Download or read book Thermodynamic Properties of Nonideal Liquid Mixtures written by Henry Marcel Renon and published by . This book was released on 1966 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book CRC Handbook of Applied Thermodynamics written by David A. Palmer and published by CRC Press. This book was released on 2019-07-23 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: This practical handbook features an overview of the importance of physical properties and thermodynamics; and the use of thermo-dynamics to predict the extent of reaction in proposed new chem-ical combinations. The use of special types of data and pre-diction methods to develop flowsheets for probing projects; and sources of critically evaluated data, dividing the published works into three categories depending on quality are given. Methods of doing one's own critical evaluation of literature, a list of known North American contract experimentalists with the types of data mea-sured by each, methods for measuring equilibrium data, and ther-modynamic concepts to carry out process opti-mization are also featured.

Download or read book Select Thermodynamic Models for Process Simulation written by Jean-Charles de Hemptinne and published by Editions TECHNIP. This book was released on 2012 with total page 418 pages. Available in PDF, EPUB and Kindle. Book excerpt: The selection of the most adequate thermodynamic model in a process simulation is an issue that most process engineer has to face sooner or later. This book, conceived as a practical guide, aims at providing adequate answers by analysing the questions to be looked at. The analysis (first chapter) yields three keys that are further discussed in three different chapters. (1) A good understanding of the properties required in the process, and their method of calculation is the first key. The second chapter provides to that end in a synthetic manner the most important equations that are derived from the fundamental principes of thermodynamics. (2) An adequate description of the mixture, which is a combination of models and parameters, is the second key. The third chapter makes the link between components and models, both from a numerical (parameterisation) and physical (molecular interactions) point of view. Finally, (3) a correct view of the phase behaviour and trends in regard of the process conditions is the third key. The fourth chapter illustrates the phase behaviour and makes model recommendations for the most significant industrial systems. A decision tree is provided at the end of this chapter. In the last chapter, the key questions are reviewed for a number of typical processes. This book is intended for process engineers, who are not specialists of thermodynamics but are confronted with this kind of problems and need a reference book, as well as process engineering students who will find an original approach to thermodynamics, complementary of traditional lectures

Download or read book Separation of a highly nonideal mixture for solvent recovery written by Andreas Raab and published by diplom.de. This book was released on 2003-01-15 with total page 82 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inhaltsangabe:Abstract: The separation of complex nonideal mixtures is a common problem in the process industries. The solvent recovery is an important task for chemical engineers to minimize burden upon the environment due to exhaustive use of solvents. The recovery of the individual components is complicated by the highly nonideal features of these mixtures. The separation of such highly nonideal mixtures can be limited by the presence of azeotropes, which can create distillation boundaries. These distillation boundaries are forming distillation regions which are difficult to overcome with the standard rectification. Distillation systems for these highly nonideal azeotropic mixtures are particularly difficult to design and to operate in an efficient way. In printing companies often four component mixtures of ethanol, ethyl acetate, isopropyl acetate, and water arise as waste. A separation scheme of multicomponent azeotropic distillation is developed and successfully used for a highly nonideal quaternary mixture. The composition of the mixture in mass percent is ethanol 30%, water 20%, ethyl acetate 25% and isopropyl acetate with 20%. The rest of the mixture (5%) consists of n-propane, isopropane, cyclohexane, and etoxypropane. For the further investigation just the quaternary mixture is examined. Generally, every component should be recovered as pure as possible from the mixture. In the mixture namely five binary and two ternary azeotropes are formed by the components. Based on the synthesis procedure proposed by Rev et al. and Mizsey et al. a new separation technology is developed followed up the vapor-liquid-liquid equilibrium behavior of the mixture. They have recommended a general framework for designing feasible schemes of multicomponent azeotropic distillation. This procedure recommends to study in detail the vapor-liquid-liquid equilibrium data to explore immiscibility regions, azeotropic points, and separatrices for ternary and quaternary regions. On the behalf of the VLLE data the set of feasible separation structures is explored. This procedure is followed and a new separation structure is developed and tested experimentally. First, the quaternary mixture is separated into two ternary mixtures by distillation. The two ternary mixtures containing ethyl acetate, ethanol, water and isopropyl acetate, ethanol, water, respectively. Due to the analogous behavior of the two ternary mixtures similar separation cycles can be designed. The two [...]

Download or read book Thermophysical Properties of Heavy Petroleum Fluids written by Bernardo Carreón-Calderón and published by Springer Nature. This book was released on 2020-09-23 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses conventional and new predictive methodologies for estimating thermophysical properties of heavy petroleum fluids. For the unidentifiable fractions forming the fluids, chemical structures are calculated so that property estimation methods for mixtures of identifiable components are now available for such fractions. Chemical and multiphase equilibriums are of utmost importance; hence, the most significant ones involving heavy petroleum fluids are determined and illustrated using advanced equations of state such as sPC-SAFT and EoS/GE. The included phase equilibriums are phase envelopes of reservoir fluids, asymmetric mixtures between light solvents and bitumen including the presence of water and asphaltenes, among others. Besides, heavy petroleum fluids are analyzed from the Newtonian and non-Newtonian viewpoints, exploring their complex rheological behavior. Finally, complemented by online an Excel program for the thermodynamic characterization of unidentifiable petroleum fractions, this book is a useful resource for engineers and researchers in the petroleum industry and is also of interest to students studying chemical and petroleum engineering.

Download or read book High Performance Computing in Science and Engineering 16 written by Wolfgang E. Nagel and published by Springer. This book was released on 2017-01-11 with total page 666 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the state-of-the-art in supercomputer simulation. It includes the latest findings from leading researchers using systems from the High Performance Computing Center Stuttgart (HLRS) in 2016. The reports cover all fields of computational science and engineering ranging from CFD to computational physics and from chemistry to computer science with a special emphasis on industrially relevant applications. Presenting findings of one of Europe’s leading systems, this volume covers a wide variety of applications that deliver a high level of sustained performance. The book covers the main methods in high-performance computing. Its outstanding results in achieving the best performance for production codes are of particular interest for both scientists and engineers. The book comes with a wealth of color illustrations and tables of results.

Download or read book Refrigeration and Air Conditioning written by ARORA, RAMESH CHANDRA and published by PHI Learning Pvt. Ltd.. This book was released on 2012-03-30 with total page 1104 pages. Available in PDF, EPUB and Kindle. Book excerpt: This textbook offers a comprehensive introduction to the theoretical principles and practical aspects of refrigeration and air conditioning systems. Written by a teacher with 30 years experience, this work is intended to provide students with a deeper understanding and a firm grasp of the basic principles of this exciting subject area. This text is ideally suited for undergraduate education in mechanical engineering programmes and specialised postgraduate education in thermosciences. The text begins by reviewing, in a simple and precise manner, the physical principles of three pillars of refrigeration and air conditioning - thermodynamics, heat transfer, and fluid mechanics. Following an overview of the history of refrigeration, subsequent chapters provide exhaustive coverage of the principles, applications and design of several types of refrigeration systems and their associated components, such as compressors, condensers, evaporators, and expansion devices. Refrigerants are examined in a separate chapter. The second part of the book, beginning with the historical background of air conditioning, discusses the subject of psychrometrics at the heart of understanding the design and implementation of air conditioning processes and systems, which are subsequently dealt with in later chapters. It also explains the design practices for cooling and heating load calculations. Each chapter contains several worked-out examples that clarify the material discussed and illustrate the use of basic principles in engineering applications. Each chapter also ends with a set of review questions.

Download or read book From Hamiltonians to Phase Diagrams written by Jürgen Hafner and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development of the modern theory of metals and alloys has coincided with great advances in quantum-mechanical many-body theory, in electronic structure calculations, in theories of lattice dynamics and of the configura tional thermodynamics of crystals, in liquid-state theory, and in the theory of phase transformations. For a long time all these different fields expanded quite independently, but now their overlap has become sufficiently large that they are beginning to form the basis of a comprehensive first-principles the ory of the cohesive, structural, and thermodynamical properties of metals and alloys in the crystalline as well as in the liquid state. Today, we can set out from the quantum-mechanical many-body Hamiltonian of the system of electrons and ions, and, following the path laid out by generations of the oreticians, we can progress far enough to calculate a pressure-temperature phase diagram of a metal or a composition-temperature phase diagram of a binary alloy by methods which are essentially rigorous and from first prin ciples. This book was written with the intention of confronting the materials scientist, the metallurgist, the physical chemist, but also the experimen tal and theoretical condensed-matter physicist, with this new and exciting possibility. Of course there are limitations to such a vast undertaking as this. The selection of the theories and techniques to be discussed, as well as the way in which they are presented, are necessarily biased by personal inclination and personal expertise.

Download or read book Thermodynamics written by Jean Vidal and published by Editions OPHRYS. This book was released on 1980 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt: The simulation and optimization of processes assumes that the thermodynamic properties and phase equilibria of the mixtures concerned are well known. This knowledge is still based upon experimentation, but it is also the result of calculation methods based on the principles of thermodynamics that govern them, insure their coherence, and confer upon them a wide range of application. This text is concerned primarily with the description of these methods and their evolution. It devotes extensive space to fundamental concepts and places particular emphasis on the models that, although based on simplified concepts of the subject matter at the molecular level, have predictive character. Computational examples are used to explain the application of these concepts and models. Contents: 1. Principles. Thermodynamic functions. The ideal gas. 2. Properties of pure substances. 3. Predicting thermodynamic properties of pure substances. General principles. Corresponding states. Group contributions. 4. Equations of state. 5. Characterization of mixtures. 6. Mixtures: liquid-vapor equilibria. 7. Deviations from ideality in the liquid phase. 8. Application of equations of state to mixtures. Calculation of liquid-vapor equilibria under pressure. 9. Liquid-liquid and liquid-liquid-vapor equilibria. 10. Fluid-solid equilibria. Crystallization. Hydrates. 11. Polymer solutions and alloys. 12. Multicomponent mixtures. 13. Chemical reactions. Appendixes. Index. Bibliography.

Download or read book Non Ideal Compressible Fluid Dynamics for Propulsion and Power written by Francesca di Mare and published by Springer Nature. This book was released on 2020-07-08 with total page 125 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book reports on advanced theories and methods aimed at characterizing the dynamics of non-ideal compressible fluids. A special emphasis is given to research fostering the use of non-ideal compressible fluids for propulsion and power engineering. Both numerical and experimental studies, as well as simulations, are described in the book, which is based on selected contributions and keynote lectures presented at the 2nd International Seminar on Non-Ideal Compressible-Fluid Dynamics for Propulsion & Power. Held on October 4-5 in Bochum, Germany, the seminar aimed at fostering collaborations between academics and professionals. The two perspectives have been gathered together in this book, which offers a timely guide to advanced fundamentals, innovative methods and current applications of non-ideal compressible fluids to developing turbomachines, and for propulsion and power generation.

Download or read book Fluid Phase Behavior for Conventional and Unconventional Oil and Gas Reservoirs written by Alireza Bahadori and published by Gulf Professional Publishing. This book was released on 2016-11-24 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fluid Phase Behavior for Conventional and Unconventional Oil and Gas Reservoirs delivers information on the role of PVT (pressure-volume-temperature) tests/data in various aspects, in particular reserve estimation, reservoir modeling, flow assurance, and enhanced oil recovery for both conventional and unconventional reservoirs. This must-have reference also prepares engineers on the importance of PVT tests, how to evaluate the data, develop an effective management plan for flow assurance, and gain perspective of flow characterization, with a particular focus on shale oil, shale gas, gas hydrates, and tight oil making. This book is a critical resource for today's reservoir engineer, helping them effectively manage and maximize a company's oil and gas reservoir assets. - Provides tactics on reservoir phase behavior and dynamics with new information on shale oil and gas hydrates - Helps readers Improve on the effect of salt concentration and application to C02-Acid Gas Disposal with content on water-hydrocarbon systems - Provides practical experience with PVT and tuning of EOS with additional online excel spreadsheet examples

Download or read book Physical Chemistry for the Biosciences written by Raymond Chang and published by University Science Books. This book was released on 2005-02-11 with total page 706 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is ideal for use in a one-semester introductory course in physical chemistry for students of life sciences. The author's aim is to emphasize the understanding of physical concepts rather than focus on precise mathematical development or on actual experimental details. Subsequently, only basic skills of differential and integral calculus are required for understanding the equations. The end-of-chapter problems have both physiochemical and biological applications.

Download or read book Phase Equilibria in Chemical Engineering written by Stanley M. Walas and published by Butterworth-Heinemann. This book was released on 2013-10-22 with total page 689 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phase Equilibria in Chemical Engineering is devoted to the thermodynamic basis and practical aspects of the calculation of equilibrium conditions of multiple phases that are pertinent to chemical engineering processes. Efforts have been made throughout the book to provide guidance to adequate theory and practice. The book begins with a long chapter on equations of state, since it is intimately bound up with the development of thermodynamics. Following material on basic thermodynamics and nonidealities in terms of fugacities and activities, individual chapters are devoted to equilibria primarily between pairs of phases. A few topics that do not fit into these categories and for which the state of the art is not yet developed quantitatively have been relegated to a separate chapter. The chapter on chemical equilibria is pertinent since many processes involve simultaneous chemical and phase equilibria. Also included are chapters on the evaluation of enthalpy and entropy changes of nonideal substances and mixtures, and on experimental methods. This book is intended as a reference and self-study as well as a textbook either for full courses in phase equilibria or as a supplement to related courses in the chemical engineering curriculum. Practicing engineers concerned with separation technology and process design also may find the book useful.

Download or read book Thermodynamics written by William C. Reynolds and published by Cambridge University Press. This book was released on 2018-09-20 with total page 425 pages. Available in PDF, EPUB and Kindle. Book excerpt: This concise text provides an essential treatment of thermodynamics and a discussion of the basic principles built on an intuitive description of the microscopic behavior of matter. Aimed at a range of courses in mechanical and aerospace engineering, the presentation explains the foundations valid at the macroscopic level in relation to what happens at the microscopic level, relying on intuitive and visual explanations which are presented with engaging cases. With ad hoc, real-word examples related also to current and future renewable energy conversion technologies and two well-known programs used for thermodynamic calculations, FluidProp and StanJan, this text provides students with a rich and engaging learning experience.

Download or read book A to Z of Thermodynamics written by Pierre Perrot and published by Supplementary Series; 27. This book was released on 1998 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt: The title is a perfect description. Arranged alphabetically this book explains the words and phrases that crop up in thermodynamics. The author does this without resorting to pages of mathematics and algebra: the author's main aim is to explain and clarify the jargon and concepts.Thermodynamics is often difficult and confusing for students. The author knows this after 20 years of teaching and does something about it with this dictionary.

Download or read book Nbs Nrc Steam Tables written by Lester Haar and published by CRC Press. This book was released on 1984-01-01 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Introduction to Supercritical Fluids written by Richard Smith and published by Newnes. This book was released on 2013-12-08 with total page 764 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text provides an introduction to supercritical fluids with easy-to-use Excel spreadsheets suitable for both specialized-discipline (chemistry or chemical engineering student) and mixed-discipline (engineering/economic student) classes. Each chapter contains worked examples, tip boxes and end-of-the-chapter problems and projects. Part I covers web-based chemical information resources, applications and simplified theory presented in a way that allows students of all disciplines to delve into the properties of supercritical fluids and to design energy, extraction and materials formation systems for real-world processes that use supercritical water or supercritical carbon dioxide. Part II takes a practical approach and addresses the thermodynamic framework, equations of state, fluid phase equilibria, heat and mass transfer, chemical equilibria and reaction kinetics of supercritical fluids. Spreadsheets are arranged as Visual Basic for Applications (VBA) functions and macros that are completely (source code) accessible for students who have interest in developing their own programs. Programming is not required to solve problems or to complete projects in the text. - Property worksheets/spreadsheets that are easy to use in learning environments - Worked examples with Excel VBA Worksheet functions allow users to design their own processes - Fluid phase equilibria and chemical equilibria worksheets allow users to change conditions, study new solutes, co-solvents, chemical systems or reactions