Download or read book Shear Thickening and Microstructures of Concentrated Charge Stabilized Suspensions written by Mei Kam Chow and published by . This book was released on 1994 with total page 548 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rheological properties and microstructures of concentrated charge stabilized suspensions are studied in this dissertation. Suspensions containing monodispersed polystyrene particles with diameters ranging from 229 to 514 nm are used. Volume fractions ranged from 0.30 to 0.59 are studied. A non-equilibrium phase diagram of critical rheological properties and microstructures as function of shear rates is constructed for the first time. A parameter to measure the degree of suspension order under shear is established. The rapid increase of suspension viscosity as the shear rate increases is examined as function of volume fraction, previous shear history and the flow geometry. Microstructures are studied using the small angle neutron scattering and the rheological measurements are obtained from both the constant stress and constant rate of strain rheometers. Dynamic variables such as the static yield stress, dynamic yield stress, catastrophic shear thinning stress and shear thickening stress are found to scale with the equilibrium modulus of the suspensions. Shear thickening is found to be dependent on the suspension's previous shear history and the size of the gap which bounds the suspension.
Download or read book The Dynamic Properties of Concentrated Charge Stabilized Suspensions written by Liang Bin Chen and published by . This book was released on 1992 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Journal of Rheology written by and published by . This book was released on 2007 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Colloidal Suspension Rheology written by Jan Mewis and published by Cambridge University Press. This book was released on 2012 with total page 417 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presented in an accessible and introductory manner, this is the first book devoted to the comprehensive study of colloidal suspensions.
Download or read book Applied Mechanics Reviews written by and published by . This book was released on 1993 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Polymer Yearbook 13 written by Richard A. Pethrick and published by CRC Press. This book was released on 2019-08-22 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer Yearbook 13 brings together reviews and information on the progress of polymer science worldwide, including useful and topical information such as a list of new publications in polymer science and a compilation of dissertation abstracts. This volume includes reviews of key aspects of polymer science, including contributions from Russia, and details of important publications., This volume also contains reviews on state-of-the-art Japanese research presented at the annual Spring and Fall meetings of the Japanese Polymer Science Society. The aim of this section is to make information on the progress of Japanese polymer science, and on topics of current interest to polymer scientists in Japan, more easily available worldwide.
Download or read book The Effects of Particle Anisotropy on the Rheology and Microstructure of Concentrated Colloidal Suspensions Through the Shear Thickening Transition written by and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Though suspensions comprised of anisotropic particles are ubiquitous in industry, little has been done to elucidate the effects of particle anisotropy on concentrated suspension rheology, or the mechanism responsible for the reversible shear thickening observed in these systems. This dissertation explores the rheology and shear-induced microstructure of anisotropic particle suspensions through the shear thickening transition, and provides the first account of anisotropic particle alignment during shear thickening. For this investigation, Poly(ethylene glycol) (PEG)-based suspensions of acicular precipitated calcium carbonate (PCC) particles of varying particle aspect ratio (nominal L/D & sim; 2, 4, 7) are generated that demonstrate both continuous and discontinuous reversible shear thickening with increasing applied shear rate or stress. The critical volume fraction for the onset of discontinuous shear thickening decreases as the average particle aspect ratio is increased. However, the critical stress for shear thickening is found to be independent of particle anisotropy and volume fraction, and can be predicted based on the minor axis dimension of the particles in agreement with the critical stress scaling for hard-sphere suspensions. Small angle neutron scattering during shear flow (Rheo-SANS) demonstrates that long-axis particle alignment with the flow direction is maintained throughout the range of shear stresses investigated, including the shear thickening regimes for both continuous and discontinuous shear thickening PCC/PEG suspensions. Investigations of particle flow alignment following flow cessation provide evidence that the critical volume fraction for shear thickening may be associated with an isotropic-nematic transition within the anisotropic particle suspensions. Rheo-SANS investigations of concentrated kaolin clay suspensions demonstrate that disk-shaped particles exhibit particle alignment with the face surfaces orthogonal to the gradient direction during both continuous and discontinuous shear thickening. The critical stress at the onset of shear thickening for discontinuous shear thickening clay suspensions is observed to scale with the particle thickness dimension. The rheology and Rheo-SANS observations for both the acicular PCC and disk-like kaolin clay suspensions invalidate earlier hypothesis suggesting that shear thickening behavior in anisotropic particle dispersions results from increased particle rotations out of flow alignment potentially leading to particle jamming. Rather, the observations suggest that shear thickening in anisotropic particle suspensions is a consequence of short range hydrodynamic lubrication forces resulting in the formation of hydroclusters at higher shear rates, analogous to the behavior established for spherical particle suspensions. Lastly, anisotropic particle suspensions are used to successfully develop of shear thickening fluid (STF)/ballistic fabric composites. Shape anisotropy imparts the advantage of lower solids loading required to achieve energy dissipative improvements compared to spherical particle STFs. The observed improvements in ballistic and stab resistance response of these composites over that of ballistic fabrics alone suggests that they could potentially be used in the development of personal body armors with improved, multi-threat protective capabilities.
Download or read book Theory and Applications of Colloidal Suspension Rheology written by Norman J. Wagner and published by Cambridge University Press. This book was released on 2021-04-15 with total page 437 pages. Available in PDF, EPUB and Kindle. Book excerpt: Essential text on the practical application and theory of colloidal suspension rheology, written by an international coalition of experts.
Download or read book Dissertation Abstracts International written by and published by . This book was released on 2005 with total page 794 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Theoretical and Applied Rheology written by P. Moldenaers and published by Elsevier. This book was released on 2013-10-22 with total page 1110 pages. Available in PDF, EPUB and Kindle. Book excerpt: More than 900 authors from over 35 countries contributed to the 1992 International Congress on Rheology. These proceedings volumes comprise 17 plenary and keynote papers, 250 oral contributions and some 200 poster presentations. All relevant aspects of rheology are covered, e.g., theoretical rheology, molecular theories, fluid mechanics, rheometry, experimental methods, foams, polymer solutions, polymer melts, rubber, solids, composites, biorheology, industrial rheology, polymer processing, food rheology and electrorheology, reflecting the development of rheology into a broad, multidisciplinary field of recognized academic and industrial relevance.
Download or read book Complex Flow of Concentrated Suspensions written by Claire Forsyth and published by . This book was released on 2015 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis describes work done to investigate the effects of flow on concentrated suspensions. The work is largely about the effects of flow on concentrated colloidal suspensions, however, a short section on the effects of flow on concentrated granular suspensions is also given. Concentrated suspensions show a variety of complex flow behaviour. They can show Newtonian, shear thinning or shear thickening behaviour, depending on the applied stress or shear rate and concentration. The shear thickening behaviour may be discontinuous and this is characterised by a dramatic increase in viscosity above a certain threshold of stress. This is thought to be closely related to flow induced jamming, which can be defined as the conversion of a liquid system into a solid by imposed stress. This behaviour is not well understood and can cause significant complications in industry. It also has potential applications, for example in shock absorption. Due to their complexities and potential applications, gaining a better understanding of how shear thickening and jamming materials behave is of interest and forms the basis of this thesis. In this work, bespoke shear cells and a novel method to detect flow induced jamming were designed and utilised. This allowed jamming to be visualised and evaluated quantitatively. Conditions where jamming occurs were mapped out and the effects of parameters such as concentration, shear stress, system geometry and system confinement were investigated. This, and an analysis of jamming statistics, allowed ways to prevent and control jamming to be identified and a better understanding of the system to be achieved. Such an analysis is lacking in literature. The conditions where jamming was detected using the novel equipment matched well with measurements using a commercial rheometer. This supported the idea of discontinuous shear thickening and flow induced jamming being closely related. The studies allowed a mechanism for flow induced jamming and discontinuous shear thickening to be proposed. By designing and using novel equipment that is not commercially available, a better understanding of the effects of flow on concentrated suspensions was achieved. This could ultimately lead to a better understanding of complex flow systems and lead to more efficient processes.
Download or read book Product Design and Engineering written by Ulrich Bröckel and published by John Wiley & Sons. This book was released on 2013-08-02 with total page 367 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covering the whole value chain - from product requirements and properties via process technologies and equipment to real-world applications - this reference represents a comprehensive overview of the topic. The editors and majority of the authors are members of the European Federation of Chemical Engineering, with backgrounds from academia as well as industry. Therefore, this multifaceted area is highlighted from different angles: essential physico-chemical background, latest measurement and prediction techniques, and numerous applications from cosmetic up to food industry. Recommended reading for process, pharma and chemical engineers, chemists in industry, and those working in the pharmaceutical, food, cosmetics, dyes and pigments industries.
Download or read book Coulson and Richardson s Chemical Engineering written by R. P. Chhabra and published by Butterworth-Heinemann. This book was released on 2019-04-26 with total page 872 pages. Available in PDF, EPUB and Kindle. Book excerpt: Coulson and Richardson's Chemical Engineering: Volume 2A: Particulate Systems and Particle Technology, Sixth Edition, has been fully revised and updated to provide practitioners with an overview of chemical engineering, including clear explanations of theory and thorough coverage of practical applications, all supported by case studies. A worldwide team of contributors has pooled their experience to revise old content and add new content. The content has been updated to be more useful to practicing engineers. This complete reference to chemical engineering will support you throughout your career, as it covers every key chemical engineering topic. Fluid Flow, Heat Transfer and Mass Transfer has been developed from the series' volume 1, 6th edition. This volume covers the three main transport process of interest to chemical engineers: momentum transfer (fluid flow), heat transfer and mass transfer and the relationships between them. Particulate Systems and Particle Technology has been developed from the series' volume 2, 5th edition. This volume covers the properties of particulate systems, including the character of individual particles and their behavior in fluids. Sedimentation of particles, both singly and at high concentrations, flow in packed and fluidized beads and filtration are then examined. Separation Processes has been developed from the series' volume 2, 5th edition. This volume covers distillation and gas absorption, which illustrate applications of the fundamental principles of mass transfer. Several techniques-adsorption, ion exchange, chromatographic and membrane separations, and process intensification-are described. Chemical and Biochemical Reactors and Reaction Engineering has been developed from the series' volume 3, 3rd edition. Features fully revised reference material converted from textbooks Covers foundational to technical topics Features emerging applications, numerical methods and computational tools
Download or read book Transient Dynamics of Concentrated Particulate Suspensions Under Shear written by Endao Han and published by . This book was released on 2018 with total page 125 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this thesis we use high-speed ultrasound imaging to probe non-invasively how the interior of a dense suspension responds to impact. Measuring the speed of sound we demonstrate that the solidification proceeds without any detectable increase in packing fraction, and imaging the evolving flow field we find that the shear intensity is maximized right at the jamming front. Taken together, this provides direct experimental evidence for jamming by shear, rather than densification, as driving the transformation.
Download or read book Medical Applications of Colloids written by Egon Matijevic and published by Springer Science & Business Media. This book was released on 2008-12-05 with total page 323 pages. Available in PDF, EPUB and Kindle. Book excerpt: The important role of ?nely dispersed matter and surfaces in medicine is not always fully understood and appreciated. Speci?cally, ?ne particles (solid or liquid) in the size range of several nanometers to several micrometers have a tremendous effect on our lives, because they can be bene?cial or detrimental to our well-being. Such particles are present in living bodies as red blood cells or cholesterol crystals in the gall bladder. They are ubiquitous in the environment, where they can cause many diseases, such as asbestosis, silicosis, and black lung disease, but they are also used in diagnostic tests, drug delivery, and numerous other applications. More recently, evidence has become available that drug formulations with active components in a ?nely dispersed state may signi?cantly affect their functionality. Furthermore, with miniaturization of medical instrumentation, the size of the components is necess- ily reduced to colloid or even smaller range. This volume is a collection of several chapters dealing with diverse topics of colloids and surfaces relevant to medical applications. Thus, Siiman describes the use of optical properties of uniform colloidal particles as probes in ?ow cytometry. Giesche focuses on the preparations and properties of exceedingly uniform silica spheres for different uses, such as in chromatography. In modi?ed forms, silica p- ticles with incorporated dyes are employed in diagnostics and those combined with tiny magnetic entities in drug delivery.
Download or read book Viscoelasticity and Rheology written by Arthur S. Lodge and published by Academic Press. This book was released on 2014-06-28 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: Viscoelasticity and Rheology covers the proceedings of a symposium by the same title, conducted by the Mathematics Research Center held at the University of Wisconsin-Madison on October 16-18, 1984. The contributions to the symposium are divided into four broad categories, namely, experimental results, constitutive theories, mathematical analysis, and computation. This 16-chapter work begins with experimental topics, including the motion of bubbles in viscoelastic fluids, wave propagation in viscoelastic solids, flows through contractions, and cold-drawing of polymers. The next chapters covering constitutive theories explore the molecular theories for polymer solutions and melts based on statistical mechanics, the use and limitations of approximate constitutive theories, a comparison of constitutive laws based on various molecular theories, network theories and some of their advantages in relation to experiments, and models for viscoplasticity. These topics are followed by discussions of the existence, regularity, and development of singularities, change of type, interface problems in viscoelasticity, existence for initial value problems and steady flows, and propagation and development of singularities. The remaining chapters deal with the numerical simulation of flow between eccentric cylinders, flow around spheres and bubbles, the hole pressure problem, and a review of computational problems related to various constitutive laws. This book will prove useful to chemical engineers, researchers, and students.
Download or read book Suspensions written by Laurier Lincoln Schramm and published by Washington, D.C. : American Chemical Society. This book was released on 1996 with total page 824 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an introduction to the nature, formation and occurrence, stability, propagation, and uses of suspensions in the petroleum industry. Its audience is scientists and engineers who may encounter or apply suspensions, whether in process design, petroleum production, or research and development. The primary focus is on the applications of the principles of particle dispersions, with attention given to practical processes and problems. The book illustrates how to understand, make, and use desirable suspensions and how to approach destabilizing, or preventing the occurrence of undesirable suspensions.
