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Book Transition Metal Carbonyl Cluster Chemistry

Download or read book Transition Metal Carbonyl Cluster Chemistry written by Paul J. Dyson and published by CRC Press. This book was released on 2018-10-03 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.

Book Synthesis and Structural Characterisation of Transition Metal Clusters

Download or read book Synthesis and Structural Characterisation of Transition Metal Clusters written by J. A. Clucas and published by . This book was released on 1988 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Characterization of Transition Metal Carbonyl Clusters

Download or read book Synthesis and Characterization of Transition Metal Carbonyl Clusters written by Frederic Roy Furuya and published by . This book was released on 1986 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Cluster Chemistry

    Book Details:
  • Author : Guillermo Gonzalez-Moraga
  • Publisher : Springer Science & Business Media
  • Release : 2013-11-09
  • ISBN : 3642859267
  • Pages : 310 pages

Download or read book Cluster Chemistry written by Guillermo Gonzalez-Moraga and published by Springer Science & Business Media. This book was released on 2013-11-09 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.

Book The Synthesis  by Rational Means  and Characterization of High Nuclearity Platinum Carbonyl Clusters

Download or read book The Synthesis by Rational Means and Characterization of High Nuclearity Platinum Carbonyl Clusters written by Karl Christopher Cairns Kharas and published by . This book was released on 1988 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Characterization of Mixed transition Metal Carbonyl Clusters and Nickel germanium and Nickel tin Carbonyl Clusters

Download or read book Synthesis and Characterization of Mixed transition Metal Carbonyl Clusters and Nickel germanium and Nickel tin Carbonyl Clusters written by Jeffrey Paul Zebrowski and published by . This book was released on 1990 with total page 594 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis of Transition Metal Carbonyl Clusters with Phosphine Ligands

Download or read book Synthesis of Transition Metal Carbonyl Clusters with Phosphine Ligands written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of transition metal chalcogenide polynuclear clusters is a rapidly expanding area. The increasing interest is due to the search for structural models and precursors of extended inorganic solids with novel electronic, magnetic and optical properties. Our interest for the synthesis of a variety of transition - etal clusters is due to their use as a model and precursors for materials and catalyst. Synthesis and study of a variety of ligand substituted iron carbonyl cluster has been carried out to understand the reactivity features and structural variety. The main focus has been on the transition metal clusters containing chalcogens which act as bridges between different metal fragments and are helpful in cluster growth reactions and maintains the cluster integrity. A synthetic strategy has been developed to prepare a mixed metal cluster when a dichloromethane solution of [Fe3Y2(CO)6], Y=S, Se, Te and ML4 (M=Pd, L=PPh3) was reacted at room temperature in presence of trimethylamine-N-oxide. Substitution reaction of carbonyl groups by triphenylphosphine and bis(diphenylphosphino)methane ligands results in the formation of different types of trinuclear clusters. Homo metallic cluster as well mixed metal clusters with phosphine ligands has been synthesized by a room temperature reaction and characterized by FTIR, proton and 31P NMR spectroscopy. Some of the transition metal cluster contains chelating phosphine ligands which stabilizes the cluster integrity.

Book Synthesis and Structural Characterisation of Transition Metal Clusters

Download or read book Synthesis and Structural Characterisation of Transition Metal Clusters written by Jennifer Anne CLUCAS and published by . This book was released on 1988 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis  Structural Characterization  and NMR Spectroscopy of Late Transition Metal and Main Group Chalcogenides

Download or read book Synthesis Structural Characterization and NMR Spectroscopy of Late Transition Metal and Main Group Chalcogenides written by Donna Marie Smith and published by . This book was released on 1997 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The synthesis, characterization and spectroscopy of all the above compounds are discussed in the following pages.

Book The Synthesis  Spectral and Structural Characterization of Oxo centered Trinuclear Early Transition Metal Carboxylic Acid Complexes

Download or read book The Synthesis Spectral and Structural Characterization of Oxo centered Trinuclear Early Transition Metal Carboxylic Acid Complexes written by Joseph Earl Bradshaw and published by . This book was released on 1987 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book SYNTHESES STRUCTURAL CHARACTER

Download or read book SYNTHESES STRUCTURAL CHARACTER written by 李軼 and published by Open Dissertation Press. This book was released on 2017-01-28 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Syntheses, Structural Characterization and Electrochemistry of Tetraosmium Carbonyl Clusters and Catalytic Properties of Tetraosmium-gold Mixed-metal Clusters" by 李軼, Yat, Li, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3124335 Subjects: Electrochemistry Osmium compounds - Synthesis Carbonyl compounds - Synthesis

Book Synthesis  characterization  and reactivity of sterically hindered sulfido   selenido   and tellurido transition metal and main group complexes

Download or read book Synthesis characterization and reactivity of sterically hindered sulfido selenido and tellurido transition metal and main group complexes written by Lora Lea Rand and published by . This book was released on 1990 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Characterization of Transition Metal Clusters

Download or read book Synthesis and Characterization of Transition Metal Clusters written by Allan George Hee and published by . This book was released on 2004 with total page 562 pages. Available in PDF, EPUB and Kindle. Book excerpt: