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Book Phase Behavior of Light Gases in Hydrocarbon and Aqueous Solvents

Download or read book Phase Behavior of Light Gases in Hydrocarbon and Aqueous Solvents written by and published by . This book was released on 1997 with total page 56 pages. Available in PDF, EPUB and Kindle. Book excerpt: Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present reporting period, our solubility apparatus was refurbished and restored to full service. To test the experimental apparatus and procedures used, measurements were obtained for the solubility Of C02 in benzene at 160°F. Having confirmed the accuracy of the newly acquired data in comparison with our previous measurements and data reported in the literature for this test system, we have begun to measure the solubility of hydrogen in hexane. The measurements for this system will cover the temperature range from 160 to 280°F at pressures to 2,500 psia. As part of our model evaluation efforts, we examined the predictive abilities of an alternative approach we have proposed for calculating the phase behavior properties of highly non-ideal systems. Using this approach, the liquid phase fugacities generated from an equation of state (EOS) are augmented by a fugacity deviation function correction. The correlative abilities of this approach are compared with those of an EOS equipped with the recently introduced Wong-Sandler (MWS) mixing rules. These two approaches are compared with the current methods for vapor-liquid equilibrium (VLE) calculations, i.e., the EOS (0/0) approach with the van der Waals mixing rules and the split (y/0) approach. The evaluations were conducted on a database comprised of non-ideal low pressure binary systems as well as asymmetric high pressure binary systems. These systems are of interest in the coal liquefaction and utilization processes. The Peng-Robinson EOS was selected for the purposes of this evaluation.

Book PHASE BEHAVIOR OF LIGHT GASES IN HYDROGEN AND AQUEOUS SOLVENTS

Download or read book PHASE BEHAVIOR OF LIGHT GASES IN HYDROGEN AND AQUEOUS SOLVENTS written by and published by . This book was released on 1999 with total page 62 pages. Available in PDF, EPUB and Kindle. Book excerpt: Under previous support from the US Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present reporting period, the solubilities of hydrogen in n-hexane, carbon monoxide in cyclohexane, and nitrogen in phenanthrene and pyrene were measured using a static equilibrium cell over the temperature range from 344.3 to 433.2 K and pressures to 22.8 MPa. The uncertainty in these new solubility measurements is estimated to be less than 0.001 in mole fraction. The data were analyzed using the Peng-Robinson (PR) equation of state (EOS). In general, the PR EOS represents the experimental data well when a single interaction parameter (C{sub ij}) is used for each isotherm. In addition, the predictive capability of the modified Park-Gasem-Robinson (PGR) equation of state (EOS) was evaluated for selected carbon dioxide + normal paraffins, ethane + normal paraffins, and hydrogen + normal paraffins. A set of mixing rules was proposed for the modified EOS to extend its predictive capabilities to mixtures. The predicted bubble point pressures for the ethane + n-paraffin and carbon dioxide + n-paraffin binaries were compared to those of the Peng-Robinson (PR), simplified-perturbed-hard-chain theory (SPHCT) and original PGR equations. The predictive capability of the proposed equation is better or comparable to the PR, SPHCT and original PGR equations of state for the ethane binaries (%AAD of 1.9) and carbon dioxide binaries (%AAD of 2.0). For the hydrogen binaries, the modified PGR EOS showed much better performance (%AAD of 1.7) than the original PGR equation and comparable to the PR equation.

Book Phase Behavior of the Hydrocarbons

Download or read book Phase Behavior of the Hydrocarbons written by University of Michigan. College of Engineering and published by . This book was released on 1953 with total page 118 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Phase Behavior of Petroleum Reservoir Fluids

Download or read book Phase Behavior of Petroleum Reservoir Fluids written by Karen Schou Pedersen and published by CRC Press. This book was released on 2024-01-26 with total page 511 pages. Available in PDF, EPUB and Kindle. Book excerpt: Developed in conjunction with several oil companies using experimental data for real reservoir fluids, Phase Behavior of Petroleum Reservoir Fluids introduces industry standard methods for modeling the phase behavior of petroleum reservoir fluids at different stages in the process. Keeping mathematics to a minimum, this book discusses sampling, characterization, compositional analyses, and equations of state used to simulate various pressure–volume–temperature (PVT) properties of reservoir fluids. The Third Edition has been updated throughout. Reflects advances in equation of state modeling for reservoir fluids and CO2-rich fluids Presents association models along with non-classical mixing rules for handling fluids with aqueous components Has an extended coverage of reservoir fluid communication, energy properties, and asphaltene precipitation Provides practical knowledge essential for achieving optimal design and cost-effective operations in a petroleum processing plant This book offers engineers working in the energy sector a solid understanding of the phase behavior of the various fluids present in a petroleum reservoir.

Book Phase Behavior and Thermodynamic Properties of Water hydrocarbon Systems

Download or read book Phase Behavior and Thermodynamic Properties of Water hydrocarbon Systems written by M. A. Hildebrand and published by . This book was released on 1981 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Fluid Phase Behavior for Conventional and Unconventional Oil and Gas Reservoirs

Download or read book Fluid Phase Behavior for Conventional and Unconventional Oil and Gas Reservoirs written by Alireza Bahadori and published by Gulf Professional Publishing. This book was released on 2016-11-24 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fluid Phase Behavior for Conventional and Unconventional Oil and Gas Reservoirs delivers information on the role of PVT (pressure-volume-temperature) tests/data in various aspects, in particular reserve estimation, reservoir modeling, flow assurance, and enhanced oil recovery for both conventional and unconventional reservoirs. This must-have reference also prepares engineers on the importance of PVT tests, how to evaluate the data, develop an effective management plan for flow assurance, and gain perspective of flow characterization, with a particular focus on shale oil, shale gas, gas hydrates, and tight oil making. This book is a critical resource for today’s reservoir engineer, helping them effectively manage and maximize a company’s oil and gas reservoir assets. Provides tactics on reservoir phase behavior and dynamics with new information on shale oil and gas hydrates Helps readers Improve on the effect of salt concentration and application to C02-Acid Gas Disposal with content on water-hydrocarbon systems Provides practical experience with PVT and tuning of EOS with additional online excel spreadsheet examples

Book Springer Handbook of Petroleum Technology

Download or read book Springer Handbook of Petroleum Technology written by Chang Samuel Hsu and published by Springer. This book was released on 2017-12-20 with total page 1243 pages. Available in PDF, EPUB and Kindle. Book excerpt: This handbook provides a comprehensive but concise reference resource for the vast field of petroleum technology. Built on the successful book "Practical Advances in Petroleum Processing" published in 2006, it has been extensively revised and expanded to include upstream technologies. The book is divided into four parts: The first part on petroleum characterization offers an in-depth review of the chemical composition and physical properties of petroleum, which determine the possible uses and the quality of the products. The second part provides a brief overview of petroleum geology and upstream practices. The third part exhaustively discusses established and emerging refining technologies from a practical perspective, while the final part describes the production of various refining products, including fuels and lubricants, as well as petrochemicals, such as olefins and polymers. It also covers process automation and real-time refinery-wide process optimization. Two key chapters provide an integrated view of petroleum technology, including environmental and safety issues.Written by international experts from academia, industry and research institutions, including integrated oil companies, catalyst suppliers, licensors, and consultants, it is an invaluable resource for researchers and graduate students as well as practitioners and professionals.

Book Phase Behavior

Download or read book Phase Behavior written by Curtis H. Whitson and published by Society of Petroleum Engineers. This book was released on 2000 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phase Behavior provides the reader with the tools needed to solve problems requiring a description of phase behavior and specific pressure/volume/temperature (PVT) properties.

Book Hydrocarbon Phase Behavior

Download or read book Hydrocarbon Phase Behavior written by Tarek H. Ahmed and published by Butterworth-Heinemann. This book was released on 1989 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book European Symposium on Computer Aided Process Engineering   10

Download or read book European Symposium on Computer Aided Process Engineering 10 written by Sauro Pierucci and published by Elsevier. This book was released on 2000-05-10 with total page 1207 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book includes papers presented at ESCAPE-10, the 10th European Symposium on Computer Aided Process -Engineering, held in Florence, Italy, 7-10th May, 2000. The scientific program reflected two complementary strategic objectives of the 'Computer Aided Process Engineering' (CAPE) Working Party: one checked the status of historically consolidated topics by means of their industrial application and their emerging issues, while the other was addressed to opening new windows to the CAPE audience by inviting adjacent Working Parties to co-operate in the creation of the technical program. The former CAPE strategic objective was covered by the topics: Numerical Methods, Process Design and Synthesis, Dynamics & Control, Process Modeling, Simulation and Optimization. The latter CAPE strategic objective derived from the European Federation of Chemical Engineering (EFCE) promotion of scientific activities which autonomously and transversely work across the Working Parties' terms of references. These activities enhance the exchange of the know-how and knowledge acquired by different Working Parties in homologous fields. They also aim to discover complementary facets useful to the dissemination of tools and of novel procedures. As a consequence, the Working Parties 'Environmental Protection', 'Loss Prevention and Safety Promotion' and 'Multiphase Fluid Flow' were invited to assist in the organization of sessions in the area of: A Process Integrated Approach for: Environmental Benefit, Loss Prevention and Safety, Computational Fluid Dynamics. A total of 473 abstracts from all over the world were evaluated by the International Scientific Committee. Out of them 197 have been finally selected for the presentation and reported into this book. Their authors come from thirty different countries. The selection of the papers was carried out by twenty-eight international reviewers. These proceedings will be a major reference document to the scientific and industrial community and will contribute to the progress in Computer Aided Process Engineering.

Book An Introduction to Reservoir Simulation Using MATLAB GNU Octave

Download or read book An Introduction to Reservoir Simulation Using MATLAB GNU Octave written by Knut-Andreas Lie and published by Cambridge University Press. This book was released on 2019-08-08 with total page 677 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a self-contained introduction to the simulation of flow and transport in porous media, written by a developer of numerical methods. The reader will learn how to implement reservoir simulation models and computational algorithms in a robust and efficient manner. The book contains a large number of numerical examples, all fully equipped with online code and data, allowing the reader to reproduce results, and use them as a starting point for their own work. All of the examples in the book are based on the MATLAB Reservoir Simulation Toolbox (MRST), an open-source toolbox popular popularity in both academic institutions and the petroleum industry. The book can also be seen as a user guide to the MRST software. It will prove invaluable for researchers, professionals and advanced students using reservoir simulation methods. This title is also available as Open Access on Cambridge Core.

Book The Equilibrium Phase Behavior of Several Solute Gases in the Solvent Phenanthrene

Download or read book The Equilibrium Phase Behavior of Several Solute Gases in the Solvent Phenanthrene written by Robert L. Robinson and published by . This book was released on 1981 with total page 23 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Pollution Control Handbook for Oil and Gas Engineering

Download or read book Pollution Control Handbook for Oil and Gas Engineering written by Nicholas P. Cheremisinoff and published by John Wiley & Sons. This book was released on 2016-04-20 with total page 1408 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is a major new handbook that covers hundreds of subjects that cross numerous industry sectors; however, the handbook is heavily slanted to oil and gas environmental management, control and pollution prevention and energy efficient practices. Multi-media pollution technologies are covered : air, water, solid waste, energy. Students, technicians, practicing engineers, environmental engineers, environmental managers, chemical engineers, petroleum engineers, and environmental attorneys are all professionals who will benefit from this major new reference source. The handbook is organized in three parts. Part A provides an extensive compilation of abbreviations and concise glossary of pollution control and engineering terminology. More than 400 terms are defined. The section is intended to provide a simple look-up guide to confusing terminology used in the regulatory field, as well as industry jargon. Cross referencing between related definitions and acronyms are provided to assist the user. Part B provides physical properties and chemical safety information. This part is not intended to be exhaustive; however it does provide supplemental information that is useful to a number of the subject entries covered in the main body of the handbook. Part C is the Macropedia of Subjects. The part is organized as alphabetical subject entries for a wide range of pollution controls, technologies, pollution prevention practices and tools, computational methods for preparing emission estimates and emission inventories and much more. More than 100 articles have been prepared by the author, providing a concise overview of each subject, supplemented by sample calculation methods and examples where appropriate, and references. Subjects included are organized and presented in a macropedia format to assist a user in gaining an overview of the subject, guidance on performing certain calculations or estimates as in cases pertinent to preliminary sizing and selection of pollution controls or in preparing emissions inventories for reporting purposes, and recommended references materials and web sites for more in-depth information, data or computational tools. Each subject entry provides a working overview of the technology, practice, piece of equipment, regulation, or other relevant issue as it pertains to pollution control and management. Cross referencing between related subjects is included to assist the reader to gain as much of a practical level of knowledge.

Book Oil Shales and Tar Sands

Download or read book Oil Shales and Tar Sands written by United States. Department of Energy and published by . This book was released on 1977 with total page 752 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Petroleum Abstracts

Download or read book Petroleum Abstracts written by and published by . This book was released on 1995-04 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Unconventional Methods for Geoscience  Shale Gas and Petroleum in the 21st Century

Download or read book Unconventional Methods for Geoscience Shale Gas and Petroleum in the 21st Century written by J. Watada and published by IOS Press. This book was released on 2023-09-11 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the turn of the century, geology has advanced dramatically, with materials derived from extra-terrestrial sources meaning that it now encompasses cosmology, and new technologies providing ever more sophisticated possibilities for the conducting of research. This book, Unconventional Methods for Geoscience, Shale Gas and Petroleum in the 21st Century, aims to provide research directions for geology in the 21st century. As Eric Hobsbawm wrote, it is difficult to write the history of one’s own days, and selecting influential methods was no easy task, but an attempt has been made to include the most influential papers that represent the smart geology of the first few decades of the 21st century. The book presents 22 papers; the first serves as an introduction to biology, which is now expanding into the science of the cosmos following the discovery of previously missing information, and the remaining 21 papers are divided into 3 sections entitled Modelling, Simulation and Optimization. The importance of theoretical approaches from physics, mathematics, and statistics underlying meta-heuristic methods, knowledge and approaches is acknowledged, and there is a chapter dedicated to deep learning. The book contributes to the exploration of various possible solutions to challenging problems in both the Earth’s geology and that of the cosmos, and will be of interest to all those working in the field.