Download or read book Reactivity in Confined Spaces written by Gareth Lloyd and published by Royal Society of Chemistry. This book was released on 2021-08-16 with total page 491 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry that occurs within confined spaces is the product of a collection of forces, often beyond the molecule, and is not easily ascribed to singular factors. There is a breadth of material types that can define a confined space (e.g. macrocycles, interlocked molecules, porous and non-porous crystals, organic and inorganic/coordination cages) which are rarely discussed together. Studies of supramolecular entities in the solution and solid states are also not often compared in the same discussion, even though the concepts are often similar or can be easily transferred between the two. Chapters in this book combine classical host-guest chemistry with catalysis, reactivity, and modern supramolecular chemistry. They cover the many different technologies used to describe and understand reactivity in confined spaces in one accessible title. With contributions from leading experts, Reactivity in Confined Spaces will be relevant for graduate students and researchers working in supramolecular chemistry, both organic- and inorganic-based, homogeneous and heterogeneous catalysis, polymer chemistry, and materials science in general.

Download or read book Chemical Reactivity in Confined Systems written by Pratim Kumar Chattaraj and published by John Wiley & Sons. This book was released on 2021-08-23 with total page 451 pages. Available in PDF, EPUB and Kindle. Book excerpt: An insightful analysis of confined chemical systems for theoretical and experimental scientists Chemical Reactivity in Confined Systems: Theory and Applications presents a theoretical basis for the molecular phenomena observed in confined spaces. The book highlights state-of-the-art theoretical and computational approaches, with a focus on obtaining physically relevant clarification of the subject to enable the reader to build an appreciation of underlying chemical principles. The book includes real-world examples of confined systems that highlight how the reactivity of atoms and molecules change upon encapsulation. Chapters include discussions on recent developments related to several host-guest systems, including cucurbit[n]uril, ExBox+4, clathrate hydrates, octa acid cavitand, metal organic frameworks (MOFs), covalent organic frameworks (COFs), zeolites, fullerenes, and carbon nanotubes. Readers will learn how to carry out new calculations to understand the physicochemical behavior of confined quantum systems. Topics covered include: A thorough introduction to global reactivity descriptors, including electronegativity, hardness, and electrophilicity An exploration of the Fukui function, as well as dual descriptors, higher order derivatives, and reactivity through information theory A practical discussion of spin dependent reactivity and temperature dependent reactivity Concise treatments of population analysis, reaction force, electron localization functions, and the solvent effect on reactivity Perfect for academic researchers and graduate students in theoretical and computational chemistry and confined chemical systems, Chemical Reactivity in Confined Systems: Theory and Applications will also earn a place in the libraries of professionals working in the areas of catalysis, supramolecular chemistry, and porous materials.

Download or read book Modelling and Simulation in the Science of Micro and Meso Porous Materials written by C.Richard A. Catlow and published by Elsevier. This book was released on 2017-09-20 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt: Modelling and Simulation in the Science of Micro- and Meso-Porous Materials addresses significant developments in the field of micro- and meso-porous science. The book includes sections on Structure Modeling and Prediction, Synthesis, Nucleation and Growth, Sorption and Separation processes, Reactivity and Catalysis, and Fundamental Developments in Methodology to give a complete overview of the techniques currently utilized in this rapidly advancing field. It thoroughly addresses the major challenges in the field of microporous materials, including the crystallization mechanism of porous materials and rational synthesis of porous materials with controllable porous structures and compositions. New applications in emerging areas are also covered, including biomass conversion, C1 chemistry, and CO2 capture. - Authored and edited by experts in the field of micro- and meso-porous materials - Includes introductory material and background both on the science of microporous materials and on the techniques employed in contemporary modeling studies - Rigorous enough for scientists conducting related research, but also accessible to graduate students in chemistry, chemical engineering, and materials science

Download or read book Chemical Energy Storage written by Robert Schlögl and published by Walter de Gruyter GmbH & Co KG. This book was released on 2022-01-19 with total page 685 pages. Available in PDF, EPUB and Kindle. Book excerpt: Energy – in the headlines, discussed controversially, vital. The use of regenerative energy in many primary forms leads to the necessity to store grid dimensions for maintaining continuous supply and enabling the replacement of fossil fuel systems. Chemical energy storage is one of the possibilities besides mechano-thermal and biological systems. This work starts with the more general aspects of chemical energy storage in the context of the geosphere and evolves to dealing with aspects of electrochemistry, catalysis, synthesis of catalysts, functional analysis of catalytic processes and with the interface between electrochemistry and heterogeneous catalysis. Top-notch experts provide a sound, practical, hands-on insight into the present status of energy conversion aimed primarily at the young emerging research front.

Download or read book Confined Space Entry and Emergency Response written by D. Alan Veasey and published by John Wiley & Sons. This book was released on 2005-12-02 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: EVERY SECOND COUNTS WHEN YOU'RE RESPONDING TO AN EMERGENCYINVOLVINGCONFINED SPACE-HERE'S THE DEFINITIVE GUIDE TO PERFORMINGFLAWLESS RESCUES! Confined Space Entry and Emergency Response utilizes a realistic,scenario-based approach to teach you-and your staff-the right wayto respond to an incident involving a confined space. The authorsprovide intensive, step-by-step guidance through the challengingmaze of training regulations, equipment needs, and procedures tokeep your response team finely tuned and ready to go under anyconditions. You'll find expert, detailed coverage of complex-and oftenconfusing-topics such as: * The basic components of rescue * OSHA's regulations for confined space entry and rescue * Confined space entry permitting * Assessing confined space hazards * Hazardous atmospheres and how to protect entrants from them * Air monitoring in confined spaces * Selection and use of personal protective equipment * The use of ropes and rigging The CD-ROM includes the Instructor's Guide along with lesson plansand useful practice tools such as worksheets, exercise handouts,performance checklists, diagrams and equipment lists for fieldexercises, instructions for building field training simulators, andguidelines for identifying rescue trainers and evaluating theircompetency as well as that of outside rescue teams. Everything you need to effectively train those working in aconfined space can truly be found within these pages and on theCD-ROM.

Download or read book Safety and Health in Confined Spaces written by Neil McManus and published by Routledge. This book was released on 2018-12-18 with total page 916 pages. Available in PDF, EPUB and Kindle. Book excerpt: Safety and Health in Confined Spaces goes beyond all other resources currently available. International in scope, the 15 chapters and 10 appendices cover every facet of this important subject. A significant addition to the literature, this book provides a confined space focus to other health and safety concepts. Confined spaces differ from other workspaces because their boundary surfaces amplify the consequences of hazardous conditions. The relationship between the individual, the boundary surface, and the hazardous condition is the critical factor in the onset, outcome, and severity of accidents in these workspaces. The author uses information about causative and other factors from analysis of fatal accidents to develop a hazard assessment and hazard management system. He provides a detailed, disciplined protocol, covering 36 hazardous conditions, that addresses all segments of work--the undisturbed space, entry preparation, work activity, and emergency preparedness and response--and illustrates how to use it. Safety and Health in Confined Spaces gives you the tools you need for preventing and responding to accidents.

Download or read book Proceedings of the Conference on Atmospheric Contamination in Confined Spaces 30 March 1 April 1965 written by and published by . This book was released on 1965 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: "The report is a complete compilation of the papers presented and the proceedings of the Conference on Atmospheric Contamination in Confined Spaces, sponsored by the Aerospace Medical Research Laboratories and held in Dayton, Ohio on 30, 31 March and 1 April 1965. Major technical areas discussed by the invited speakers, panel members and conference attendees included continuous inhalation exposure techniques, statistical methods for evaluation and interpretation of exposure data, minimum criteria for continuous exposure studies and toxicological qualification of space cabin materials. The conference participants were provided the opportunity to tour the Toxic Hazards Research Unit at Wright-Patterson Air Force Base and to ask questions regarding its operation. A discussion of the Clean Air Act of 1963 was presented by a representative of the Federal Department of Health, Education and Welfare."--Abstract

Download or read book Effects of Nanoconfinement on Catalysis written by Rinaldo Poli and published by Springer. This book was released on 2017-01-24 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book highlights the recent advances and state of the art in the use of functionalized nanostructured environments on catalysis. Nanoconfinements considered include well-defined molecular cages, imprinted self-assembled supramolecules, polymers made by living or controlled polymerization, metallorganic frameworks, carbon nanotubes, mesoporous inorganic solids, and hybrids thereof. Advantages of nanoconfinement of catalysts discussed include higher activities, improved selectivities, catalyst stabilization, cooperativity effects, simplified protocols for cascade syntheses, better catalyst recovery, and recyclability. The multiple applications that these materials offer are revolutionizing industrial sectors such as energy, electronics, sensors, biomedicine, and separation technology.

Download or read book Organic Solid State Reactions written by Fumio Toda and published by Springer Science & Business Media. This book was released on 2002-04-30 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Most organic reactions have long been carried out in organic solvents without concern for their real necessity, reaction efficiency, and pollution problems. Very recently, we have found that most organic reactions can be carried out in the absence of a solvent, namely, in the solid state. In many cases, the solid-state reaction proceeds more easily and efficiently, and even more selectively than solution reaction. This shows that molecules move easily and selectively in the solid state. This finding changed the classical idea which suggests "molecules do not move and reactions do not occur in the solid state", and opened up a new research field for the study molecular dynamics in the solid state. The organic solid state reactions have many possibilities to be developed. For example, enantioselective reactions can easily be accomplished by carrying out the reaction in an inclusion complex crystal with an optically active host compound. Catalytic reactions also proceed in the solid state. Moreover, the solid-state reactions are more economical and ecologically sound. In the future, pollution-free synthetic procedures in the solid state will become increasingly important, not only in chemical industries but also in university laboratories.

Download or read book Handbook of Industrial Toxicology and Hazardous Materials written by Nicholas P. Cheremisinoff and published by CRC Press. This book was released on 1999-01-12 with total page 925 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing vital safety information on over 1000 commerical chemicals, this work explores up-to-date data on fire and chemical compatibility, response methods for incidents involving chemical spills and fires, and personnel and worksite safety monitoring and sampling. The book includes more than 700 illustrations, structures, equations and tables, and a glossary with over 700 definitions.

Download or read book Fire and Explosion Hazards Handbook of Industrial Chemicals written by Nicholas P. Cheremisinoff and published by Elsevier. This book was released on 2013-10-22 with total page 493 pages. Available in PDF, EPUB and Kindle. Book excerpt: The handbook provides ready information on the fire and chemical reactivity of commonly used chemicals. Its purpose is to provide basic information important to the safe handling of chemicals and to help provide guidance in responding to a hazardous materials incident, in particular, incidents involving reactive chemicals and materials posing fire and explosion hazards. The volume has been written for chemical handling specialists, first responders to hazardous materials incidents, and firefighters. The basic definition used for a hazard materials incident is any situation that may potentially lead to catastrophic fire or explosion, and or human exposed to a toxic chemical. This situation may result from a spill of a hazardous material, a leak from a storage vessel or shipping container, or the mixing of incompatible chemicals whereby a chemical reaction could occur resulting in the release of energy and generation of toxic and perhaps flammable by-products. The volume provides chemical specific information, providing the reader with rigorous information on the chemical of interest.This book is a compendium of chemical specific fire and chemical reactivity data and information. More than 1,000 chemicals have been researched and organized into a reference handbook for fire specialists, chemical handling specialists, and plant safety engineers. The specific information provided for chemicals includes the flammability characteristics, recommended fire extinguishing practices, fire extinguishing agents not to be used, behavior in fires, burning characteristics, chemical reactivity with regard to water and common materials, incompatible chemical mixtures, containment and neutralization methods for spills. This reference book has been designed as a data bank for the hazardous materials handling specialist and industrial safety managers dealing with large chemical inventories. It is intended to be used by fire and loss prevention specialists and as a basis for developing procedures for safe storing and handling of chemicals. The authors have included an extensive physical properties section on chemicals, with information most pertinent to fire response situations.

Download or read book Handbook of Green Chemicals written by Michael Ash and published by Synapse Info Resources. This book was released on 2004 with total page 1364 pages. Available in PDF, EPUB and Kindle. Book excerpt: More than 7000 trade name products and more than 2500 generic chemicals that can be used in formulations to meet envionmental concerns and government regulations. This reference is designed to serve as an essential tool in the strategic decision-making process of chemical selection when focusing on human and environmental safety factors.Industries Covered: Adhesives ? Refrigerants ? Water Treatment ? Plastics ? Rubber ? Surfactants ? Paints & Coatings ? Food ? PharmaceuticalsCosmetics ? Petroleum Processing ? Metal Treatment ? TextilesThe chemicals and materials included are used in every aspect of the chemical industry. The reference is organized so that the reader can access the information based on the trade name, chemical components, functions and application areas, 'green' attributes, manufacturer, CAS number, and EINECS/ELINCS number.It contains a unique cross-reference that groups the trade name chemicals by one or more of these green chemical attributes: Biodegradable ? Environmentally Safe ? Environmentally Friendly ? Halogen-Free ? HAP's-Free ? Low Global WarmingLow Ozone-Depleting ? Nonozone-Depleting ? Low Vapor Pressure ? Noncarcinogenic ? Non-CFC ? Non-HCFCNonhazardous ? Nontoxic ? Recyclable ? SARA-Nonreportable ? SNAP (Significant New Alternative Policy) CompliantVOC-Compliant ? Low-VOC ? VOC-Free

Download or read book Advances in the Theory of Quantum Systems in Chemistry and Physics written by Philip E. Hoggan and published by Springer Science & Business Media. This book was released on 2011-11-16 with total page 630 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in the Theory of Quantum Systems in Chemistry and Physics is a collection of 32 selected papers from the scientific contributions presented at the 15th International Workshop on Quantum Systems in Chemistry and Physics (QSCP-XV), held at Magdalene College, Cambridge, UK, from August 31st to September 5th, 2010. This volume discusses the state of the art, new trends, and the future of methods in molecular quantum mechanics and their applications to a wide range of problems in chemistry, physics, and biology. The breadth and depth of the scientific topics discussed during QSCP-XV are gathered in seven sections: I. Fundamental Theory; II. Model Atoms; III. Atoms and Molecules with Exponential-Type Orbitals; IV. Density-Oriented Methods; V. Dynamics and Quantum Monte-Carlo Methodology; VI. Structure and Reactivity; VII. Complex Systems, Solids, Biophysics. Advances in the Theory of Quantum Systems in Chemistry and Physics is written for research students and professionals in Quantum systems of chemistry and physics. It also constitutes and invaluable guide for those wishing to familiarize themselves with research perspectives in the domain of quantum systems for thematic conversion or simply to gain insight into the methodological developments and applications to physics chemistry and biology that have actually become feasible by the end of 2010.

Download or read book Dynamics in Small Confining Systems written by and published by . This book was released on 2000 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Dynamics in Small Confining Systems V Volume 651 written by J. M. Drake and published by . This book was released on 2001-08-02 with total page 412 pages. Available in PDF, EPUB and Kindle. Book excerpt: The MRS Symposium Proceeding series is an internationally recognised reference suitable for researchers and practitioners.

Download or read book Emergency Response Guidebook written by U.S. Department of Transportation and published by Simon and Schuster. This book was released on 2013-06-03 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: Does the identification number 60 indicate a toxic substance or a flammable solid, in the molten state at an elevated temperature? Does the identification number 1035 indicate ethane or butane? What is the difference between natural gas transmission pipelines and natural gas distribution pipelines? If you came upon an overturned truck on the highway that was leaking, would you be able to identify if it was hazardous and know what steps to take? Questions like these and more are answered in the Emergency Response Guidebook. Learn how to identify symbols for and vehicles carrying toxic, flammable, explosive, radioactive, or otherwise harmful substances and how to respond once an incident involving those substances has been identified. Always be prepared in situations that are unfamiliar and dangerous and know how to rectify them. Keeping this guide around at all times will ensure that, if you were to come upon a transportation situation involving hazardous substances or dangerous goods, you will be able to help keep others and yourself out of danger. With color-coded pages for quick and easy reference, this is the official manual used by first responders in the United States and Canada for transportation incidents involving dangerous goods or hazardous materials.

Download or read book HazMat Data written by Richard P. Pohanish and published by John Wiley & Sons. This book was released on 2005-02-18 with total page 1311 pages. Available in PDF, EPUB and Kindle. Book excerpt: The HazMat Data, 2nd Edition provides a detailed reference for emergency responders and people who transport chemicals. Considering the events of September 11, the book is especially oriented toward first responder and emergency management personnel. Additions to this new Second Edition include Spanish language synonyms for all entries, and an increased overall number of synonyms. New to this edition is information on chemical warfare (CW) agents and Weapons of Mass Destruction (WMD)-nerve gasses, blister agents/vesicants, "blood agents," choking/pulmonary agents, and crowd-control agents (tear gasses, pepper sprays, etc.)-that might be used as weapons of terrorism. It clearly explains symptoms of exposure and appropriate treatment for the exposure when available, and describes what to do in an emergency situation. The book also gives the NFPA hazard classifications, as well as chemical hazard class information. Newly updated, The HazMat Data, 2nd Editio provides a comprehensive, up-to-date summary of this vital information.