membrane processes; polymer thermodynamics; enthalpy of reaction; chemical equilibria, and more. -Explains thermodynamic fundamentals used in process simulation with solved examples -Includes new chapters about modern measurement techniques, retrograde condensation, and simultaneous description of chemical equilibrium -Comprises numerous solved examples, which simplify the understanding of the often complex calculation procedures, and discusses advantages and disadvantages of models and procedures -Includes estimation methods for thermophysical properties and phase equilibria thermodynamics of alternative separation processes -Supplemented with MathCAD-sheets and DDBST programs for readers to reproduce the examples Chemical Thermodynamics for Process Simulation is an ideal resource for those working in the fields of process development, process synthesis, or process optimization, and an excellent book for students in the engineering sciences.
Download or read book Process Systems Engineering for Biofuels Development written by Adrian Bonilla-Petriciolet and published by John Wiley & Sons. This book was released on 2020-10-05 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive overview of current developments and applications in biofuels production Process Systems Engineering for Biofuels Development brings together the latest and most cutting-edge research on the production of biofuels. As the first book specifically devoted to process systems engineering for the production of biofuels, Process Systems Engineering for Biofuels Development covers theoretical, computational and experimental issues in biofuels process engineering. Written for researchers and postgraduate students working on biomass conversion and sustainable process design, as well as industrial practitioners and engineers involved in process design, modeling and optimization, this book is an indispensable guide to the newest developments in areas including: Enzyme-catalyzed biodiesel production Process analysis of biodiesel production (including kinetic modeling, simulation and optimization) The use of ultrasonification in biodiesel production Thermochemical processes for biomass transformation to biofuels Production of alternative biofuels In addition to the comprehensive overview of the subject of biofuels found in the Introduction of the book, the authors of various chapters have provided extensive discussions of the production and separation of biofuels via novel applications and techniques.
Download or read book Phase Equilibria Phase Diagrams and Phase Transformations written by Mats Hillert and published by Cambridge University Press. This book was released on 2007-11-22 with total page 525 pages. Available in PDF, EPUB and Kindle. Book excerpt: Computational tools allow material scientists to model and analyze increasingly complicated systems to appreciate material behavior. Accurate use and interpretation however, requires a strong understanding of the thermodynamic principles that underpin phase equilibrium, transformation and state. This fully revised and updated edition covers the fundamentals of thermodynamics, with a view to modern computer applications. The theoretical basis of chemical equilibria and chemical changes is covered with an emphasis on the properties of phase diagrams. Starting with the basic principles, discussion moves to systems involving multiple phases. New chapters cover irreversible thermodynamics, extremum principles, and the thermodynamics of surfaces and interfaces. Theoretical descriptions of equilibrium conditions, the state of systems at equilibrium and the changes as equilibrium is reached, are all demonstrated graphically. With illustrative examples - many computer calculated - and worked examples, this textbook is an valuable resource for advanced undergraduates and graduate students in materials science and engineering.
Download or read book Phase Equilibria written by J. David Raal and published by . This book was released on 1998 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: First published in 1996. Routledge is an imprint of Taylor & Francis, an informa company.
Download or read book Phase Diagrams and Heterogeneous Equilibria written by Bruno Predel and published by Springer. This book was released on 2004-09-14 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: This advanced comprehensive textbook introduces the practical application of phase diagrams to the thermodynamics of materials consisting of several phases. It describes the fundamental physics and thermodynamics as well as experimental methods, treating all material classes: metals, glasses, ceramics, polymers, organic materials, aqueous solutions. With many application examples and realistic cases from chemistry and materials science, it is intended for students and researchers in chemistry, metallurgy, mineralogy, and materials science as well as in engineering and physics. The authors treat the nucleation of phase transitions, the production and stability of technologically important metastable phases, and metallic glasses. Also concisely presented are the thermodynamics and composition of polymer systems. This innovative text puts this powerful analytical approach into a readily understandable and practical context, perhaps for the first time.
Download or read book A TEXTBOOK OF CHEMICAL ENGINEERING THERMODYNAMICS written by K. V. NARAYANAN and published by PHI Learning Pvt. Ltd.. This book was released on 2013-01-11 with total page 528 pages. Available in PDF, EPUB and Kindle. Book excerpt: Designed as an undergraduate-level textbook in Chemical Engineering, this student-friendly, thoroughly class-room tested book, now in its second edition, continues to provide an in-depth analysis of chemical engineering thermodynamics. The book has been so organized that it gives comprehensive coverage of basic concepts and applications of the laws of thermodynamics in the initial chapters, while the later chapters focus at length on important areas of study falling under the realm of chemical thermodynamics. The reader is thus introduced to a thorough analysis of the fundamental laws of thermodynamics as well as their applications to practical situations. This is followed by a detailed discussion on relationships among thermodynamic properties and an exhaustive treatment on the thermodynamic properties of solutions. The role of phase equilibrium thermodynamics in design, analysis, and operation of chemical separation methods is also deftly dealt with. Finally, the chemical reaction equilibria are skillfully explained. Besides numerous illustrations, the book contains over 200 worked examples, over 400 exercise problems (all with answers) and several objective-type questions, which enable students to gain an in-depth understanding of the concepts and theory discussed. The book will also be a useful text for students pursuing courses in chemical engineering-related branches such as polymer engineering, petroleum engineering, and safety and environmental engineering. New to This Edition • More Example Problems and Exercise Questions in each chapter • Updated section on Vapour–Liquid Equilibrium in Chapter 8 to highlight the significance of equations of state approach • GATE Questions up to 2012 with answers