Download or read book Reaction Pathways and Mechanisms in Thermocatalytic Biomass Conversion II written by Marcel Schlaf and published by Springer. This book was released on 2015-10-30 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume II presents the latest advances in catalytic hydrodeoxygenation and other transformations of some cellulosic platform chemicals to high value-added products. It presents the theoretical evaluation of the energetics and catalytic species involved in potential pathways of catalyzed carbohydrate conversion, pathways leading to the formation of humin-based by-products, and thermal pathways in deriving chemicals from lignin pyrolysis and hydrodeoxygenation. Catalytic gasification of biomass under extreme thermal conditions as an extension of pyrolysis is also discussed. Marcel Schlaf, PhD, is a Professor at the Department of Chemistry, University of Guelph, Canada. Z. Conrad Zhang, PhD, is a Professor at the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, China.
Download or read book Reaction Pathways and Mechanisms in Thermocatalytic Biomass Conversion I written by Marcel Schlaf and published by Springer. This book was released on 2015-09-25 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume I mainly focuses on the current understanding of the reaction pathways and mechanisms involved in several important catalytic conversions of cellulose and carbohydrates. It starts with nanoscale illustrations of biomass structures and describes various reactions including cellulose depolymerization to sugars, catalytic aldose-ketose isomerization and dehydration, selective oxidation, hydrogenolysis of cellulose and sugars, and the conversion of short carbohydrates. The specificity and function of different catalysts and reaction media in relation to the catalytic performances for these reactions are discussed with significant mechanistic details. Marcel Schlaf, PhD, is a Professor at the Department of Chemistry, University of Guelph, Canada. Z. Conrad Zhang, PhD, is a Professor at the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, China.
Download or read book Biofuels and Bioenergy written by Baskar Gurunathan and published by Elsevier. This book was released on 2022-06-14 with total page 840 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biofuels and Bioenergy: A Techno-Economic Approach provides an in-depth analysis of the economic aspects of biofuels production from renewable feedstock. Taking a biorefinery approach, the book analyzes a wide range of feedstocks, processes and products, including common biofuels such as bioethanol, biobutanol, biooil and biodiesel, feedstocks such as lignocellulosic biomass, non-edible feedstocks like vegetable oils, algae and microbial lipids, and solid and liquid wastes, performance assessments of biodiesel in diesel engine, and the latest developments in catalytic conversion and microbial electrosynthesis technologies. This book offers valuable insights into the commercial feasibility of biofuels products for researchers and students working in the area of bioenergy and renewable energy, but it is also ideal for practicing engineers in the biorefinery and biofuel industry who are looking to develop commercial products. - Focuses on an in-depth, techno-economic analysis of biofuel and bioenergy products, including all important feedstocks, processes and products, all of which are supported by industry case studies - Includes environmental impacts and lifecycle assessments of biofuels production alongside techno-economic analyses - Provides a critical guide to assessing the commercial viability and feasibility of bioenergy production from renewable sources
Download or read book Chemical Catalysts for Biomass Upgrading written by Mark Crocker and published by John Wiley & Sons. This book was released on 2020-03-09 with total page 634 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive reference to the use of innovative catalysts and processes to turn biomass into value-added chemicals Chemical Catalysts for Biomass Upgrading offers detailed descriptions of catalysts and catalytic processes employed in the synthesis of chemicals and fuels from the most abundant and important biomass types. The contributors?noted experts on the topic?focus on the application of catalysts to the pyrolysis of whole biomass and to the upgrading of bio-oils. The authors discuss catalytic approaches to the processing of biomass-derived oxygenates, as exemplified by sugars, via reactions such as reforming, hydrogenation, oxidation, and condensation reactions. Additionally, the book provides an overview of catalysts for lignin valorization via oxidative and reductive methods and considers the conversion of fats and oils to fuels and terminal olefins by means of esterification/transesterification, hydrodeoxygenation, and decarboxylation/decarbonylation processes. The authors also provide an overview of conversion processes based on terpenes and chitin, two emerging feedstocks with a rich chemistry, and summarize some of the emerging trends in the field. This important book: -Provides a comprehensive review of innovative catalysts, catalytic processes, and catalyst design -Offers a guide to one of the most promising ways to find useful alternatives for fossil fuel resources -Includes information on the most abundant and important types of biomass feedstocks -Examines fields such as catalytic cracking, pyrolysis, depolymerization, and many more Written for catalytic chemists, process engineers, environmental chemists, bioengineers, organic chemists, and polymer chemists, Chemical Catalysts for Biomass Upgrading presents deep insights on the most important aspects of biomass upgrading and their various types.
Download or read book The Organometallic Chemistry of the Transition Metals written by Robert H. Crabtree and published by John Wiley & Sons. This book was released on 2019-07-18 with total page 466 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides vital information on organometallic compounds, their preparation, and use in synthesis, and explores the fundamentals of the field and its modern applications Fully updated and expanded to reflect recent advances, the new, seventh edition of this bestselling text presents students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. Increased focus is given to organic synthesis applications, nanoparticle science, and green chemistry. This edition features up-to-date examples of fundamental reaction steps and greater emphasis on key topics like oxidation catalysis, CH functionalization, nanoclusters and nanoparticles, and green chemistry. New coverage is added for computational chemistry, energy production, and biochemical aspects of organometallic chemistry. The Organometallic Chemistry of the Transition Metals, Seventh Edition provides new/enhanced chapter coverage of ligand-assisted additions and eliminations; proton-coupled electron transfer; surface, supported, and cooperative catalysis; green, energy, and materials applications; and photoredox catalysis. It covers coordination chemistry; alkyls and hydrides; Pi-complexes; and oxidative addition and reductive elimination. The book also features sections on insertion and elimination; spectroscopy; metathesis polymerization and bond activation; and more. Provides an excellent foundation of the fundamentals of organometallic chemistry Includes end-of-chapter problems and their solutions Expands and includes up-to-date examples of fundamental reaction steps and focuses on important topics such as oxidation catalysis, CH functionalization, nanoparticles, and green chemistry Features all new coverage for computational chemistry, energy production, and biochemical aspects of organometallic chemistry The Organometallic Chemistry of the Transition Metals, Seventh Edition is an insightful book that will appeal to all advanced undergraduate and graduate students in organic chemistry, organometallic chemistry, inorganic chemistry, and bioinorganic chemistry, as well as any practicing chemist in those fields.
Download or read book Production of Biofuels and Chemicals with Pyrolysis written by Zhen Fang and published by Springer Nature. This book was released on 2020-10-27 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a collection of studies on state-of-art techniques for converting biomass to chemical products by means of pyrolysis, which are widely applicable to the valorization of biomass. In addition to discussing the fundamentals and mechanisms for producing bio-oils, chemicals, gases and biochar using pyrolysis, it outlines key reaction parameters and reactor configurations for various types of biomass. Written by leading experts and providing a broad range of perspectives on cutting-edge applications, the book is a comprehensive reference guide for academic researchers and industrial engineers in the fields of natural renewable materials, biorefinery of lignocellulose, biofuels, and environmental engineering, and a valuable resource for university students in the fields of chemical engineering, material science and environmental engineering.
Download or read book Biofuels Production and Processing Technology written by M.R. Riazi and published by CRC Press. This book was released on 2017-10-10 with total page 690 pages. Available in PDF, EPUB and Kindle. Book excerpt: The importance of biofuels in greening the transport sector in the future is unquestionable, given the limited available fossil energy resources, the environmental issues associated to the utilization of fossil fuels, and the increasing attention to security of supply. This comprehensive reference presents the latest technology in all aspects of biofuels production, processing, properties, raw materials, and related economic and environmental aspects. Presenting the application of methods and technology with minimum math and theory, it compiles a wide range of topics not usually covered in one single book. It discusses development of new catalysts, reactors, controllers, simulators, online analyzers, and waste minimization as well as design and operational aspects of processing units and financial and economic aspects. The book rounds out by describing properties, specifications, and quality of various biofuel products and new advances and trends towards future technology.
Download or read book Plant Biomass Derived Materials 2 Volumes written by Seiko Jose and published by John Wiley & Sons. This book was released on 2024-04-22 with total page 629 pages. Available in PDF, EPUB and Kindle. Book excerpt: Plant Biomass Derived Materials Comprehensive overview of materials derived from biomass, including extraction techniques, important building blocks, and a wide range of applications Plant Biomass Derived Materials provides insights into the different sources and kinds of biomass and covers a variety of techniques to derive important building blocks from raw resources; after foundational knowledge is covered, the text continues to discuss a comprehensive list of materials and applications, ranging from nanomaterials, polymers, enzymes, dyes, and composites, to applications in energy, biomedical, water purification, aeronautics, automotive and food applications, and more. Written by four highly qualified authors with significant experience in both industry and academia, Plant Biomass Derived Materials includes information on: Biomass and its relationship to the environment, chemistry of biomass, lignin and starch, and recent trends of cashew nutshell liquid in the field Plant biomass mucilage, plant based colorants, revival of sustainable fungal based natural pigments, and algal-based natural pigments for textiles Biorefinery from plant biomass (including a case study in sugarcane straw), forest and agricultural biomass, and manufacture of monomers and precursors Chemical routes for the transformation of bio-monomers into polymers and manufacture of polymer composites from plant fibers Providing foundational knowledge on the subject and a wide array of specific applications of biomass, Plant Biomass Derived Materials is an essential resource for chemists, materials scientists, and all academics and professionals in fields that intersect with biomass: an abundant renewable resource used for many diverse purposes.
Download or read book Nanoporous Catalysts for Biomass Conversion written by Feng-Shou Xiao and published by John Wiley & Sons. This book was released on 2017-11-06 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive introduction to the design, synthesis, characterization, and catalytic properties of nanoporous catalysts for the biomass conversion With the specter of peak oil demand looming on the horizon, and mounting concerns over the environmental impact of greenhouse gas emissions, biomass has taken on a prominent role as a sustainable alternative fuel source. One critical aspect of the biomass challenge is the development of novel catalytic materials for effective and controllable biomass conversion. Edited by two scientists recognized internationally for their pioneering work in the field, this book focuses on nanoporous catalysts, the most promising class of catalytic materials for the conversion of biomass into fuel and other products. Although various catalysts have been used in the conversion of biomass-derived feedstocks, nanoporous catalysts exhibit high catalytic activities and/or unique product selectivities due to their large surface area, open nanopores, and highly dispersed active sites. This book covers an array of nanoporous catalysts currently in use for biomass conversion, including resins, metal oxides, carbons, mesoporous silicates, polydivinylbenzene, and zeolites. The authors summarize the design, synthesis, characterization and catalytic properties of these nanoporous catalysts for biomass conversions, discussing the features of these catalysts and considering future opportunities for developing more efficient catalysts. Topics covered include: Resins for biomass conversion Supported metal oxides/sulfides for biomass oxidation and hydrogenation Nanoporous metal oxides Ordered mesoporous silica-based catalysts Sulfonated carbon catalysts Porous polydivinylbenzene Aluminosilicate zeolites for bio-oil upgrading Rice straw Hydrogenation for sugar conversion Lignin depolymerization Timely, authoritative, and comprehensive, Nanoporous Catalysts for Biomass Conversion is a valuable working resource for academic researchers, industrial scientists and graduate students working in the fields of biomass conversion, catalysis, materials science, green and sustainable chemistry, and chemical/process engineering.
Download or read book Natural Polymers and Biopolymers II written by Sylvain Caillol and published by MDPI. This book was released on 2021-05-05 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: BioPolymers could be either natural polymers – polymer naturally occurring in Nature, such as cellulose or starch…, or biobased polymers that are artificially synthesized from natural resources. Since the late 1990s, the polymer industry has faced two serious problems: global warming and anticipation of limitation to the access to fossil resources. One solution consists in the use of sustainable resources instead of fossil-based resources. Hence, biomass feedstocks are a promising resource and biopolymers are one of the most dynamic polymer area. Additionally, biodegradability is a special functionality conferred to a material, bio-based or not. Very recently, facing the awareness of the volumes of plastic wastes, biodegradable polymers are gaining increasing attention from the market and industrial community. This special issue of Molecules deals with the current scientific and industrial challenges of Natural and Biobased Polymers, through the access of new biobased monomers, improved thermo-mechanical properties, and by substitution of harmful substances. This themed issue can be considered as collection of highlights within the field of Natural Polymers and Biobased Polymers which clearly demonstrate the increased interest in this field. We hope that this will inspire researchers to further develop this area and thus contribute to futures more sustainable society.”
Download or read book A Study on Catalytic Conversion of Non Food Biomass into Chemicals written by Mizuho Yabushita and published by Springer. This book was released on 2016-01-13 with total page 171 pages. Available in PDF, EPUB and Kindle. Book excerpt: The topic of this thesis is catalytic conversion of non-food, abundant, and renewable biomass such as cellulose and chitin to chemicals. In biorefinery, chemical transformation of polymers to valuable compounds has attracted worldwide interest for building sustainable societies. First, the current situation of this hot research area has been summarized well in the general introduction of the thesis, which helps readers to become familiar with this topic. Next, the author explains high-yielding production of glucose from cellulose by using an alkali-activated carbon as a catalyst, resulting in a yield of glucose as high as 88%, which is one of the highest yields ever reported. The characterization of carbon materials has indicated that weak acid sites on the catalyst promote the reaction, which is markedly different from reported catalytic systems that require strong acids. In addition, the first catalytic transformation of chitin with retention of N-acetyl groups has been developed. The combination of mechanocatalytic hydrolysis and thermal solvolysis enables the production of N-acetylated monomers in good yields of up to 70%. The catalytic systems demonstrated in this thesis are unique in the fields of both chemistry and chemical engineering, and their high efficiencies can contribute to green and sustainable chemistry in the future. Meanwhile, mechanistic studies based on characterization, thermodynamics, kinetics, and model reactions have also been performed to reveal the roles of catalysts during the reactions. The results will be helpful for readers to design and develop new catalysts and reaction systems.
Download or read book Production of Biofuels and Chemicals with Bifunctional Catalysts written by Zhen Fang and published by Springer. This book was released on 2017-12-27 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides state-of-the-art reviews, current research, prospects and challenges of the production of biofuels and chemicals such as furanic biofuels, biodiesel, carboxylic acids, polyols and others from lignocellulosic biomass, furfurals, syngas and γ-valerolactone with bifunctional catalysts, including catalytic, and combined biological and chemical catalysis processes. The bifunctionality of catalytic materials is a concept of not only using multifunctional solid materials as activators, but also design of materials in such a way that the catalytic materials have synergistic characteristics that promote a cascade of transformations with performance beyond that of mixed mono-functional catalysts. This book is a reference designed for researchers, academicians and industrialists in the area of catalysis, energy, chemical engineering and biomass conversion. Readers will find the wealth of information contained in chapters both useful and essential, for assessing the production and application of various biofuels and chemicals by chemical catalysis and biological techniques.
Download or read book Zeolites in Catalysis written by Jiří Čejka and published by Royal Society of Chemistry. This book was released on 2017-06-07 with total page 547 pages. Available in PDF, EPUB and Kindle. Book excerpt: Accessible references for researchers and industrialists in this exciting field, covering both developments and applications of catalysis.
Download or read book Aqueous phase Catalytic Conversions of Renewable Feedstocks for Sustainable Biorefineries written by Georgios Papadogianakis and published by Frontiers Media SA. This book was released on 2024-08-23 with total page 196 pages. Available in PDF, EPUB and Kindle. Book excerpt: Today, there is growing interest in aqueous-phase catalytic conversions for the valorization of renewable biomass-based feedstocks for biorefineries to produce, in a sustainable way, biofuels, chemicals, power, energy, materials, pharmaceuticals and food. This is because of the highly polar nature of water which makes it an ideal medium to convert polar biomass-based lignocellulose (cellulose, hemicellulose, lignin), with high oxygen content, and their upgraded products such as hydrophilic carbohydrates, platform chemicals and their derivatives. Another reason which makes water the solvent of choice is that water itself is involved either as a reagent or as a byproduct even in large amounts in typical conversions for the valorization of biomass. The obtained intermediates further react in the aqueous medium, often without any separation and purification, to manufacture more valuable products. This results in substantial energy savings, lower emissions and economic benefits. Furthermore, water could act as a catalyst in conversions of biomass-based feedstocks such as in liquefaction reactions under subcritical conditions. Moreover, novel types of catalytic reactivity have been observed in the aqueous solvent, not only with water-soluble transition metal catalytic complexes, but also with conventional heterogeneous catalysts and catalytic nanoparticles in a broad spectrum of different reactions such as, inter alia, aldol condensations and hydrogenation reactions. For example, in the aqueous-phase hydrogenation of the biomass-based key platform chemical levulinic acid into γ-valerolactone and beyond, employing heterogeneous catalysts and nanoparticles the presence of water has a beneficial effect and accelerates the reaction rates, whereas in organic solvents much lower activities were observed. This promotional effect of water in the hydrogenation of levulinic acid was proved by many experimental and theoretical studies using a broad spectrum of different types of catalytic systems.
Download or read book Recent Advances in Thermochemical Conversion of Biomass written by Ashok Pandey and published by Elsevier. This book was released on 2015-01-28 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides general information and data on one of the most promising renewable energy sources: biomass for its thermochemical conversion. During the last few years, there has been increasing focus on developing the processes and technologies for the conversion of biomass to liquid and gaseous fuels and chemicals, in particular to develop low-cost technologies. This book provides date-based scientific information on the most advanced and innovative processing of biomass as well as the process development elements on thermochemical processing of biomass for the production of biofuels and bio-products on (biomass-based biorefinery). The conversion of biomass to biofuels and other value-added products on the principle biorefinery offers potential from technological perspectives as alternate energy. The book covers intensive R&D and technological developments done during the last few years in the area of renewable energy utilizing biomass as feedstock and will be highly beneficial for the researchers, scientists and engineers working in the area of biomass-biofuels- biorefinery. - Provides the most advanced and innovative thermochemical conversion technology for biomass - Provides information on large scales such as thermochemical biorefinery - Useful for researchers intending to study scale up - Serves as both a textbook for graduate students and a reference book for researchers - Provides information on integration of process and technology on thermochemical conversion of biomass
Download or read book Fast Pyrolysis of Biomass written by Robert C Brown and published by Royal Society of Chemistry. This book was released on 2017-07-07 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fast pyrolysis and related catalytic pyrolysis are of increasing interest as pathways to advanced biofuels that closely mimic traditional petroleum products. Research has moved from empirical investigations to more fundamental studies of pyrolysis mechanisms. Theories on the chemical and physical pathways from plant polymers to pyrolysis products have proliferated as a result. This book brings together the latest developments in pyrolysis science and technology. It examines, reviews and challenges the unresolved and sometimes controversial questions about pyrolysis, helping advance the understanding of this important technology and stimulating discussion on the various competing theories of thermal deconstruction of plant polymers. Beginning with an introduction to the biomass-to-biofuels process via fast pyrolysis and catalytic pyrolysis, chapters address prominent questions such as whether free radicals or concerted reactions dominate deconstruction reactions. Finally, the book concludes with an economic analysis of fast pyrolysis versus catalytic pyrolysis. This book will be of interest to advanced students and researchers interested in the science behind renewable fuel technology, and particularly the thermochemical processing of biomass.
Download or read book The Role of Catalysis for the Sustainable Production of Bio fuels and Bio chemicals written by Kostas Triantafyllidis and published by Newnes. This book was released on 2013-03-19 with total page 607 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals describes the importance of catalysis for the sustainable production of biofuels and biochemicals, focused primarily on the state-of-the-art catalysts and catalytic processes expected to play a decisive role in the "green" production of fuels and chemicals from biomass. In addition, the book includes general elements regarding the entire chain of biomass production, conversion, environment, economy, and life-cycle assessment. Very few books are available on catalysis in production schemes using biomass or its primary conversion products, such as bio-oil and lignin. This book fills that gap with detailed discussions of: - Catalytic pyrolysis of lignocellulosic biomass - Hybrid biogasoline by co-processing in FCC units - Fischer-Tropsch synthesis to biofuels (biomass-to-liquid process) - Steam reforming of bio-oils to hydrogen With energy prices rapidly rising, environmental concerns growing, and regulatory apparatus evolving, this book is a resource with tutorial, research, and technological value for chemists, chemical engineers, policymakers, and students. - Includes catalytic reaction mechanism schemes and gives a clear understanding of catalytic processes - Includes flow diagrams of bench-, pilot- and industrial-scale catalytic processing units and demonstrates the various process technologies involved, enabling easy selection of the best process - Incorporates many tables, enabling easy comparison of data based on a critical review of the available literature
