Download or read book Stabilisers for Polyolefins written by C. Krohnke and published by iSmithers Rapra Publishing. This book was released on 2001 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt: This review describes the main types of stabilisers with the focus on those categories for polyolefins. It also elucidates some of the physical and chemical aspects of such products when incorporated into the polymer matrix, discussing stability during weathering, heat ageing and processing. The review is supported by several hundred relevant abstracts selected from the Polymer Library.
Download or read book Degradation and Stabilisation of Polyolefins written by Norman S. Allen and published by . This book was released on 1983 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Antioxidative Stabilization Of Polymers written by Y A Shlyapnikov and published by CRC Press. This book was released on 1996-10-09 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymers play a vital role in manufacturing processes of many kinds, and the development of new polymeric materials is of increasing importance in the field of materials science. Because of this, there is a need to understand why the properties of polymers change, what can be done to avoid degradation and failure, and how performance can be maintained over a much longer lifespan. The authors deal firstly with the process of degradation through oxidation, and then explain how the addition of various antioxidants can inhibit or retard this process. They present a unique discussion of the physico-chemical aspects, particularly the chemical kinetics of antioxidant action and of branched chain reaction kinetics, and the theory of critical phenomena inhibited oxidation. The last part of the book offers practical advice on methods of oxidation investigation, on selection of appropriate antixodants, and on the basic principles of performance prognosis. The book also includes a unique coverage of the regularities of additive solubility.
Download or read book Stabilization of Polymeric Materials written by Hans Zweifel and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 225 pages. Available in PDF, EPUB and Kindle. Book excerpt: Plastics are used worldwide in everyday life, e.g. as food packaging, electronics, construction, automotive parts, and household appliances. To produce these products with the desired service lifetimes the use of suitable stabilizers is necessary. This book provides a concise and comprehensive overview of the basic mechanisms of plastic degradation processes caused by heat and light. At its core is a detailed description of the stabilization of different polymers, including an explanation of stabilization mechanisms and the influence of commonly used additives such as fillers, flame retardents and pigments on the stability of plastic. Every polymer scientist, material technologist, or application engineer dealing with the design of the properties of plastics will benefit from this new overview.
Download or read book Polymer Degradation and Stabilisation written by Norman Grassie and published by CUP Archive. This book was released on 1988-04-14 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: The study of polymer degradation and stabilisation is of considerable practical importance as the industrial uses of polymeric materials continue to expand. In this book, the authors lucidly relate technological phenomena to the chemistry and physics of degradation and stabilisation processes. Degradation embraces a variety of technologically important phenomena ranging from relatively low temperature processes such as 'weathering' of plastics, 'fatigue' of rubbers through the processing of polymers in shearing mixers to very high temperature processes such as flammability and ablation. All these technological phenomena have in common certain basic chemical reactions. Thus 'weathering' has its roots in photo-oxidation, 'fatigue' and melt-degradation in mechano-oxidation and flammability, and ablation in ablation in pyrolysis and vapour phase oxidation.
Download or read book Handbook of Plastic Films written by Elsayed M. Abdel-Bary and published by iSmithers Rapra Publishing. This book was released on 2003 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: Plastic films are high-performance materials which play an essential part in modern life. The plastics films industry uses state-of-the-art manufacturing processes and is continuously seeking out new technologies to improve its performance. The understanding of the nature of plastic films, their production techniques, applications and their characterisation is essential for producing new types of plastic films. This handbook has been written to discuss the production and main uses of plastic films. Plastic films are high-performance materials which play an essential part in modern life. Plastic films are mostly used in packaging applications but as will be seen from this book they are also used in the agricultural, medical and engineering fields. The plastics films industry uses state-of-the-art manufacturing processes and is continuously seeking out new technologies to improve its performance. The understanding of the nature of plastic films, their production techniques, applications and their characterisation is essential for producing new types of plastic films. This handbook has been written to discuss the production and main uses of plastic films.
Download or read book Aging and Stabilization of Polymers written by M. B. Neiman and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt: The need for a broad development of the production of polymer ma terials has become evident. All these materials are subject to various types of aging (destruction); hence, stabilizers which permit the stor age, reprocessing, and use of polymer materials without any appreci able change in their properties must be introduced into them. In recent years, this problem of stabilizing polymers has attracted the attention of many scientists and technologists, both in the USSR and abroad. The scientific basis of the foreign studies will be found in a number of theo retical premises, but chiefly the theory of chain reactions with un branched chains. In the Soviet Union, the concepts of Academician N. N. Semenov on chain reactions with degenerate branches have become the starting point of theoretical studies of the stabilization and destruction of polymers. Soviet scientists have developed a theory of critical concentrations of antioxidants and have shown that the processes of stabilization have a very complex chemical character. The nature of the polymers them selves greatly affects these processes and consequently, different stabil izers are required for polymers of different structures. In addition, it has been shown that the antioxidants used thus far can not only cause chain termination, but can also initiate oxidation and give rise to de generate branches.
Download or read book Additives in Polymers written by Jan C. J. Bart and published by John Wiley & Sons. This book was released on 2005-04-08 with total page 836 pages. Available in PDF, EPUB and Kindle. Book excerpt: This industrially relevant resource covers all established and emerging analytical methods for the deformulation of polymeric materials, with emphasis on the non-polymeric components. Each technique is evaluated on its technical and industrial merits. Emphasis is on understanding (principles and characteristics) and industrial applicability. Extensively illustrated throughout with over 200 figures, 400 tables, and 3,000 references.
Download or read book Developments in Polymer Stabilisation 8 written by G. Scott and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 303 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of the present series of publications is two-fold. In the first place it is intended to review progress in the development of practical stabilising systems for a wide range of polymers and applications. A complementary and ultimately more important objec tive is to accommodate these practical developments within the framework of antioxidant theory, since there can be little question that further major advances in the practice of stabilisation technology will only be possible on the basis of a firm mechanistic foundation. Research into the role of 'stable' free radicals as antioxidants and stabilisers for polymers has intensified in recent years. Nitroxyl radicals (nitroxides) were the earliest long-lived radicals to be investi gated in detail and Maslov and Zaikov review the developments that have taken place in understanding their reaction mechanisms from the time when they were first investigated in liquid hydrocarbon systems to the present day when their outstanding performance as light stabilisers has been the object of much scientific research. Although some features of their reactivity remain obscure, the authors approach the problem kinetically and indicate the factors limiting their effectiveness.
Download or read book Mechanisms of Polymer Degradation and Stabilisation written by G. Scott and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this publication is two-fold. In the first place it is intended to review progress in the development of practical stabilising systems for a wide range of polymers and applications. A complemen tary and ultimately more important objective is to accommodate these practical developments within the framework of antioxidant theory, since there can be little question that further major advances in the practice of stabilisation technology will only be possible on a firm mechanistic foundation. With the continual increase in the number of commercial anti oxidants and stabilisers, often functioning by mechanisms not even considered ten years ago, there is a need for a general theory which will allow the potential user to predict the performance of a particular antioxidant structure under specific practical conditions. Any such predictive tool must involve a simplified kinetic approach to inhibited oxidation and, in Chapter 1, Denisov outlines a possible mechanistic approach with the potential to predict the most useful antioxidant to use and the limits of its usefulness. In Chapter 2, Schwetlick reviews the current state of knowledge on the antioxidant mechanisms of the phosphite esters with particular emphasis on their catalytic peroxidolytic activity. Dithiophosphate v vi PREFACE derivatives show a similar behaviour but for quite different reasons and, in Chapter 3, AI-Malaika reviews information available from analytical studies, particularly using 31p_NMR spectroscopy, to elucid ate the complex chemistry that leads to the formation of the antioxidant -active agents.
Download or read book Polyolefin Fibres written by S C O Ugbolue and published by Elsevier. This book was released on 2009-01-28 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyolefins are one of the most widely used commercial polymers. This book reviews the most important polyolefins, including polyethylene and polypropylene. These versatile fibres are durable, chemically resistant, lightweight, economical and functional. Polyolefin fibres: industrial and medical applications provides a comprehensive review of the structure and properties of this group of fibres, together with methods to improve the functionality of polyolefins and their range of applications. The first set of chapters discusses the different types of polyolefins, their structural and chemical properties as well as their production methods. The second group of chapters examines how to improve the functionality of polyolefin fibres. A final group of chapters addresses how polyolefins can be incorporated into specific applications such as industrial, medical and automotive products. Written by a distinguished team of international contributors, Polyolefin fibres: industrial and medical applications is a quintessential reference for textile technologists, fibre scientists, yarn and fabric manufacturers and also those in academia. Reviews the most important polyolefins including polyethylene and polyproplene, their structural and chemical properties as well as production methods Examines methods to improve the functionality of polyolefin fibres including production methods and quality control
Download or read book Biodegradable Polymers for Industrial Applications written by Robin Smith and published by Elsevier. This book was released on 2005-05-06 with total page 548 pages. Available in PDF, EPUB and Kindle. Book excerpt: The vast majority of plastic products are made from petroleum-based synthetic polymers that do not degrade in a landfill or in a compost-like environment. Therefore, the disposal of these products poses a serious environmental problem. An environmentally-conscious alternative is to design/synthesize polymers that are biodegradable. Biodegradable polymers for industrial applications introduces the subject by outlining the classification and development of biodegradable polymers. Materials available for the production of biodegradable polymers are explored. Polymers derived from sugars, natural fibres, renewable forest resources, poly(lactic acid) and protein-nanoparticle composites are looked at in detail in this section. The properties and mechanisms of degradation are looked at, prefacing the subject with a chapter on current standards. The final part explores opportunities for industrial applications, with chapters on packing, agriculture and biodegradable polycaprolactone foams in supercritical carbon dioxide. Biodegradable polymers for industrial applications explores the fundamental concepts concerning the development of biodegradable polymers, degradable polymers from sustainable sources, degradation and properties and industrial applications. It is an authoritative book that is invaluable for academics, researchers and policy makers in the industry. Reviews the importance and industrial use of biodegradable polymers and degradable polymers from sustainable sources An invaluable resource for both academics and industry Edited by a leading authority in the field with contributions from a worldwide team of experts
Download or read book Chemical Analysis of Polymers written by G. Lawson and published by iSmithers Rapra Publishing. This book was released on 1991-12 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book World Index of Polyolefine Stabilizers written by T. J. Henman and published by Gulf Publishing Company. This book was released on 1982 with total page 347 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Thermal Oxidative and Light Stabilization of Polypropylene written by Science Surveys, Mountainside, N.J. and published by . This book was released on 1966 with total page 152 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Handbook of Environmental Degradation of Materials written by Myer Kutz and published by William Andrew. This book was released on 2018-06-15 with total page 684 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook of Environmental Degradation of Materials, Third Edition, explains how to measure, analyze and control environmental degradation for a wide range of industrial materials, including metals, polymers, ceramics, concrete, wood and textiles exposed to environmental factors, such as weather, seawater, and fire. This updated edition divides the material into four new sections, Analysis and Testing, Types of Degradation, Protective Measures and Surface Engineering, then concluding with Case Studies. New chapters include topics on Hydrogen Permeation and Hydrogen Induced Cracking, Weathering of Plastics, the Environmental Degradation of Ceramics and Advanced Materials, Antimicrobial Layers, Coatings, and the Corrosion of Pipes in Drinking Water Systems. Expert contributors to this book provide a wealth of insider knowledge and engineering expertise that complements their explanations and advice. Case Studies from areas such as pipelines, tankers, packaging and chemical processing equipment ensure that the reader understands the practical measures that can be put in place to save money, lives and the environment. Introduces the reader to the effects of environmental degradation on a wide range of materials, including metals, plastics, concrete, wood and textiles Describes the kind of degradation that effects each material and how best to protect it Includes case studies that show how organizations, from small consulting firms, to corporate giants design and manufacture products that are more resistant to environmental effects
Download or read book Handbook of Antioxidants written by Evgeny T. Denisov and published by CRC Press. This book was released on 1999-11-11 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt: Designed for scientists and engineers involved in the chemistry and technology of antioxidants, the Second Edition of this popular handbook continues to provide comprehensive data on the thermodynamics and reactivity of antioxidants. Fully revised and updated, the Second Edition provides the latest data on antioxidants and polymer stabilizers, new data for biological antioxidants, a corrected list of bond dissociation energies, and a full bibliography. Additions and changes in the New Edition: The latest data on O-H bond dissociation energies of phenols and the new scale these values Thermodynamic functions of antioxidants and their intermediate presented in tables A table with current data on dissociation energies of C-H bonds of hydrocarbons and oxygen-containing compounds Rate constants and activation energies of reactions of antioxidants with ozone, nitrogen dioxide, and hydroperoxide Kinetic characteristics of benzoquinine reactions with antioxidants Rate constants of free radical generation through biomolecular reactions with ozone, nitrogen dioxide, and hydroperoxide All calculated data from the first edition has been recalculated in accordance with new data on dissociation energies and parameters of reactivity Data on thermodynamics of hydrogen bond formation of antioxidants All data on cyclic mechanisms of chain termination by antioxidants collected into a special chapter Special chapters on bioantioxidants and stabilization of polymers The Handbook of Antioxidants puts essential data at your fingertips. Its comprehensive nature and ease-of-use make it the resource for scientific researchers and engineers working in the field of physical chemistry of antioxidants.
