Download or read book Synthetic Multidentate Macrocyclic Compounds written by Reed Izatt and published by Elsevier. This book was released on 2012-12-02 with total page 335 pages. Available in PDF, EPUB and Kindle. Book excerpt: Synthetic Multidentate Macrocyclic Compounds attempts to bring together selected chapters in which the authors discuss in depth investigations in important areas of macrocycle research. The chapters deal mainly with macrocyclic compounds (saturated polyethers and their derivatives), and macrobicyclic compounds (cryptates). The book contains six chapters and opens with a first-hand account of the initial synthesis of the cyclic polyethers. This is followed by separate chapters on the synthesis of cyclic polyethers, polyether amines, and polyether sulfides; the synthesis of multidentate compounds; and the structure of synthetic macrocyclic compounds and their cation complexes. Subsequent chapters deal with the rates of reactions and the mechanism by which synthetic macrocyclic ligands complex substrates in solution; and commercial applications of the synthetic macrocyclic ligands. This book is primarily aimed at researchers and students in organic, physical, analytical, and inorganic chemistry, and in chemical engineering. However, it will also be of interest to many in the areas of biology, biochemistry, and physiology. Extensive literature references are found in each chapter.
Download or read book Kinetic Studies of Synthetic Multidentate Macrocyclic Compounds written by Gerard W. Liesegang and published by . This book was released on 1976 with total page 65 pages. Available in PDF, EPUB and Kindle. Book excerpt: The recent literature on the kinetic properties of a variety of synthetic multidentate macrocyclic compounds has been reviewed and discussed. At the beginning of this chapter, a brief discussion of kinetic and mechanistic studies of antibiotics has been reviewed. Then the synthetic macrocyclic compounds are treated within the framework of their different classes; i.e. crown ethers, cryptates and macrocyclic tetramines. In addition to a review of the kinetic research, attempts were made to clarify certain aspects of the literature and to discuss similarities and differences between the various classes. Finally, the last section discusses possible kinetic studies of more novel Host molecules designed and synthesized by Cram.
Download or read book Template Synthesis of Macrocyclic Compounds written by N. V. Gerbeleu and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 574 pages. Available in PDF, EPUB and Kindle. Book excerpt: The synthesis of macrocycles is an art in itself. Template-controlled synthesis provides elegant access to fascinating macrocyclic structures. Polyazamacrocycles, crown ethers, cryptands, rotaxanes, knots -- the range of macrocyclic compounds is as broad as their potential application as molecular switches, in ion exchange, electron transfer or catalysis. This book provides authoritative information on all aspects of template-controlled macrocyclizations. It covers in depth the current state of research on template processes - novel synthetic techniques and mechanistic approaches. The critical discussion of the diverse synthetic routes includes the detailed characterization of the broad variety of macrocyclic products. References to applications of macrocyclic compounds and over 1,500 citations make this handbook an indispensable tool for chemists in academia and industry. Researchers in organic and supramolecular chemistry, biotechnology, and inorganic chemistry will find inspiration for the design, synthesis, and myriad uses of new synthetic macrocycles.
Download or read book Host Guest Complex Chemistry Macrocycles written by F. Vögtle and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 421 pages. Available in PDF, EPUB and Kindle. Book excerpt: The scientific and practical interest in coronands (crown ethers), cryptands, podands as complexing agents for cations as well as for anions and neutral low molecular species is undeniable 1,2). The chemistry of crown compounds is steadily increasing. About 250 original papers dealing with crown chemistry appeared only in 1980. New molecules· with crown ether properties are constantly synthesized and new applications discov,?red. Owing to lack of space, only a small number of the original publications is men tioned here. Thus, in the literature compilation only some, but relevant works are selected for each chapter. Whenever possible, reference is made to reviews or review-like articles alone by means of which origin,al works can be consulted. The reviews given under ref. 1) are considered to be the most relevant. The formulae presented in the figures should be understood as representative structures outlining a specific field. 2 Classification of Oligo-/Multidentate Neutral Ligands and of their Complexes Today, a distinction is made between the classical ring oligoethers (crown ethers) and monocyclic coronands, oligocyclic spherical cryptands and the acyclic podands with respect to topological aspects 3). This classification and the topology are illustrated in Fig. 1, each figure representing the minimum number of donor atoms and chain segments characteristic of each class of compounds. Multidentate mono cyclic ligands with any type of donor atoms are called coronands ("crown compounds"), while the term crown ether should be reserved for cyclic oligoethers exclusively containing oxygen as donor atom.
Download or read book Macrocyclic Polyamines written by Xiaoqi Yu and published by John Wiley & Sons. This book was released on 2018-02-20 with total page 226 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first comprehensive book focusing on synthesis and applications of macrocyclic polyamines and their derivatives Macrocyclic polyamines are a class of widely used important compounds. This is the first book that systematically summarizes the synthesis and applications of macrocyclic polyamines and their analogues, including the properties and synthetic methods of macrocyclic polyamines, chemical nucleases based on macrocyclic polyamines, the derivatives of macrocyclic polyamines as nano-vector materials, macrocyclic polyamines derivatives for bio-imaging, chemical sensors based on macrocyclic polyamines, and other applications of macrocyclic polyamines. Macrocyclic Polyamines: Synthesis and Applications includes most of the studies involving macrocyclic polyamines and their derivatives, and may be used as a reference for the researchers in related fields. It offers in-depth coverage of cyclization modes; special procedures for tetraza macrocyclic compounds; diacids-diamines condensation; oxidative DNA cleaving by macrocyclic polyamines; lipids with cationic MPA headgroups; the derivatives of DOTA, DO3A, and PCTA; receptors for anions; sensors for bioactive molecules; macrocyclic polyamines for solvent extraction and membrane transport of amino acids and their derivatives, electrophoretic separation, and open-tubular CEC; and much more. ?The first book that systematically summarizes the chemistry of macrocyclic polyamines and their derivatives in terms of synthetic methods for their preparation, functionalization, and application in the main fields of chemical sensors, chemical nucleases, drug-delivery, bio-imaging and vector materials ?Provides a comprehensive reference for the researchers working on macrocyclic polyamines ?Offers train of thought in related research fields such as organic chemistry, coordination chemistry, analytical chemistry, supramolecular chemistry, biomaterials, etc. Macrocyclic Polyamines: Synthesis and Applications will not only provide a reference for the researchers working on macrocyclic polyamines, but also offer opportunities for researchers in related research fields to understand the benefits of these key compounds.
Download or read book Synthesis of Macrocyclic Multidentate Compounds written by Larry Don Bratton and published by . This book was released on 1989 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Calixarenes A Versatile Class of Macrocyclic Compounds written by Jacques Vicens and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Design of Macrocyclic Compounds for Biomedical Applications written by Pavel Padnya and published by Frontiers Media SA. This book was released on 2021-09-13 with total page 101 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Cation Binding by Macrocycles written by Inoue and published by Routledge. This book was released on 2018-10-03 with total page 684 pages. Available in PDF, EPUB and Kindle. Book excerpt: This reference details the theory and application of cation complexation, including the design and synthesis of various cyclic systems, these materials' use as transport systems, in complexation and selectivity studies by macrocyclic systems, and methodologies for understanding these phenomena. In a
Download or read book Synthetic Coordination and Organometallic Chemistry written by Alexander D. Garnovskii and published by CRC Press. This book was released on 2003-04-25 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.
Download or read book Liquid Membranes written by Takeo Araki and published by CRC Press. This book was released on 1990-05-09 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt: This interesting work extensively describes newer applications of liquid membrane systems which contain molecular and/or ion recognizing carrier compounds and the related characteristic membrane materials. This volume focuses on the current knowledge about chemistry, biology and related technology of liquid membranes. It reviews the most recent advances in design and characteristics of synthetic liquid membrane transport. Additionally, this fascinating reference discusses up-to-date topics in the analytical and separation science, plus biomimetic membrane technology. Because this book is presented in a compact, understandable format, readers can start from biological cell membranes, then net aspects of host-guest chemistry for effective recognition of ions and molecules, followed by its application for artificial sensors-such as neuro-systems, functionalized new detergents, mechanochemical systems, and separation chemistry. This publication is ideal for graduate-level students and will stimulate university and industry researchers.
Download or read book Oligomer Technology and Applications written by Uglea and published by CRC Press. This book was released on 1998-01-05 with total page 1025 pages. Available in PDF, EPUB and Kindle. Book excerpt: Details laboratory and industrial synthesis and applications of oligomers-suggesting practical solutions to the on-the-job problems as well as exploring processing devices and techniques for industrial-scale production of new oligomer types.
Download or read book Nobel Laureates in Chemistry 1901 1992 written by James K. Laylin and published by Chemical Heritage Foundation. This book was released on 1993-10-30 with total page 820 pages. Available in PDF, EPUB and Kindle. Book excerpt: Through new perspectives from a mix of original monographs, biographies, autobiographical memoirs, edited collections of essays and documentary sources, translations, classic reprints, and pictorial volumes, this series will document the individuals, ideas, institutions, and innovations that have created the modern chemcial sciences.
Download or read book The Chemistry of Macrocyclic Ligand Complexes written by Leonard F. Lindoy and published by Cambridge University Press. This book was released on 1989-03-23 with total page 281 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book contains an overview of complex formation by macrocyclic ligand systems. The study of macrocyclic chemistry represents a major area of activity which impinges on a range of other areas in both chemistry and biochemistry. The field has characteristically yielded many interesting and unusual compounds. The text discusses the structures and properties of macrocyclic compounds; the synthesis of macrocycles; polyether crown and related systems; metal-ion and molecular recognition (host-guest chemistry); as well as kinetic, thermodynamic and electrochemical aspects of a range of macrocyclic systems. A discussion of the different categories of naturally occurring macrocycles is also included. Specialist and non-specialist alike will find this a useful text. Apart from serving as a convenient reference for established workers in the field, it should also prove useful to new graduate students as well as to researchers from other areas who seek a general introduction to the subject. The topics discussed also provide a suitable basis for a senior undergraduate or graduate course in macrocyclic chemistry and inorganic complexes.
Download or read book Bioenergetics and Thermodynamics Model Systems written by A. Braibanti and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 471 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the NATO Advanced Study Institute, Tabiano, Parma, Italy, May 21-June 1, 1979
Download or read book Macrocyclic Compounds in Analytical Chemistry written by Yu A. Zolotov and published by Wiley-Interscience. This book was released on 1997-07-15 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: Macrocycles are an important class of reagents in modern analytical chemistry because of their high selectivity. Macrocyclic chemistry is still a relatively new field, but as research progresses, the volume of data about macrocycles and their analytical applications continues to grow at a breathtaking pace. Written for analytical chemists who need to keep abreast of state-of-the-art applied macrocyclic chemistry, this groundbreaking volume presents the findings of chemists from around the world who have devoted themselves to the study of macrocycles. Macrocyclic Compounds in Analytical Chemistry covers all classes of macrocyclic compounds. Two chapters that will be of general interest across all analytical specialties are those treating the synthesis of macrocyclic compounds and complexation and selectivity. Other topics covered in detail are: Solvent extractionseparation and subsequent determination of elementsfrom crown ethers and alkali cations to porphyrins and transition metals Sorption and chromatographyincludes examples from most chromatographic techniques Ion-selective electrodes Separation and determination of organic compoundscovers both fundamental and analytical uses of host-guest complexation Macrocyclic Compounds in Analytical Chemistry is a valuable reference for research and practicing analytical chemists as well as inorganic chemists specializing in hydrometallurgy and extraction. It will also be of interest to organic and theoretical chemists interested in the practical applications of organic, synthetic macrocyles. This is the first book devoted to the macrocyclic chemistry research conducted between the 1960s and the 1990s. Covering all classes of macrocyclic compounds, this groundbreaking volume presents the findings of chemists from around the world who have devoted themselves to the study of macrocycles. An indispensable reference for research and practicing analytical chemists, Macrocyclic Compounds in Analytical Chemistry reports previously unpublished findings concerning a wide range of topics, including: Macrocyclic synthesis Complexation and selectivity Solvent extraction and separation Sorption and chromatography Ion-selective electrodes Separation and determination of organic compounds
Download or read book Topics in Stereochemistry written by Ernest L. Eliel and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: This seminal series, first edited by Ernest Eliel, responsible for some of the major advances in stereochemistry and the winner of the ACS Priestley Medal in 1996, provides coverage of the major developments of the field of stereochemistry. The scope of this series is broadly defined to encompass all fields of chemical and biological sciences that are founded on molecular and supramolecular interactions. Insofar as chemical, physical, and biological properties are determined by molecular shape and structure, the importance of stereochemistry is fundamental to and consequential for all natural sciences. Topics in Stereochemistry serves as a multidisciplinary series that enriches all of chemistry. Aimed at advanced students, university professors and teachers as well as researchers in pharmaceutical, agricultural, biotechnological, polymer, materials, and fine chemical industries, Topics in Stereochemistry publishes definitive and scholarly reviews in stereochemistry and has long been recognized as the gold standard reference work in this field. Covering the effect of chirality on all aspects of molecular interaction from the fundamental physical chemical properties of molecules and their molecular physics to the application of chirality in new areas such as its applications in materials science, Topics in Stereochemistry explores a wide variety of properties, both physical and chemical of isomers with a view to their applications in a number of disciplines from biochemistry to materials science.
