Download or read book Thermodynamic Modeling and Experimental Study of the Al Cr Cu Fe Mg Mn Si System written by Senlin Cui and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: "Aluminum alloys are extensively used in civil engineering, ship building, automotive, and aerospace industry. The requirement of improving fuel efficiency and weight reduction of vehicle triggers a resurgence of research of aluminum in automobile industry. Al 6xxx series alloys are commonly utilized as extruded materials because of their high strength, formability and ductility, weldability, corrosion resistance, and low cost. The whole chain of Al alloy component manufacturing starts from aluminum melt refining, to casting, homogenization, rolling/extrusion, and finally heat treatment. The microstructure evolution of Al alloys is controlled by both thermodynamics and kinetics. The driving forces for each processing step basically include the chemical driving force or thermodynamic driving force, the interfacial energy, the mechanical driving force, etc. Thermodynamics related to chemical reactions and phase transformations is thus of fundamental importance.The study of thermochemical properties and phase diagram of Al alloys is helpful for new Al alloy composition design and process optimization. The CALPHAD (CALculation of PHAse Diagram) approach is one of the most efficient ways to study alloy thermodynamics systematically. With a well-developed Al alloy thermodynamic database, the phase equilibria and thermodynamic properties can be calculated for complex alloy systems. As a cornerstone for the understanding of various phenomena in Al 6xxx alloys, the current work focuses on the development of a thermodynamic database for the Al-Cr-Cu-Fe-Mg-Mn-Si system via a coupled experimental and thermodynamic modeling approach. Isothermal sections in the Al rich corner of the Al-Cr-Mg system were measured at 400, 450, and 500 °C via equilibrated alloys, diffusion couples, and differential thermal analysis (DSC). The thermodynamic optimizations of the binary Al-Cr, Cu-Cr, Cu-Mg, Cr-Si, and Fe-Si systems were newly performed, and the thermodynamic descriptions of the Al-Mn, Cu-Mn, Cr-Fe, Cr-Mg, and Cr-Mn systems were revised. The ternary Al-Cu-Cr, Al-Cu-Mg, Al-Cu-Si, Al-Cr-Mg, Al-Cr-Mn, Al-Cr-Si, Cu-Fe-Cr, Cu-Fe-Mn, Cu-Mg-Si, Cr-Fe-Si, and Fe-Mg-Si systems were thermodynamically modeled, and the Al-Cu-Mn system was revised. Moreover, the quaternary Al-Cu-Mg-Si system was remodeled. The optimization or revision of the thermodynamic descriptions of all the systems were based on the current experimental results and the critically evaluated literature data including phase diagram, enthalpy of mixing, activity, Gibbs energy of formation, enthalpy of formation, standard entropy, heat capacity, etc. The liquid phase was described using the Modified Quasi-chemical Model (MQM) in pair approximation, and the Compound Energy Formalism (CEF) was utilized for the descriptions of all the solid phases. The order-disorder transitions (bcc_A2/bcc_B2 transition and bcc_B2/bcc_D03 transition) were modeled using the split compound energy formalism. A self-consistent set of thermodynamic description for the Al-Cr-Cu-Fe-Mg-Mn-Si system was obtained by combining the currently assessed thermodynamic parameters with the thermodynamic parameters available in the literature. The obtained thermodynamic database was applied to investigate the recycling of Al alloys. The effect of each major and impurity alloying element on the types of precipitates and their amounts in both the solidification and equilibrium conditions were also systematically investigated for the Al 6xxx series alloys using the thermodynamic calculations with the present new database." --

Download or read book Thermodynamic Modeling and Experimental Investigation of the Al Cu Mg Zn Quaternary System written by Haiyan Liang and published by . This book was released on 1998 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Thermodynamic Modeling and Experimental Investigation of the Mg Al Ca Sr System written by Mohammad Aljarrah and published by . This book was released on 2008 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this work, a self-consistent thermodynamic database for the Mg-Al-Ca-Sr system using the modified quasichemical model has been constructed. The thermodynamic description of the quaternary system was established by combining the thermodynamic descriptions of the constituent binary and ternary sub-systems. The Mg-Al-Ca and Mg-Al-Sr systems were investigated by combining thermodynamic modeling and experimental investigation. The experimental investigation has been performed using DSC, XRD, SEM and EPMA. Also, isothermal sections at 300°C and 400°C were constructed for the Mg-Al-Ca and Mg-Al-Sr systems. In the Mg-Al-Sr system, six ternary solubilities of the binary compounds extended into the ternary system have been found and denoted as (Mg 17 Sr 2), (Mg 23 Sr 6), (Mg 38 Sr 9), (Mg 2 Sr), (Al 4 Sr) and (Al 2 Sr). The reported ternary compound in the literature (Mg 58 Al 38 Sr 4) has been observed in this work. In the Mg-Al-Ca system, three binary compounds were found to dissolve the third component in the ternary system and were denoted as (Al 2 Ca), (Al 3 Ca 8), and (Mg 2 Ca). The ternary compound (C36) reported in the literature has been confirmed. A comparison between the calculated liquidus projection of the Mg-Ca-Sr system using the modified quasichemical model and random solution model has been presented. It was found that while the random solution model agrees well with the experimental phase diagram, the modified quasichemical model gives better agreement with the experimental thermodynamic data and the experimental phase diagram. Liquidus projection of the Al-Ca-Sr system was calculated using the modified quasichemical model and combined with the other three ternaries in one database for the Mg-Al-Ca-Sr system.

Download or read book Multicomponent Phase Diagrams Applications for Commercial Aluminum Alloys written by Nikolay A. Belov and published by Elsevier. This book was released on 2005-07-01 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt: Despite decades of extensive research and application, commercial aluminum alloys are still poorly understood in terms of the phase composition and phase transformations occurring during solidification, cooling, and heating. Multicomponent Phase Diagrams: Applications for Commercial Aluminum Alloys aims to apply multi-component phase diagrams to commercial aluminum alloys, and give a comprehensive coverage of available and assessed phase diagrams for aluminum-based alloy systems of different dimensionality. - Features data on non-equilibrium phase diagrams, which can rarely be obtained from other publications - Extensive coverage of all groups of commercially important alloys and materials

Download or read book Thermodynamic and Solidification Modeling Coupled with Experimental Investigation of the Multicomponent Aluminum Alloys written by Xinyan Yan and published by . This book was released on 2001 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Experimental Investigation and Thermodynamic Modeling of the Al Cr Mo Ni System and Its Sub systems written by Jian Peng and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Extraction 2018 written by Boyd R. Davis and published by Springer. This book was released on 2018-08-18 with total page 2862 pages. Available in PDF, EPUB and Kindle. Book excerpt: This three volume set presents papers from the first collaborative global metallurgy conference focused exclusively on extractive topics, including business and economic issues. Contributions examine new developments in foundational extractive metallurgy topics and techniques, and present the latest research and insights on emerging technologies and issues that are shaping the global extractive metallurgy industry. The book is organized around the following main themes: hydrometallurgy, pyrometallurgy, sulfide flotation, and extractive metallurgy markets and economics.

Download or read book 13th International Conference on Aluminum Alloys ICAA 13 written by Hasso Weiland and published by Springer. This book was released on 2017-02-28 with total page 1857 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is a collection of papers presented at the 13th International Conference on Aluminum Alloys (ICAA-13), the premier global conference for exchanging emerging knowledge on the structure and properties of aluminum materials. The papers are organized around the topics of the science of aluminum alloy design for a range of market applications; the accurate prediction of material properties; novel aluminum products and processes; and emerging developments in recycling and applications using both monolithic and multi-material solutions.

Download or read book Thermodynamic Modeling and Materials Data Engineering written by J.-P. Caliste and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 406 pages. Available in PDF, EPUB and Kindle. Book excerpt: J.-P. CALISTE, A. TRUYOL AND J. WESTBROOK The Series, "Data and Knowledge in a Changing World", exemplifies CODATA's primary purpose of collecting, from widely different fields, a wealth of information on efficient exploitation of data for progress in science and technology and making that information available to scientists and engineers. A separate and complementary CODATA Reference Series will present Directories of compiled and evaluated data and Glossaries of data-related terms. The present book "Thermodynamic Modeling and Materials Data Engineering" discusses thermodynamic, structural, systemic and heuristic approaches to the modeling of complex materials behavior in condensed phases, both fluids and solids, in order to evaluate their potential applications. Itwas inspired by the Symposium on "Materials and Structural Properties" held during the 14th International CODATA Conference in Chambery, France. The quality of the contributions to this Symposium motivated us to present" a coherent book of interest to the field. Updated contributions inspired by Symposium discussions and selections from other CODATA workshops concerning material properties data and Computer Aided Design combine to highlight the complexity of material data issues on experimental, theoretical and simulation levels Articles were selected for their pertinence in three areas. Complex data leading to interesting developments and tools such as: • new developments in state equations and their applications, • prediction and validation of physical and energy data by group correlations for pure compounds, • modeling and prediction of mixture properties.

Download or read book Coupled Experimental and Thermodynamic Modeling of A12O3 CaO FeO Fe2O3 MgO MnO Mn2O3 SiO2 TiO3 TiO2 System written by Sourav Panda and published by . This book was released on 2019 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: "The phase diagram and thermodynamic properties of the Al2O3-CaO-FeO-Fe2O3-MgO-MnO-Mn2O3-SiO2-Ti2O3-TiO2 system are important in various applications such as steelmaking, refractories, advanced ceramics, petrology and geochemistry. In the present work, the available thermodynamic database for the Al2O3-CaO-FeO-Fe2O3-MgO-SiO2 system was expanded toward the Mn and Ti oxide systems to develop an accurate thermodynamic database for the ten-component system. For this purpose, a complete literature review, critical evaluation and thermodynamic optimization of the phase diagrams and thermodynamic properties of related systems at 1 atm was performed. As part of the thermodynamic study, key phase diagram experiments were performed in the Fe-Ti-O, Mn-Ti-O, Al-Ti-O, Fe-Mn-Ti-O, Mg-Mn-Ti-O, Mn-Si-Ti-O, and Mn-Al-Ti-O systems in air to obtain unknown phase equilibria between the liquid phase and complex solid solutions and resolve any inconsistencies among existing experimental data in the literature.Phase diagram experiments were performed using the classical equilibration and quenching technique. Phase analysis was performed using Electron Probe Microanalysis (EPMA) and X-ray Diffraction (XRD) on all the quenched samples. In the Al-Ti-O system, the solubility of Al2O3 in the rutile (TiO2) solid solution was measured at high temperature. In the Fe-Ti-O system, the liquidus, solubility of Fe2O3 in the rutile (TiO2) solution, and the homogeneity ranges of Fe2O3-FeTiO3 ilmenite and Fe2TiO5-Ti3O5 pseudobrookite solutions were determined at high temperature. In the Mn-Ti-O system, the liquidus, MnO solubility in rutile and the homogeneity range of Mn3O4-Mn2TiO4 spinel were measured. In the Mg-Mn-Ti-O, Fe-Mn-Ti-O and Mn-Si-Ti-O systems, the complex phase equilibria between liquid and solid solutions were experimentally elucidated for the first time in air atmosphere. For the thermodynamic optimization, the liquid phase was described using the Modified Quasichemical Model considering short-range ordering in the molten oxide and the Gibbs energies of the complex solid solutions pseudobrookite, ilmenite and spinel were described using the Compound Energy Formalism considering the crystal structure of each solid solution. Using the thermodynamic models with optimized model parameters in binary and ternary systems, the phase diagrams and thermodynamic properties of higher order systems in the Al2O3-CaO-FeO-Fe2O3-MgO-MnO-Mn2O3-SiO2-Ti2O3-TiO2 system were well calculated. The database containing the optimized model parameters in this study is compatible with the other FactSage thermodynamic databases and can be used to calculate any unexplored phase diagram and thermodynamic properties within the ten-component system. The database can be used for the complex thermodynamic calculations applicable to pyrometallurgy and advanced ceramics and used for the optimization of industrial processes and the development of new materials. " --

Download or read book IRON Binary Phase Diagrams written by O. Kubaschewski and published by Springer Science & Business Media. This book was released on 2013-03-14 with total page 194 pages. Available in PDF, EPUB and Kindle. Book excerpt: At the official dinner of a· meeting in May 1939, I was seated next to Max Hansen. When I congratulated him on the well deserved success of his "Aufbau der Zweistoff-Legierungen", he smiled: "yes, it was a struggle with the hydra, and so it has taken me seven years", meaning that whenever he had thought to have finished the phase diagram of a particular system, new evidence would turn up like the new heads of the Greek monster. There is no need to point out the importance of assessed phase diagrams to metallurgists or even anyone concerned with the technology and applica tion of metals and alloys. The information contained therein is fundamental to considerations concerning the chemical, physical and mechanical properties of alloys. Hansen's German monograph was followed by a revised English edition in 1958 with K. Anderko and the supplements by R.P. Elliott (1965) and F.A. Shunk (1969). All those who have made use of these volumes will admit that much diligent labour has gone into this work, necessary to cope with the ever increasing number of publications and the consequent improvements.

Download or read book Thermodynamic Modeling and Experimental Investigation of the Mg Cu Ni Y Quaternary System written by Md. Mezbahul Islam and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Metals Abstracts Index written by and published by . This book was released on 1996 with total page 1622 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Bibliography written by Pierre Villars and published by Walter de Gruyter. This book was released on 2012-12-21 with total page 1827 pages. Available in PDF, EPUB and Kindle. Book excerpt: By browsing about 10 000 000 scientific articles of over 200 major journals mainly in a 'cover to cover approach' some 200 000 publications were selected. The extracted data is part of the following fundamental material research fields: crystal structures (S), phase diagrams (also called constitution) (C) and the comprehensive field of intrinsic physical properties (P). This work has been done systematically starting with the literature going back to 1900. The above mentioned research field codes (S, C, P) as well as the chemical systems investigated in each publication were included in the present work. The aim of the Inorganic Substances Bibliography is to provide researchers with a comprehensive compilation of all up to now published scientific publications on inorganic systems in only three handy volumes.

Download or read book THERMEC 2013 written by B. Mishra and published by Trans Tech Publications Ltd. This book was released on 2014-05-23 with total page 2938 pages. Available in PDF, EPUB and Kindle. Book excerpt: Collection of selected, peer reviewed papers from THERMEC 2013, 8th International Conference on PROCESSING & MANUFACTURING OF ADVANCED MATERIALS Processing, Fabrication, Properties, Applications, December 2-6, 2013, Las Vegas, USA. The 470 papers are grouped as follows: Chapter 1: Al Alloys, Chapter 2: Mg Alloys (Prof Karl U. Kainer Symposium), Chapter 3: Ti Alloys/ Aerospace Structural Metallic Materials, Chapter 4: Steels, Chapter 5: TMP Microalloyed Steels (Prof. A. J. DeArdo Symposium), Chapter 6: High & Ultra High Temperature Materials, Chapter 7: Bio Materials, Chapter 8: Advanced Protective Coatings/Surface Engineering, Chapter 9: Composites (MMC, CMC)/ Nanocomposites/ Synthetic & Foams), Chapter 10: Interfaces & Grain Boundaries, Chapter 11: Fuel Cells, Hydrogen Storage Technologies, Batteries, Supercapacitors & Thermoelectric Materials, Chapter 12: Friction Stir Processing/Welding, Chapter 13: Materials Under Extreme Conditions, Chapter 14: Metallic Glasses/ Bulk Metallic Amorphous Materials, Chapter 15: Nanomaterials for Structural & Energy Applications, Chapter 16: Neutron Scattering & X-Ray Studies of Advanced Materials, Chapter 17: Modelling & Simulation, Chapter 18: Materials Performance, Chapter 19: Smart/Intelligent Materials & Processes, Chapter 20: Texture of Materials (Prof. G. Gottstein Symposium), Chapter 21: Ultra-Fine – Grained Materials (Prof. T. G. Langdon Symposium), Chapter 22: Welding & Joining of Advanced and Special Materials

Download or read book Metals Abstracts written by and published by . This book was released on 1998 with total page 1076 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Computational Thermodynamics written by H. L. Lukas and published by . This book was released on 2007-07-12 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phase diagrams are used in materials research and engineering to understand the interrelationship between composition, microstructure and process conditions. In complex systems, computational methods such as CALPHAD are employed to model thermodynamic properties for each phase and simulate multicomponent phase behavior. Written by recognized experts in the field, this is the first introductory guide to the CALPHAD method, providing a theoretical and practical approach. Building on core thermodynamic principles, this book applies crystallography, first principles methods and experimental data to computational phase behavior modeling using the CALPHAD method. With a chapter dedicated to creating thermodynamic databases, the reader will be confident in assessing, optimizing and validating complex thermodynamic systems alongside database construction and manipulation. Several case studies put the methods into a practical context, making this suitable for use on advanced materials design and engineering courses and an invaluable reference to those using thermodynamic data in their research or simulations.