Download or read book Synthesis and Characterization of Novel Anionic Transition Metal Borohydrides written by Jennifer R. Eliseo and published by . This book was released on 2007 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis and Characterization of Novel 3 4 Hydroxypyridinato Transition Metal Complexes written by Hannah R. Caron and published by . This book was released on 2015 with total page 80 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis and Characterization of Novel Ternary Transition Metal Borides and New Synthesis Methods for Superhard ReB2 and Clathrate of Type 1 written by Burcu Uslu and published by . This book was released on 2010 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis and characterization of solvent ligated transition metal complexes containing weakly coordinating anions and their catalytic reactivity written by Yanmei Zhang and published by . This book was released on 2004 with total page 174 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis Characterization and Computational Studies of Unsaturated Transition Metal Complexes written by Lori Anne Watson and published by . This book was released on 2004 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis and Characterization of Transition Metal Di tert butyl amido Compounds written by Gregory R. Potratz and published by . This book was released on 2000 with total page 106 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis and Characterization of 3d Transition Metal Complexes with Nicotinic and Isonicotinic Acid N oxides written by Larry Stuart Gelfand and published by . This book was released on 1980 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis Characterization and Reactiviity of Transition Metal Boroalkoxide Complexes written by Aaron B. Frederick and published by . This book was released on 1994 with total page 146 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis and Characterization of Heterocyclic and Aromatic Thiosemicarbazones and Their Transition Metal Ion Complexes written by Jill Susanne Saleda and published by . This book was released on 1992 with total page 202 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis Characterization and Reactivity of Electron Rich Transition Metal Organometallic Complexes written by James Joseph Welter and published by . This book was released on 1980 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis and Characterization of Metal Metal Multiply Bonded Complexes and Catalytic Applications of Solvent Stabilized Transition Metal Complexes for Polymerization of Olefins written by Guofang Zhang and published by . This book was released on 2001 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis and Characterization of Transition Metal Complexes Kinetic Investigation with Biomolecules DNA BSA Binding Abilities and Cytotoxic Studies written by Milan M. Milutinovic and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Übergangsmetalle und ihre Komplexe besitzen einen wichtigen Stellenwert in der Chemie und werden generell in vielen wichtigen biologischen Prozessen gefunden. Ruthenium und Rhodium sind zwei Vertreter von Edelmetallen und einige Komplexe dieser beiden Metalle haben eine biologische Aktivität gegen Krebs gezeigt. Mit dem Ziel die koordinative Umgebung von Ru- und Rh komplexen zu verändern wird in dieser Doktorarbeit eine Serie von Ru(II)polypyridyl und Rh(III)-Pincer-Typ-Komplexen präsentiert. Alle neuen Ru(II)- und Rh(III)-Komplexe wurden mittels NMR-Spektroskopie, ESI-MS Spektroskopie und UV-Vis Spektroskopie charakterisiert. Die Substitutionsreaktion von Ru(II)- und Rh(III)-Komplexen wurden mit Mononukleotiden, Oligonukleotiden und Aminosäuren mittels UV-Vis Spektroskopie quantitativ untersucht. Die Messungen der Aktivierungsenthalpien und -entropien für alle neuen synthetisierten Komplexe unterstützen einen assoziativen Mechanismus für den Substitutionsprozess. NMR-spektroskopische Untersuchungen wurden für einige Ru(II)-Komplexe durchgeführt, wobei sich zeigte, dass nach der Hydrolyse der Metall-Chlorid Bindungen die Komplexe mit Guanin-Derivaten monofunktionale Addukte über das N7-Atom bilden. Die Wechselwirkungen der Ru(II)- und Rh(III)-Komplexe mit komplett komplementären 15-mer und 22-mer Duplexes von DNA und komplett komplementären 13-mer Duplexes von RNA wurden mittels UV-Vis Spektroskopie untersucht. Die Interaktionen der Ru(II)- und Rh(III)-Komplexe mit DNA aus der Thymusdrüse von Kälbern und Heringshoden wurden mittles UV-Vis Spektroskopie und Emissionsfluoreszenz Spektroskopie evaluiert. Im letzteren Fall wurden dabei die Studien mit Ehidiumbromid durchgeführt, wobei dieses durch die Komplexe in der DNA ausgetauscht wurde. Zusätzlich wurden auch Viskositätsmessungen durchgeführt. - Transition metals and their complexes have an important impact on chemistry and are found in many application in life in general. Ruthenium and rhodium are two members of noble metals and proved to be suitable for anticancer activity. With the aim of changing the coordination environment in ruthenium and rhodium complexes, this thesis presents a series of Ru(II) polypyridyl and Rh(III) pincer-type complexes. All new Ru(II) and Rh(III) complexes were characterized by NMR spectroscopy, ESI-MS spectrometry and UV-Vis spectrophotometry . For some of the complexes a single crystal X-ray crystallography was performed. The substitution reactions of Ru(II) and Rh(III) complexes with mononucleotides, oligonucleotides and amino acids were studied quantitatively by UV-Vis spectroscopy. Measurements of the activation enthalpies and entropies for all synthesized complexes are supporting an associative mechanism for the substitution process. NMR spectroscopy studies were performed on some Ru(II) complexes where after the hydrolyses of the metal-Cl bond the complexes are capable to interact with guanine derivatives forming monofunctional adducts via N7 atom. The interactions of Ru(II) and Rh(III) complexes with fully complementary 15-mer and 22-mer duplexes of DNA and fully complementary 13-mer duplexes of RNA were studied by UV-Vis spectroscopy. The interactions of ruthenium(II) and rhodium(III) complexes with calf thymus and herring testes DNA were examined by absorption using UV-Vis spectroscopy, fluorescence emission spectral studies by ethidium bromide displacement studies and viscosity measurements.

Download or read book Synthesis Characterization and Reactivity Evaluation of Late Transition Metal Aluminum Heterobimetallic Complexes Toward Molecular Hydrogen written by Roland Malcolm Charles III and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The investigation and development of heterobimetallic systems has seen a meteoric surge over the past decade. Generally, these heterobimetallic systems involve two transition metals with distinct properties used together to activate chemical bonds. Many heterobimetallics consist of a soft, low-valent metal and a harder, high-valent metal. The unique electronics afforded by heterobimetallics of this sort can be exploited, yielding access to novel reactivities that may be otherwise inaccessible to a single transition metal. Less studied are heterobimetallic complexes composed of one late transition metal (LTM) and one Lewis-acidic p-block (Group 13) metal. Due to its electropositivity being the highest among Group 13 metals as well as its high earth-abundance, aluminum holds particular interest to the Brewster laboratory. In contrast to their exhaustively investigated boron analogues, the field of aluminum-containing heterobimetallics is relatively uncultivated due to the high reactivity and synthetic difficulty of aluminum species, making isolation and characterization quite challenging. One of the aims of the Brewster lab is to develop heterobimetallic systems comprised of an electron-rich, low-valent transition metal and aluminum to investigate potential synergistic reactivity between both metal centers. In this dissertation, I report the successful synthesis and electronic characterization of myriad novel mono- and heterobimetallic complexes of either iridium or rhodium and aluminumover 35 new complexes in total. Moreover, I detail the ability of selected heterobimetallic complexes to facilitate activation of molecular hydrogen as well as hydrogenolysis, thereby generating alkane gas..

Download or read book Synthesis and Characterization of 1 1 dicarbodiimidoferrocenes written by Orhi Esarte Palomero and published by . This book was released on 2020 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The initial synthesis and characterization of a new family of amido-bis(amidate) early transition metal compounds has lead to the development of a new class of 1,1’-dicarbodiimidoferrocene proligands. These proligands and related 2,4-diimino-1,3-diazetidine compounds are useful precursors for 1,1’-bis(guanidinate)ferrocene early transition metal complexes exhibiting novel reactivity. Additionally, 1,1’-dicarbodiimidoferrocenes can be utilized, in the form of boramidinates, to study the reactivity of boramidinate frustrated Lewis pairs with boranes, CO, CO2 and other small molecules

Download or read book Synthesis Structure and Properties of Novel Metal Borohydrides written by Dorthe B. Ravnsbæk and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis and Characterization of Tridentate Amido Ligand Derivatives of Early Transition metals written by Abdul-Razak Habib Al-Soudani and published by . This book was released on 1993 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis and Characterization of Tridentate Amido Ligand Derivaties of Early Transition metals written by Abdul-Razak Habib Al-Soudani and published by . This book was released on 1992 with total page 548 pages. Available in PDF, EPUB and Kindle. Book excerpt: