Download or read book Surface Enhancement Factors for Raman Scattering at Silver Electrodes Role of Adsorbate Surface Interactions and Electronic Structure written by M. J. Weaver and published by . This book was released on 1985 with total page 31 pages. Available in PDF, EPUB and Kindle. Book excerpt: The integrated Raman band intensities for internal vibrational modes of various adsorbates at roughened silver electrodes are combined with surface concentrations obtained electrochemically to yield surface Raman scattering cross sections. These data together with the corresponding bulk-phase Raman intensities provide estimates of the degree of enhancement of the vibrational bands at the silver surface with respect to the bulk medium, i.e., the surface enhancement factors (SEF). For surface-attached thiocyanate, isothiocyanate-bridged Cr(III) complexes, and also for Cr(III) and Co(III) hexammines that are electrostatically attracted to chloride-coated silver, SEF values are obtained that are relatively insensitive to both the vibrational mode and the adsorbate, even though substantial (up to 500 fold) variations are observed in the Raman cross sections. This finding applies to stretching modes involving nonbridging ammine groups as well as to bridging thiocyanate modes, although the frequencies of the latter, but not of the former, are perturbed strongly by the silver surface. Comparisons were also made between Raman cross sections, surface enhancement factors, and excitation profiles for pyrazinepentaammineosmium(III) and (II) to explore the influence of electronic resonance since the Os(II) form displays an intense charge-transfer band in the vicinity of the laser wavelengths (460-650 nm) employed. A pronounced peak in the Os(II) excitation profile, absent for Os(III), is obtained that is markedly (ca. 100 nm) red shifted for the adsorbed versus bulk complex.
Download or read book Surface Enhanced Raman Scattering written by Richard Chang and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the course of the development of surface science, advances have been identified with the introduction of new diagnostic probes for analytical characterization of the adsorbates and microscopic structure of surfaces and interfaces. Among the most recently de veloped techniques, and one around which a storm of controversy has developed, is what has now been earmarked as surface enhanced Raman scattering (SERS). Within this phenomenon, molecules adsorbed onto metal surfaces under certain conditions exhibit an anomalously large interaction cross section for the Raman effect. This makes it possible to observe the detailed vibrational signature of the adsorbate in the ambient phase with an energy resolution much higher than that which is presently available in electron energy loss spectroscopy and when the surface is in contact with a much larger amount of material than that which can be tolerated in infrared absorption experiments. The ability to perform vibrational spectroscopy under these conditions would lead to a new understanding about the chemical identity, geome try, and bonding of adsorbed material at a level previously unacces sible. It is for these reasons that the last few years have brought an explosion of activity surrounding the exploitation of SERS. The search for the origines) of the anomalous enhancement has given rise to a research sub-activity of its own. Efforts to explain the en hancement have led to an increased understanding of the whole range of phenomena associated with the interaction of photons with adsor bates and metal surfaces.
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1986 with total page 1040 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Surface Enhanced Raman Scattering New Theoretical Approaches Materials and Strategies written by Ivano Alessandri and published by Frontiers Media SA. This book was released on 2020-03-25 with total page 175 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Surface Enhanced Raman Scattering written by Zhong-Qun Tian and published by John Wiley & Sons Incorporated. This book was released on 2010-06-14 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Surface-Enhanced Raman Spectroscopy: Principles, Experiments, and Applications is a comprehensive, up to date, and balanced treatment of the theoretical and practical aspects of Surface-Enhanced Raman Scattering (SERS), a useful branch of spectroscopy for several areas of science. This book describes the basic principles of SERS, including SERS mechanisms, performing SERS measurements, and interpreting data. Also emphasized are applications in electrochemistry; catalysis; surface processing and corrosion; Self-Assemble-Layer and L-B Films; polymer science; biology; medicine and drug analysis; sensors; fuel cells; forensics; and archaeology. It is an essential guide for student and professional analytical chemists.
Download or read book Selected Papers on Surface enhanced Raman Scattering written by Milton Kerker and published by . This book was released on 1990 with total page 728 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Surface Enhanced Vibrational Spectroscopy written by Ricardo Aroca and published by John Wiley & Sons. This book was released on 2006-05-15 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: Surface Enhanced Vibrational Spectroscopy (SEVS) has reachedmaturity as an analytical technique, but until now there has beenno single work that describes the theory and experiments of SEVS.This book combines the two important techniques of surface-enhancedRaman scattering (SERS) and surface-enhanced infrared (SEIR) intoone text that serves as the definitive resource on SEVS. * Discusses both the theory and the applications of SEVS andprovides an up-to-date study of the state of the art * Offers interpretations of SEVS spectra for practicinganalysts * Discusses interpretation of SEVS spectra, which can often bevery different to the non-enhanced spectrum - aids the practicinganalyst
Download or read book Government Reports Announcements Index written by and published by . This book was released on 1986 with total page 1104 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Summaries of Projects Completed in Fiscal Year written by and published by . This book was released on 1979 with total page 718 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Summaries of Projects Completed written by National Science Foundation (U.S.) and published by . This book was released on with total page 728 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Summaries of Projects Completed in Fiscal Year written by National Science Foundation (U.S.) and published by . This book was released on 1979 with total page 720 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Application and investigation of surface enhanced raman scattering from adsorbates on copper silver and gold electrodes written by Alice Batts Apkarian and published by . This book was released on 1983 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Raman and SERS Investigations of Pharmaceuticals written by Monica Baia and published by Springer Science & Business Media. This book was released on 2008-06-11 with total page 221 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last several years it has become apparent to most researchers that interdisciplinary research is the key to success in the sciences’ future. The present book exemplifies such interdisciplinary work. Thus, some new derivatives have been prepared by chemists and consecutively analyzed by physicists in order to better understand their physical-chemical properties for future tests to be performed by pharmacists. The book consists of an introductory section and other eight chapters. First, the fundamentals of infrared, Raman and surface-enhanced Raman spectroscopy and those of the theoretical methods employed for the vibrational prediction modes are highlighted. The SERS investigations illustrated in the following chapters are focused on different kinds of drugs: tranquilizers and sedatives, anti-inflammatory drugs, vitamins, drugs with anti-bacterial properties, etc. Since there is an increased interest in designing highly effective and controllable SERS-active substrates, a few newly developed substrates that could contribute to a deeper understanding and knowledge of the adsorption behavior of various types of molecules of pharmaceutical and medical interest are also presented.
Download or read book Government Reports Annual Index written by and published by . This book was released on 1986 with total page 900 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Raman Spectroscopy Applied to Earth Sciences and Cultural Heritage written by J. Dubessy and published by The Mineralogical Society of Great Britain and Ireland. This book was released on 2012-11-20 with total page 519 pages. Available in PDF, EPUB and Kindle. Book excerpt: Spectroscopic methods such as Raman are used to investigate the structure and dynamics of matter. They are essential for the study of the different types of mineral or organic materials produced at the Earths surface or interior. As a result of technological improvements in gratings, detectors, filters and personal computers in the last decade, many micro-Raman spectrometers have become plug-and-play instruments, very easy to use and available at a lower cost than the early Raman microprobes. Thus, many laboratories in Earth Sciences and Cultural Heritage are equipped with these new spectrometers. Commercial, portable Raman spectrometers working in the field have also contributed to the spread of Raman spectroscopy. Poor levels of education in terms of Raman spectroscopy in undergraduate courses in Earth Sciences make it difficult for individuals to obtain information of the highest quality relevant to Earth sciences and Cultural Heritage. This volume is, therefore, timely. Four main topics are addressed: Theory; Methodology, including the instrumentation; Experimental aspects; and Application.
Download or read book Physics Briefs written by and published by . This book was released on 1985-07 with total page 936 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Government Reports Annual Index Keyword A L written by and published by . This book was released on 1986 with total page 1164 pages. Available in PDF, EPUB and Kindle. Book excerpt:
