Download or read book Studies of Transition Metal Complexes Containing Intramolecular Aromatic Substitution written by John Raymond Blickensderfer and published by . This book was released on 1971 with total page 174 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book On Being Well coordinated A Half century Of Research On Transition Metal Complexes written by John L Burmeister and published by World Scientific. This book was released on 2003-10-14 with total page 654 pages. Available in PDF, EPUB and Kindle. Book excerpt: This invaluable book distils the research accomplishments of Professor Fred Basolo during the five decades when he served as a world leader in the modern renaissance of inorganic chemistry. Its primary focus is on the very important area of chemistry known as coordination chemistry.Most of the elements in the periodic table are metals, and most of the chemistry of metals involves coordination chemistry. This is the case in the currently significant areas of research, including organometallic homogenous catalysis, biological reactions of metalloproteins, and even the solid state extended structures of new materials. In these systems, the metals are of primary importance because they are the sites of ligand substitution or redox reactions. In the solid materials, the coordination number of the metal and its stereochemistry are of major importance.Some fifty years of research on transition metal complexes carried out in the laboratory of Professor Basolo at Northwestern University is recorded here as selected scientific publications. The book is divided into three different major research areas, each dealing with some aspect of coordination chemistry. In each case, introductory remarks are presented which indicate what prompted the research projects and what the major accomplishments were. Although the research was of the academic, curiosity-driven type, some aspects have proven to be useful to others involved in projects that were much more applied in nature.
Download or read book Transition Metals in the Synthesis of Complex Organic Molecules written by Louis S. Hegedus and published by University Science Books. This book was released on 1999 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.
Download or read book Transition Metals in Supramolecular Chemistry written by L. Fabbrizzi and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 445 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the pioneering publications on coordination chemistry by Lehn and Pedersen in the late 1960s, coupled with the more orthodox interest from the transition metal chemists on template reactions (Busch, 1964), the field of supramolecular chemistry has grown at an astonishing rate. The use of transition metals as essential constituents of multi-component assemblies has been especially sharp in recent years, since the metals are prone to quick and reversible redox changes, and there is a wide variety of metal--ligand interactions. Such properties make supramolecular complexes of transition metal ions suitable candidates for exploration as light--energy converters and signal processors. Transition Metals in Supramolecular Chemistry focuses on the following main topics: (1) metal controlled organization of novel molecular assemblies and shapes; (2) design of molecular switches and devices operating through metal centres; (3) supramolecular catalysts that mimic metalloenzymes; (4) metal-containing sensory reagents and supramolecular recognition; and (5) molecular materials that display powerful electronic, optoelectronic and magnetic properties.
Download or read book On Being Well coordinated written by Fred Basolo and published by World Scientific Publishing Company Incorporated. This book was released on 2003-01-01 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: This invaluable book distils the research accomplishments of Professor Fred Basolo during the five decades when he served as a world leader in the modern renaissance of inorganic chemistry. Its primary focus is on the very important area of chemistry known as coordination chemistry. Most of the elements in the periodic table are metals, and most of the chemistry of metals involves coordination chemistry. This is the case in the currently significant areas of research, including organometallic homogenous catalysis, biological reactions of metalloproteins, and even the solid state extended structures of new materials. In these systems, the metals are of primary importance because they are the sites of ligand substitution or redox reactions. In the solid materials, the coordination number of the metal and its stereochemistry are of major importance. Some fifty years of research on transition metal complexes carried out in the laboratory of Professor Basolo at Northwestern University is recorded here as selected scientific publications. The book is divided into three different major research areas, each dealing with some aspect of coordination chemistry. In each case, introductory remarks are presented which indicate what prompted the research projects and what the major accomplishments were. Although the research was of the academic, curiosity-driven type, some aspects have proven to be useful to others involved in projects that were much more applied in nature.
Download or read book Transition Metals in Coordination Environments written by Ewa Broclawik and published by Springer. This book was released on 2019-03-16 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on the electronic properties of transition metals in coordination environments. These properties are responsible for the unique and intricate activity of transition metal sites in bio- and inorganic catalysis, but also pose challenges for both theoretical and experimental studies. Written by an international group of recognized experts, the book reviews recent advances in computational modeling and discusses their interplay using experiments. It covers a broad range of topics, including advanced computational methods for transition metal systems; spectroscopic, electrochemical and catalytic properties of transition metals in coordination environments; metalloenzymes and biomimetic compounds; and spin-related phenomena. As such, the book offers an invaluable resource for all researchers and postgraduate students interested in both fundamental and application-oriented research in the field of transition metal systems.
Download or read book Fundamental Transition Metal Organometallic Chemistry written by Charles M. Lukehart and published by Thomson Brooks/Cole. This book was released on 1985 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Studies of Transition Metal Complexes Containing Synthetic Macrocyclic Ligands written by George Antonopoulos and published by . This book was released on 1985 with total page 644 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organometallic Chemistry written by Ian J S Fairlamb and published by Royal Society of Chemistry. This book was released on 2012-11-06 with total page 143 pages. Available in PDF, EPUB and Kindle. Book excerpt: A series of critical reviews and perspectives focussing on specific aspects of organometallic chemistry interfacing with other fields of study are provided. For this volume, the critical reviews cover topics such as the activation of "inert" carbon-hydrogen bonds, ligand design and organometallic radical species. For example, Charlie O'Hara discusses how mixed-metal compounds may perform the highly selective activation of C-H bonds and, in particular, how synergic relationships between various metals are crucial to this approach. The chemistry of a remarkable series of air-stable chiral primary phosphine ligands is discussed in some depth by Rachel Hiney, Arne Ficks, Helge M3ller-Bunz, Declan Gilheany and Lee Higham. This article focuses on the preparation of these ligands and also how they may be applied in various catalytic applications. Bas De Bruin reports on how ligand radical reactivity can be employed in synthetic organometallic chemistry and catalysis to achieve selectivity in radical-type transformations. As well as highlighting ligand-centered radical transformations in open-shell transition metals, an overview of the catalytic mechanism of Co(II)-catalysed olefin cyclopropanation is given, showing that enzyme-like cooperative metal-ligand-radical reactivity is no longer limited to real enzymes. Valuable and informative comprehensive reviews in the field of organometallic chemistry are also covered in this volume. For example, organolithium and organocuprate chemistry are reviewed by Joanna Haywood and Andrew Wheatley; aspects in Group 2 (Be-Ba) and Group 12 (Zn-Hg) compounds by Robert Less, Rebecca Melen and Dominic Wright; metal clusters by Mark Humphrey and Marie Cifuentes; and recent developments in the chemistry of the elements of Group 14 - focusing on low-coordination number compounds by Richard Layfield. This volume therefore covers many synthetic and applied aspects of modern organometallic chemistry which ought to be of interest to inorganic, organic and applied catalysis fields.
Download or read book Electron Paramagnetic Resonance written by John A. Weil and published by John Wiley & Sons. This book was released on 2007-01-09 with total page 690 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an introduction to the underlying theory, fundamentals, and applications of EPR spectroscopy, as well as new developments in the area. Knowledge of the topics presented will allow the reader to interpret of a wide range of EPR spectra, as well as help them to apply EPR techniques to problem solving in a wide range of areas: organic, inorganic, biological, and analytical chemistry; chemical physics, geophysics, and minerology. Includes updated information on high frequency and multi-frequency EPR, pulsed microwave techniques and spectra analysis, dynamic effects, relaxation phenomena, computer-based spectra simulation, biomedical aspects of EPR, and more Equips readers with sufficient knowledge of EPR techniques to go on in their specialized area of interest Provides problem sets and concise bibliographies at the end of each chapter, plus several tutorial appendices on topics like mathematical operations, quantum mechanics of angular momentum, experimental considerations.
Download or read book Asymmetric Dearomatization Reactions written by Shu-Li You and published by John Wiley & Sons. This book was released on 2016-09-13 with total page 422 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first comprehensive account of the rapidly growing field of asymmetric dearomatization reactions with a focus on catalytic methods. It introduces the concept of dearomatization and describes recent progress in asymmetric reaction procedures with different catalyst systems, such as organocatalysts, transition metal catalysts, and enzymes. Chapters on dearomatizations of electron-deficient aromatic rings, dearomatization reactions via transition metal-catalyzed cross-couplings as well as dearomatization strategies in the synthesis of complex natural products are also included. Written by pioneers in the field, this is a highly valuable source of information not only for professional synthetic chemists in academia and industry but also for all those are interested in asymmetric methodologies and organic synthesis in general.
Download or read book Organometallic Chemistry written by M Green and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 321 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry.
Download or read book Macromolecules Containing Metal and Metal Like Elements Volume 6 written by Alaa S. Abd-El-Aziz and published by John Wiley & Sons. This book was released on 2005-10-27 with total page 235 pages. Available in PDF, EPUB and Kindle. Book excerpt: This series provides a useful, applications-oriented forum for the next generation of macromolecules and materials. The sixth volume in this series provides useful descriptions of the transition metals and their applications, edited by high-quality team of macromolecular experts from around the world.
Download or read book Studies in Transition Metal and Fullerene Chemistry written by Xian Bluemoon Powers and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The research presented in this dissertation focuses on two areas of study: (1) fullerene cocrystallization and structural determination and (2) four-coordinate nickel(II) complexes known to undergo temperature driven conversions from planar to tetrahedral in the solid-state. This dissertation does not cover all the research that was performed in collaboration with other research groups or other members of the Balch-Olmstead lab, however, a full list of publications is provided in Appendix A. Chapter 1 reports the structure of Sc2C2@C[subscript s](hept)-C88, the first crystallographically non-isolated pentagon rule metallic carbide clusterfullerene containing a heptagonal ring. The structure contains 13 pentagons, 32 hexagons, and 1 heptagon. Calculations suggest that the fullerene could be a kinetically trapped species. Chapter 2 compares two related nickel porphyrins, etioporphyrin-I (Etio-I) and octaethylporphyrin (OEP), and their structures when cocrystallized with C70, C70·Ni(Etio-I)·2C6H6 and C70·Ni(OEP)·2C6H6. Etio-I is a modification of OEP, in which four alternating ethyl arms are replaced by methyl substituents. This substitution leads to non-trivial crystallographic consequences. Chapter 3 details the synthesis and characterization of a series of late first-row transition-metal complexes coordinated by a family of a [beta]-diketoamine ligands having the general formula M[C-6H5COCHC(NHR)CH3]2, where M = Co2+, Ni2+, Cu2+, or Zn2+ and R = CH2CH3 or CH2C6H5. These compounds can have planar or tetrahedral coordination, including two polymorphs of a four coordinate nickel(II) compound, Ni[C6H5COCHC(NHCH2CH3)CH3]2 (Ni(B-Et)2), previously reported to undergo a temperature driven conversion from planar to tetrahedral in the solid state upon heating. Chapter 4 involves the study of another complex known to exhibit planar-tetrahedral isomerism: NiBr2(PEtPh2)2. In our efforts to synthesize the complex, we also synthesized [Ni{SC(PEtPh2)2}Br(PEtPh2)]Br, where ethyldiphenylphosphine cleaved carbon disulfide in the presence of nickel(II) bromide. The nickel complex contains an unprecedented ligand in which two ethyldiphenylphosphine molecules have added to the carbon atom while that carbon atom and the sulfur atom are coordinated to nickel. We have also synthesized a further complex with an analogous ligand, [Ni{SC(P[superscript n]PrPh2)2}Br(P[superscript n]PrPh2)]Br.
Download or read book Transition Metal Complexes as Drugs and Chemotherapeutic Agents written by Nicholas Farrell and published by Springer. This book was released on 1989-09-30 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: When this book was first conceived as a project the expanding interest in the clinical use of platinum and gold complexes made a survey of the relevant biological properties of metal complexes timely and appropriate. This timeliness has not diminished during the gestation and final publica tion of the manuscript. The introduction contains an explanation of the layout and approach to the book, which I wrote as an overall survey of the wide variety of biological properties of metal complexes. Hopefully, the reader will see the parallels in mechanisms and behavior, even in different organisms. The writing was considerably helped by the enthusiasm and confidence (totally unearned on my part) in the project of Professor Brian James and lowe him my special thanks. I also owe a great debt of gratitude to my colleagues, and especially to Eucler Paniago, of the Universidade Federal de Minas Gerais, for their comprehension and for the initial leave of absence which allowed me to begin the project. To those who read some or all of the manuscript and made suggestions, Bernhard Lippert, Kirsten Skov, and Tom Tritton, as well as the editor's reviewer I am also grateful. As usual, the final responsibility for errors or otherwise rests with the author.
Download or read book Advances in Organometallic Chemistry written by Anthony F. Hill and published by Academic Press. This book was released on 2012-12-31 with total page 193 pages. Available in PDF, EPUB and Kindle. Book excerpt: Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field that has expanded enormously since the publication of Volume 1 in 1964. Contributions from leading authorities Informs and updates on all the latest developments in the field
Download or read book Transition Metal Complexes of Cyclic Polyolefins written by G. Deganello and published by . This book was released on 1979 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt:
