Download or read book Study of Transport and Dissolution of a Nonaqueous Phase Liquid in Porous Media written by Mirrya Mosier Fontenot and published by . This book was released on 2001 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt: The transport and dissolution of residual non-aqueous phase liquids (NAPLS) trapped in water saturated porous media is a problem pertinent to both environmental and petrochemical industries. In this work we have quantitatively examined the complete dissolution of residual entrapped NAPL at the pore-scale in three dimensions using refractive index matching techniques along with planar laser induced fluorescence. The results yielded pore-scale information regarding ganglia volume, surface area, and position over time at various Capillary numbers. We found that with increasing Capillary numbers, the time for total dissolution decreased. In addition, it appears that large ganglia exhibit fractal area to volume scaling. We were also able to examine the distributions of the ganglia in the direction of flow over time. The use of low-frequency flow pulsations as a removal technique was also examined. A two dimensional micro model was used for these studies. We found that for this system, lower frequencies and higher amplitudes were more effective in NAPL removal due to breakup and mobilization. We also examined the effect of increasing amplitude and continuous versus pulsed stimulation. In addition, mass transport in the presence of a surfactant was also enhanced due to flow pulsation with lower frequencies and higher amplitudes again being most effective.

Download or read book Dissolution of a Nonaqueous Phase Liquid in Saturated Porous Media written by Paul T. Imhoff and published by . This book was released on 1992 with total page 688 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Dissolution of Non aqueous Phase Organic Liquids in Porous Media written by Jil Talkovsky Geller and published by . This book was released on 1990 with total page 412 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Recent Advances in Problems of Flow and Transport in Porous Media written by J.M. Crolet and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: Porous media, and especially phenomena of transport in such materials, are an impor1ant field of interest for geologists, hydrogeologists, researchers in soil and fluid mechanics, petroleum and chemical engineers, physicists and scientists in many other disciplines. The development of better numerical simulation techniques in combination with the enormous expansion of computer tools, have enabled numerical simulation of transport phenomena (mass of phases and components, energy etc. ) in porous domains of interest. Before any practical application of the results of such simulations can be used, it is essential that the simulation models have been proven to be valid. In order to establish the greatest possible coherence between the models and the physical reality, frequent interaction between numericians, mathematicians and the previously quoted researchers, is necessary. Once this coherence is established, the numerical simulations could be used to predict various phenomena such as water management, propagation of pollutants etc. These simulations could be, in many cases, the only financially acceptable tool to carry out an investigation. Current studies within various fields of applications include not only physical comprehension aspects of flow and energy or solute transport in saturated or unsaturated media but also numerical aspects in deriving strong complex equations. Among the various fields of applications generally two types of problems can be observed. Those associated with the pollution of the environment and those linked to water management. The former are essentially a problem in industrialized countries, the latter are a major source of concern in North-Africa.

Download or read book Nonaqueous Phase Liquid Dissolution in Porous Media written by and published by . This book was released on 2007 with total page 25 pages. Available in PDF, EPUB and Kindle. Book excerpt: Industrial organic solvents such as trichloroethylene (TCE) and tetrachloroethylene (PCE) constitute a principal class of groundwater contaminants. Cleanup of groundwater plume source areas associated with these compounds is problematic, in part, because the compounds often exist in the subsurface as dense nonaqueous phase liquids (DNAPLs). Ganglia (or 'blobs') of DNAPL serve as persistent sources of contaminants that are difficult to locate and remediate (e.g. Fenwick and Blunt, 1998). Current understanding of the physical and chemical processes associated with dissolution of DNAPLs in the subsurface is incomplete and yet is critical for evaluating long-term behavior of contaminant migration, groundwater cleanup, and the efficacy of source area cleanup technologies. As such, a goal of this project has been to contribute to this critical understanding by investigating the multi-phase, multi-component physics of DNAPL dissolution using state-of-the-art experimental and computational techniques. Through this research, we have explored efficient and accurate conceptual and numerical models for source area contaminant transport that can be used to better inform the modeling of source area contaminants, including those at the LLNL Superfund sites, to re-evaluate existing remediation technologies, and to inspire or develop new remediation strategies. The problem of DNAPL dissolution in natural porous media must be viewed in the context of several scales (Khachikian and Harmon, 2000), including the microscopic level at which capillary forces, viscous forces, and gravity/buoyancy forces are manifested at the scale of individual pores (Wilson and Conrad, 1984; Chatzis et al., 1988), the mesoscale where dissolution rates are strongly influenced by the local hydrodynamics, and the field-scale. Historically, the physico-chemical processes associated with DNAPL dissolution have been addressed through the use of lumped mass transfer coefficients which attempt to quantify the dissolution rate in response to local dissolved-phase concentrations distributed across the source area using a volume-averaging approach (Figure 1). The fundamental problem with the lumped mass transfer parameter is that its value is typically derived empirically through column-scale experiments that combine the effects of pore-scale flow, diffusion, and pore-scale geometry in a manner that does not provide a robust theoretical basis for upscaling. In our view, upscaling processes from the pore-scale to the field-scale requires new computational approaches (Held and Celia, 2001) that are directly linked to experimental studies of dissolution at the pore scale. As such, our investigation has been multi-pronged, combining theory, experiments, numerical modeling, new data analysis approaches, and a synthesis of previous studies (e.g. Glass et al, 2001; Keller et al., 2002) aimed at quantifying how the mechanisms controlling dissolution at the pore-scale control the long-term dissolution of source areas at larger scales.

Download or read book Pore Scale Study of the Dissolution of Residual Non aqueous Phase Liquids in Porous Media written by Nahla Adnan Sahloul and published by . This book was released on 2000 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Dissolution of Nonaqueous Phase Liquids in Porous Media written by Thomas Scott Soerens and published by . This book was released on 1995 with total page 584 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Computational Methods for Flow and Transport in Porous Media written by J.M. Crolet and published by Springer Science & Business Media. This book was released on 2013-03-14 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first Symposium on Recent Advances in Problems of Flow and Transport in Porous Media was held in Marrakech in June '96 and has provided a focus for the utilization of computer methods for solving the many complex problems encountered in the field of solute transport in porous media. This symposium has been successful in bringing together scientists, physicists, hydrogeologists, researchers in soil and fluid mechanics and engineers involved in this multidisciplinary subject. It is clear that the utilization of computer-based models in this domain is still rapidly expanding and that new and novel solutions are being developed. The contributed papers which form this book reflect the recent advances, in particular with respect to new methods, inverse problems, reactive transport, unsaturated media and upscaling. These have been subdivided into the following sections: I. Numerical methods II. Mass transport and heat transfer III. Comparison with experimentation and simulation of real cases This book contains reviewed articles of the top presentations held during the International Symposium on Computer Methods in Porous Media Engineering which took place in Giens (France) in October 1998. All of the presentations and the optimism shown during the meeting provided further evidence that computer modeling is making remarkable progress and is indeed becoming an essential toolkit in the field of porous media and solute transport. I believe that the content of this book provides evidence of this and furthermore gives a comprehensive review of the theoretical developments and applications.

Download or read book Dissolution of Non aqueous Phase Liquid Pools in Saturated Porous Media written by Michael P. Whelan and published by . This book was released on 1992 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Dissolution of Nonaqueous Phase Liquids in Saturated Subsurface Systems written by Susan E. Powers and published by . This book was released on 1992 with total page 406 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Dissolution of Nonaqueous Phase Liquid Pools in Saturated Porous Media written by Kenneth Y. Lee and published by . This book was released on 1999 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Handbook of Chemical Mass Transport in the Environment written by Louis J. Thibodeaux and published by CRC Press. This book was released on 2010-10-21 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive account of the state of the science of environmental mass transport Edited by Louis J. Thibodeaux and Donald Mackay, renowned experts in this field, the Handbook of Chemical Mass Transport in the Environment covers those processes which are critically important for assessing chemical fate, exposure, and risk. In a comprehensive and authoritative format, this unique handbook provides environmental chemists, geoscientists, engineers, and modelers with the essential capabilities to understand and quantify transport. In addition, it offers a one-stop resource on environmental mass transfer and mass transport coefficient estimation methods for all genres. The book begins by discussing mass transport fundamentals from an environmental perspective. It introduces the concept of mobility — key to environmental fate, since transport must occur prior to any reaction or partitioning within the natural multimedia compartments. The fugacity approach to environmental mass transfer and the conventional approach are examined. This is followed by a description of the individual mass transport processes and the appropriate flux equations required for a quantitative expression. The editors have identified 41 individual processes believed to be the most environmentally significant, which form the basis for the remainder of the book Using a consistent format for easy reference, each chapter: Introduces the specific processes Provides a detailed qualitative description Presents key theoretical mathematical formulations Describes field or laboratory measurements of transport parameters Gives data tables and algorithms for numerical estimates Offers a guide for users familiar with the process who are seeking a direct pathway to obtain the numerical coefficients Presents computed example problems, case studies and/or exercises with worked-through solutions and answers The final chapter presents the editors’ insight into future needs and emerging priorities. Accessible and relevant to a broad range of science and engineering users, this volume captures the state of the transport science and practice in this critical area.

Download or read book Handbook of Soil Sciences Two Volume Set written by Pan Ming Huang and published by CRC Press. This book was released on 2018-10-03 with total page 2249 pages. Available in PDF, EPUB and Kindle. Book excerpt: An evolving, living organic/inorganic covering, soil is in dynamic equilibrium with the atmosphere above, the biosphere within, and the geology below. It acts as an anchor for roots, a purveyor of water and nutrients, a residence for a vast community of microorganisms and animals, a sanitizer of the environment, and a source of raw materials for co

Download or read book Dense Nonaqueous Phase Liquids written by and published by . This book was released on 1992 with total page 92 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Handbook of Environmental Fluid Dynamics Volume One written by Harindra Joseph Fernando and published by CRC Press. This book was released on 2012-12-12 with total page 638 pages. Available in PDF, EPUB and Kindle. Book excerpt: With major implications for applied physics, engineering, and the natural and social sciences, the rapidly growing area of environmental fluid dynamics focuses on the interactions of human activities, environment, and fluid motion. A landmark for the field, the two-volume Handbook of Environmental Fluid Dynamics presents the basic principles, fundamental flow processes, modeling techniques, and measurement methods used in the study of environmental motions. It also offers critical discussions of environmental sustainability related to engineering. The handbook features 81 chapters written by 135 renowned researchers from around the world. Covering environmental, policy, biological, and chemical aspects, it tackles important cross-disciplinary topics such as sustainability, ecology, pollution, micrometeorology, and limnology. Volume One: Overview and Fundamentals provides a comprehensive overview of the basic principles. It starts with general topics that emphasize the relevance of environmental fluid dynamics research in society, public policy, infrastructure, quality of life, security, and the law. It then discusses established and emerging focus areas. The volume also examines the sub-mesoscale flow processes and phenomena that form the building blocks of environmental motions, with emphasis on turbulent motions and their role in heat, momentum, and species transport. As communities face existential challenges posed by climate change, rapid urbanization, and scarcity of water and energy, the study of environmental fluid dynamics becomes increasingly relevant. This volume is a valuable resource for students, researchers, and policymakers working to better understand the fundamentals of environmental motions and how they affect and are influenced by anthropogenic activities. See also Handbook of Environmental Fluid Dynamics, Two-Volume Set and Volume Two: Systems, Pollution, Modeling, and Measurements.

Download or read book Contaminants in the Subsurface written by National Research Council and published by National Academies Press. This book was released on 2005-04-23 with total page 371 pages. Available in PDF, EPUB and Kindle. Book excerpt: At hundreds of thousands of commercial, industrial, and military sites across the country, subsurface materials including groundwater are contaminated with chemical waste. The last decade has seen growing interest in using aggressive source remediation technologies to remove contaminants from the subsurface, but there is limited understanding of (1) the effectiveness of these technologies and (2) the overall effect of mass removal on groundwater quality. This report reviews the suite of technologies available for source remediation and their ability to reach a variety of cleanup goals, from meeting regulatory standards for groundwater to reducing costs. The report proposes elements of a protocol for accomplishing source remediation that should enable project managers to decide whether and how to pursue source remediation at their sites.

Download or read book Water Flow Solute and Heat Transfer in Groundwater written by Alexander Yakirevich and published by MDPI. This book was released on 2021-01-06 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: Groundwater is an essential and vital water resource for drinking water production, agricultural irrigation, and industrial processes. Having a better understanding of physical and chemical processes in aquifers enables more reliable decisions and reduces investments concerning water management. This Special Issue on “Water Flow, Solute, and Heat Transfer, in Groundwater” of Water focuses on the recent advances in groundwater dynamics, and it includes high-quality papers that cover a wide range of issues on different aspects related to groundwater: protection from contamination, recharge, heat transfer, hydraulic parameters estimation, well hydraulics, microbial community, colloid transport, and mathematical models. This integrative volume aims to transfer knowledge to hydrologists, hydraulic engineers, and water resources planners, who are engaged in the sustainable development of groundwater resources.