Download or read book Stereochemistry and Bonding in Inorganic Chemistry written by J. E. Fergusson and published by Prentice Hall. This book was released on 1974 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt: A chronicle of Jamestown, the first English colony to survive in the wilderness of the New World.
Download or read book A Textbook of Inorganic Chemistry Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Download or read book Stereochemistry of Organometallic and Inorganic Compounds written by Ivan Bernal and published by . This book was released on 1986 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Advanced Inorganic Chemistry written by Narayan S. Hosmane and published by Academic Press. This book was released on 2017-04-27 with total page 278 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Inorganic Chemistry: Applications in Everyday Life connects key topics on the subject with actual experiences in nature and everyday life. Differing from other foundational texts with this emphasis on applications and examples, the text uniquely begins with a focus on the shapes (geometry) dictating intermolecular forces of attractions, leading to reactivity between molecules of different shapes. From this foundation, the text explores more advanced topics, such as: Ligands and Ligand Substitution Processes with an emphasis on Square-Planar Substitution and Octahedral Substitution Reactions in Inorganic Chemistry and Transition Metal Complexes, with a particular focus on Crystal-Field and Ligand-Field Theories, Electronic States and Spectra and Organometallic, Bioinorganic Compounds, including Carboranes and Metallacarboranes and their applications in Catalysis, Medicine and Pollution Control. Throughout the book, illustrative examples bring inorganic chemistry to life. For instance, biochemists and students will be interested in how coordination chemistry between the transition metals and the ligands has a direct correlation with cyanide or carbon monoxide poisoning (strong-field Cyanide or CO ligand versus weak-field Oxygen molecule). - Engaging discussion of key concepts with examples from the real world - Valuable coverage from the foundations of chemical bonds and stereochemistry to advanced topics, such as organometallic, bioinorganic, carboranes and environmental chemistry - Uniquely begins with a focus on the shapes (geometry) dictating intermolecular forces of attractions, leading to reactivity between molecules of different shapes
Download or read book Stereochemistry of Organometallic and Inorganic Compounds written by Bozzano G Luisa and published by Elsevier. This book was released on 2012-12-02 with total page 395 pages. Available in PDF, EPUB and Kindle. Book excerpt: The authors of this fourth volume in the series have reviewed the making and breaking of chemical bonds in a sophisticated manner. In particular, new pressures brought about by environmental concerns, larger demands for the medical and pharmaceutical sectors and economics of the market place are forcing us into demanding greater stereochemical control and better product yields for chemical reactions capable of producing useful products. The chapters are written by leading experts in this area and give excellent overviews of the strengths and weaknesses of the various methodologies.In Chapter 1 newer discoveries in such tried and true methods of C-C bond formation as alkylations and aldol reactions of metal enolates are reviewed. The author of Chapter 2 discusses the ability of ab-initio methods to justify the results of empirical observations in the field of transition metal derivatives of small molecules such as N2, CO2 and similar small molecules. Having established the strengths and weaknesses of the various approaches to such theoretical calculations, a more interesting approach to these methods is pursued, namely, their ability to predict, in those areas in which they are particularly strong and reliable, chemical and stereochemical events and/or results in advance of experiments, later carried out in the laboratory. Finally, Chapter 3 reviews the stereochemical results of electron transfer reactions in mononuclear copper compounds.
Download or read book Introduction to Coordination Chemistry written by Geoffrey A. Lawrance and published by John Wiley & Sons. This book was released on 2013-03-15 with total page 307 pages. Available in PDF, EPUB and Kindle. Book excerpt: At the heart of coordination chemistry lies the coordinate bond, in its simplest sense arising from donation of a pair of electrons from a donor atom to an empty orbital on a central metalloid or metal. Metals overwhelmingly exist as their cations, but these are rarely met ‘naked’ – they are clothed in an array of other atoms, molecules or ions that involve coordinate covalent bonds (hence the name coordination compounds). These metal ion complexes are ubiquitous in nature, and are central to an array of natural and synthetic reactions. Written in a highly readable, descriptive and accessible style Introduction to Coordination Chemistry describes properties of coordination compounds such as colour, magnetism and reactivity as well as the logic in their assembly and nomenclature. It is illustrated with many examples of the importance of coordination chemistry in real life, and includes extensive references and a bibliography. Introduction to Coordination Chemistry is a comprehensive and insightful discussion of one of the primary fields of study in Inorganic Chemistry for both undergraduate and non-specialist readers.
Download or read book Nomenclature of Inorganic Chemistry written by International Union of Pure and Applied Chemistry and published by Royal Society of Chemistry. This book was released on 2005 with total page 379 pages. Available in PDF, EPUB and Kindle. Book excerpt: The 'Red Book' is the definitive guide for scientists requiring internationally approved inorganic nomenclature in a legal or regulatory environment.
Download or read book Advanced Structural Inorganic Chemistry written by Wai-Kee Li and published by Oxford University Press. This book was released on 2008-03-27 with total page 842 pages. Available in PDF, EPUB and Kindle. Book excerpt: A revised and updated English edition of a textbook based on teaching at the final year undergraduate and graduate level. It presents structure and bonding, generalizations of structural trends, crystallographic data, as well as highlights from the recent literature.
Download or read book Orbital Interaction Theory of Organic Chemistry written by Arvi Rauk and published by John Wiley & Sons. This book was released on 2004-04-07 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: A practical introduction to orbital interaction theory and its applications in modern organic chemistry Orbital interaction theory is a conceptual construct that lies at the very heart of modern organic chemistry. Comprising a comprehensive set of principles for explaining chemical reactivity, orbital interaction theory originates in a rigorous theory of electronic structure that also provides the basis for the powerful computational models and techniques with which chemists seek to describe and exploit the structures and thermodynamic and kinetic stabilities of molecules. Orbital Interaction Theory of Organic Chemistry, Second Edition introduces students to the fascinating world of organic chemistry at the mechanistic level with a thoroughly self-contained, well-integrated exposition of orbital interaction theory and its applications in modern organic chemistry. Professor Rauk reviews the concepts of symmetry and orbital theory, and explains reactivity in common functional groups and reactive intermediates in terms of orbital interaction theory. Aided by numerous examples and worked problems, he guides readers through basic chemistry concepts, such as acid and base strength, nucleophilicity, electrophilicity, and thermal stability (in terms of orbital interactions), and describes various computational models for describing those interactions. Updated and expanded, this latest edition of Orbital Interaction Theory of Organic Chemistry includes a completely new chapter on organometallics, increased coverage of density functional theory, many new application examples, and worked problems. The text is complemented by an interactive computer program that displays orbitals graphically and is available through a link to a Web site. Orbital Interaction Theory of Organic Chemistry, Second Edition is an excellent text for advanced-level undergraduate and graduate students in organic chemistry. It is also a valuable working resource for professional chemists seeking guidance on interpreting the quantitative data produced by modern computational chemists.
Download or read book Stereochemistry of Organic Compounds written by Ernest L. Eliel and published by John Wiley & Sons. This book was released on 1994-09-28 with total page 1296 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stereochemistry of Organic Compounds The first fully referenced, comprehensive book on this subject in more than thirty years, Stereochemistry of Organic Compounds contains up-to-date coverage and insightful exposition of all important new concepts, developments, and tools in the rapidly advancing field of stereochemistry, including: * Asymmetric and diastereoselective synthesis * Conformational analysis * Properties of enantiomers and racemates * Separation and analysis of enantiomers and diastereoisomers * Developments in spectroscopy (including NMR), chromatography, and molecular mechanics as applied to stereochemistry * Prostereoisomerism * Conceptual foundations of stereochemistry, including terminology and symmetry concepts * Chiroptical properties Written by the leading authorities in the field, the text includes more than 4,000 references, 1,000 illustrations, and a glossary of stereochemical terms.
Download or read book The Chemical Bond in Inorganic Chemistry written by I. David Brown and published by Oxford University Press. This book was released on 2016-09-29 with total page 313 pages. Available in PDF, EPUB and Kindle. Book excerpt: The bond valence model, a description of acid-base bonding, is widely used for analysing and modelling the structures and properties of solids and liquids. Unlike other models of inorganic chemical bonding, the bond valence model is simple, intuitive, and predictive, and is accessible to anyone with a pocket calculator and a secondary school command of chemistry and physics. This new edition of 'The Chemical Bond in Inorganic Chemistry: The Bond Valence Model' shows how chemical properties arise naturally from the conflict between the constraints of chemistry and those of three-dimensional space. The book derives the rules of the bond valence model, as well as those of the traditional covalent, ionic and popular VSEPR models, by identifying the chemical bond with the electrostatic flux linking the bonded atoms. Most of the new edition is devoted to showing how to apply these ideas to real materials including crystals, liquids, glasses and surfaces. The work includes detailed examples of applications, and the final chapter explores the relationship between the flux and quantum theories of the bond.
Download or read book Basic Principles of Inorganic Chemistry written by Brian J Hathaway and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 165 pages. Available in PDF, EPUB and Kindle. Book excerpt: General chemistry textbooks are usually lengthy and present chemistry to the student as an unconnected list of facts. In inorganic chemistry, emphasis should be placed on the connections between valence shell electron configuration and the physical and chemical properties of the element. Basic Principles of Inorganic Chemistry: Making the Connections is a short, concise book that emphasises these connections, in particular the chemistry of the Main Group compounds. With reference to chemical properties, Lewis Structures, stoichiometry and spider diagrams, students will be able to predict or calculate the chemistry of simple polyatomic compounds from the valence shell configuration and will no longer be required to memorise vast amounts of factual chemistry. This book is ideal for students taking chemistry as a subsidiary subject as well as honours degree students.
Download or read book Advanced Inorganic Chemistry written by F. Albert Cotton and published by John Wiley & Sons. This book was released on 1999-04-13 with total page 1380 pages. Available in PDF, EPUB and Kindle. Book excerpt: For more than a quarter century, Cotton and Wilkinson's Advanced Inorganic Chemistry has been the source that students and professional chemists have turned to for the background needed to understand current research literature in inorganic chemistry and aspects of organometallic chemistry. Like its predecessors, this updated Sixth Edition is organized around the periodic table of elements and provides a systematic treatment of the chemistry of all chemical elements and their compounds. It incorporates important recent developments with an emphasis on advances in the interpretation of structure, bonding, and reactivity.“/p> From the reviews of the Fifth Edition: "The first place to go when seeking general information about the chemistry of a particular element, especially when up-to-date, authoritative information is desired." —Journal of the American Chemical Society "Every student with a serious interest in inorganic chemistry should have [this book]." —Journal of Chemical Education "A mine of information . . . an invaluable guide." —Nature "The standard by which all other inorganic chemistry books are judged." —Nouveau Journal de Chimie "A masterly overview of the chemistry of the elements." —The Times of London Higher Education Supplement "A bonanza of information on important results and developments which could otherwise easily be overlooked in the general deluge of publications." —Angewandte Chemie
Download or read book Molecular Visions Organic Inorganic Organometallic Molecular Model Kit 1 by Darling Models to accompany Organic Chemistry written by Darling Models and published by McGraw-Hill Education. This book was released on 2000-04-07 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular models are as vital a tool for the study of chemistry as calculators are for the study of mathematics. Molecular Visions models may be assembled in infinite combinations enabling the user to construct not only familiar configurations but also undiscovered possibilities. Models are intended to inspire the imagination, stimulate thought, and assist the visualization process. They present the user with a solid form of an abstract object that can otherwise only be visualized by the chemist. While chemistry textbooks use letters and graphics to describe molecules, molecular models make them "real". MOLECULAR VISIONS Organic Kit #1 is in a green plastic box, 9"x4"x2"
Download or read book Chemistry Inorganic Chemistry Atomic Structure Chemical Bonding and Fundamentals of Organic Chemistry written by Dr. Mohd. Irfan Ahmad Khan and published by Thakur Publication Private Limited. This book was released on 2020-03-19 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: Buy Latest (Chemistry) Inorganic Chemistry: Atomic Structure,Chemical Bonding and Fundamentals of Organic Chemistry in English language for B.Sc 1st Semester Bihar State By Thakur publication.
Download or read book Chemical Bonds written by Jeremy K. Burdett and published by John Wiley & Sons. This book was released on 1997-05-28 with total page 182 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inorganic Chemistry This series reflects the breadth of modern research in inorganic chemistry and fulfils the need for advanced texts. The series covers the whole range of inorganic and physical chemistry, solid state chemistry, coordination chemistry, main group chemistry and bioinorganic chemistry. Chemical Bonds A Dialog Jeremy K. Burdett The University of Chicago, USA Understanding the nature of the chemical bond is the key to understanding all chemistry, be it inorganic, physical, organic or biochemistry. In the form of a question and answer tutorial the fundamental concepts of chemical bonding are explored. These range from the nature of the chemical bond, via the regular hexagonal structure of benzene and the meaning of the term 'metallic bond', to d-orbital involvement in hypervalent compounds and the structure of N_2O. Chemical Bonds: A Dialog provides * a novel format in terms of a dialog between two scientists * insights into many key questions concerning chemical bonds * an orbital approach to quantum chemistry
Download or read book Boron Hydride Chemistry written by Earl Muetterties and published by Elsevier. This book was released on 2012-12-02 with total page 545 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boron Hydride Chemistry covers the significant contributions of boron hydride research in the subjects of bonding, structure, and stereochemistry. This book contains 12 chapters that illustrate the merging of certain areas of boron hydride chemistry with other disciplines, such as organic, organometallic, and transition metal chemistry. After providing an overview of the general geometric, stereochemical, and dynamic stereochemical features of boron hydrides, this book goes on exploring the bonding theory and theoretical research on boron hydrides, with an emphasis on boron hydrides that have open polyhedral structures. These topics are followed by discussions on gas phase and solution reactions of borane and substituted boranes. A chapter focuses on the chemistry of cations containing boron atoms bonded to hydrogen. The remaining chapters examine the syntheses, structures, bonding, spectral properties, and chemistry of specific boron hydrides, including borazines, closo-boron hydrides, carboranes, icosahedral carboranes, and close- and nido-heteroboranes. Inorganic chemists and researchers, teachers, and undergraduate inorganic chemistry students will find this book invaluable.
