Download or read book Synthesis and Reaction Kinetics of Transition Metal Complexes written by Murray Kitchener Park and published by . This book was released on 1994 with total page 82 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Kinetics and Mechanism of Reactions of Transition Metal Complexes written by Ralph G. Wilkins and published by Wiley-VCH. This book was released on 1991-08-28 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thoroughly revised and updated edition of one of the classics of kinetics text books continues the successful concept of the 1974 edition: In its first part, a simplified approach to the determination of rate laws and mechnisms is given steadily working up to complex situations. In the following chapters the principles developed there are extensively used in a comprehensive account of reactions of transition metal complexes, including reactions of biological signifacance. The text is illustrated by numerous figures and tables. Points of further interest are highlighted in special insets. 140 problems, taken from the original literature, enable the student to apply and deepen his newly acquired knowledge and make the book highly useful for courses in inorganic and organometallic reaction mechanisms. Furthermore, a wealth of over 1700 references renders it an indispensable work for the active researcher.
Download or read book Transition Metals in the Synthesis of Complex Organic Molecules written by Louis S. Hegedus and published by University Science Books. This book was released on 1999 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.
Download or read book Kinetics and Mechanism of Reactions of Transition Metal Complexes written by Wilkins and published by . This book was released on 1997 with total page 476 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a comprehensive introduction to the field of chemistry, covering kinetic and mechanistic aspects of the reactions of transition metal complexes. Intended for academics, chemical institutes, inorganic chemists, and libraries, the text takes a problem/solution approach.
Download or read book Inorganic Reactions and Methods The Formation of Bonds to Transition and Inner Transition Metals written by A. P. Hagen and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 727 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boasting numerous industrial applications, inorganic chemistry forms the basis for research into new materials and bioinorganic compounds such as calcium that act as biological catalysts. Now complete, this highly acclaimed series presents current knowledge in all areas of inorganic chemistry, including chemistry of the elements; organometallic, polymeric and solid-state materials; and compounds relevant to bioinorganic chemistry.
Download or read book The Study of Kinetics and Mechanism of Reactions of Transition Metal Complexes written by Ralph G. Wilkins and published by . This book was released on 1974 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book On Being Well coordinated A Half century Of Research On Transition Metal Complexes written by John L Burmeister and published by World Scientific. This book was released on 2003-10-14 with total page 654 pages. Available in PDF, EPUB and Kindle. Book excerpt: This invaluable book distils the research accomplishments of Professor Fred Basolo during the five decades when he served as a world leader in the modern renaissance of inorganic chemistry. Its primary focus is on the very important area of chemistry known as coordination chemistry.Most of the elements in the periodic table are metals, and most of the chemistry of metals involves coordination chemistry. This is the case in the currently significant areas of research, including organometallic homogenous catalysis, biological reactions of metalloproteins, and even the solid state extended structures of new materials. In these systems, the metals are of primary importance because they are the sites of ligand substitution or redox reactions. In the solid materials, the coordination number of the metal and its stereochemistry are of major importance.Some fifty years of research on transition metal complexes carried out in the laboratory of Professor Basolo at Northwestern University is recorded here as selected scientific publications. The book is divided into three different major research areas, each dealing with some aspect of coordination chemistry. In each case, introductory remarks are presented which indicate what prompted the research projects and what the major accomplishments were. Although the research was of the academic, curiosity-driven type, some aspects have proven to be useful to others involved in projects that were much more applied in nature.
Download or read book Reaction Mechanisms of Metal Complexes written by R W Hay and published by Elsevier. This book was released on 2000-03-01 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text provides a general background as a course module in the area of inorganic reaction mechanisms, suitable for advanced undergraduate and postgraduate study and/or research. The topic has important research applications in the metallurgical industry and is of interest in the science of biochemistry, biology, organic, inorganic and bioinorganic chemistry. In addition to coverage of substitution reactions in four-, five- and six-coordinate complexes, the book contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands. It is relevant in other fields such as organic, bioinorganic and biological chemistry, providing a bridge to organic reaction mechanisms. The book also contains a chapter on the kinetic background to the subject with many illustrative examples which should prove useful to those beginning research. Provides a general background as a course module in the area of inorganic reaction mechanisms, which has important research applications in the metallurgical industry Contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands
Download or read book Synthesis and Oxidation Kinetics of Transition Metal Complexes written by Rhonda Lucas and published by . This book was released on 2001 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Textbook of Inorganic Chemistry Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Download or read book Transition Metal Reagents and Catalysts written by Jiro Tsuji and published by John Wiley & Sons. This book was released on 2002-08-16 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: Im Laufe der vergangenen 35 Jahre wurden unzahlige Synthesewege entwickelt, bei denen Ubergangsmetallkomplexe entweder als Reagenzien oder als Katalysatoren fungieren. Dieses Buch bietet besonders denjenigen Synthesechemikern interessante und moderne Einblicke, die bisher noch nicht mit den vielfaltigen Moglichkeiten der Organometallchemie mit Ubergangsmetallen vertraut sind. Zu wichtigen ubergangsmetallkatalysierten Reaktionen werden Anwendungsbeispiele diskutiert. (01/00)
Download or read book Synthesis and Characterization of Transition Metal Complexes written by Milan M. Milutinović and published by . This book was released on 2019 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metals and their complexes have an important impact on chemistry and are found in many application in life in general. Ruthenium and rhodium are two members of noble metals and proved to be suitable for anticancer activity. With the aim of changing the coordination environment in ruthenium and rhodium complexes, this thesis presents a series of Ru(II) polypyridyl and Rh(III) pincer-type complexes. All new Ru(II) and Rh(III) complexes were characterized by NMR spectroscopy, ESI-MS spectrometry and UV-Vis spectrophotometry . For some of the complexes a single crystal X-ray crystallography was performed. The substitution reactions of Ru(II) and Rh(III) complexes with mononucleotides, oligonucleotides and amino acids were studied quantitatively by UV-Vis spectroscopy. Measurements of the activation enthalpies and entropies for all synthesized complexes are supporting an associative mechanism for the substitution process. NMR spectroscopy studies were performed on some Ru(II) complexes where after the hydrolyses of the metal-Cl bond the complexes are capable to interact with guanine derivatives forming monofunctional adducts via N7 atom. The interactions of Ru(II) and Rh(III) complexes with fully complementary 15-mer and 22-mer duplexes of DNA and fully complementary 13-mer duplexes of RNA were studied by UV-Vis spectroscopy. The interactions of ruthenium(II) and rhodium(III) complexes with calf thymus and herring testes DNA were examined by absorption using UV-Vis spectroscopy, fluorescence emission spectral studies by ethidium bromide displacement studies and viscosity measurements. ; eng
Download or read book Transition Metals Quantitative Kinetics and Applied Organic Chemistry written by Brian Chapman and published by Nelson Thornes. This book was released on 2004 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt: The revised edition of the highly successful Nelson Advanced Science series for A Level Chemistry - Transition Metals, Quantitative Kinetics and Applied Organic Chemistry provides full content coverage of Unit 5 of the AS and A2 specifications.
Download or read book Direct Synthesis of Metal Complexes written by B.I. Kharisov and published by Elsevier. This book was released on 2018-04-19 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt: Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water Includes experimental procedures, with examples of direct synthesis, at the end of each chapter
Download or read book Synthesis and Oxidation Kinetics of Transition Metal Complexes written by Rodney George Francis Clarke and published by . This book was released on 1995 with total page 90 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Alkene Polymerization Reactions with Transition Metal Catalysts written by Yury Kissin and published by Elsevier. This book was released on 2008-03-10 with total page 607 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes:1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure.2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands.3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts.4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymersThe book contains over 2000 references, the most recent up to end of 2006.
Download or read book Macromolecule Metal Complexes written by Francesco Ciardelli and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 333 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first concise overview on the topic, spanning the spectrum from fundamentals to new application areas. The synthesis, kinetics and thermodynamics of these complexes are covered in detail, while much emphasis is placed on special properties such as gas transport, charge transport, catalysis and light-induced processes. Furthermore, the authors treat the actual working areas for new application methods. In all, a very helpful tool for polymer and materials scientists, as well as organic and physical chemists working in these fields.
