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Book Synthesis of Transition Metal Carbonyl Clusters with Phosphine Ligands

Download or read book Synthesis of Transition Metal Carbonyl Clusters with Phosphine Ligands written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of transition metal chalcogenide polynuclear clusters is a rapidly expanding area. The increasing interest is due to the search for structural models and precursors of extended inorganic solids with novel electronic, magnetic and optical properties. Our interest for the synthesis of a variety of transition - etal clusters is due to their use as a model and precursors for materials and catalyst. Synthesis and study of a variety of ligand substituted iron carbonyl cluster has been carried out to understand the reactivity features and structural variety. The main focus has been on the transition metal clusters containing chalcogens which act as bridges between different metal fragments and are helpful in cluster growth reactions and maintains the cluster integrity. A synthetic strategy has been developed to prepare a mixed metal cluster when a dichloromethane solution of [Fe3Y2(CO)6], Y=S, Se, Te and ML4 (M=Pd, L=PPh3) was reacted at room temperature in presence of trimethylamine-N-oxide. Substitution reaction of carbonyl groups by triphenylphosphine and bis(diphenylphosphino)methane ligands results in the formation of different types of trinuclear clusters. Homo metallic cluster as well mixed metal clusters with phosphine ligands has been synthesized by a room temperature reaction and characterized by FTIR, proton and 31P NMR spectroscopy. Some of the transition metal cluster contains chelating phosphine ligands which stabilizes the cluster integrity.

Book Homoleptic and Heteroleptic Early Transition Metal Carbonyl Complexes

Download or read book Homoleptic and Heteroleptic Early Transition Metal Carbonyl Complexes written by Wiebke Unkrig and published by . This book was released on 2020 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Index to Theses with Abstracts Accepted for Higher Degrees by the Universities of Great Britain and Ireland and the Council for National Academic Awards

Download or read book Index to Theses with Abstracts Accepted for Higher Degrees by the Universities of Great Britain and Ireland and the Council for National Academic Awards written by and published by . This book was released on 1998 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Theses on any subject submitted by the academic libraries in the UK and Ireland.

Book The Preparation and Reactions of Transition Metal Carbonyl Cluster Compounds

Download or read book The Preparation and Reactions of Transition Metal Carbonyl Cluster Compounds written by G. C. Casey and published by . This book was released on 1974 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis of Pnictosulfide Anions and Their Reactions with Transition Metal Complexes

Download or read book Synthesis of Pnictosulfide Anions and Their Reactions with Transition Metal Complexes written by Kristie L. Bowman and published by . This book was released on 1996 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Metal Amide Chemistry

    Book Details:
  • Author : Michael Lappert
  • Publisher : John Wiley & Sons
  • Release : 2008-12-23
  • ISBN : 9780470740378
  • Pages : 370 pages

Download or read book Metal Amide Chemistry written by Michael Lappert and published by John Wiley & Sons. This book was released on 2008-12-23 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by internationally recognised leaders in the field, Metal Amide Chemistry is the authoritative survey of this important class of compounds, the first since Lappert and Power’s 1980 book “Metal and Metalloid Amides.” An introduction to the topic is followed by in-depth discussions of the amide compounds of: alkali metals alkaline earth metals zinc, cadmium and mercury the transition metals group 3 and lanthanide metals group 13 metals silicon and the group 14 metals group 15 metals the actinide metals Accompanied by a substantial bibliography, this is an essential guide for researchers and advanced students in academia and research working in synthetic organometallic, organic and inorganic chemistry, materials chemistry and catalysis.

Book Applied Homogeneous Catalysis with Organometallic Compounds

Download or read book Applied Homogeneous Catalysis with Organometallic Compounds written by Boy Cornils and published by John Wiley & Sons. This book was released on 2017-12-26 with total page 1778 pages. Available in PDF, EPUB and Kindle. Book excerpt: The completely revised third edition of this four-volume classic is fully updated and now includes such topics as as CH-activation and multicomponent reactions. It describes the most important reaction types, new methods and recent developments in catalysis. The internationally renowned editors and a plethora of international authors (including Nobel laureate R. Noyori) guarantee high quality content throughout the book. A "must read" for everyone in academia and industry working in this field.

Book Activation of Small Molecules

Download or read book Activation of Small Molecules written by William B. Tolman and published by John Wiley & Sons. This book was released on 2006-12-13 with total page 382 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first to combine both the bioinorganic and the organometallic view, this handbook provides all the necessary knowledge in one convenient volume. Alongside a look at CO2 and N2 reduction, the authors discuss O2, NO and N2O binding and reduction, activation of H2 and the oxidation catalysis of O2. Edited by the highly renowned William Tolman, who has won several awards for his research in the field.

Book Organometallics and Catalysis

Download or read book Organometallics and Catalysis written by Manfred Bochmann and published by Oxford University Press, USA. This book was released on 2015 with total page 429 pages. Available in PDF, EPUB and Kindle. Book excerpt: A succinct review of the essential concepts of organometallic chemistry, enriched throughout with examples that demonstrate how our understanding of organometallic chemistry has led to new applications in research and industry - not least in relation to catalysis.

Book Organometallic Chemistry in Industry

Download or read book Organometallic Chemistry in Industry written by Thomas J. Colacot and published by John Wiley & Sons. This book was released on 2020-05-26 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: Showcases the important role of organometallic chemistry in industrial applications and includes practical examples and case studies This comprehensive book takes a practical approach to how organometallic chemistry is being used in industrial applications. It uniquely offers numerous, real-world examples and case studies that aid working R&D researchers as well as Ph.D. and postdoc students preparing to ace interviews in order to enter the workforce. Edited by two world-leading and established industrial chemists, the book covers flow chemistry (catalytic and non-catalytic organometallic chemistry), various cross-coupling reactions (C-C, C-N, and C-B) in classical batch chemistry, conjugate addition reactions, metathesis, and C-H arylation and achiral hydrogenation reactions. Beginning with an overview of the many industrial milestones within the field over the years, Organometallic Chemistry in Industry: A Practical Approach provides chapters covering: the design, development, and execution of a continuous flow enabled API manufacturing route; continuous manufacturing as an enabling technology for low temperature organometallic chemistry; the development of a nickel-catalyzed enantioselective Mizoroki-Heck coupling; and the development of iron-catalyzed Kumada cross-coupling for the large scale production of Aliskiren intermediates. The book also examines aspects of homogeneous hydrogenation from industrial research; the latest industrial uses of olefin metathesis; and more. -Includes rare industrial case studies difficult to find in current literature -Helps readers successfully carry out their own reactions -Covers topics like flow chemistry, cross-coupling reactions, and dehydrative decarbonylation -Features a foreword by Nobel Laureate R. H. Grubbs -A perfect resource for every R&D researcher in industry -Useful for PhD students and postdocs: excellent preparation for a job interview Organometallic Chemistry in Industry: A Practical Approach is an excellent resource for all chemists, including those working in the pharmaceutical industry and organometallics.

Book Molecular Clusters of the Main Group Elements

Download or read book Molecular Clusters of the Main Group Elements written by Matthias Driess and published by John Wiley & Sons. This book was released on 2008-11-21 with total page 460 pages. Available in PDF, EPUB and Kindle. Book excerpt: With more than 20 contributions from leading research groups, this book provides essential information for chemists and materials scientists working with molecular clusters. It treats both homonuclear and heteronuclear clusters, including: the theory and concepts in main-group cluster chemistry, * novel boranes and heteroboranes, * silicon/germanium/tin clusters, * alkali metal suboxides, * clusters in alloys with mercury, * chalkogen clusters * and numerous other compound classes. The whole is illustrated by examples of the great potential for technical applications such as electron storage, cancer therapy and in optoelectronic devices. Its systematic coverage of all relevant main group elements makes this the prime reference source in the field.

Book N Heterocyclic Carbenes

    Book Details:
  • Author : Silvia Diez-Gonzalez
  • Publisher : Royal Society of Chemistry
  • Release : 2016-11-04
  • ISBN : 1782626816
  • Pages : 637 pages

Download or read book N Heterocyclic Carbenes written by Silvia Diez-Gonzalez and published by Royal Society of Chemistry. This book was released on 2016-11-04 with total page 637 pages. Available in PDF, EPUB and Kindle. Book excerpt: In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of excess ligand in catalytic reactions. Also, NHC‒metal complexes are often insensitive to air and moisture, and have proven remarkably resistant to oxidation. This book showcases the wide variety of applications of NHCs in different chemistry fields beyond being simple phosphine mimics. This second edition has been updated throughout, and now includes a new chapter on NHC‒main group element complexes. It covers the synthesis of NHC ligands and their corresponding metal complexes, as well as their bonding and stereoelectronic properties and applications in catalysis. This is complemented by related topics such as organocatalysis and biologically active complexes. Written for organic and inorganic chemists, this book is ideal for postgraduates, researchers and industrialists.

Book The Organometallic Chemistry of the Transition Metals

Download or read book The Organometallic Chemistry of the Transition Metals written by Robert H. Crabtree and published by John Wiley & Sons. This book was released on 2005-06-14 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.

Book Fundamentals of Organometallic Catalysis

Download or read book Fundamentals of Organometallic Catalysis written by Dirk Steinborn and published by John Wiley & Sons. This book was released on 2011-11-30 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vor allem an Studenten fortgeschrittener Semester und Doktoranden gerichtet ist dieses Lehrbuch der Katalyse mit metallorganischen Verbindungen, das auch biologisch relevanten Reaktionen viel Platz einräumt. Hervorragend zum Selbststudium geeignet - mit zahlreichen Übungsaufgaben, nach Schwierigkeitsgraden geordnet und durch Lösungen ergänzt.