Download or read book Plasma Deposition of Oxide coated Cathodes written by Ryan Jonathan Umstattd and published by . This book was released on 1998 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vacuum arc deposition is employed to create a barium and/or strontium plasma which is subsequently deposited/implanted onto a nickel cathode substrate. The primary motivation for this work is the critical need for a reliable, repeatable, long-lived thermionic cathode for the production of high power, microsecond duration microwave pulses; such cathodes may also have applicability for lower current density continuous wave devices. This novel approach to manufacturing an oxide cathode eliminates the binders that may subsequently (and unpredictably) poison cathode emission. Removal of the poisoning mechanisms has yielded oxide cathodes capable of emission densities in the 20 A/sq cm regime. Cathode lifetime and emission may be varied via the control over the deposition parameters such as coating thickness, implantation energy, and plasma stoichiometry. The deposition is performed by generating a cathodic arc discharge at the surface of a barium or barium-strontium alloy rod. The metal plasma thus created is then deposited on the substrate which can be negatively biased to encourage implantation during the deposition process. The deposition is performed with sufficient background oxygen present to oxidize the highly reactive metal coating. The plasma deposition is monitored via a rate thickness monitor, an optical emission spectrometer for plasma composition information, and an electrostatic Langmuir probe for the determination of the plasma density and temperature profile. Cathodes thus produced are analyzed by drawing pulsed current at a constant voltage for various values of decreasing cathode temperature in order to generate practical work function distributions which provide an indication of the quality and expected life time of the cathode.

Download or read book Oxide Electronics written by Asim K. Ray and published by John Wiley & Sons. This book was released on 2021-04-22 with total page 624 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxide Electronics Multiple disciplines converge in this insightful exploration of complex metal oxides and their functions and properties Oxide Electronics delivers a broad and comprehensive exploration of complex metal oxides designed to meet the multidisciplinary needs of electrical and electronic engineers, physicists, and material scientists. The distinguished author eschews complex mathematics whenever possible and focuses on the physical and functional properties of metal oxides in each chapter. Each of the sixteen chapters featured within the book begins with an abstract and an introduction to the topic, clear explanations are presented with graphical illustrations and relevant equations throughout the book. Numerous supporting references are included, and each chapter is self-contained, making them perfect for use both as a reference and as study material. Readers will learn how and why the field of oxide electronics is a key area of research and exploitation in materials science, electrical engineering, and semiconductor physics. The book encompasses every application area where the functional and electronic properties of various genres of oxides are exploited. Readers will also learn from topics like: Thorough discussions of High-k gate oxide for silicon heterostructure MOSFET devices and semiconductor-dielectric interfaces An exploration of printable high-mobility transparent amorphous oxide semiconductors Treatments of graphene oxide electronics, magnetic oxides, ferroelectric oxides, and materials for spin electronics Examinations of the calcium aluminate binary compound, perovoksites for photovoltaics, and oxide 2Degs Analyses of various applications for oxide electronics, including data storage, microprocessors, biomedical devices, LCDs, photovoltaic cells, TFTs, and sensors Suitable for researchers in semiconductor technology or working in materials science, electrical engineering, and physics, Oxide Electronics will also earn a place in the libraries of private industry researchers like device engineers working on electronic applications of oxide electronics. Engineers working on photovoltaics, sensors, or consumer electronics will also benefit from this book.

Download or read book Lubricating Properties of Some Bonded Fluoride and Oxide Coatings for Temperature to 1500 F written by Harold E. Sliney and published by . This book was released on 1960 with total page 30 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Rustless Coatings written by M. P. Wood and published by . This book was released on 1905 with total page 502 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis and Pyrolysis of Metal Alkoxides as Potential Refractory Oxide Coatings for Graphite written by K. S. Mazdiyasni and published by . This book was released on 1963 with total page 54 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Oxide Based Fiber Reinforced Ceramic Matrix Composites written by Bilge Saruhan and published by Springer Science & Business Media. This book was released on 2013-11-27 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of Oxide-Based Fiber-Reinforced Ceramic-Matrix Composites is to provide comprehensive information on the most recent successful findings. The book consists of six chapters which characterize the current state of the art concerning oxide-based fiber-reinforced composites. Chapter one provides an introduction, examples of application areas and background information. Chapter two deals with the primary material properties for the areas of application and lists the possible constituent parts of the composites, depending on particular demands. Chapter three explains both the past and present fabrication methods which can affect the performance of the composites. Chapter four defines the interphase-related phenomena and describes the mechanical characteristics of the oxide-based fiber-reinforced composite, produced with different interphases. Chapter five deals with the fabrication route, functionality and mechanical characterization of the porous-matrix composites. The last chapter summarizes the present achievements and identifies requirements for reaching the goal, thereby providing a promising course for future research.

Download or read book Preliminary Operation of Oxide coated Brush Cathodes in Electron bombardment Ion Thrustors written by William R. Kerslake and published by . This book was released on 1965 with total page 20 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book High Temperature Coatings written by Sudhangshu Bose and published by Butterworth-Heinemann. This book was released on 2017-11-27 with total page 418 pages. Available in PDF, EPUB and Kindle. Book excerpt: High Temperature Coatings, Second Edition, demonstrates how to counteract the thermal effects of rapid corrosion and degradation of exposed materials and equipment that can occur under high operating temperatures. This is the first true practical guide on the use of thermally protective coatings for high-temperature applications, including the latest developments in materials used for protective coatings. It covers the make-up and behavior of such materials under thermal stress and the methods used for applying them to specific types of substrates, as well as invaluable advice on inspection and repair of existing thermal coatings. With his long experience in the aerospace gas turbine industry, the author has compiled the very latest in coating materials and coating technologies, as well as hard-to-find guidance on maintaining and repairing thermal coatings, including appropriate inspection protocols. The book is supplemented with the latest reference information and additional support to help readers find more application- and industry-type coatings specifications and uses. - Offers an overview of the underlying fundamental concepts of thermally-protective coatings, including thermodynamics, energy kinetics, crystallography and equilibrium phases - Covers essential chemistry and physics of underlying substrates, including steels, nickel-iron alloys, nickel-cobalt alloys and titanium alloys - Provides detailed guidance on a wide variety of coating types, including those used against high temperature corrosion and oxidative degradation and thermal barrier coatings

Download or read book Protective Metallic Coatings written by Henry S. Rawdon and published by . This book was released on 1928 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Metal Oxides written by Maria Luisa Grilli and published by MDPI. This book was released on 2020-12-15 with total page 170 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Special Issue contains ten research papers, three of which review papers. It is a miscellaneous composition encompassing several applications where metal oxides play a key role. Some papers also give insights into novel synthesis methods and processes aiming to reduce negative environmental impacts and increase materials and process efficiency, thus also covering a broader concern of sustainability issues. The topics covered in this issues are: transparent conductive oxides, ceramic composites for tool applications, oxides nanoparticles for A-TIG welding, critical raw materials saving, metallurgical waste treatment, oxides for high temperature applications, nanostructured oxides and composites for gas sensing and desulfuration, and metal oxides sorbents for CO2 capture.

Download or read book Physical vapor deposition and thermal stability of hard oxide coatings written by Ludvig Landälv and published by Linköping University Electronic Press. This book was released on 2019-04-26 with total page 42 pages. Available in PDF, EPUB and Kindle. Book excerpt: The state-of-the-art tools for machining metals are primarily based on a metal-ceramic composite (WC-Co) coated with different combinations of carbide, nitride, and oxide coatings. Combinations of these coating materials are optimized to withstand specific wear conditions. Oxide coatings, mainly α-Al2O3, are especially desired because of their high hot-hardness, chemical inertness with respect to the workpiece, and their low friction. The search for possible alloy elements, which may facilitate the deposition of such oxides by means of physical vapor deposition (PVD) techniques, has been the goal of this thesis. The sought alloy should form thermodynamically stable or metastable compounds, compatible with the temperature of use in metal cutting application. This thesis deals with process development and coating characterization of such new oxide alloy thin films, focusing on the Al-V-O, Al-Cr-Si-O, and Cr-Zr-O systems. Alloying aluminum oxide with iso-valent vanadium is a candidate for forming the desired alloys. Therefore, coatings of (Al1-xVx)2O3, with x ranging from 0 to 1, were deposited with reactive sputter deposition. X-ray diffraction showed three different crystal structures depending on V-metal fraction in the coating: α-V2O3 rhombohedral structure for 100 at.% V, a defect spinel structure for the intermediate region, (63 - 42 at.% V), and a gamma-alumina-like solid solution at lower V-content, (18 and 7 at.%), were observed, the later was shifted to larger d-spacing compared to the pure γ-Al2O3 sample obtained if deposited with only Al-target. Annealing the Al-rich coatings in air resulted in formation of V2O5 crystals on the surface of the coating after annealing to 500 °C for 42 at.% V and 700 °C for 18 at.% V metal fraction respectively. The highest thermal stability was shown for pure γ-Al2O3-coating which transformed to α-Al2O3 after annealing to 1100° C. Highest hardness was observed for the Al-rich oxides, ~24 GPa. The hardness then decreases with increasing V-content, larger than 7 at.% V metal fraction. Doping the Al2O3 coating with 7 at.% V resulted in a significant surface smoothening compared to the binary oxide. The measured hardness after annealing in air decreased in conjunction with the onset of further oxidation of the coatings. This work increases the understanding of this complicated material system with respect to possible phases formed with pulsed DC magnetron sputtering deposition as well as their response to annealing in air. The inherent difficulties of depositing insulating oxide films with PVD, requiring a closed electrical circuit, makes the investigation of process stability an important part of this research. In this context, I investigated the influence of adding small amount of Si in Al-Cr cathode on the coating properties in a pulsed DC industrial cathodic arc system and the plasma characteristics, process parameters, and coating properties in a lab DC cathodic arc system. Si was chosen here due to a previous study showing improved erosion behavior of Al-Cr-Si over pure Al-Cr cathode without Si incorporation in the coating. The effect of Si in the Al-Cr cathode in the industrial cathodic arc system showed slight improvements on the cathode erosion but Si was found in all coatings where Si was added in the cathode. The Si addition promoted the formation of the B1-like metastable cubic oxide phase and the incorporation led to reduced or equal hardness values compared to the corresponding Si-free processes. The DC-arc plasma study on the same material system showed only small improvements in the cathode erosion and process stability (lower pressure and cathode voltage) when introducing 5 at.% Si in the Al70Cr30-cathode. The presence of volatile SiO species could be confirmed through plasma analysis, but the loss of Si through these species was negligible, since the coating composition matched the cathode composition also under these conditions. The positive effect of added Si on the process stability at the cathode surface, should be weighed against Si incorporation in the coating. This incorporation seems to lead to a reduction in mechanical properties in the as-deposited coatings and promote the formation of a B1-like cubic metastable oxide structure for the (Al,Cr)2O3 oxide. This formation may or may not be beneficial for the final application since literature indicates a slight stabilization of the metastable phase upon Si-incorporation, contrary to the effect of Cr, which stabilizes the α-phase. The thermal stability of alloys for metal cutting application is crucial for their use. Previous studies on another alloy system, Cr-Zr-O, had shown solid solution, for Cr-rich compositions in that material system, in the sought corundum structure. The thermal stability of α-Cr0.28Zr0.10O0.61 coating deposited by reactive radio frequency (RF)-magnetron sputtering at 500 °C was therefore investigated here after annealing in vacuum up to 870 °C. The annealed samples showed transformation of α-(Cr,Zr)2O3 and amorphous ZrOx-rich areas into tetragonal ZrO2 and bcc-Cr. The instability of the α-(Cr,Zr)2O3 is surprising and possibly related to the annealing being done under vacuum, facilitating the loss of oxygen. Further in situ synchrotron XRD annealing studies on the α-Cr0.28Zr0.10O0.61 coating in air and in vacuum showed increased stability for the air annealed sample up to at least 975 °C, accompanied with a slight increase in ex-situ measured nanohardness. The onset temperature for formation of tetragonal ZrO2 was similar to that for isothermally vacuum annealing. The synchrotron-vacuum annealed coating again decomposed into bcc-Cr and t-ZrO2, with an addition of monoclinic–ZrO2 due to grain growth. The stabilization of the room temperature metastable tetragonal ZrO2 phase, due to surface energy effects present with small grains sizes, may prove to be useful for metal cutting applications. The observed phase segregation of α-(Cr,Zr)2O3 and formation of tetragonal ZrO2 with corresponding increase in hardness for this pseudobinary oxide system also opens up design routes for pseudobinary oxides with tunable microstructural and mechanical properties.

Download or read book Ultrathin Oxide Layers for Solar and Electrocatalytic Systems written by Heinz Frei and published by Royal Society of Chemistry. This book was released on 2022-01-04 with total page 378 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ultrathin metal oxide layers have emerged in recent years as a powerful approach for substantially enhancing the performance of photo, electro, or thermal catalytic systems for energy, in some cases even enabling the use of highly attractive materials previously found unsuitable. This development is due to the confluence of new synthetic preparation methods for ultrathin oxide layers and a more advanced understanding of interfacial phenomena on the nano and atomic scale. This book brings together the fundamentals and applications of ultrathin oxide layers while highlighting connections and future opportunities with the intent of accelerating the use of these materials and techniques for new and emerging applications of catalysis for energy. It comprehensively covers the state-of-the-art synthetic methods of ultrathin oxide layers, their structural and functional characterization, and the broad range of applications in the field of catalysis for energy. Edited by leaders in the field, and with contributions from global experts, this title will be of interest to graduate students and researchers across materials science and chemistry who are interested in ultrathin oxide layers and their applications in solar energy conversion, renewable energy, photocatalysis, electrocatalysis and protective coatings.

Download or read book Advances in Medium and High Temperature Solid Oxide Fuel Cell Technology written by Marta Boaro and published by Springer. This book was released on 2016-11-24 with total page 347 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book well-known experts highlight cutting-edge research priorities and discuss the state of the art in the field of solid oxide fuel cells giving an update on specific subjects such as protonic conductors, interconnects, electrocatalytic and catalytic processes and modelling approaches.Fundamentals and advances in this field are illustrated to help young researchers address issues in the characterization of materials and in the analysis of processes, not often tackled in scholarly books.

Download or read book Cerium Oxide CeO2 Synthesis Properties and Applications written by Salvatore Scire and published by Elsevier. This book was released on 2019-08-21 with total page 402 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cerium Oxide (CeO2): Synthesis, Properties and Applications provides an updated and comprehensive account of the research in the field of cerium oxide based materials. The book is divided into three main blocks that deal with its properties, synthesis and applications. Special attention is devoted to the growing number of applications of ceria based materials, including their usage in industrial and environmental catalysis and photocatalysis, energy production and storage, sensors, cosmetics, radioprotection, glass technology, pigments, stainless steel and toxicology. A brief historical introduction gives users background, and a final chapter addresses future perspectives and outlooks to stimulate future research. The book is intended for a wide audience, including students, academics and industrial researchers working in materials science, chemistry and physics. - Addresses a wide range of applications of ceria-based materials, including catalysis, energy production and storage, sensors, cosmetics and toxicology - Provides the fundamentals of ceria-based materials, including synthesis methods, materials properties, toxicology and surface chemistry - Includes nanostructured ceria-based materials and a discussion of future prospects and outlooks

Download or read book Official Gazette of the United States Patent and Trademark Office written by United States. Patent and Trademark Office and published by . This book was released on 2001 with total page 1382 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Metal Oxide Nanomaterials for Chemical Sensors written by Michael A. Carpenter and published by Springer Science & Business Media. This book was released on 2012-11-09 with total page 559 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a state-of-the-art summary and critical analysis of work recently performed in leading research laboratories around the world on the implementation of metal oxide nanomaterial research methodologies for the discovery and optimization of new sensor materials and sensing systems. The book provides a detailed description and analysis of (i) metal oxide nanomaterial sensing principles, (ii) advances in metal oxide nanomaterial synthesis/deposition methods, including colloidal, emulsification, and vapor processing techniques, (iii) analysis of techniques utilized for the development of low temperature metal oxide nanomaterial sensors, thus enabling a broader impact into sensor applications, (iv) advances, challenges and insights gained from the in situ/ex situ analysis of reaction mechanisms, and (v) technical development and integration challenges in the fabrication of sensing arrays and devices.

Download or read book Advances in Solid Oxide Fuel Cells and Electronic Ceramics II Volume 37 Issue 3 written by Mihails Kusnezoff and published by John Wiley & Sons. This book was released on 2017-01-31 with total page 211 pages. Available in PDF, EPUB and Kindle. Book excerpt: This issue contains 13 papers from The American Ceramic Society’s 40th International Conference on Advanced Ceramics and Composites, held in Daytona Beach, Florida, January 24-29, 2016 presented in Symposium 3 - 13th International Symposium on Solid Oxide Fuel Cells: Materials, Science, and Technology and Symposium 14 – Single Crystalline Materials for Electrical, Optical, and Medical Applications.