Download or read book The Iron Speciation Paleoredox Proxy written by Simon W. Poulton and published by Cambridge University Press. This book was released on 2021-03-04 with total page 34 pages. Available in PDF, EPUB and Kindle. Book excerpt: In one form or another, iron speciation has had a long history as a paleoredox proxy. The technique has been refined considerably over the years, and the most recent scheme is unique in its potential to distinguish three major oceanic redox states - oxygenated, ferruginous and euxinic. This Element covers the theory behind the proxy, methods involved in applying the technique, and potential complications in interpreting Fe speciation data. A series of case studies are also provided, which highlight how more advanced consideration of the data, often in concert with other techniques, can provide unprecedented insight into the redox state of ancient oceans.
Download or read book Molybdenum as a Paleoredox Proxy written by Stephan R. Hlohowskyj and published by Cambridge University Press. This book was released on 2021-09-09 with total page 57 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molybdenum (Mo) is a widely used trace metal for investigating redox conditions. However, unanswered questions remain that concentration and bulk isotopic analysis cannot specially answer. Improvements can be made by combining new geochemical techniques to traditional methods of Mo analysis. In this Element, we propose a refinement of Mo geochemistry within aquatic systems, ancient rocks, and modern sediments through molecular geochemistry (systematically combining concentration, isotope ratio, elemental mapping, and speciation analyses). Specifically, to intermediate sulfide concentrations governing Mo behavior below the 'switch-point' and dominant sequestration pathways in low oxygen conditions. The aim of this work is to 1) aid and improve the breadth of Mo paleoproxy interpretations by considering Mo speciation and 2) address outstanding research gaps concerning Mo systematics (cycling, partitioning, sequestration, etc.). The Mo paleoproxy has potential to solve ever complex research questions. By using molecular geochemical recommendations, improved Mo paleoproxy interpretations and reconstruction can be achieved.
Download or read book The Uranium Isotope Paleoredox Proxy written by Kimberly V. Lau and published by Cambridge University Press. This book was released on 2019-08-29 with total page 57 pages. Available in PDF, EPUB and Kindle. Book excerpt: Uranium isotopes (238U/235U) have emerged as a proxy to reconstruct the redox conditions of the Earth's oceans and atmosphere based upon the large isotopic fractionation between reduced U(IV) and oxidized U(VI). Variations in 238U/235U, particularly when recorded in carbonate sediments, can track global trends in marine oxygenation and de-oxygenation. It is unique from other proxies because reduction primarily occurs at the sediment-water interface, and this sensitivity makes U isotopes especially relevant for the habitability of benthic animals. This Element covers the background, methods, and case studies of this promising tool for understanding Earth's environmental transitions, as rapid development continues to refine the accuracy of interpretations of 238U/235U records.
Download or read book Iron Formations as Palaeoenvironmental Archives written by Kaarel Mänd and published by Cambridge University Press. This book was released on 2022-01-20 with total page 66 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ancient iron formations - iron and silica-rich chemical sedimentary rocks that formed throughout the Precambrian eons - provide a significant part of the evidence for the modern scientific understanding of palaeoenvironmental conditions in Archaean (4.0–2.5 billion years ago) and Proterozoic (2.5–0.539 billion years ago) times. Despite controversies regarding their formation mechanisms, iron formations are a testament to the influence of the Precambrian biosphere on early ocean chemistry. As many iron formations are pure chemical sediments that reflect the composition of the waters from which they precipitated, they can also serve as nuanced geochemical archives for the study of ancient marine temperatures, redox states, and elemental cycling, if proper care is taken to understand their sedimentological context.
Download or read book Reconstructing Precambrian pCO2 and pO2 Using Paleosols written by Nathan D. Sheldon and published by Cambridge University Press. This book was released on 2021-03-04 with total page 38 pages. Available in PDF, EPUB and Kindle. Book excerpt: Paleosols formed in direct contact with the Earth's atmosphere, so they can record the composition of the atmosphere through weathering processes and products. Herein we critically review a variety of different approaches for reconstructing atmospheric O2 and CO2 over the past three billion years. Paleosols indicate relatively low CO2 over that time, requiring additional greenhouse forcing to overcome the 'faint young Sun' paradox in the Archean and Mesoproterozoic, as well as low O2 levels until the Neoproterozoic. Emerging techniques will revise the history of Earth's atmosphere further and may provide a window into atmospheric evolution on other planets.
Download or read book Vanadium Isotopes written by Sune G. Nielsen and published by Cambridge University Press. This book was released on 2021-01-31 with total page 75 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vanadium isotope ratios (51V/50V) have potential to provide information about changes in past ocean oxygen contents. In particular, V isotopes may find utility in tracing variations at non-zero oxygen concentrations because the redox couple that controls V elemental and isotopic abundances in seawater (vanadate-vanadyl) appears to operate around 10M O2. This characteristic sets V isotopes apart from many other metal isotope redox proxies that require more reducing conditions to register significant changes in their isotope budgets. The oxygen abundance sensitivity range of V isotopes suggests that this paleoproxy could be particularly useful in tracing marine oxygenation changes throughout the Phanerozoic and potentially beyond.
Download or read book Earth History of Oxygen and the iprOxy written by Zunli Lu and published by Cambridge University Press. This book was released on 2020-10-08 with total page 49 pages. Available in PDF, EPUB and Kindle. Book excerpt: How oxygen levels in Earth's atmosphere and oceans evolved has always been a central question in Earth System Science. Researchers have developed numerous tracers to tackle this question, utilizing geochemical characteristics of different elements. Iodine incorporated in calcium carbonate (including biogenic) minerals, reported as I/Ca, is a proxy for dissolved oxygen in seawater. Here we review the rationale behind this proxy, its recent applications and some potential future research directions.
Download or read book Emerging Patterns in Proterozoic Lipid Biomarker Records written by Gordon D. Love and published by Cambridge University Press. This book was released on 2021-03-25 with total page 82 pages. Available in PDF, EPUB and Kindle. Book excerpt: Diverse and abundant lipid biomarker assemblages have been reported from a variety of Proterozoic marine environments from the careful analysis of well-preserved rocks and oils. These molecular biosignatures have provided unique insights into the communities and the environmental conditions which characterized the Proterozoic marine biosphere. We summarize some of the major temporal patterns evident in Proterozoic lipid biomarkers found to date, whilst emphasizing the scale of local heterogeneity found within Neoproterozoic oceans from region to region, and their relationship with the evolving ecological, climatic and ocean/atmospheric redox conditions. Short commentaries on a selection of papers published from the last 15 years of biomarker literature are given. The focus here is on key studies, highlighted for further reading, which have helped to better constrain the timing of the ecological expansion of eukaryotes in Proterozoic oceans or which have impacted on our knowledge of the biological sources of Proterozoic biomarkers.
Download or read book Sr Isotopes in Seawater written by B. Lynn Ingram and published by Cambridge University Press. This book was released on 2022-03-31 with total page 51 pages. Available in PDF, EPUB and Kindle. Book excerpt: Studies of Sr isotopic composition of thousands of samples of marine sediments and fossils have yielded a curve of 87Sr/86Sr versus age for seawater Sr that extends back to 1 billion years. The ratio has fluctuated with large amplitude during this time period, and because the ratio is always uniform in the oceans globally at any one time, it is useful as a stratigraphic correlation and age-dating tool. The ratio also appears to reflect major tectonic and climatic events in Earth history and hence provides clues as to the causes, timing, and consequences of those events. The seawater 87Sr/86Sr ratio is generally high during periods marked by continent-continent collisions, and lower when continental topography is subdued, and seafloor generation rates are high. There is evidence that major shifts in the seawater ratio can be ascribed to specific orogenic events and correlate with large shifts in global climate.
Download or read book Local and Global Controls on Carbon Isotope Chemostratigraphy written by Anne-Sofie Ahm and published by Cambridge University Press. This book was released on 2022-03-31 with total page 48 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over million-year timescales, the geologic cycling of carbon controls long-term climate and the oxidation of Earth's surface. Inferences about the carbon cycle can be made from time series of carbon isotopic ratios measured from sedimentary rocks. The foundational assumption for carbon isotope chemostratigraphy is that carbon isotope values reflect dissolved inorganic carbon in a well-mixed ocean in equilibrium with the atmosphere. However, when applied to shallow-water platform environments, where most ancient carbonates preserved in the geological record formed, recent research has documented the importance of considering both local variability in surface water chemistry and diagenesis. These findings demonstrate that carbon isotope chemostratigraphy of platform carbonate rarely represent the average carbonate sink or directly records changes in the composition of global seawater. Understanding what causes local variability in shallow-water settings, and what this variability might reveal about global boundary conditions, are vital questions for the next generation of carbon isotope chemostratigraphers.
Download or read book Magnesium Isotopes written by Edward T. Tipper and published by Cambridge University Press. This book was released on 2022-03-03 with total page 34 pages. Available in PDF, EPUB and Kindle. Book excerpt: Magnesium is a major constituent in silicate and carbonate minerals, the hydrosphere and the biosphere. Magnesium is constantly cycled between these reservoirs. Since each of the major planetary reservoirs of magnesium have different magnesium isotope ratios, there is scope to use magnesium isotope ratios to trace 1) the processes that cycle Magnesium at a spatial scales from the entire planet to microscopic and 2) the relative fluxes between these reservoirs. This review summarises some of the key motivations, successes and challenges facing the use of magnesium isotopes to construct a budget of seawater magnesium, present and past.
Download or read book Barium Isotopes written by Tristan J. Horner and published by Cambridge University Press. This book was released on 2021-04-22 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the modern marine environment, barium isotope (δ138Ba) variations are primarily driven by barite cycling—barite incorporates 'light' Ba isotopes from solution, rendering the residual Ba reservoir enriched in 'heavy' Ba isotopes by a complementary amount. Since the processes of barite precipitation and dissolution are vertically segregated and spatially heterogeneous, barite cycling drives systematic variations in the barium isotope composition of seawater and sediments. This Element examines these variations; evaluates their global, regional, local, and geological controls; and, explores how δ138Ba can be exploited to constrain the origin of enigmatic sedimentary sulfates and to study marine biogeochemistry over Earth's history.
Download or read book Atmospheric Evolution on Inhabited and Lifeless Worlds written by David C. Catling and published by Cambridge University Press. This book was released on 2017-04-13 with total page 595 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive and authoritative text on the formation and evolution of planetary atmospheres, for graduate-level students and researchers.
Download or read book Proxies in Late Cenozoic Paleoceanography written by C. Hillaire-Marcel and published by Elsevier. This book was released on 2007-05-25 with total page 863 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume is the first in a series of two books dedicated to the paleoceanography of the Late Cenozoic ocean. The need for an updated synthesis on paleoceanographic science is urgent, owing to the huge and very diversified progress made in this domain during the last decade. In addition, no comprehensive monography still exists in this domain. This is quite incomprehensible in view of the contribution of paleoceanographic research to our present understanding of the dynamics of the climate-ocean system. The focus on the Late Cenozoic ocean responds to two constraints. Firstly, most quantitative methods, notably those based on micropaleontological approaches, cannot be used back in time beyond a few million years at most. Secondly, the last few million years, with their strong climate oscillations, show specific high frequency changes of the ocean with a relatively reduced influcence of tectonics. The first volume addresses quantitative methodologies to reconstruct the dynamics of the ocean andthe second, major aspects of the ocean system (thermohaline circulation, carbon cycle, productivity, sea level etc.) and will also present regional synthesis about the paleoceanography of major the oceanic basins. In both cases, the focus is the "open ocean leaving aside nearshore processes that depend too much onlocal conditions. In this first volume, we have gathered up-to-date methodologies for the measurement and quantitative interpretation of tracers and proxies in deep sea sediments that allow reconstruction of a few key past-properties of the ocean( temperature, salinity, sea-ice cover, seasonal gradients, pH, ventilation, oceanic currents, thermohaline circulation, and paleoproductivity). Chapters encompass physical methods (conventional grain-size studies, tomodensitometry, magnetic and mineralogical properties), most current biological proxies (planktic and benthic foraminifers, deep sea corals, diatoms, coccoliths, dinocysts and biomarkers) and key geochemical tracers (trace elements, stable isotopes, radiogenic isotopes, and U-series). Contributors to the book and members of the review panel are among the best scientists in their specialty. They represent major European and North American laboratories and thus provide a priori guarantees to the quality and updat of the entire book. Scientists and graduate students in paleoclimatology, paleoceanography, climate modeling, and undergraduate and graduate students in marine geology represent the target audience. This volume should be of interest for scientists involved in several international programs, such as those linked to the IPCC (IODP – Integrated Ocean Drilling Program; PAGES – Past Global Changes; IMAGES – Marine Global Changes; PMIP: Paleoclimate Intercomparison Project; several IGCP projects etc.), That is, all programs that require access to time series illustrating changes in the climate-ocean system. - Presents updated techniques and methods in paleoceanography - Reviews the state-of-the-art interpretation of proxies used for quantitative reconstruction of the climate-ocean system - Acts as a supplement for undergraduate and graduate courses in paleoceanography and marine geology
Download or read book Large Igneous Provinces written by Richard E. Ernst and published by Cambridge University Press. This book was released on 2014-09-25 with total page 667 pages. Available in PDF, EPUB and Kindle. Book excerpt: Large igneous provinces (LIPs) are intraplate magmatic events, involving volumes of mainly mafic magma upwards of 100,000 km3, and often above 1 million km3. They are linked to continental break-up, global environmental catastrophes, regional uplift and a variety of ore deposit types. In this up-to-date, fascinating book, leading expert Richard E. Ernst explores all aspects of LIPs, beginning by introducing their definition and essential characteristics. Topics covered include continental and oceanic LIPs; their origins, structures, and geochemistry; geological and environmental effects; association with silicic, carbonatite and kimberlite magmatism; and analogues of LIPs in the Archean, and on other planets. The book concludes with an assessment of LIPs' influence on natural resources such as mineral deposits, petroleum and aquifers. This is a one-stop resource for researchers and graduate students in a wide range of disciplines, including tectonics, igneous petrology, geochemistry, geophysics, Earth history, and planetary geology, and for mining industry professionals.
Download or read book Stable Isotope Geochemistry written by Jochen Hoefs and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 333 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stable Isotope Geochemistry is an introduction to the use of stable isotopes in the fields of geoscience. It is subdivided into three parts: - theoretical and experimental principles; - fractionation mechanisms of light elements; - the natural variations of geologically important reservoirs. In this updated 4th edition many of the chapters have been expanded, especially those on techniques and environmental aspects. The main focus is on recent results and new developments. For students and scientists alike the book will be a primary reference with regard to how and where stable isotopes can be used to solve geological problems.
Download or read book Mineral Deposits of North Africa written by Mohammed Bouabdellah and published by Springer. This book was released on 2016-06-21 with total page 585 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume presents an exhaustive overview of major orebodies and mineral deposits of North Africa. It is intended both for academic researchers and especially for exploration geologists interested in mineral exploration in the northern part of the African continent. Recent changes in the mining laws of most countries in this region have encouraged international mining companies to invest in local mineral industries. Accordingly, this volume will be very useful for these professionals, as well as for researchers in the field of economic geology.
