Download or read book The Occurrence and Mobility of Arsenic in Soils and Sediments written by Aimee Hegan and published by . This book was released on 2012 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Occurrence of Arsenic in Soils and Stream Sediments Town of Hudson New Hampshire written by Frederick H. Chormann and published by . This book was released on 1985 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Arsenic Chemistry in Soils and Sediments written by and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Arsenic is a naturally occurring trace element that poses a threat to human and ecosystem health, particularly when incorporated into food or water supplies. The greatest risk imposed by arsenic to human health results from contamination of drinking water, for which the World Health Organization recommends a maximum limit of 10 [mu]g L−1. Continued ingestion of drinking water having hazardous levels of arsenic can lead to arsenicosis and cancers of the bladder, skin, lungs and kidneys. Unfortunately, arsenic tainted drinking waters are a global threat and presently having a devastating impact on human health within Asia. Nearly 100 million people, for example, are presently consuming drinking water having arsenic concentrations exceeding the World Health Organization's recommended limit (Ahmed et al., 2006). Arsenic contamination of the environment often results from human activities such as mining or pesticide application, but recently natural sources of arsenic have demonstrated a devastating impact on water quality. Arsenic becomes problematic from a health perspective principally when it partitions into the aqueous rather than the solid phase. Dissolved concentrations, and the resulting mobility, of arsenic within soils and sediments are the combined result of biogeochemical processes linked to hydrologic factors. Processes favoring the partitioning of As into the aqueous phase, potentially leading to hazardous concentrations, vary extensively but can broadly be grouped into four categories: (1) ion displacement, (2) desorption (or limited sorption) at pH values> 8.5, (3) reduction of arsenate to arsenite, and (4) mineral dissolution, particularly reductive dissolution of Fe and Mn (hydr)oxides. Although various processes may liberate arsenic from solids, a transition from aerobic to anaerobic conditions, and commensurate arsenic and iron/manganese reduction, appears to be a dominant, but not exclusive, means by which high concentrations of dissolved arsenic are generated. Within the subsequent sections of this chapter, we explore and describe the biological and chemical processes that control the partitioning of arsenic between the solid and aqueous phase.
Download or read book Arsenic in Soil and Groundwater Environment written by Prosun Bhattacharya and published by Elsevier. This book was released on 2007-06-29 with total page 685 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume presents the recent developments in the field of arsenic in soil and groundwater. Arranged into nine sections, the text emphasizes the global occurrences of arsenic in the environment, particularly on its source, pathways, behavior, and effects it has on soils, plants, water, animals, and humans. It also covers the diverse issues of arsenic in the mining environment, arsenic emanating from hydrothermal springs, and the geochemical modeling of arsenic adsorption to oxide surfaces. Finally, the text includes different cost effective removal mechanisms of arsenic from drinking water using natural red earth, solar oxidation, and arsenic oxidation by ferrrate.Written in simple English, and few technical terms, the book is designed to create interest within the countries with occurrences of arsenic in drinking water with ·an update the current status of knowledge on the dynamics of natural arsenic from the aquifers through groundwater to food chain and efficient techniques for arsenic removal.·serve as a standard text book for graduate, postgraduate students and researchers in the field of Environmental Sciences and Hydrogeochemistry as well as researchers, environmental scientists and chemists, toxicologists, medical scientists and even for general public seeking an in-depth view of arsenic which had been classed as a carcinogen. ·bring awareness, among administrators, policy makers and company executives, on the problem and to improve the international cooperation
Download or read book Bioavailability of Contaminants in Soils and Sediments written by National Research Council and published by National Academies Press. This book was released on 2003-05-03 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioavailability refers to the extent to which humans and ecological receptors are exposed to contaminants in soil or sediment. The concept of bioavailability has recently piqued the interest of the hazardous waste industry as an important consideration in deciding how much waste to clean up. The rationale is that if contaminants in soil and sediment are not bioavailable, then more contaminant mass can be left in place without creating additional risk. A new NRC report notes that the potential for the consideration of bioavailability to influence decision-making is greatest where certain chemical, environmental, and regulatory factors align. The current use of bioavailability in risk assessment and hazardous waste cleanup regulations is demystified, and acceptable tools and models for bioavailability assessment are discussed and ranked according to seven criteria. Finally, the intimate link between bioavailability and bioremediation is explored. The report concludes with suggestions for moving bioavailability forward in the regulatory arena for both soil and sediment cleanup.
Download or read book Arsenic in Soils and Sediments Adjacent to Birch Swamp Brook in the Vicinity of Texas Road downstream from the Imperial Oil Company Superfund Site Monmouth County New Jersey written by and published by . This book was released on 2001 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Managing Arsenic in the Environment written by Ravi Naidu and published by CSIRO PUBLISHING. This book was released on 2006-02-07 with total page 656 pages. Available in PDF, EPUB and Kindle. Book excerpt: Arsenic is one of the most toxic and carcinogenic elements in the environment. This book brings together the current knowledge on arsenic contamination worldwide, reviewing the field, highlighting common themes and pointing to key areas needing future research. Contributions discuss methods for accurate identification and quantification of individual arsenic species in a range of environmental and biological matrices and give an overview of the environmental chemistry of arsenic. Next, chapters deal with the dynamics of arsenic in groundwater and aspects of arsenic in soils and plants, including plant uptake studies, effects on crop quality and yield, and the corresponding food chain and human health issues associated with these exposure pathways. These concerns are coupled with the challenge to develop efficient, cost effective risk management and remediation strategies: recent technological advances are described and assessed, including the use of adsorbants, photo-oxidation, bioremediation and electrokinetic remediation. The book concludes with eleven detailed regional perspectives of the extent and severity of arsenic contamination from around the world. It will be invaluable for arsenic researchers as well as environmental scientists and environmental chemists, toxicologists, medical scientists, and statutory authorities seeking an in-depth view of the issues surrounding this toxin.
Download or read book Behavior of Metals in Soils written by Joan E. McLean and published by . This book was released on 1992 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Form Distribution and Mobility of Arsenic in Soilscontaminated by Arsenic Trioxide at Sites in Southeast USA written by and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Soils from many industrial sites in southeastern USA arecontaminated with As because of the application of herbicide containingAs2O3. Among those contaminated sites, two industrial sites, FW and BH, which are currently active and of most serious environmental concerns, were selected to characterize the occurrence of As in the contaminatedsoils and to evaluate its environmental leachability. The soils are bothsandy loams with varying mineralogical and organic matter contents. Microwave-assisted acid digestion (EPA method 3051) of the contaminatedsoils indicated As levels of up to 325 mg/kg and 900 mg/kg (dry weightbasis) for FW and BH soils, respectively. However, bulk X-ray powderdiffraction (XRD) analysis failed to find any detectable As-bearingphases in either of the studied soil samples. Most of the soil As wasobserved by scanning electron microscopy, coupled with energy dispersiveX-ray spectroscopy (SEM/EDX), to be disseminated on the surfaces offine-grained soil particles in close association with Al and Fe. A fewAs-bearing particles were detected in BH soil using electron microprobeanalysis (EMPA). Synchrotron micro-XRD and X-ray absorption near-edgestructure (XANES) analyses indicated that these As-rich particles werepossibly phaunouxite, a mineral similar to calcium arsenate, which couldhave been formed by natural weathering after the application of As2O3. However, the scarcity of those particles eliminated them from playing anyimportant role in Assequestration. Synthetic acid rain sequential batchleaching experiments showed distinct As leaching behaviors of the twostudied soil samples: BH soil, which has the higher As content, showed aslow, steady release of As, while FW soil, with a lower As content, showed a much quicker release and lower overall retention of As uponleaching. Sequential chemical extraction experiments were carried outusing a simplified 4-step sequential chemical extraction procedure (SCEP)previously developed to characterize the fractionation of As and betterunderstand the different leaching behaviors of the two studied soils. Itwas shown that only about 50 percent of the total extractable As wasremoved by the first two extraction steps, which represented the mostweakly bonded and readily available As forenvironmental leaching.Compared with the sequential leaching experiments, it was furtherindicated that only half of the As associated with phases extracted bythe second SCEP step was mobilized by SPLP leaching. Althoughmicrowave-assisted acid digestion results showed similar Al and Fecontents in both soils, the sequential chemical extraction experimentsindicated that BH soil has a much higher content of amorphous Al and Fephases and that a comparably higher portion of soil As was associatedwith those materials. The experimental results suggest that remediationefforts for the contaminated sites can be directed towards enhancing theformation of more stable As-bearing compounds in the soils to reduce theenvironmental leachability of As.
Download or read book Scientific Investigations Report written by Sharon E. Kroening and published by . This book was released on 2004 with total page 122 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Heavy Metals in Soils written by Brian J. Alloway and published by Springer Science & Business Media. This book was released on 2012-07-18 with total page 615 pages. Available in PDF, EPUB and Kindle. Book excerpt: This third edition of the book has been completely re-written, providing a wider scope and enhanced coverage. It covers the general principles of the natural occurrence, pollution sources, chemical analysis, soil chemical behaviour and soil-plant-animal relationships of heavy metals and metalloids, followed by a detailed coverage of 21 individual elements, including: antimony, arsenic, barium, cadmium, chromium, cobalt, copper, gold, lead, manganese, mercury, molybdenum, nickel, selenium, silver, thallium, tin, tungsten, uranium, vanadium and zinc. The book is highly relevant for those involved in environmental science, soil science, geochemistry, agronomy, environmental health, and environmental engineering, including specialists responsible for the management and clean-up of contaminated land.
Download or read book Environmental Chemistry of Arsenic written by William T. Frankenberger, Jr and published by CRC Press. This book was released on 2001-12-04 with total page 420 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions from world-renowned experts in the field, this book explores developments in the transport kinetics, seasonal cycling, accumulation, geochemistry, transformation, and toxicology of arsenic. It details advances in the prevention and control of arsenic and arsenic compounds in the air, soil, and water and offers analytical methods for the detection and study of arsenic in the environment and human body. Providing bioremediation techniques for effective treatment of contaminated water supplies, the book discusses factors that influence the removal of arsenic from water as well as diurnal and seasonal variations in the arsenic concentration of surface water supplies.
Download or read book Characterization of Arsenic Occurrence Mobility and Retardation in Sandstone and Dolomite Aquifers of the Fox River Valley Wisconsin written by Katie L. Thornburg and published by . This book was released on 2003 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Natural Arsenic in Groundwaters of Latin America written by Jochen Bundschuh and published by CRC Press. This book was released on 2008-09-23 with total page 784 pages. Available in PDF, EPUB and Kindle. Book excerpt: Groundwater resources naturally contain high levels of arsenic in many parts of the world. Over the last two decades, the As-containing groundwater in South-East Asia has received much attention, but the situation is just as crucial in Latin America, where the number of studies is still relatively low, and the extent and severity of As-exposure in the populations has yet to be fully evaluated. This book aims to promote knowledge of the occurrence and genesis of As-rich groundwater in Latin America. It deals with constraints on the mobility of As in groundwater, As-uptake from soil and water by plants, As-propagation through the food chain, human health impacts, and As-removal technologies. Case studies are presented from Argentina, Bolivia, Chile, Ecuador, El Salvador, Mexico, Nicaragua and Peru, amongst others, and are viewed against the background of experience from other world regions. The book is a state-of-art overview of arsenic research in Latin America. It aims to create interest within the Latin American countries affected by the presence of arseniferous aquifers and to increase awareness among administrators, policy makers and company executives. It will also serve to inform the international scientific community, and improve international cooperation on arsenic in groundwater.
Download or read book Geochemical Processes written by Horst D. Schulz and published by Wiley-VCH. This book was released on 2002-12-25 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a result of the Priority Programme 546 run by the Deutsche Forschungsgemeinschaft. It presents the various ideas, concepts and conclusions that resulted from this Programme on the subject of geochemical processes with long-term effects in anthropogenically influenced drainage and ground water.
Download or read book Arsenic in Ground Water written by Alan H. Welch and published by Springer Science & Business Media. This book was released on 2007-05-08 with total page 476 pages. Available in PDF, EPUB and Kindle. Book excerpt: Interest in arsenic in ground water has greatly increased in the past decade because of the increased awareness of human health effects and the costs of avoidance or treatment of ground water supplies used for consumption. The goal of this book is to provide a description of the basic processes that affect arsenic occurrence and transport by providing sufficient background information on arsenic geochemistry and descriptions of hi- arsenic ground water, both affected and unaffected by human activity. An understanding of thermodynamics, adsorption, and the speciation of arsenic in solid phases, which are described in first three chapters, is needed to predict the fate of arsenic in ground water systems. Large-scale and deep movement of ground water can and has redistributed arsenic in the near surface environment, as described in the next two chapters. These large-scale systems can affect large volumes of both ground water and surface water, such as in the Yellowstone system, and can produce mineralised zones that subsequently release arsenic to ground water supplies. Regional identification of high-arsenic ground water and its consumption as described in the next three chapters clearly demonstrates a need for increased wat- quality monitoring, particularly in south and southeast Asia. Chapters 9-11 provide examples of high arsenic ground water associated with sulfide mineral oxidation and alkaline conditions. Finally, smaller scale studies of the effects of human activities that have produced high-arsenic ground water and methods for attenuation of ground water are presented.
Download or read book Impacts of Sea Level Rise on Arsenic Mobility and Cycling in Contaminated Coastal Soils written by Joshua J. LeMonte and published by . This book was released on 2016 with total page 104 pages. Available in PDF, EPUB and Kindle. Book excerpt: The impacts of sea level rise (SLR) on biogeochemical processes in contaminated soils and sediments along the world’s coastlines remains poorly understood. Elevated levels of the carcinogen arsenic (As), from both geogenic and anthropogenic sources, are found along many coasts, most notably in south and southeast Asia, but also in the US, particularly along the Mid-Atlantic coast. In this work, a combination of laboratory and field techniques were used to ascertain the potential impacts of impending SLR on As mobility and cycling, and the current state of As mobility in a contaminated coastal zone of Delaware, USA. Advanced biogeochemical microcosm reactors were used to simulate inundation with natural sea and river waters on two historically As-contaminated Delaware coastal soils – a wetland soil and ditch sediment – across a wide range of redox potentials while monitoring chemical variables that are known to impact As mobility. Direct As speciation of the soils after reaction at different Eh values was obtained by bulk X-ray absorption near-edge structure (XANES) spectroscopy, X-ray fluorescence (XRF) imaging, and XANES spectroscopy. Reducing conditions led to As release and partial reduction of solid-phase As for both inundation scenarios and both soils. Sulfur speciation was also determined via XANES spectroscopy and showed evidence of sulfate reduction. Prolonged reducing conditions induced by SLR will drive the release of As from historically contaminated soils, but As release may be tempered when inundated by seawater as compared to river water for some soils (e.g. ditch sediment), possibly due to reduced microbial growth in high salinity conditions or preferential sulfate reduction limiting reductive dissolution of As-bearing Fe oxides. However, other soils (e.g. wetland) may see ionic exchange driving pH shifts as a prominent factor driving As release in addition to Eh levels. To assess the contaminant mobility at one of these former industrial sites along the Christina River, we conducted quantitative comparisons of hydrologic and biogeochemical dynamics across time scales ranging from hours to months, and throughout seasonal environmental variations. The use of synchrotron-based X-ray absorption spectroscopy as a geoforensic tool suggests that As from a neighboring Superfund site is likely contributing to recent accumulation of As at the site studied. Data were collected from pressure transducers in wells, multi-level redox sensors, and porewater samplers. Results indicate that groundwater surface interaction induced a tidally controlled redox gradient. In the tidally impacted variably saturated zone, redox potential varied between oxidizing and reducing conditions depending on the water table elevation. This strong correlation indicates that a rising water table may increase contaminant mobility. Porewater samples also confirm increasing arsenic (As) concentration during the rising tide.
