Download or read book Organic Syntheses by Oxidation with Metal Compounds written by W.J. Mijs and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 924 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is concerned with the synthetic aspects of oxidation reactions involving metal compounds. which are readily available or easy to prepare. The sequence followed in the chapters is as follows: a general introduction. a limited treatment of reaction mechanisms to serve as a basis for synthesis. and scope and limitations of the oxidant system. mostly in terms of substrate and product classes. Finally, at the end of each chapter. representative synthetic procedures are given together with relevant experimental considerations. A general table is included as an appendix. This contains substrate classes and resulting product classes, referring to the oxidative procedures in the chapters. The table provides the synthetic organic chemist with a quick overview of oxidation possibilities with metal-contain ing oxidants, enabling him to select the right method for his purpose. The editors hope that not only organic research chemists in industry and at universities, but also advanced undergraduate and graduate students in organic chemistry, will find this book a useful guide in the design, understanding, and practical performance of oxidative organic syntheses. The editors are grateful to the authors not only for their contributions. containing interesting new developments in oxidation chemistry, but also for the way they fitted the text into the general framework given for the book. Their suggestions and comments are gratefully acknowledged. Thanks are also due to Mrs. A. I. Rohnstrom-Ouwejan, secretary to the editors, for her administrative support.

Download or read book Organic Synthesis with Palladium Compounds written by Jiro Tsuji and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 221 pages. Available in PDF, EPUB and Kindle. Book excerpt: Around 30 years ago the transition metal chemistry received great impulses. In the focus have been reactions of nickel and cobalt and herein especially their carbonyls. Also industrial processes have been developed. When the technical oxidation of ethylene with palladium chloride had been discovered, and a great number oflaboratory reactions, many groups have turned towards this subject. Apart from two important industrial processes - acetaldehyde and vinylacetate from ethylene - a great number of conversions and catalytic reactions with palladium compounds have been researched. Their mechanisms have been cleared up and have con tributed to a better understanding of the complex chemistry of palladium. Last but not least these reactions have also served for more understanding of organic transition metal compounds and catalyses in general. Numerous conventional reactions appear today in a different light. The effects of co-

Download or read book Organic Syntheses with Noble Metal Catalysts written by Paul N. Rylander and published by Elsevier. This book was released on 2012-12-02 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Chemistry, Volume 28: Organic Syntheses with Noble Metal Catalysts provides information pertinent to the catalysis by noble metals, which is presented in a form as to be of use to those interested in organic synthesis. This book discusses the mechanistic aspects of reactions. Organized into nine chapters, this volume begins with an overview of catalytic dehydrogenation over platinum metals, which provides a convenient method for synthesis of organic compounds. This text then examines the mechanisms and kinetics of homogeneous hydrogenation. Other chapters consider the oxidation of organic compounds in the presence of noble metal catalysts that may affect a variety of changes, including introduction of alcohol, epoxide, carbonyl, and halogen functions into the molecule. This book discusses as well the differences between osmium tetroxide and ruthenium tetroxide in their reactions with organic compounds. The final chapter deals with noble metal catalysts. This book is a valuable resource for synthetic organic chemists.

Download or read book Metal Catalyzed Oxidations of Organic Compounds written by Roger Sheldon and published by Elsevier. This book was released on 2012-12-02 with total page 447 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic focuses on the oxidative transformations of functional groups. This book explores oxidation as being extensively used in the laboratory synthesis of fine organic chemicals and in the manufacture of large-volume petrochemicals. Organized into two parts encompassing 13 chapters, this book starts with an overview of the mechanistic principles of oxidation–reduction in biochemical, organic, and inorganic systems. This text then proceeds with a discussion of the use of molecular oxygen, hydrogen peroxide, and alkyl hydroperoxides as primary oxidants. Other chapters explore stoichiometric oxidations with metal oxidants, which include permanganate and chromic acid. This book discusses as well the synthetic applications of catalytic oxidations as well as the technology of petrochemical oxidation. The final chapter deals with the autoxidations of sulfur, phosphorus, and nitrogen compounds. This book is intended for chemists involved in organic synthesis, catalysis, and organometallic chemistry, both in academic institutions and in industrial laboratories.

Download or read book New Pathways for Organic Synthesis written by H.M. Colquhoun and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 459 pages. Available in PDF, EPUB and Kindle. Book excerpt: The continually growing contribution of transition metal chemistry to synthetic organic chemistry is, of course, widely recognized. Equally well known is the difficulty in keeping up-to-date with the multifarious reactions and procedures that seem to be spawned at an ever-increasing rate. These can certainly be summarized on the basis of reviews under the headings of the individual transition metals. More useful to the bench organic chemist, however, would be the opposite type of concordance based on the structural type of the desired synthetic product. This is the approach taken in the present monograph, which presents for each structural entity a conspectus of the transition metal-mediated processes that can be employed in its production. The resulting comparative survey should be a great help in devising the optimum synthetic approach for a particular goal. It is presented from an essentially practical viewpoint, with detailed direc tions interspersed in the Houben-Weyl style. The wide scope of the volume should certainly encourage synthetic organic chemists to utilize fully the range and versatility of these transition metal-mediated processes. This will certainly be a well-thumbed reference book! R. A. RAPHAEL Cambridge University v Preface In recent years an enormous amount of work has been done on the catalysis of organic reactions by various transition metal species and on the organic reactivity of organo-transition-metal compounds.

Download or read book Green Oxidation in Organic Synthesis written by Ning Jiao and published by John Wiley & Sons. This book was released on 2019-07-13 with total page 701 pages. Available in PDF, EPUB and Kindle. Book excerpt: A valuable introduction to green oxidation for organic chemists interested in discovering new strategies and new reactions for oxidative synthesis Green Oxidation in Organic Synthesis provides a comprehensive introduction and overview of chemical preparation by green oxidative processes, an entry point to the growing journal literature on green oxidation in organic synthesis. It discusses both experimental and theoretical approaches for the study of new catalysts and methods for catalytic oxidation and selective oxidation. The book highlights the discovery of new reactions and catalysts in recent years, discussing mechanistic insights into the green oxidative processes, as well as applications in organic synthesis with significant potential to have a major impact in academia and industry. Chapters are organized according to the functional groups generated in the reactions, presenting interesting achievements for functional group formation by green oxidative processes with O2, H2O2, photocatalytic oxidation, electrochemical oxidation, and enzymatic oxidation. The mechanisms of these novel transformations clearly illustrated. Green Oxidation in Organic Synthesis will serve as an excellent reference for organic chemists interested in discovering new strategies for oxidative synthesis which address the priorities of green and sustainable chemistry.

Download or read book Liquid Phase Oxidation via Heterogeneous Catalysis written by Mario G. Clerici and published by John Wiley & Sons. This book was released on 2013-04-26 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sets the stage for environmentally friendly industrial organic syntheses From basic principles to new and emerging industrial applications, this book offers comprehensive coverage of heterogeneous liquid-phase selective oxidation catalysis. It fully examines the synthesis, characterization, and application of catalytic materials for environmentally friendly organic syntheses. Readers will find coverage of all the important classes of catalysts, with an emphasis on their stability and reusability. Liquid Phase Oxidation via Heterogeneous Catalysis features contributions from an international team of leading chemists representing both industry and academia. The book begins with a chapter on environmentally benign oxidants and then covers: Selective oxidations catalyzed by TS-1 and other metal-substituted zeolites Selective catalytic oxidation over ordered nanoporous metallo-aluminophosphates Selective oxidations catalyzed by mesoporous metal-silicates Liquid phase oxidation of organic compounds by supported metal-based catalysts Selective liquid phase oxidations in the presence of supported polyoxometalates Selective oxidations catalyzed by supported metal complexes Liquid phase oxidation of organic compounds by metal-organic frameworks Heterogeneous photocatalysis for selective oxidations with molecular oxygen All the chapters dedicated to specific types of catalysts follow a similar organization and structure, making it easy to compare the advantages and disadvantages of different catalysts. The final chapter examines the latest industrial applications, such as the production of catechol and hydroquinone, cyclohexanone oxime, and propylene oxide. With its unique focus on liquid phase heterogeneous oxidation catalysis, this book enables researchers in organic synthesis and oxidation catalysis to explore and develop promising new catalytic materials and synthetic routes for a broad range of industrial applications.

Download or read book Science of Synthesis Catalytic Oxidation in Organic Synthesis written by Kilian Muñiz and published by Thieme. This book was released on 2018-03-23 with total page 1425 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development of catalytic systems for the oxidation of organic compounds continues to be of great importance. There is an ongoing and increasing demand for methods that are selective, proceed under mild conditions, and adhere to green chemistry principles. "Science of Synthesis: Catalytic Oxidation in Organic Synthesis" includes the latest developments in the field, as well as selective coverage of more well-established methods. Systems based on metal catalysts, organocatalysts, and biomimetic oxidation are covered, and there is a particular focus on asymmetric processes. Scope, limitations, and mechanism of the reactions are discussed and key experimental procedures are included. Typical examples of target synthesis are often provided to show the utility and inspire further applications.

Download or read book Organometallic Syntheses written by R. Bruce King and published by Elsevier. This book was released on 2013-10-22 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over 160 detailed and tested procedures for the preparation of specific organometallic compounds are given in Volume 4. Part I contains procedures for the synthesis of 76 types of transition metal organometallic compounds, and Part II procedures for the synthesis of 85 nontransition metal organometallic compounds. In both parts, the editors have sought to include procedures that give the safe, reliable synthesis of organometallic compounds that can lay some claim to significance in current chemical research. This significance may be based on various factors such as: (a) the synthesis describes the formation of an unusual or less common structural type; (b) the compound prepared is a useful intermediate in other syntheses; (c) the compound is a model reagent for investigating the mechanisms of various fundamental or industrial processes, such as the Fischer-Tropsch reaction; (d) the compound is a useful reagent in organic synthesis; and (e) the techniques employed in the synthesis of the compound are unusual and worthy of further application, such as metal-atom and electrochemical procedures.Each specific or generalized procedure is organized into the following sections: an Introduction which discusses the available procedures and the reasons guiding the choice of the one selected; a Procedure section which strives to describe the modus operandi, the safety concerns and pitfalls in the preparation; a Properties section that offers further physical and chemical data on the product and, where appropriate, indications of how the compounds can be employed in research; and a Reference section which gives both leading literature citations and supplemental comments on the procedure.Research laboratories in organometallic chemistry, organic chemistry, inorganic chemistry and molecular catalysis have in this book a rich source of information on the preparation of organometallic compounds.

Download or read book Organotransition Metal Chemistry Applications to Organic Synthesis written by S. G. Davies and published by Elsevier. This book was released on 2013-10-22 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt: Although organotransition metal chemistry has been developing rapidly over the past 20 years, it is only recently that applications of transition metal complexes to organic synthesis have started to be exploited. This unique book provides an introduction to organometallic chemistry for chemists who have little or no experience in the field, describes the work that has already been done using organotransition metal complexes for synthesis, and indicates to organic and organometallic chemists the type of synthetic problems that can be solved using organometallic compounds. It covers all major advances that have been made in this rapidly expanding area of chemistry, including not only reactions that already have well established applications for synthesis but also many recently discovered potentially useful reactions, providing a survey of recent literature.

Download or read book Catalysis in Organic syntheses 1977 written by Gerard Smith and published by Elsevier. This book was released on 2012-12-02 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysis in Organic Syntheses 1977 is a collection of papers presented at the Sixth Conference on Catalysis in Organic Syntheses, held in Boston by the Organic Reactions Catalysis Society on May 10-11, 1976. This book contains 15 chapters that specifically consider the homogeneous and heterogeneous aspects of catalysis. The chapters are organized to deal with a specific catalytic reaction, the catalysts used, and the effect of selected process parameters. This text considers the hydrogenation, aromatic, hydrogenolysis, selective oxidation, substitution, and hydroformylation reactions. The concluding chapter describes syntheses and reaction of various organic compounds, with particular emphasis on the reactions with carbon tetrachloride and other perhalomethanes. This book will be of benefit to organic chemists and researchers.

Download or read book Main Group Metals in Organic Synthesis written by Hisashi Yamamoto and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 905 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the first handbook to cover in detail all aspects of this fascinating field of chemistry. In this handy two-volume set, readers will instantly find the information they need, clearly structured according to the individual metals in the main groups, hitherto only accessible after much time-consuming research. The result is in indispensable aid for everyday work in the lab. Alongside all the classical organic reactions, this book focuses on the modern variations as well as novel, current reactions in organic synthesis that are closely linked to main group elements - both stoechiometric and catalytic. With this work the two prizewinning editors have succeeded in producing a comprehensive compendium of the main group metals as reagents for organic reactions. In short, this is a must for every organic chemist, whether as an efficient introduction to current research, for retaining an overview or for looking up detailed information.

Download or read book Main Group Metal Organometallics in Organic Synthesis written by A. McKillop and published by Elsevier. This book was released on 2004-09-16 with total page 698 pages. Available in PDF, EPUB and Kindle. Book excerpt: The individual chapters in this volume cover the scope and impact of main group organometallic compounds and reagents on organic synthesis during the last ten to fifteen years. In a number of chapters, topics are dealt with in detail that either were not covered at all in COMC (eg selenium, tellurium) or were given scant attention (eg oxymercuration, organoantimony compounds). Certain topics, like directed metallation and LiKOR bases have only achieved prominence in synthesis in the last ten years, and are now reviewed by leading experts.

Download or read book Oxidation in Organic Synthesis written by V. K. Ahluwalia and published by CRC Press. This book was released on 2012-02-13 with total page 323 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxidation plays a crucial role in organic synthesis. This volume presents the array of oxidizing agents and their applications in oxidations. The book describes in great detail a number of reagents of importance. The text includes oxidation of specific types of organic compounds including hydrocarbons, alcohols, phenols, ethers, carbonyl compounds, carboxylic acids, amides, hydrazides, nitro compounds, nitroso compounds, hydroxylamines, azo compounds, azides, hydrazo compounds, amines, phosphorus, arsenic and sulphur compounds. It also covers enzymatic or microbial oxidations as well as oxidations under benign conditions.

Download or read book Catalytic Oxidation Reagents written by Philip L. Fuchs and published by John Wiley & Sons. This book was released on 2013-07-29 with total page 2037 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook is part of the Handbook of Reagents for Organic Chemistry series, aiming at collecting articles on a particular theme that individual researchers in academia or industry can use on a daily basis. The Handbook starts with a section discussing the most important aspects of heteroarene functionalization. The introduction is followed by the alphabetical listing of the most relevant reagents drawn from the EROS database. The Editor, André Charette from the University of Montreal, has selected 120 reagent descriptions, many of them updated with heteroarene-specific reactions for this Handbook. Following the standard format for EROS, each article contains an overview of the synthesis and physical properties of the reagents or catalyst, conditions for its storage, and purification methods. Given the importance of heteroarenes in biology and especially in medicinal chemistry, a Handbook that focuses exclusively on heteroarene functionalization has been long overdue. This Handbook will have a broad appeal to many individuals engaged in the area of medicinal chemistry, fine chemical synthesis and industrial-scale chemistry. Key features: Builds on the success of the previously published Handbooks of Reagents for Organic Synthesis Compares the numerous new C-H functionalization reactions that have been developed in the past decade Heteroarene functionalization is widely used in the development of pharmaceuticals and other bioactive compounds Contains listings of secondary reagents for which more information is available in the online edition

Download or read book Metal catalyzed Oxidations of Organic Compounds written by Roger A. Sheldon and published by . This book was released on 1981 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic focuses on the oxidative transformations of functional groups. This book explores oxidation as being extensively used in the laboratory synthesis of fine organic chemicals and in the manufacture of large-volume petrochemicals. Organized into two parts encompassing 13 chapters, this book starts with an overview of the mechanistic principles of oxidation-reduction in biochemical, organic, and inorganic systems. This text then proceeds with a discussion of the use of molecular oxygen, hydrogen peroxide, and alkyl hydroperoxides as primary oxidants. Other chapters explore stoichiometric oxidations with metal oxidants, which include permanganate and chromic acid. This book discusses as well the synthetic applications of catalytic oxidations as well as the technology of petrochemical oxidation. The final chapter deals with the autoxidations of sulfur, phosphorus, and nitrogen compounds.

Download or read book Organic Synthesis by Means of Transition Metal Complexes written by Jiro Tsuji and published by . This book was released on 1975 with total page 199 pages. Available in PDF, EPUB and Kindle. Book excerpt: