Download or read book Seasonal and Flow driven Dynamics of Particulate and Dissolved Mercury and Methylmercury in a Stream Impacted by an Industrial Mercury Source written by and published by . This book was released on 2015 with total page 15 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sediments and floodplain soils in the East Fork Poplar Creek watershed (Oak Ridge, TN, USA) are contaminated with high levels of mercury (Hg) from an industrial source at the headwaters. Although baseflow conditions have been monitored, concentrations of Hg and methylmercury (MeHg) during high-flow storm events, when the stream is more hydrologically connected to the floodplain, have yet to be assessed. This paper evaluated baseflow and event-driven Hg and MeHg dynamics in East Fork Poplar Creek, 5 km upstream of the confluence with Poplar Creek, to determine the importance of hydrology to in-stream concentrations and downstream loads and to ascertain whether the dynamics are comparable to those of systems without an industrial Hg source. Particulate Hg and MeHg were positively correlated with discharge (r2 = 0.64 and 0.58, respectively) and total suspended sediment (r2 = 0.97 and 0.89, respectively), and dissolved Hg also increased with increasing flow (r2 = 0.18) and was associated with increases in dissolved organic carbon (r2 = 0.65), similar to the dynamics observed in uncontaminated systems. Dissolved MeHg decreased with increases in discharge (r2 = 0.23) and was not related to dissolved organic carbon concentrations (p = 0.56), dynamics comparable to relatively uncontaminated watersheds with a small percentage of wetlands (
Download or read book Environmental chemistry of mercury Sources pathways transformations and impact written by Ashu Dastoor and published by Frontiers Media SA. This book was released on 2024-01-29 with total page 149 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Mercury in Fish Bed Sediment and Water from Streams Across the United States 1998 2005 written by Barbara C. Scudder and published by DIANE Publishing. This book was released on 2010-08 with total page 86 pages. Available in PDF, EPUB and Kindle. Book excerpt: Report on how mercury (Hg) was examined in top-predator fish, bed sediment, and water from streams that spanned regional and national gradients of Hg source strength and other factors thought to influence methylmercury bioaccum. Sampled settings include stream basins that were agr¿l, urbanized, undeveloped, and mined. Predator fish were targeted for collection, and composited samples of fish were analyzed for total Hg (THg), as most of the Hg found in fish tissue is MeHg. Samples of bed sediment and stream water were analyzed for THg, MeHg, and characteristics thought to affect Hg methylation, such as loss-on-ignition and acid-volatile sulfide in bed sediment, and pH, dissolved organic carbon, and dissolved sulfate in water. Illus.
Download or read book Mercury and Dissolved Organic Matter Dynamics During Snowmelt in a Montane Watershed Provo River Utah written by Brian Noel Packer and published by . This book was released on 2018 with total page 34 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mercury (Hg) transport in streams is typically facilitated by dissolved organic matter (DOM), however, the dynamics of Hg and DOM during snowmelt in montane watersheds are poorly understood. Hg transport during snowmelt is widely recognized as a significant source of Hg to downstream lakes and reservoirs, such Jordanelle Reservoir where fish consumption advisories are in effect due to elevated Hg concentrations in certain species of fish. For this study, total mercury (THg), methylmercury (MeHg), and DOM samples were collected at three sites in the upper sites in the upper Provo River, northern Utah, during the 2016 and 2017 water years. To evaluate Hg and DOM sources, samples were collected from snowpack and ephemeral streams in the watershed. In-situ fluorescent DOM (fDOM) data and other parameters were measured in the river to characterize high-frequency variation in water chemistry. Excitation-emissions matrices (EEMs) were used to determine changes in DOM characteristics during snowmelt. Hg concentrations increased in the upper Provo River from 1 ng/L during baseflow to 7 ng/L during the snowmelt period (~April-July), with filtered THg concentrations approximately ~75% of the unfiltered concentrations. In the watershed, filtered THg concentrations ranged from ~0.4 ng/L in snowpack to ~8 ng/L in ephemeral streams. Annual THg loading from the Provo River to Jordanelle Reservoir was approximately 1 kg/yr with ~90% of the flux occurring during the snowmelt period. High correlations between filtered THg and fDOM allowed for the development of a high frequency filtered THg proxy using in-situ fDOM sensors. DOM characteristic during the snowmelt period showed that Hg transport was facilitated by humic substances which was sourced from upland soils. Fractions of filtered methylmercury (MeHg) and filtered THg (filtered MeHg:filtered THg) were ~0.1 during baseflow and reduced to ~0.01 during snowmelt, implying that snowmelt runoff has little impact on the MeHg flux to Jordanelle Reservoir. The results suggest that Hg and DOM are flushed from soils during snowmelt, and that a significant majority of the Hg flux occurs the snowmelt period. Our study has implications for understanding Hg sources and transport mechanisms in other snowmelt dominated watersheds.
Download or read book Mercury as a Global Pollutant written by Donald B. Porcella and published by Springer. This book was released on 2014-08-23 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: ACKNOWLEDGEMENTS xiv PART I MERCURY AND HUMAN HEALTH B. WHEATLEY and S. PARADIS I Exposure of Canadian Aboriginal Peoples to Methylmercury 3-11 M. GIRARD and C. DUMONT I Exposure of James Bay Cree to Methylmercury during Pregnancy for the Years 1983-91 13-19 M. RICHARDSON, M. MITCHELL, S. COAD and R. RAPHAEL I Exposure to Mercury in Canada: A Multimedia Analysis 21-30 M. RICHARDSON, M. EGYED and D. J. CURRIE I Human Exposure to Mercury may Decrease as Acidic Deposition Increases 31-39 L. E. FLEMING, S. WATKINS, R. KADERMAN, B. LEVIN, D. R. AVYAR, M. BIZZIO, D. STEPHENS and J. A. BEAN I Mercury Exposure in Humans through Food Consumption from the Everglades of Florida 41-48 J. M. GEARHART, H. J. CLEWELL III, K. S. CRUMP, A. M. SHIPP and A. SILVERS I Pharmacokinetic Dose Estimates of Mercury in Children and Dose-Response Curves of Performance Tests in a Large Epidemiological Study 49-58 I. SKARE I Mass Balance and Systemic Uptake of Mercury Released from Dental Amalgam Fillings 59-67 J. DELLINGER, N. KMIECIK, S. GERSTENBERGER and H. NGU I Mercury Contamina tion of Fish in the Ojibwa Diet: I. Walleye Fillets and Skin-On versus Skin-Off Sampling 69-76 J. DELLINGER, L. MALEK and M. BEATTIE I Mercury Contamination of Fish in the Ojibwa Diet: II. Sensory Evoked Responses in Rats Fed Walleye 77-83 H. AKAGI, O. MALM, F. J. P. BRANCHES, Y. KINJO, Y. KASHIMA, J. R. D. GUIMARAES, R. B. OLIVEIRA, K. HARAGUCHI, W. C. PFEIFFER, Y.
Download or read book FINAL REPORT ON THE AQUATIC MERCURY ASSESSMENT STUDY written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In February 2000, the United States Environmental Protection Agency (EPA) Region 4 issued a proposed Total Maximum Daily Load (TMDL) for total mercury in the middle and lower Savannah River. The initial TMDL, which would have imposed a 1 ng/l mercury limit for discharges to the middle/lower Savannah River, was revised to 2.8 ng/l in the final TMDL released in February 2001. The TMDL was intended to protect people from the consumption of contaminated fish, which is the major route of mercury exposure to humans. The most bioaccumulative form of mercury is methylmercury, which is produced in aquatic environments by the action of microorganisms on inorganic mercury. Because of the environmental and economic significance of the mercury discharge limits that would have been imposed by the TMDL, the Savannah River Site (SRS) initiated several studies concerning: (1) mercury in SRS discharges, SRS streams and the Savannah River, (2) mercury bioaccumulation factors for Savannah River fish, (3) the use of clams to monitor the influence of mercury from tributary streams on biota in the Savannah River, and (4) mercury in rainwater falling on the SRS. The results of these studies are presented in detail in this report. The first study documented the occurrence, distribution and variation of total and methylmercury at SRS industrial outfalls, principal SRS streams and the Savannah River where it forms the border with the SRS. All of the analyses were performed using the EPA Method 1630/31 ultra low-level and contaminant-free techniques for measuring total and methylmercury. Total mercury at National Pollutant Discharge Elimination System (NPDES) outfalls ranged from 0.31-604 ng/l with a mean of 8.71 ng/l. Mercury-contaminated groundwater was the source for outfalls with significantly elevated mercury concentrations. Total mercury in SRS streams ranged from 0.95-15.7 ng/l. Mean total mercury levels in the streams varied from 2.39 ng/l in Pen Branch to 5.26 ng/l in Tims Branch. Methylmercury ranged from 0.002 ng/l in Upper Three Runs to 2.60 ng/l in Tims Branch. Total mercury in the Savannah River ranged from 0.62 ng/l to 43.9 ng/l, and methylmercury ranged from 0.036 ng/l to 7.54 ng/l. Both total and methylmercury concentrations were consistently high in the river near the mouth of Steel Creek. Total mercury was positively correlated with methylmercury (r = 0.88). Total mercury bound to particulates ranged from 41% to 57% in the river and from 28% to 90% in the streams. Particulate methylmercury varied from 9% to 37% in the river and from 6% to 79% in the streams. Small temporary pools in the Savannah River swamp area near and around Fourmile Branch had the highest concentrations observed in the Savannah River watershed, reaching 1,890 ng/l for total mercury and 34.0 ng/l for methylmercury. The second study developed a mercury bioaccumulation factor (BAF) for the Savannah River near SRS. A BAF is the ratio of the concentration of mercury in fish flesh to the concentration of mercury in the water. BAFs are important in the TMDL process because target concentrations for mercury in water are computed from BAFs. Mercury BAFs are known to differ substantially among fish species, water bodies, and possibly seasons. Knowledge of such variation is needed to determine a BAF that accurately represents average and extreme conditions in the water body under study. Analysis of fish tissue and aqueous methylmercury samples collected at a number of locations and over several seasons in a 110 km (68 mile) reach of the Savannah River demonstrated that BAFs for each species under study varied by factors of three to eight. Influences on BAF variability were location, habitat and season-related differences in fish mercury levels and seasonal differences in methylmercury levels in the water. Overall (all locations, habitats, and seasons) average BAFs were 3.7 x 106 for largemouth bass, 1.4 x 106 for sunfishes, and 2.5 x 106 for white catfish. This study showed that determination of representative BAFs for large rivers requires the collection of large numbers of fish and aqueous methylmercury samples over at least one complete seasonal cycle from the entire area and all habitats to be represented by the TMDL. The third study concerned the use of clams as an indicator of the influence of SRS discharges on mercury levels in Savannah River biota. Mercury levels were compared in Asiatic clams (Corbicula fluminea) collected from the discharge plumes and just upstream of the mouths of SRS creeks and two creeks located downstream from the SRS. Asiatic clams were selected for study because their relatively sedentary behavior made them a better indicator of local mercury exposure than mobile organisms.
Download or read book Water Quality Assessments written by Deborah V Chapman and published by CRC Press. This book was released on 1996-08-22 with total page 658 pages. Available in PDF, EPUB and Kindle. Book excerpt: This guidebook, now thoroughly updated and revised in its second edition, gives comprehensive advice on the designing and setting up of monitoring programmes for the purpose of providing valid data for water quality assessments in all types of freshwater bodies. It is clearly and concisely written in order to provide the essential information for all agencies and individuals responsible for the water quality.
Download or read book Mercury Contaminated Sites written by Ralf Ebinghaus and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 538 pages. Available in PDF, EPUB and Kindle. Book excerpt: An up-to-date overview of the characterization, risk assessment and remediation of mercury-contaminated sites. The book summarizes, for the first time, works from Europe, Russia and the American continent, and review chapters are supplemented by detailed, international case studies.
Download or read book Biogeochemistry of Wetlands written by K. Ramesh Reddy and published by CRC Press. This book was released on 2022-09-10 with total page 926 pages. Available in PDF, EPUB and Kindle. Book excerpt: The globally important nature of wetland ecosystems has led to their increased protection and restoration as well as their use in engineered systems. Underpinning the beneficial functions of wetlands are a unique suite of physical, chemical, and biological processes that regulate elemental cycling in soils and the water column. This book provides an in-depth coverage of these wetland biogeochemical processes related to the cycling of macroelements including carbon, nitrogen, phosphorus, and sulfur, secondary and trace elements, and toxic organic compounds. In this synthesis, the authors combine more than 100 years of experience studying wetlands and biogeochemistry to look inside the black box of elemental transformations in wetland ecosystems. This new edition is updated throughout to include more topics and provide an integrated view of the coupled nature of biogeochemical cycles in wetland systems. The influence of the elemental cycles is discussed at a range of scales in the context of environmental change including climate, sea level rise, and water quality. Frequent examples of key methods and major case studies are also included to help the reader extend the basic theories for application in their own system. Some of the major topics discussed are: Flooded soil and sediment characteristics Aerobic-anaerobic interfaces Redox chemistry in flooded soil and sediment systems Anaerobic microbial metabolism Plant adaptations to reducing conditions Regulators of organic matter decomposition and accretion Major nutrient sources and sinks Greenhouse gas production and emission Elemental flux processes Remediation of contaminated soils and sediments Coupled C-N-P-S processes Consequences of environmental change in wetlands# The book provides the foundation for a basic understanding of key biogeochemical processes and its applications to solve real world problems. It is detailed, but also assists the reader with box inserts, artfully designed diagrams, and summary tables all supported by numerous current references. This book is an excellent resource for senior undergraduates and graduate students studying ecosystem biogeochemistry with a focus in wetlands and aquatic systems.
Download or read book Toxicological Effects of Methylmercury written by National Research Council and published by National Academies Press. This book was released on 2000-10-27 with total page 365 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mercury is widespread in our environment. Methylmercury, one organic form of mercury, can accumulate up the aquatic food chain and lead to high concentrations in predatory fish. When consumed by humans, contaminated fish represent a public health risk. Combustion processes, especially coal-fired power plants, are major sources of mercury contamination in the environment. The U.S. Environmental Protection Agency (EPA) is considering regulating mercury emissions from those plants. Toxicological Effects of Methylmercury reviews the health effects of methylmercury and discusses the estimation of mercury exposure from measured biomarkers, how differences between individuals affect mercury toxicity, and appropriate statistical methods for analysis of the data and thoroughly compares the epidemiological studies available on methylmercury. Included are discussions of current mercury levels on public health and a delineation of the scientific aspects and policy decisions involved in the regulation of mercury. This report is a valuable resource for individuals interested in the public health effects and regulation of mercury. The report also provides an excellent example of the implications of decisions in the risk assessment process for a larger audience.
Download or read book Canadian Water Quality Guidelines for the Protection of Aquatic Life written by Canada. Environment Canada and published by . This book was released on 2003 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt: Distributed by the Government of Canada Depository Services Program.
Download or read book Mercury Dynamics in Streams Lakes and Fish in the Northeastern United States written by Jason A. Dittman and published by . This book was released on 2010 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Mercury in Fish Bed Sediment and Water from Streams Across the United States 1998 2005 written by and published by . This book was released on 2009 with total page 88 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Water Quality for Ecosystem and Human Health written by Geneviève M. Carr and published by UNEP/Earthprint. This book was released on 2008 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt: This document is intended to provide an overview of the major components of surface and ground water quality and how these relate to ecosystem and human health. Local, regional and global assessments of water quality monitoring data are used to illustrate key features of aquatic environments, and to demonstrate how human activities on the landscape can influence water quality in both positive and negative ways. Clear and concise background knowledge on water quality can serve to support other water assessments.
Download or read book Hydrodynamics and Water Quality written by Zhen-Gang Ji and published by John Wiley & Sons. This book was released on 2017-07-05 with total page 612 pages. Available in PDF, EPUB and Kindle. Book excerpt: The primary reference for the modeling of hydrodynamics and water quality in rivers, lake, estuaries, coastal waters, and wetlands This comprehensive text perfectly illustrates the principles, basic processes, mathematical descriptions, case studies, and practical applications associated with surface waters. It focuses on solving practical problems in rivers, lakes, estuaries, coastal waters, and wetlands. Most of the theories and technical approaches presented within have been implemented in mathematical models and applied to solve practical problems. Throughout the book, case studies are presented to demonstrate how the basic theories and technical approaches are implemented into models, and how these models are applied to solve practical environmental/water resources problems. This new edition of Hydrodynamics and Water Quality: Modeling Rivers, Lakes, and Estuaries has been updated with more than 40% new information. It features several new chapters, including one devoted to shallow water processes in wetlands as well as another focused on extreme value theory and environmental risk analysis. It is also supplemented with a new website that provides files needed for sample applications, such as source codes, executable codes, input files, output files, model manuals, reports, technical notes, and utility programs. This new edition of the book: Includes more than 120 new/updated figures and 450 references Covers state-of-the-art hydrodynamics, sediment transport, toxics fate and transport, and water quality in surface waters Provides essential and updated information on mathematical models Focuses on how to solve practical problems in surface waters—presenting basic theories and technical approaches so that mathematical models can be understood and applied to simulate processes in surface waters Hailed as “a great addition to any university library” by the Journal of the American Water Resources Association (July 2009), Hydrodynamics and Water Quality, Second Edition is an essential reference for practicing engineers, scientists, and water resource managers worldwide.
Download or read book Fluvial Transport of Mercury Dissolved Organic Carbon Suspended Sediment and Selected Major Ions in Contrasting Stream Basins in South Carolina and New York October 2004 to September 2009 written by Celeste A. Journey and published by CreateSpace. This book was released on 2014-07-11 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt: A spatially extensive assessment of the environmental controls on mercury transport and bioaccumulation in stream ecosystems in New York and South Carolina was conducted as part of the U.S. Geological Survey National Water-Quality Assessment Program and included the determination of suvial transport of mercury and associated constituents during water years 2005–2009. (A water year extends from October of one calendar year to September of the next calendar year.) In the Coastal Plain region of South Carolina, the study area included the Edisto River and its headwater tributary, McTier Creek. In the Adirondack region of New York, the study area included the upper Hudson River and its headwater tributary, Fishing rook. Median concentrations of altered total mercury ranged from 1.55 nanograms per liter (ng/L) at the Hudson River site to 2.77 ng/L at the Edisto River site. The Edisto River site had the greatest mediana ltered methylmercury concentration, at 0.32 ng/L, and the Hudson River site had the least median altered methylmercury concentration, at 0.07 ng/L.
Download or read book Influences on Mercury Bioaccumulation Factors for the Savannah River written by and published by . This book was released on 2003 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mercury TMDLs (Total Maximum Daily Loads) are a regulatory instrument designed to reduce the amount of mercury entering a water body and ultimately to control the bioaccumulation of mercury in fish. TMDLs are based on a BAF (bioaccumulation factor), which is the ratio of methyl mercury in fish to dissolved methyl mercury in water. Analysis of fish tissue and aqueous methyl mercury samples collected at a number of locations and over several seasons in a 118 km reach of the Savannah River demonstrated that species specific BAFs varied by factors of three to eight. Factors contributing to BAF variability were location, habitat and season related differences in fish muscle tissue mercury levels and seasonal differences in dissolved methyl mercury levels. Overall (all locations, habitats, and seasons) average BAFs were 3.7 x 106 for largemouth bass, 1.4 x 106 for sunfishes, and 2.5 x 106 for white catfish. Inaccurate and imprecise BAFs can result in unnecessary economic impact or insufficient protection of human health. Determination of representative and precise BAFs for mercury in fish from large rivers necessitates collecting large and approximately equal numbers of fish and aqueous methyl mercury samples over a seasonal cycle from the entire area and all habitats to be represented by the TMDL.
