Download or read book Synthesis Characterization and Catalytic Activity of New Manganese II Carboxylate Complexes written by Martin Curran and published by . This book was released on 1996 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis Characterization and Reactivity of Manganese II Complexes Containing N heterocyclic Carbene Ligands written by Venkateswaran Mahesh Krishnan and published by . This book was released on 2013 with total page 74 pages. Available in PDF, EPUB and Kindle. Book excerpt: A series of divalent manganese complexes containing N -heterocyclic carbene (NHC) ligands were synthesized and characterized in solution and the solid state. Chlorido complexes of Mn(II) containing the NHC ligands 1,3-dimesitylimidazol-2-ylidene (IMes) and 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) were prepared in straightforward fashion by direct carbene addition to MnCl 2 (thf)1.5. The chlorido complexes were found to be ineffective precatalysts in Kumada-type coupling reactions of simple aryl halides. Cyclic voltammetry studies of one of the chloride complexes, [MnCl2 (IMes)2 ], demonstrate no electrochemically accessible reduction events in tetrahydrofuran, possibly accounting for the lack of catalytic activity. Chlorido complexes containing both IMes and IPr ligands serve as precursors to alkyl and aryl compounds of Mn(II). Characterization of the alkyl and aryl complexes is reported, and comparisons are made between these complexes and similar compounds in the chemical literature.

Download or read book Synthesis Characteristics and Catalytic Activity of New Manganese II Amino Acid Complexes written by Maura Jackman and published by . This book was released on 1996 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis Characterization And Catalytic Activity Of Ba II Complexes written by Rohit Patel and published by LAP Lambert Academic Publishing. This book was released on 2015-10-25 with total page 108 pages. Available in PDF, EPUB and Kindle. Book excerpt: In order to explain the formulae and structures of the complex compounds or complexes, formed by transition metal salts with molecular species such as ammonia, Werner coined the terms primary valence and secondary valence.. These concepts remain valid today except that the term oxidation state has replaced 'primary valence' and the term coordination number has replaced 'secondary valence' Werner had recognized that a transition metal salt could form a complex compound in which the metal ion became bonded to a number of groups which need not necessarily be the counter anions originally present in the salt. The orientations in space of these metal-bond groups would lead to the complex having a particular geometric structure. Coordination compound has always been a challenge to the inorganic chemistry. The scientists of coordination of compound are Kooser, Lewis, Sidgwick, etc.

Download or read book Synthesis Characterization and Antibacterial Activities of Manganese II Cobalt II Copper II Iron II Nickel II and Cadmium II Mixed Ligand Complexes Containing Amino Acid L Lysine and 1 10 Phenanthroline Int written by Taghreed H. Al-Noor and published by . This book was released on 2012 with total page 20 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis and Characterization of a CCC NHC Manganese Complex and Its Catalytic Activity in Alpha alkylation Reactions of Ketones Using Alcohols Acceptorless Dehydrogenative Coupling Reaction written by Thi Bao Tran Nguyen and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: N-heterocyclic carbenes are essential for the synthesis and stabilization of various metal complexes due to the tendency to act as sigma-donor of sp2 hybridized lone pair in carbene into sigma-accepting orbital of metals. Meanwhile, the electronic and steric properties of pincer complexes can be fine-tuned by modifying three sites bonded to the metals. Utilizing advantages of both NHCs and the pincer structures, NHCs-based pincer complexes have become increasingly developed in recent years. After the discovery of zirconium and rhodium complexes with CCC-NHC backbones reported in 2005, Hollis’s group has been interested in applying the CCC-NHC pincer precursor for other transition metals. Manganese, the third most abundant transition metal in the earth’s crust, has lower cost and less toxic features compared to most of the others. Herein, the CCC-NHCs manganese pincer complex is synthesized and characterized and its catalytic activity in alpha- alkylation reaction of ketones using alcohols was studied.

Download or read book Advances in the Development of Artificial Metalloenzymes written by Tatjana N. Parac-Vogt and published by Frontiers Media SA. This book was released on 2019-11-05 with total page 167 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactions catalyzed by metalloenzymes have great potential for applications in the biotechnology and pharmaceutical industries. While only a few of these enzymes have yet been used in such applications, in the last few decades numerous efficient, selective, environmentally friendly and economical synthetic analogues have been described, including supramolecular, polymeric, nanoparticulate and lowmolecular- weight organometallic complexes, and metal organic frameworks. In this Research Topic, we present a collection of original research and review articles that show significant recent advances made in the rational design of such artificial metalloenzymes.

Download or read book Complexes of tetraphenylporphinato Manganese IV and Iodosylbenzene written by John Anthony Smegal and published by . This book was released on 1983 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Spin States in Biochemistry and Inorganic Chemistry written by Marcel Swart and published by John Wiley & Sons. This book was released on 2015-09-17 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: It has long been recognized that metal spin states play a central role in the reactivity of important biomolecules, in industrial catalysis and in spin crossover compounds. As the fields of inorganic chemistry and catalysis move towards the use of cheap, non-toxic first row transition metals, it is essential to understand the important role of spin states in influencing molecular structure, bonding and reactivity. Spin States in Biochemistry and Inorganic Chemistry provides a complete picture on the importance of spin states for reactivity in biochemistry and inorganic chemistry, presenting both theoretical and experimental perspectives. The successes and pitfalls of theoretical methods such as DFT, ligand-field theory and coupled cluster theory are discussed, and these methods are applied in studies throughout the book. Important spectroscopic techniques to determine spin states in transition metal complexes and proteins are explained, and the use of NMR for the analysis of spin densities is described. Topics covered include: DFT and ab initio wavefunction approaches to spin states Experimental techniques for determining spin states Molecular discovery in spin crossover Multiple spin state scenarios in organometallic reactivity and gas phase reactions Transition-metal complexes involving redox non-innocent ligands Polynuclear iron sulfur clusters Molecular magnetism NMR analysis of spin densities This book is a valuable reference for researchers working in bioinorganic and inorganic chemistry, computational chemistry, organometallic chemistry, catalysis, spin-crossover materials, materials science, biophysics and pharmaceutical chemistry.

Download or read book Part I Manganese Oxide Containing Layered Double Hydroxides Materials Synthesis and Characterization written by Josanlet C. Villegas and published by . This book was released on 2006 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis Characterization Application Of Mn III Complex Compound written by Seema Gudden and published by LAP Lambert Academic Publishing. This book was released on 2012-05 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: Manganese has variable oxidation states and appears as Mn(III) with redox function. It plays an important role in numerous biological processes associated with utilization or generation of hydrogen peroxide or dioxygen. The functions of these type are known viz manganese superoxide dismutase, manganese catalase , manganese peroxidase, manganese ribonucleotide reductase and oxygen involving complex in photo system-II. This has prompted to under take the coordination of Mn(III) ions with ligands. The oxygen donar ligands used for the coordination are -diketones since -diketones anions are powerful chelating species and they give stable Mn(III) complex which can further be used for preparing other Mn(III) species that can be used as catalysts. The tris ( -diketonate) Mn(III) complex gives substitution as well as addition reactions with other ligands. Here nitrogen donar ligands used are ethylenediamine, propylenediamine and hexamethylenediamine. The nitrogen donar atom ligands ultimately result in the mixed ligand complexes for Mn(III) which are more stable in this oxidation state of manganese. In this way the aim of preparing stable Mn(III) complexes is achieved by the oxygen donor

Download or read book Synthesis Characterization and Catalytic Testing of Manganese III imine Complex as Catalyst for Epoxidation Reaction written by Nurul Atiqah Mat Deris and published by . This book was released on 2010 with total page 34 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Manganese II Indenyl Compounds written by Ryan M. Meier and published by . This book was released on 2012 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Index to Theses with Abstracts Accepted for Higher Degrees by the Universities of Great Britain and Ireland and the Council for National Academic Awards written by and published by . This book was released on 2009 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Clathrochelates written by Y.Z. Voloshin and published by Elsevier. This book was released on 2002-09-19 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: Clathrochelates are compounds which contain a metal ion encapsulated within a three dimensional cage of macrobicyclic ligand atoms. Within this cage the metal has unique properties and is to a great extent isolated from environmental factors. Such complexes are suitable as models of the most essential biological systems, membrane transport, electron carriers, highly selective and sensitive analytical reagents, catalysts for photochemical and redox processes, cation and anion receptors, etc. The aim of this monograph is to generalize and analyze experimental and theoretical data on clathrochelates in order to promote further research in this promising field of chemistry. Chapter 1 gives general concepts of complexes with encapsulated metal ions, discusses basic specific features of these compounds, considers and characterizes the main types of compounds with encapsulated metal ions and the main classes of clathrochelates, and includes the current nomenclature. Chapter 2 deals with the pathways of clathrochelate synthesis and the general procedures for the synthesis of macrobicyclic tris-dioximates, phosphorus-containing tris-diiminates, sepulchrates, sarcophagi-nates, and polyene and other types of clathrochelate complexes. Chapter 3 concerns studies of the electronic and spatial structure of clathrochelate complexes. In Chapter 4, the kinetics and mechanism of synthesis and decomposition reactions of macrobicyclic tris-dioximates, sarcophaginates, and sepulchrates in solution and gas phases are discussed. Chapter 5 considers the electrochemical, photochemical, and some other characteristics of clathrochelates and their applications associated with these characteristics. Finally, the practical applications of the unique properties of clathrochelates and perspectives on the synthesis of new clathrochelates are described in Chapters 6 and 7, respectively.

Download or read book From Octahedral Open Structures to Octahedral Tetrahedral Open Structures written by Wei Tong and published by . This book was released on 2001 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Olefin Polymerization written by Walter Kaminsky and published by Wiley-VCH. This book was released on 2006-08-18 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: With an enormous velocity, olefin polymerization has expanded to one of the most significant fields in polymers since the first industrial use about 50 years ago. In 2005, 100 million tons of polyolefins were produced - the biggest part was catalyzed by metallorganic compounds. The Hamburg Macromolecular Symposium 2005 with the title "Olefin Polymerization" involved topics such as new catalysts and cocatalysts, kinetics, mechanism and polymer reaction engineering, synthesis of special polymers, and characterization of polyolefins. The conference combined scientists from different disciplines to discuss latest research results of polymers and to offer each other the possibility of cooperation. This is reflected in this volume, which contains invited lectures and selected posters presented at the symposium.