Download or read book Spectrophotometric Determination of Equilibrium Constants in Solution written by W. A. E. McBryde and published by . This book was released on 1974 with total page 26 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Determination of Stability Constants written by Francis J. C. Rossotti and published by . This book was released on 1961 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Spectrophotometric Determination of Equilibrium Constants of Some Cresolsulfonephtahlein Indicators in Liquid Ammonia written by Norman T. Kobayashi and published by . This book was released on 1965 with total page 112 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Computational Methods for the Determination of Formation Constants written by David J. Leggett and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is concerned with methods that are available for the calculation of for mation constants, in particular computational procedures. Although graphical meth ods have considerable value in the exploration of primary (raw) data they have been overtaken by computational methods, which, for the most part, take primary data and return the refined formation constants. Graphical methods are now considered com plementary to these general computational procedures. This volume brings together programs that span the lifetime of computer-assisted determination of formation constants. On one hand the reader will find listings of programs that are derived from LETAGROP (b.l961) and the GAUSS-G/SCOGS (b. 1962) families. On the other hand programs are presented that are the newest mem bers of the SCOGS lineage and from the on-going MINIQUAD series. One program is presented that describes a computational approach to the classical Hedstrom Osterberg methods; another that takes care of electrode calibration in a simple yet rigorous manner. Potentiometry and spectrophotometry are the most popular experimental tech niques for equilibrium studies, and the programs in this volume reflect this. Four programs handle potentiometric data, two will process spectrophotometric data, and one makes use of both types of data separately or in combination.
Download or read book Computation of Solution Equilibria written by Milan Meloun and published by Ellis Horwood. This book was released on 1988 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Rapid Spectrophotometric Method for the Determination of Equilibrium Constants Applied in the Study of the Thermodynamics of Hemerythrin Equilibria written by Eileen Genevra Gorman and published by . This book was released on 1978 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Determination of Stability Constants and Other Equilibrium Constants in Solution written by Richard Nelson Current and published by . This book was released on 1961 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Solution Equilibria written by F. R. Hartley and published by Ellis Horwood. This book was released on 1980 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Quantitative Chemical Analysis Sixth Edition written by Daniel C. Harris and published by Macmillan. This book was released on 2003 with total page 948 pages. Available in PDF, EPUB and Kindle. Book excerpt: For instructors who wish to focus on practical, industrial, or research chemistry. Includes case studies, applications boxes, and spreadsheet applications.
Download or read book Frontiers in Medicinal Chemistry Volume 1 written by Atta-ur Rahman and published by Bentham Science Publishers. This book was released on 2010-12-10 with total page 680 pages. Available in PDF, EPUB and Kindle. Book excerpt: ""Frontiers in Medicinal Chemistry" is an Ebook series devoted to the review of areas of important topical interest to medicinal chemists and others in allied disciplines. "Frontiers in Medicinal Chemistry" covers all the areas of medicinal chemistry, incl"
Download or read book A Critical Review of Equilibrium Data for Proton and Metal Complexes of 1 10 Phenanthroline 2 2 Bipyridyl and Related Compounds written by W.A.E. McBryde and published by Elsevier. This book was released on 2013-10-22 with total page 85 pages. Available in PDF, EPUB and Kindle. Book excerpt: A Critical Review of Equilibrium Data for Proton- and Metal Complexes of 1,10-Phenanthroline, 2,2'-Bipyridyl and Related Compounds is a compilation of acidity constants for the 1,10-phenanthrolinium and 2,2'-bipyridinium ions and their derivatives, as well as stability constants for metal complexes formed by the conjugate bases of these. These equilibrium data are critically examined. This monograph includes values determined in non-aqueous or mixed solvents, as well as those for a large number of ""mixed"" metal complexes incorporating these bases and a second ligand. The survey also contains known values for the enthalpies and entropies of formation for the proton- and metal-ion complexes. The compilation indicates the conditions under which the equilibrium constants apply and the methods by which they were determined. The acid-base properties of the compounds are represented by the acidity constant of the phenanthrolinium or bipyridinium ion expressed as a pK value. Nearly all the values listed were obtained either potentiometrically or spectrophotometrically, both of which depend fundamentally on measurements of pH or hydrogen-ion concentration. This book will be of value to chemists.
Download or read book A Textbook of Inorganic Chemistry Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Download or read book Critical Evaluation of Equilibrium Constants in Solution written by J. Stary and published by . This book was released on 1977 with total page 42 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Contemporary Chemical Analysis written by Judith F. Rubinson and published by . This book was released on 1998 with total page 648 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a readable yet rigorous introduction to analytical methods with a focus on problem-solving skills. It stresses the fundamental concepts of chemical analysis and, through examples from current journals and other science media, shows how the principles and practice of analytical chemistry are used to produce answers to questions in all areas of scientific study and practice.Features a balance of topics that is closer to contemporary analytical practice than those covered by other books. Introduces the tools that are ubiquitous in analytical chemistry e.g., statistics, sampling and sample preparation. Discusses methods depending on chemical kinetics which are so widely used in medicine and biology. Features a number of problems that call for the use of a speadsheet to generate data, which is then plotted to show trends. Includes answers for all numerical problems in an appendix.
Download or read book Determination of an Equilibrium Constant by Spectrophotometry written by James M. Postma and published by W H Freeman & Company. This book was released on 2000-01-15 with total page 16 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Binding Constants written by Kenneth A. Connors and published by Wiley-Interscience. This book was released on 1987-05-04 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: This unique book presents a systematic review of the methods for the determination of binding constants of complex formation in solution. Collects material that has been scattered throughout the literature of several separate fields. Offered here are methods from the areas of acid-base chemistry, metal-ion coordination compounds, hydrogen-bonding, charge-transfer complexation, hydrophobic interaction, and protein-binding. Discusses the relevant thermodynamics, modelling, statistics and regression analysis, and interpretation of data. Includes fresh discussions of random association (contact complexes), selection of standard states, and comparison of results. Treats all of the experimental methods useful for measuring these equilibrium constants, including those based on spectrophotometry, nuclear magnetic resonance, reaction kinetics, potentiometry, solubility, liquid-liquid partitioning, dialysis, chromatography, flourimetry, and many others.
Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1976 with total page 612 pages. Available in PDF, EPUB and Kindle. Book excerpt:
