Download or read book Numerical Modeling of Interface Dynamics and Transport Phenomena in Transport limited Electrolysis Processes written by Wanida Pongsaksawad and published by . This book was released on 2006 with total page 117 pages. Available in PDF, EPUB and Kindle. Book excerpt: (Cont.) A new stability criterion for metal reduction in a liquid-liquid system is derived and agrees well with the model results. Next, the phase field model is extended for a ternary system to model titanium reduction in a supported electrolyte system. The model can simulate phase boundaries migration depending on the composition of the electrolyte and also electronically mediated reactions. Finally, Solid Oxide Membrane Electrolytic Smelting with Rotating Cathode (SOMERC), an emerging technology to electrolytically reduce titanium oxide from molten salt, is investigated. In the SOMERC process, rotational flow is introduced to create shear force that is expected to stabilize the interface. Computational fluid dynamics models of rotational flow are carried out to estimate the relationship between cathode rotational speed, shear strain rate, and boundary layer thicknesses. The phase field model presented in this thesis can be applied to any electrochemical reduction processes that are in the mass-transport controlled regime. Stability criteria and detailed morphology in two and three dimensions can be explored.
Download or read book Modeling of Carrier Transport Phenomena at Photocatalytic Semiconductor liquid Interfaces written by Asif Iqbal and published by . This book was released on 2019 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: "The conversion of solar energy into a carbon-free chemical form of fuel comprises a key constituent of the economic paradigm based on renewable energy. Throughout the last two decades, the growing and pervasive impact of anthropogenic climate change continue to drive the demand for efficient, eco-friendly and large-scale solar- to-chemical fuel conversion. In the same spirit, solar-assisted water splitting, by utilizing light-absorbing and earth-abundant semiconductors, is of paramount interest as it can delineate a route to low-cost and scalable production of H2-fuel and possibly serve as the backbone of a renewable economic paradigm. Nevertheless, inadequate understanding of the intricate charge transfer processes governing semiconductor photocatalysis significantly impedes the realization of cost-competitive monolithic photoelectrodes pertaining to solar water splitting in an unassisted fashion. Extensive ongoing research in this direction has outlined critical scientific problems that entail urgent resolution through combined theoretical and experimental efforts. The research in this dissertation demonstrates numerical modeling of an archetypical semiconductor-aqueous electrolyte junction and theoretically probes the electrostatics and charge transport processes determining interfacial photoelectrochemical performance. Our numerical approach concomitantly incorporates the drift-diffusion methods developed for the solid state semiconductor devices with the Gouy-Chapman- Stern model for aqueous electrolyte. This research, along with the complete numerical description of the system, tackles some of the key numerical problems related to the semiclassical modeling of the photocatalytic semiconductor-liquid junctions. To numerically capture both the photovoltage and photocurrent at semiconductor-liquid interfaces we show that it is necessary to simultaneously solve both the majority and minority carrier transport equations. The solutions of the minority and majority carrier transport equations are needed to respectively calculate the interfacial photocurrent and photovoltage. In this regard, a floating boundary condition for the electrostatic potential in the bulk and a pseudo-Schottky boundary conditions for the interfacial electron and hole currents must also be imposed. In addition, this work also extends the scope of the semiclassical modeling in theoretically exploring the phenomena due to the presence of surface states and bulk trap states. By utilizing a distinct Fermi-level for surface state occupation, this work provides insights regarding the equilibration of surface states and unravels the non-trivial trends in Mott-Schottky analysis. Conversely, computational studies regarding the impact of bulk trapping of the carriers are shown to demonstrate severe degradation of the maximum attainable photovoltage along with poor majority carrier conduction properties. Furthermore, the utility of the methodology is demonstrated by correlating theoretical calculations with experimental measurements reported in the literature. This includes, but is not limited to: computation of the photovoltage, onset and saturation of the photocurrent, interfacial transfer and bulk relaxation of the minority carriers, various generation/recombination processes, impacts of surface states and bulk trap states, Mott-Schottky analysis and capacitance spectroscopy, charge screening at the photo- electrochemical interface, and the suppression of back-reactions. Finally, our results decouple the interfacial transfer of the minority carriers from the recombination at the interface/space charge region, underscore the significance of bulk processes and elucidate possible methods to engineer the transfer process at water splitting electrodes. In general, this work is intended to expand the scope of photocatalytic device design tools and thereby aid the design of the practical photoelectrodes en route to unassisted solar water splitting" --
Download or read book Electrokinetic and Colloid Transport Phenomena written by Jacob H. Masliyah and published by John Wiley & Sons. This book was released on 2006-05-26 with total page 733 pages. Available in PDF, EPUB and Kindle. Book excerpt: A new, definitive perspective of electrokinetic and colloid transport processes Responding to renewed interest in the subject of electrokinetics, Electrokinetic and Colloid Transport Phenomena is a timely overview of the latest research and applications in this field for both the beginner and the professional. An outgrowth of an earlier text (by coauthor Jacob Masliyah), this self-contained reference provides an up-to-date summary of the literature on electrokinetic and colloid transport phenomena as well as direct pedagogical insight into the development of the subject over the past several decades. A distinct departure from standard colloid science monographs, Electrokinetic and Colloid Transport Phenomena presents the most salient features of the theory in a simple and direct manner, allowing the book to serve as a stepping-stone for further learning and study. In addition, the book uniquely discusses numerical simulation of electrokinetic problems and demonstrates the use of commercial finite element software for solving these multiphysics problems. Among the topics covered are: * Mathematical preliminaries * Colloidal systems * Electrostatics and application of electrostatics * Electric double layer * Electroosmosis and streaming potential * Electrophoresis and sedimentation potential * London-Van der Waals forces and the DLVO theory * Coagulation and colloid deposition * Numerical simulation of electrokinetic phenomena * Applications of electrokinetic phenomena Because this thorough reference does not require advanced mathematical knowledge, it enables a graduate or a senior undergraduate student approaching the subject for the first time to easily interpret the theories. On the other hand, the application of relevant mathematical principles and the worked examples are extremely useful to established researchers and professionals involved in a wide range of areas, including electroosmosis, streaming potential, electrophoretic separations, industrial practices involving colloids and complex fluids, environmental remediation, suspensions, and microfluidic systems.
Download or read book Transport Phenomena in Materials Processing written by David R. Poirier and published by Springer. This book was released on 2016-12-06 with total page 652 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text provides a teachable and readable approach to transport phenomena (momentum, heat, and mass transport) by providing numerous examples and applications, which are particularly important to metallurgical, ceramic, and materials engineers. Because the authors feel that it is important for students and practicing engineers to visualize the physical situations, they have attempted to lead the reader through the development and solution of the relevant differential equations by applying the familiar principles of conservation to numerous situations and by including many worked examples in each chapter. The book is organized in a manner characteristic of other texts in transport phenomena. Section I deals with the properties and mechanics of fluid motion; Section II with thermal properties and heat transfer; and Section III with diffusion and mass transfer. The authors depart from tradition by building on a presumed understanding of the relationships between the structure and properties of matter, particularly in the chapters devoted to the transport properties (viscosity, thermal conductivity, and the diffusion coefficients). In addition, generous portions of the text, numerous examples, and many problems at the ends of the chapters apply transport phenomena to materials processing.
Download or read book PEM Water Electrolysis written by Dmitri Bessarabov and published by Academic Press. This book was released on 2018-08-04 with total page 140 pages. Available in PDF, EPUB and Kindle. Book excerpt: PEM Water Electrolysis, a volume in the Hydrogen Energy and Fuel Cell Primers series presents the most recent advances in the field. It brings together information that has thus far been scattered in many different sources under one single title, making it a useful reference for industry professionals, researchers and graduate students. Volumes One and Two allow readers to identify technology gaps for commercially viable PEM electrolysis systems for energy applications and examine the fundamentals of PEM electrolysis and selected research topics that are top of mind for the academic and industry community, such as gas cross-over and AST protocols. The book lays the foundation for the exploration of the current industrial trends for PEM electrolysis, such as power to gas application and a strong focus on the current trends in the application of PEM electrolysis associated with energy storage. - Presents the fundamentals and most current knowledge in proton exchange membrane water electrolyzers - Explores the technology gaps and challenges for commercial deployment of PEM water electrolysis technologies - Includes unconventional systems, such as ozone generators - Brings together information from many different sources under one single title, making it a useful reference for industry professionals, researchers and graduate students alike
Download or read book Supercapacitors written by Francois Beguin and published by John Wiley & Sons. This book was released on 2013-04-02 with total page 596 pages. Available in PDF, EPUB and Kindle. Book excerpt: Supercapacitors are a relatively new energy storage system that provides higher energy density than dielectric capacitors and higher power density than batteries. They are particularly suited to applications that require energy pulses during short periods of time, e.g., seconds or tens of seconds. They are recommended for automobiles, tramways, buses, cranes, fork-lifts, wind turbines, electricity load leveling in stationary and transportation systems, etc. Despite the technological maturity of supercapacitors, there is a lack of comprehensive literature on the topic. Many high performance materials have been developed and new scientific concepts have been introduced. Taking into account the commercial interest in these systems and the new scientific and technological developments now is the ideal time to publish this book, capturing all this new knowledge. The book starts by giving an introduction to the general principles of electrochemistry, the properties of electrochemical capacitors, and electrochemical characterization techniques. Electrical double layer capacitors and pseudocapacitors are then discussed, followed by the various electrolyte systems. Modelling, manufacture of industrial capacitors, constraints, testing, and reliability as well as applications are also covered. 'Supercapacitors - Materials, Systems, and Applications' is part of the series on Materials for Sustainable Energy and Development edited by Prof. G.Q. Max Lu. The series covers advances in materials science and innovation for renewable energy, clean use of fossil energy, and greenhouse gas mitigation and associated environmental technologies.
Download or read book Systems Electrochemistry written by I. Kiss and published by The Electrochemical Society. This book was released on 2015-04-30 with total page 27 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Computational Heat Transfer written by Yogesh Jaluria and published by Routledge. This book was released on 2017-10-19 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: This new edition updated the material by expanding coverage of certain topics, adding new examples and problems, removing outdated material, and adding a computer disk, which will be included with each book. Professor Jaluria and Torrance have structured a text addressing both finite difference and finite element methods, comparing a number of applicable methods.
Download or read book Plasma Chemistry written by Alexander Fridman and published by Cambridge University Press. This book was released on 2008-05-05 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing a fundamental introduction to all aspects of modern plasma chemistry, this book describes mechanisms and kinetics of chemical processes in plasma, plasma statistics, thermodynamics, fluid mechanics and electrodynamics, as well as all major electric discharges applied in plasma chemistry. Fridman considers most of the major applications of plasma chemistry, from electronics to thermal coatings, from treatment of polymers to fuel conversion and hydrogen production and from plasma metallurgy to plasma medicine. It is helpful to engineers, scientists and students interested in plasma physics, plasma chemistry, plasma engineering and combustion, as well as chemical physics, lasers, energy systems and environmental control. The book contains an extensive database on plasma kinetics and thermodynamics and numerical formulas for practical calculations related to specific plasma-chemical processes and applications. Problems and concept questions are provided, helpful in courses related to plasma, lasers, combustion, chemical kinetics, statistics and thermodynamics, and high-temperature and high-energy fluid mechanics.
Download or read book Theoretical Chemical Engineering Abstracts written by and published by . This book was released on 1982 with total page 630 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Particle Image Velocimetry written by Markus Raffel and published by Springer Science & Business Media. This book was released on 2007-08-09 with total page 460 pages. Available in PDF, EPUB and Kindle. Book excerpt: This immensely practical guide to PIV provides a condensed, yet exhaustive guide to most of the information needed for experiments employing the technique. This second edition has updated chapters on the principles and extra information on microscopic, high-speed and three component measurements as well as a description of advanced evaluation techniques. What’s more, the huge increase in the range of possible applications has been taken into account as the chapter describing these applications of the PIV technique has been expanded.
Download or read book Electrochemical Methods written by Allen J. Bard and published by Wiley Global Education. This book was released on 2012-04-13 with total page 862 pages. Available in PDF, EPUB and Kindle. Book excerpt: Das führende Werk auf seinem Gebiet - jetzt durchgängig auf den neuesten Stand gebracht! Die theoretischen Grundlagen der Elektrochemie, erweitert um die aktuellsten Erkenntnisse in der Theorie des Elektronentransfers, werden hier ebenso besprochen wie alle wichtigen Anwendungen, darunter modernste Verfahren (Ultramikroelektroden, modifizierte Elektroden, LCEC, Impedanzspektrometrie, neue Varianten der Pulsvoltammetrie und andere). In erster Linie als Lehrbuch gedacht, läßt sich das Werk aber auch hervorragend zum Selbststudium und zur Auffrischung des Wissensstandes verwenden. Lediglich elementare Grundkenntnisse der physikalischen Chemie werden vorausgesetzt.
Download or read book Micro and Nanoscale Fluid Mechanics written by Brian J. Kirby and published by Cambridge University Press. This book was released on 2010-07-26 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text focuses on the physics of fluid transport in micro- and nanofabricated liquid-phase systems, with consideration of gas bubbles, solid particles, and macromolecules. This text was designed with the goal of bringing together several areas that are often taught separately - namely, fluid mechanics, electrodynamics, and interfacial chemistry and electrochemistry - with a focused goal of preparing the modern microfluidics researcher to analyse and model continuum fluid mechanical systems encountered when working with micro- and nanofabricated devices. This text serves as a useful reference for practising researchers but is designed primarily for classroom instruction. Worked sample problems are included throughout to assist the student, and exercises at the end of each chapter help facilitate class learning.
Download or read book Active Protective Coatings written by Anthony E. Hughes and published by Springer. This book was released on 2016-03-01 with total page 429 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers a broad range of materials science that has been brought to bear on providing solutions to the challenges of developing self-healing and protective coatings for a range of metals. The book has a strong emphasis on characterisation techniques, particularly new techniques that are beginning to be used in the coatings area. It features many contributions written by experts from various industrial sectors which examine the needs of the sectors and the state of the art. The development of self-healing and protective coatings has been an expanding field in recent years and applies a lot of new knowledge gained from other fields as well as other areas of materials science to the development of coatings. It has borrowed from fields such as the food and pharmaceutical industries who have used, polymer techniques, sol-gel science and colloidosome technology for a range encapsulation techniques. It has also borrowed from fields like hydrogen storage such as from the development of hierarchical and other materials based on organic templating as “nanocontainers” for the delivery of inhibitors. In materials science, recent developments in high throughput and other characterisation techniques, such as those available from synchrotrons, are being increasing used for novel characterisation – one only needs to look at the application of these techniques in self healing polymers to gauge wealth of new information that has been gained from these techniques. This work is largely driven by the need to replace environmental pollutants and hazardous chemicals that represent risk to humans such as chromate inhibitors which are still used in some applications.
Download or read book Fundamentals of Electromigration Aware Integrated Circuit Design written by Jens Lienig and published by Springer. This book was released on 2018-02-23 with total page 171 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book provides a comprehensive overview of electromigration and its effects on the reliability of electronic circuits. It introduces the physical process of electromigration, which gives the reader the requisite understanding and knowledge for adopting appropriate counter measures. A comprehensive set of options is presented for modifying the present IC design methodology to prevent electromigration. Finally, the authors show how specific effects can be exploited in present and future technologies to reduce electromigration’s negative impact on circuit reliability.
Download or read book Gas Transport in Solid Oxide Fuel Cells written by Weidong He and published by Springer. This book was released on 2014-09-03 with total page 87 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive overview of contemporary research and emerging measurement technologies associated with gas transport in solid oxide fuel cells. Within these pages, an introduction to the concept of gas diffusion in solid oxide fuel cells is presented. This book also discusses the history and underlying fundamental mechanisms of gas diffusion in solid oxide fuel cells, general theoretical mathematical models for gas diffusion, and traditional and advanced techniques for gas diffusivity measurement.
Download or read book Lattice Boltzmann Modeling written by Michael C. Sukop and published by Springer Science & Business Media. This book was released on 2007-04-05 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt: Here is a basic introduction to Lattice Boltzmann models that emphasizes intuition and simplistic conceptualization of processes, while avoiding the complex mathematics that underlies LB models. The model is viewed from a particle perspective where collisions, streaming, and particle-particle/particle-surface interactions constitute the entire conceptual framework. Beginners and those whose interest is in model application over detailed mathematics will find this a powerful 'quick start' guide. Example simulations, exercises, and computer codes are included.
