Download or read book Solid state Sodium Batteries Using Polymer Electrolytes and Sodium Intercalation Electrode Materials written by Yanping Ma and published by . This book was released on 1996 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Solid state Sodium Batteries Using Polymer Electrolytes and Sodium Intercalation Electrode Materials written by and published by . This book was released on 1996 with total page 156 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solid-state sodium cells using polymer electrolytes (polyethylene oxide mixed with sodium trifluoromethanesulfonate: PEO{sub n}NaCF3SO3) and sodium cobalt oxide positive electrodes are characterized in terms of discharge and charge characteristics, rate capability, cycle life, and energy and power densities. The P2 phase Na(subscript x)CoO2 can reversibly intercalate sodium in the range of x = 0.3 to 0.9, giving a theoretical specific energy of 440 Wh/kg and energy density of 1,600 Wh/l. Over one hundred cycles to 60% depth of discharge have been obtained at 0.5 mA/cm2. Experiments show that the electrolyte/Na interface is stable and is not the limiting factor to cell cycle life. Na{sub 0.7}CoO2 composite electrodes containing various amounts of carbon black additive are investigated. The transport properties of polymer electrolytes are the critical factors for performance. These properties (the ionic conductivity, salt diffusion coefficient, and ion transference number) are measured for the PEO{sub n}NaCF3SO3 system over a wide range of concentrations at 85 C. All the three transport properties are very salt-concentration dependent. The ionic conductivity exhibits a maximum at about n = 20. The transference number, diffusion coefficient, and thermodynamic factor all vary with salt concentration in a similar fashion, decreasing as the concentration increases, except for a local maximum. These results verify that polymer electrolytes cannot be treated as ideal solutions. The measured transport-property values are used to analyze and optimize the electrolytes by computer simulation and also cell testing. Salt precipitation is believed to be the rate limiting process for cells using highly concentrated solutions, as a result of lower values of these properties, while salt depletion is the limiting factor when a dilute solution is used.

Download or read book Sodium Ion Batteries written by Maria-Magdalena Titirici and published by John Wiley & Sons. This book was released on 2022-12-06 with total page 767 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents uparalleled coverage of Na-ion battery technology, including the most recent research and emerging applications Na-ion battery technologies have emerged as cost-effective, environmentally friendly alternatives to Li-ion batteries, particularly for large-scale storage applications where battery size is less of a concern than in portable electronics or electric vehicles. Scientists and engineers involved in developing commercially viable Na-ion batteries need to understand the state-of-the-art in constituent materials, electrodes, and electrolytes to meet both performance metrics and economic requirements. Sodium-Ion Batteries: Materials, Characterization, and Technology provides in-depth coverage of the material constituents, characterization, applications, upscaling, and commercialization of Na-ion batteries. Contributions by international experts discuss the development and performance of cathode and anode materials and their characterization - using methods such as NMR spectroscopy, magnetic resonance imaging (MRI), and computational studies - as well as ceramics, ionic liquids, and other solid and liquid electrolytes. Discusses the development of battery technology based on the abundant alkali ion sodium Features a thorough introduction to Na-ion batteries and their comparison with Li-ion batteries Reviews recent research on the structure-electrochemical performance relationship and the development of new solid electrolytes Includes a timely overview of commercial perspectives, cost analysis, and safety issues of Na-ion batteries Covers emerging technologies including Na-ion capacitors, aqueous sodium batteries, and Na-S batteries The handbook Sodium-Ion Batteries: Materials, Characterization, and Technology is an indispensable reference for researchers and development engineers, materials scientists, electrochemists, and engineering scientists in both academia and industry.

Download or read book Sodium Ion Batteries written by Inamuddin and published by Materials Research Forum LLC. This book was released on 2020-07-05 with total page 278 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sodium-ion batteries are likely to be the next-generation power sources. They offer higher safety than lithium-ion batteries and, most important, sodium is available in unlimited abundance. The book covers the fundamental principles and applications of sodium-ion batteries and reports experimental work on the use of electrolytes and different electrode materials, such as silicon, carbon, conducting polymers, and Mn- and Sn-based materials. Also discussed are state-of-the-art, future prospects and challenges in sodium-ion battery technology. Keywords: Sodium-Ion Batteries, Lithium-Ion Batteries, Carbon Nanofibers, Conducting Polymers, Electrode Materials, Electrolytes, Graphene, Carbon Anodes, Magnetic Nanomaterials, Mn-based Materials, Sn-based Materials, Na-O2 Batteries, NASICON Electrodes, Organic Electrodes, Polyacetylene, Polyaniline, Polyphenylene, Redox Mediators, Reversible Capacity, Singlet Oxygen, Superoxide Stability.

Download or read book Polymer based Solid State Batteries written by Daniel Brandell and published by Walter de Gruyter GmbH & Co KG. This book was released on 2021-07-19 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent years has seen a tremendous growth in interest for solid state batteries based on polymer electrolytes, with advantages of higher safety, energy density, and ease of processing. The book explains which polymer properties guide the performance of the solid-state device, and how these properties are best determined. It is an excellent guide for students, newcomers and experts in the area of solid polymer electrolytes.

Download or read book Solid State Batteries Materials Design and Optimization written by Christian Julien and published by Springer Science & Business Media. This book was released on 2013-11-27 with total page 577 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of solid state ionics is multidisciplinary in nature. Chemists, physicists, electrochimists, and engineers all are involved in the research and development of materials, techniques, and theoretical approaches. This science is one of the great triumphs of the second part of the 20th century. For nearly a century, development of materials for solid-state ionic technology has been restricted. During the last two decades there have been remarkable advances: more materials were discovered, modem technologies were used for characterization and optimization of ionic conduction in solids, trial and error approaches were deserted for defined predictions. During the same period fundamental theories for ion conduction in solids appeared. The large explosion of solid-state ionic material science may be considered to be due to two other influences. The first aspect is related to economy and connected with energy production, storage, and utilization. There are basic problems in industrialized countries from the economical, environmental, political, and technological points of view. The possibility of storing a large amount of utilizable energy in a comparatively small volume would make a number of non-conventional intermittent energy sources of practical convenience and cost. The second aspect is related to huge increase in international relationships between researchers and exchanges of results make considerable progress between scientists; one find many institutes joined in common search programs such as the material science networks organized by EEC in the European countries.

Download or read book Fast Ion Transport in Solids written by B. Scrosati and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 375 pages. Available in PDF, EPUB and Kindle. Book excerpt: The main motivation for the organization of the Advanced Research Workshop in Belgirate was the promotion of discussions on the most recent issues and the future perspectives in the field of Solid State lonics. The location was chosen on purpose since Belgirate was the place were twenty years ago, also then under the sponsorship of NATO, the very first international meeting on this important and interdisciplinary field took place. That meeting was named "Fast Ion Transport in Solids" and gathered virtually everybody at that time having been active in any aspect of motion of ions in solids. The original Belgirate Meeting made for the first time visible the technological potential related to the phenomenon of the fast ionic transport in solids and, accordingly, the field was given the name "Solid State lonics". This field is now expanded to cover a wide range of technologies which includes chemical sensors for environmental and process control, electrochromic windows, mirrors and displays, fuel cells, high performance rechargeable batteries for stationary applications and electrotraction, chemotronics, semiconductor ionics, water electrolysis cells for hydrogen economy and other applications. The main idea for holding an anniversary meeting was that of discussing the most recent issues and the future perspectives of Solid State lonics just twenty years after it has started at the same location on the lake Maggiore in North Italy.

Download or read book Solid State Batteries written by Nithyadharseni Palaniyandy and published by Springer Nature. This book was released on 2022-11-01 with total page 298 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive analysis of novel design strategies in higher energy solid-state lithium batteries. It describes synthesis and experimental techniques to characterize the physical, chemical and electrochemical properties of the electrode and electrolytes. The book reports on electrochemical measurements of conductivity and related parameters in solid electrolytes and its interfaces. It also presents various technologies that have been used for the fabrication of all-solid-state lithium-ion batteries such as thin-film, 3D printing (additive manufacturing) and atomic layer deposition. A large part of the text focus on the description on the complete functioning and challenges with the electrochemistry of the electrodes and solid electrolyte interfaces. The book also supplies valuable insight into potential growth opportunities in this exciting market and cost-effective design tactics in solid-state assemblies.

Download or read book Na ion Batteries written by and published by John Wiley & Sons. This book was released on 2021-05-11 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers both the fundamental and applied aspects of advanced Na-ion batteries (NIB) which have proven to be a potential challenger to Li-ion batteries. Both the chemistry and design of positive and negative electrode materials are examined. In NIB, the electrolyte is also a crucial part of the batteries and the recent research, showing a possible alternative to classical electrolytes – with the development of ionic liquid-based electrolytes – is also explored. Cycling performance in NIB is also strongly associated with the quality of the electrode-electrolyte interface, where electrolyte degradation takes place; thus, Na-ion Batteries details the recent achievements in furthering knowledge of this interface. Finally, as the ultimate goal is commercialization of this new electrical storage technology, the last chapters are dedicated to the industrial point of view, given by two startup companies, who developed two different NIB chemistries for complementary applications and markets.

Download or read book Design of Advanced Polymer Electrolyte for High Performance Lithium and Sodium Batteries written by Wenfeng Liang and published by . This book was released on 2020 with total page 259 pages. Available in PDF, EPUB and Kindle. Book excerpt: The energy density of lithium ion batteries (LIBs) is limited by the capacities of the electrode materials. Lithium metal is a promising anode material for future LIBs due to its high theoretical specific capacity (3,860 mAh/g) and low redox potential (-3.04 V vs. standard hydrogen electrode). However, lithium plating in liquid electrolyte will form Li dendritic structure and subsequently penetrate the porous polymeric separator, resulting in battery short circuiting. A straightforward method to suppress the growth of lithium dendrites is to replace the liquid phase electrolyte with a solid-state one. Among different solid-state electrolyte candidates, solid polymer electrolyte (SPE) is advantageous due to its flexible nature and low-cost raw material. However, SPE typically exhibits low ionic conductivity compared to its liquid electrolyte counterpart, which thus could result in restricted use in battery applications. In this work, a rational approach to achieve highly ionic conductive and electrochemically stable SPEs will be discussed. A phase-diagram was firstly mapped out to provide guidance in designing a composite electrolyte with high ionic conductivity at room temperature. The thermal and electrochemical stability of SPE were then characterized. A dual-salt base electrolyte with lithium bis(oxalate)borate (LiBOB) and bis(trifluoromethanesulphonyl)imide (LiTFSI) exhibited excellent electrochemical stability from the passivation layer formed between the electrode/electrolyte interface. In addition, SPEs based on crosslinked fluoropolymer and poly(ethylene glycol) diacrylate (PEGDA) were investigated. Those properties of SPE enable the fabrication of solid-state batteries with lithium metal as an anode. Lithium plating/striping experiments and battery tests were conducted, and the results indicated that the dual-salt SPE could be a promising candidate electrolyte for next generation solid-state rechargeable battery. Sodium ion batteries display good performance yet with limited protection for the inevitable sodium dendrite growth if coupled with metallic sodium electrode, which is an adverse phenomenon that would eventually result in the deterioration of the battery. SPEs with superior ionic conductivity and outstanding electrochemical stability are promising for the all solid-state sodium batteries in grid-storage applications. In this study, a transparent free-standing SPE membrane comprising sodium perchlorate (NaClO4), PEGDA and plastic crystal molecules was fabricated. This sodium based SPE exhibits high sodium-ion conductive property (over 0.925 mS/cm at 30 oC) while being electrochemically stable. A rational approach has also been designed and achieved by using the phase diagram. The NaClO4-based SPE can not only exhibit excellent electrochemical stability with metallic sodium electrode, but also provide remarkable current rate and long-term cycling performance for the solid-state sodium metal batteries (SMB).

Download or read book Solid State Batteries written by César A.C. Sequeira and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 567 pages. Available in PDF, EPUB and Kindle. Book excerpt: The holding of an Advanced Study Institute on the topic of "Solid State Batteries" at this time represented a logical progression in a series of NATO-sponsored events. Summer Schools at Belgerati, Italy in 1972 and Ajaccio, Corsica in 1975 on the topic of "Solid -State IOllics" dealt with fundamental aspects of solid-state electro chemistry and materials science. The application of specific solid ionic conductors played a significant role in the Science Committee Institute on "Materials for Advanced Batteries" held at Aussois, France in 1979. Interest in these and related fields has grown substantially over this period, and is sustained today. Research and development programmes exist within universities, governmental research laboratories and industry, worldwide and a series of international conferences and collaborations have been set up. Advanced batteries, both secondary and primary, have a potentially important role ~o play in the development of many areas of tech nology in the late 20th century and beyond. Applications include stationary storage, vehicle traction and remote power sources, as well as industrial and domestic cordless products and consumer and military electronics. The concept of an all-so lid-state battery is not new but, until recently, their performance has precluded their use in other than specialist low power, primary, applications. Recent materials' developments, however, make the solid-state battery a real possibility in all of the application sectors mentioned above. Further, such cells offer many attractive features over alternative present-day and advanced systems.

Download or read book Handbook Of Solid State Batteries Second Edition written by Nancy J Dudney and published by World Scientific. This book was released on 2015-07-09 with total page 835 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solid-state batteries hold the promise of providing energy storage with high volumetric and gravimetric energy densities at high power densities, yet with far less safety issues relative to those associated with conventional liquid or gel-based lithium-ion batteries. Solid-state batteries are envisioned to be useful for a broad spectrum of energy storage applications, including powering automobiles and portable electronic devices, as well as stationary storage and load-leveling of renewably generated energy. This comprehensive handbook covers a wide range of topics related to solid-state batteries, including advanced enabling characterization techniques, fundamentals of solid-state systems, novel solid electrolyte systems, interfaces, cell-level studies, and three-dimensional architectures. It is directed at physicists, chemists, materials scientists, electrochemists, electrical engineers, battery technologists, and evaluators of present and future generations of power sources. This handbook serves as a reference text providing state-of-the-art reviews on solid-state battery technologies, as well as providing insights into likely future developments in the field. It is extensively annotated with comprehensive references useful to the student and practitioners in the field.

Download or read book Solid State Ionics for Batteries written by M. Tatsumisago and published by Springer Science & Business Media. This book was released on 2006-04-19 with total page 287 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book, recent progress in batteries is firstly reviewed by researchers in three leading Japanese battery companies, SONY, Matsushita and Sanyo, and then the future problems in battery development are stated. Then, recent development of solid state ionics for batteries, including lithium ion battery, metal-hydride battery, and fuel cells, are reviewed. A battery comprises essentially three components: positive electrode, negative electrode, and electrolyte. Each component is discussed for the construction of all-solid-state Batteries. Theoretical understanding of properties of battery materials by using molecular orbital calculations is also introduced.

Download or read book Solid State Battery written by Fouad Sabry and published by One Billion Knowledgeable. This book was released on 2022-10-15 with total page 378 pages. Available in PDF, EPUB and Kindle. Book excerpt: What Is Solid State Battery Instead of the liquid or polymer gel electrolytes found in lithium-ion or lithium polymer batteries, solid-state batteries make use of solid electrodes and a solid electrolyte. This kind of battery technology is known as solid-state battery technology. How You Will Benefit (I) Insights, and validations about the following topics: Chapter 1: Solid-state battery Chapter 2: Lithium-ion battery Chapter 3: Molten-salt battery Chapter 4: Nanobatteries Chapter 5: Lithium-ion capacitor Chapter 6: Rechargeable lithium-metal battery Chapter 7: Lithium-sulfur battery Chapter 8: Thin-film lithium-ion battery Chapter 9: Nanoarchitectures for lithium-ion batteries Chapter 10: Lithium-air battery Chapter 11: Metal-air electrochemical cell Chapter 12: Potassium-ion battery Chapter 13: Sodium-ion battery Chapter 14: Peter Bruce Chapter 15: Aluminium-ion battery Chapter 16: Research in lithium-ion batteries Chapter 17: Magnesium battery Chapter 18: Glass battery Chapter 19: Calcium battery Chapter 20: Lithium aluminium germanium phosphate Chapter 21: Solid state silicon battery (II) Answering the public top questions about solid state battery. (III) Real world examples for the usage of solid state battery in many fields. (IV) 17 appendices to explain, briefly, 266 emerging technologies in each industry to have 360-degree full understanding of solid state battery' technologies. Who This Book Is For Professionals, undergraduate and graduate students, enthusiasts, hobbyists, and those who want to go beyond basic knowledge or information for any kind of solid state battery.

Download or read book Sodium Ion Batteries written by Man Xie and published by Walter de Gruyter GmbH & Co KG. This book was released on 2022-08-01 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an in-depth coverage of basic theories, progress and applications of sodium-ion batteries, and introduces the various technologies and mechanisms for anodes, cathodes, and electrolytes. In addition, this book gives insight into industrial applications of sodium-ion batteries.

Download or read book Rechargeable Battery Electrolytes written by Jianmin Ma and published by Royal Society of Chemistry. This book was released on 2024-02-26 with total page 380 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rechargeable batteries are one of the crucial ways we are going to solve the sustainable energy crisis. Lithium-ion batteries have been commercialised and are heavily relied upon, however, the scarcity of lithium resources increases the production cost and hinders further application. Additionally, the toxic and flammable electrolyte brings many potential safety hazards including environmental pollution. Looking for low-cost, safe, and environmentally friendly alternatives to LIBs has become a valuable research direction. The modification of batteries is focused on the anode, the cathode and electrolyte. Globally, researchers have moved onto new rechargeable batteries based on multivalent metal ions which have been extensively studied, including K+, Ca2+, Mg2+ and Al3+. However, the electrolyte is a very important component of a battery as its physical and chemical properties directly affect the electrochemical performance and energy storage mechanism. Finding and selecting an appropriate electrolyte system is a crucial factor that must be taken into account to make these post-lithium-ion batteries commercially viable. Until now, it has been challenging to develop a suitable electrolyte with a wide electrochemical stability window and stable anode interface. This book covers all the major ion-battery groups and their electrolytes, examining their performance and suitability in different solvents: aqueous, non-aqueous, solid gel and polymer. It is suitable for all levels of students and researchers who want to understand the fundamentals and future challenges of developing electrolytes.

Download or read book Prospects For Li ion Batteries And Emerging Energy Electrochemical Systems written by Laure Monconduit and published by World Scientific. This book was released on 2018-02-28 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Li-ion battery market is growing fast due to its ever increasing number of applications, from electric vehicles to portable devices. These devices are in demand due to safety reasons, energy efficiency, high power density and long life duration, which drive the need for more efficient electrochemical energy storage systems. The aim of this book is to provide the challenges and perspectives for Li-ion batteries (chapters 1 and 2), at the negative electrode as well as at the positive electrode, and for technologies beyond the Li-ion with the emerging Na-ion batteries and multivalent (Mg, Al, Ca, etc) systems (chapters 4 and 5). The aim is also to alert on the necessity to develop the recycling methods of the millions of produced batteries which are going to further flood our societies (chapter 3), and also to continuously increase the safety of the energy storage systems. For the latter challenge, it is interesting to seriously consider polymer electrolytes and batteries as an alternative (chapter 6).This book will take readers inside recent breakthroughs made in the electrochemical energy systems. It is a collaborative work of experts from the most known teams in the batteries field in Europe and beyond, from academics as well as from manufacturers.