Download or read book Nanoporous Catalysts for Biomass Conversion written by Feng-Shou Xiao and published by John Wiley & Sons. This book was released on 2017-09-05 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive introduction to the design, synthesis, characterization, and catalytic properties of nanoporous catalysts for the biomass conversion With the specter of peak oil demand looming on the horizon, and mounting concerns over the environmental impact of greenhouse gas emissions, biomass has taken on a prominent role as a sustainable alternative fuel source. One critical aspect of the biomass challenge is the development of novel catalytic materials for effective and controllable biomass conversion. Edited by two scientists recognized internationally for their pioneering work in the field, this book focuses on nanoporous catalysts, the most promising class of catalytic materials for the conversion of biomass into fuel and other products. Although various catalysts have been used in the conversion of biomass-derived feedstocks, nanoporous catalysts exhibit high catalytic activities and/or unique product selectivities due to their large surface area, open nanopores, and highly dispersed active sites. This book covers an array of nanoporous catalysts currently in use for biomass conversion, including resins, metal oxides, carbons, mesoporous silicates, polydivinylbenzene, and zeolites. The authors summarize the design, synthesis, characterization and catalytic properties of these nanoporous catalysts for biomass conversions, discussing the features of these catalysts and considering future opportunities for developing more efficient catalysts. Topics covered include: Resins for biomass conversion Supported metal oxides/sulfides for biomass oxidation and hydrogenation Nanoporous metal oxides Ordered mesoporous silica-based catalysts Sulfonated carbon catalysts Porous polydivinylbenzene Aluminosilicate zeolites for bio-oil upgrading Rice straw Hydrogenation for sugar conversion Lignin depolymerization Timely, authoritative, and comprehensive, Nanoporous Catalysts for Biomass Conversion is a valuable working resource for academic researchers, industrial scientists and graduate students working in the fields of biomass conversion, catalysis, materials science, green and sustainable chemistry, and chemical/process engineering.

Download or read book Nanoporous Materials for Energy and the Environment written by Gilbert Rios and published by CRC Press. This book was released on 2016-04-19 with total page 317 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book disseminates and discusses relevant best case examples and research practices that show how nanomaterial research and related engineering concepts may provide answers and viable solutions to a variety of socioeconomic issues and concerns. The first section is dedicated to the development of new materials and their characterization. The se

Download or read book Nanoporous Solid Acid Materials for Biomass Conversion Into Value added Chemicals written by Hong Je Cho and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Growing environmental concerns associated with diminishing reserves of fossil fuels has led to accelerated research efforts towards the discovery of new catalytic processes for converting renewable lignocellulosic biomass into value-added chemicals. For this conversion, nanoporous solid acid materials have been widely used because of their excellent hydrothermal stability and molecular sieving capability. In the thesis, hierarchical Lewis acid zeolites with ordered mesoporosity and MFI topology (three dimensionally ordered mesoporous imprinted (3DOm-i) Sn-MFI) were successfully synthesized within the confined space of three dimensionally ordered mesoporous (3DOm) carbon by a seeded growth method. The obtained 3DOm-i Sn-MFI showed at least 3 times higher catalytic activities for the biomass-derived sugar isomerization than conventional Sn-MFI zeolites. This is because the mesopores in the hierarchical zeolites greatly enhance molecular transport. In addition, Lewis acid Sn-MFI combined with Pt metal nanoparticles (Pt/Sn-MFI) could oxidize glycerol to produce lactic acid (LA) under base-free conditions. Glycerol is a by-product in biodiesel synthesis. 80.5% selectivity of LA was achieved at 89.8% conversion of glycerol using a bifunctional Pt/Sn-MFI catalyst under base-free conditions. In the tandem reaction pathway, selective oxidation of glycerol to glyceraldehyde (GLA) and dihydroxyacetone (DHA) by using Pt catalysts was cascaded with Lewis acid catalyzed isomerization of GLA/DHA into LA. Moreover, morphology-tunable Lewis acid Sn-BEA with hydrophobicity was successfully synthesized by recrystallization of post-synthesized Sn-BEA (Sn-BEA-PS) using ammonium fluoride (NH4F) and tetraethylammonium bromide (TEABr). This recrystallization includes simultaneous procedures of dissolution-reassembly: i) the dissolution of Si-O bonds around silanol nests by fluoride ions, and ii) the reassembly of fragmented silica species into defect-free zeolite framework in the presence of TEA ions. The recrystallization also increased open Lewis acid Sn sites. These findings can explain why a 2.5 times higher rate of aqueous glucose isomerization was achieved on recrystallized Sn-BEA (Sn-BEA-RC), compared with Sn-BEA-PS. Moreover, in the isomerization of bulky lactose (C12 sugar) dissolved in MeOH, hierarchical Sn-BEA-RC showed a 3.2-fold higher activity than hydrothermally synthesized Sn-BEA (Sn-BEA-HF), due to the mesopores and enhanced organophobic character of the recrystallized catalyst. In the final part, renewable p-xylene synthesis was investigated. p-Xylene is a major commodity chemical used for the production of polyethylene terephthalate (PET) with applications in polyester fibers, films and bottles. Diels-Alder cycloaddition of 2,5-dimethylfuran (DMF) and ethylene with subsequent dehydration of the cycloadduct intermediate to produce p-xylene is an attractive reaction pathway for its production from biomass feedstocks. It was shown that phosphorous-containing zeolite BEA (P-BEA) is active, stable and selective for this reaction with an unprecedented p-xylene yield of 97%. It can selectively catalyze the dehydration reaction from the furan-ethylene cycloadduct to p-xylene, without performing side reactions which include alkylation and oligomerization. This acid catalyst establishes a commercially attractive process for renewable p-xylene production.

Download or read book Nanoporous Materials for Molecule Separation and Conversion written by Jian Liu and published by Elsevier. This book was released on 2020-07-04 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanoporous Materials for Molecule Separation and Conversion cover the topic with sections on nanoporous material synthesis and characterization, nanoporous materials for molecule separation, and nanoporous materials for energy storage and renewable energy. Typical nanoporous materials including carbon, zeolite, silica and metal-organic frameworks and their applications in molecule separation and energy related applications are covered. In addition, the fundamentals of molecule adsorption and molecule transport in nanoporous materials are also included, providing readers with a stronger understanding of the principles and topics covered. This is an important reference for anyone exploring nanoporous materials, including researchers and postgraduate students in materials science and chemical engineering. In addition, it is ideal for industry professionals working on a wide range of applications for nanoporous materials. Outlines the fundamental principles of nanoporous materials design Explores the application of nanoporous materials in important areas such as molecule separation and energy storage Gives real-life examples of how nanoporous materials are used in a variety of industry sector

Download or read book Chemical Catalysts for Biomass Upgrading written by Mark Crocker and published by John Wiley & Sons. This book was released on 2020-03-09 with total page 634 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive reference to the use of innovative catalysts and processes to turn biomass into value-added chemicals Chemical Catalysts for Biomass Upgrading offers detailed descriptions of catalysts and catalytic processes employed in the synthesis of chemicals and fuels from the most abundant and important biomass types. The contributors?noted experts on the topic?focus on the application of catalysts to the pyrolysis of whole biomass and to the upgrading of bio-oils. The authors discuss catalytic approaches to the processing of biomass-derived oxygenates, as exemplified by sugars, via reactions such as reforming, hydrogenation, oxidation, and condensation reactions. Additionally, the book provides an overview of catalysts for lignin valorization via oxidative and reductive methods and considers the conversion of fats and oils to fuels and terminal olefins by means of esterification/transesterification, hydrodeoxygenation, and decarboxylation/decarbonylation processes. The authors also provide an overview of conversion processes based on terpenes and chitin, two emerging feedstocks with a rich chemistry, and summarize some of the emerging trends in the field. This important book: -Provides a comprehensive review of innovative catalysts, catalytic processes, and catalyst design -Offers a guide to one of the most promising ways to find useful alternatives for fossil fuel resources -Includes information on the most abundant and important types of biomass feedstocks -Examines fields such as catalytic cracking, pyrolysis, depolymerization, and many more Written for catalytic chemists, process engineers, environmental chemists, bioengineers, organic chemists, and polymer chemists, Chemical Catalysts for Biomass Upgrading presents deep insights on the most important aspects of biomass upgrading and their various types.

Download or read book Environmental Catalysis and the Corresponding Catalytic Mechanism written by Zhimin Ao and published by Frontiers Media SA. This book was released on 2019-05-15 with total page 113 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Development of Functionalized Nanoporous Materials for Biomass Transformation to Chemicals and Fuels written by and published by . This book was released on 2015 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Innovations in Thermochemical Technologies for Biofuel Processing written by Sonil Nanda and published by Elsevier. This book was released on 2022-03-15 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt: Innovations in Thermochemical Technologies for Biofuel Processing broadly covers current technologies in alternate fuels and chemical production, a few of which include biomass-to-liquid, biomass-to-gas and gas-to-liquid biomass conversion technologies. The topics in this book include elaborative discussions on biomass feedstocks, biomass-to-liquid technologies (liquefaction, pyrolysis and transesterification), biomass-to-gas technologies (gasification), gas-to-liquid technologies (syngas fermentation and Fischer-Tropsch synthesis), co-processing technologies, fuel upgrading technologies (hydrotreating and reforming), novel catalyst development for biorefining, biorefining process optimization, unit operations, reaction kinetics, artificial neural network, and much more. The book comprehensively discusses the strengths, weaknesses, opportunities and threats of notable biofuels (e.g., bio-oil, biocrude oil, biodiesel, bioethanol, biobutanol, bio-jet fuels, biohydrogen, biomethane, synthesis gas, hydrocarbon fuels, etc.). Addresses solutions for clean fuel, energy security, waste management, waste valorization, reduced greenhouse gas emissions, carbon capture and sequestration, circular economy and climate change mitigation Includes applications of thermochemical conversion and reforming technologies for waste biomass to biofuels Covers current technologies in alternate fuels and chemicals production, a few of which include conversion technologies (i.e., liquefaction, gasification, pyrolysis, torrefaction, transesterification, organic transformation, carbon-carbon and carbon-heteroatom coupling reactions, oxidation, and reforming processes, etc.), hydrotreating technologies (i.e., hydrogenation, hydrodesulfurization, hydrodenitrogenation, hydrodearomatization and hydrodemetalization) and catalytic processes.

Download or read book Handbook of Biofuels Production written by Rafael Luque and published by Woodhead Publishing. This book was released on 2016-05-19 with total page 772 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Biofuels Production, Second Edition, discusses advanced chemical, biochemical, and thermochemical biofuels production routes that are fast being developed to address the global increase in energy usage. Research and development in this field is aimed at improving the quality and environmental impact of biofuels production, as well as the overall efficiency and output of biofuels production plants. The book provides a comprehensive and systematic reference on the range of biomass conversion processes and technology. Key changes for this second edition include increased coverage of emerging feedstocks, including microalgae, more emphasis on by-product valorization for biofuels’ production, additional chapters on emerging biofuel production methods, and discussion of the emissions associated with biofuel use in engines. The editorial team is strengthened by the addition of two extra members, and a number of new contributors have been invited to work with authors from the first edition to revise existing chapters, thus offering fresh perspectives. Provides systematic and detailed coverage of the processes and technologies being used for biofuel production Discusses advanced chemical, biochemical, and thermochemical biofuels production routes that are fast being developed to address the global increase in energy usage Reviews the production of both first and second generation biofuels Addresses integrated biofuel production in biorefineries and the use of waste materials as feedstocks

Download or read book Nano and Biocatalysts for Biodiesel Production written by Avinash P. Ingle and published by John Wiley & Sons. This book was released on 2021-06-25 with total page 371 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reviews recent advances in catalytic biodiesel synthesis, highlighting various nanocatalysts and nano(bio)catalysts developed for effective biodiesel production Nano- and Biocatalysts for Biodiesel Production delivers an essential reference for academic and industrial researchers in biomass valorization and biofuel industries. The book covers both nanocatalysts and biocatalysts, bridging the gap between homogenous and heterogenous catalysis. Readers will learn about the techno-economical and environmental aspects of biodiesel production using different feedstocks and catalysts. They will also discover how nano(bio)catalysts can be used as effective alternatives to conventional catalysts in biodiesel production due to their unique properties, including reusability, high activation energy and rate of reaction, easy recovery, and recyclability. Readers will benefit from the inclusion of: Introductions to CaO nanocatalysts, zeolite nanocatalysts, titanium dioxide-based nanocatalysts and zinc-based in biodiesel production An exploration of carbon-based heterogeneous nanocatalysts for the production of biodiesel Practical discussions of bio-based nano catalysts for biodiesel production and the application of nanoporous materials as heterogeneous catalysts for biodiesel production An analysis of the techno-economical considerations of biodiesel production using different feedstocks Nano- and Biocatalysts for Biodiesel Production focuses on recent advances in the field and offers a complete and informative guide for academic researchers and industrial scientists working in the fields of biofuels and bioenergy, catalysis, biotechnology, bioengineering, nanotechnology, and materials science.

Download or read book Biomass Conversion through Nanomaterials written by Tariq Altalhi and published by Elsevier. This book was released on 2025-02-01 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biomass Conversion through Nanomaterials: Green Sustainable Process for Chemical and Environmental Engineering and Science (GSPCEES) presents the catalytic processing of biomass to produce fuels as well as chemicals. The book employs diverse monomers including glucose/fructose as well as polymers such as starch/cellulose in various catalytic processes. It shows that nanomaterials with porous structures, with increased surface areas, and acidity strengthen the catalytic roles as well as that numerous additional nanomaterials with comparable qualities, such as those based on carbon, resins, metal oxides, zeolites, silica, organic polymers, and many others, enhance the bioconversion processes of biomass. The book also highlights the importance of nanotechnology in the emergence of successful biomass for producing high-quality bioenergy and thoroughly covers varied bioenergy applications using nanomaterials. It highlights the possibility that enabling biomass through nanomaterials improves the effectiveness of various bioenergy sources, such as biofuels, microbial fuel cells, etc. After reading the book you gained a better understanding of biomass conversion using nanomaterials, its associated technologies, and its various applications.

Download or read book Nanomaterials in Biomass Conversion written by Komal Rizwan and published by Elsevier. This book was released on 2024-03-01 with total page 534 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanomaterials in Biomass Conversion: Advances and Applications for Bioenergy, Biofuels and Bio-based Products critically reviews the basic principles through to the latest advances in the emerging field of nanotechnology for the production of biofuels and bioenergy. Divided into 3 parts, the first five chapters explain the fundamentals of nanomaterials, their properties, characterization, and basic processes for synthesis. Part 2, which constitutes the majority of the book, reviews the various methods and technologies for the conversion of biomass to bioenergy, biofuels, and value-added products using nanomaterials. This includes homogeneous and heterogeneous nano-catalytic systems, nano-photocatalytic conversion, nanomaterial-assisted anaerobic digestion, nanoparticles-immobilized enzymes conversion, the production of biogas, volatile fatty acids, and value-added products, and in carbon capture and conversion to sustainable energy products, as well as the potential of nano-biochar, nano-cellulose, and other nanomaterials in microbial fuel cells, bioelectrochemical systems, and batteries. Finally, Part 3 addresses the techno-economics and financial viability in the context of the circular economy, risk related to toxicology, stability, and environmental impacts, and considers the various challenges and future opportunities of biomass conversion through nanomaterials. Nanomaterials in Biomass Conversion is an invaluable resource for researchers and engineers involved in the production of bioenergy, biofuel, and bioproducts, and will also be of benefit to those interested in environmental remediation, pollution management, and cleaner energy production. Critically examines the role of nanomaterials in the management of waste biomass as applied to bioenergy and biofuels Explains various nanotechnological methods for the conversion of waste biomass into value-added products Discusses the basic principles, operational aspects, ongoing developments, and future perspectives related to the applications of nanotechnologies and nanomaterials in biomass conversion Provides solutions to the key challenges of nanotechnologies and nanomaterials in the conversion of biomass, along with future challenges and risks

Download or read book Solid Catalysts for the Upgrading of Renewable Sources written by Nicoletta Ravasio and published by MDPI. This book was released on 2019-03-26 with total page 226 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of solid catalysts for the upgrade of renewable sources gives the opportunity to combine the two main cores of green chemistry, that is, on the one hand, the set-up of sustainable processes and, on the other, the use of biomass-derived materials. Solid catalysts have taken on a leading role in traditional petrochemical processes and could represent a key tool in new biorefinery-driven technologies. This book will cover topics related to the preparation and use of heterogeneous catalytic systems for the transformation of renewable sources, as well as of materials deriving from agro-industrial wastes and by-products. At the same time, the ever-increasing importance of bioproducts, due to the acceptance and request of consumers, makes the upgrade of biomass into chemicals and materials not only an environmental issue, but also an economical advantage.

Download or read book Heterogeneous Nanocatalysis for Energy and Environmental Sustainability Volume 1 written by Putla Sudarsanam and published by John Wiley & Sons. This book was released on 2023-01-04 with total page 420 pages. Available in PDF, EPUB and Kindle. Book excerpt: An essential companion for catalysis researchers and professionals studying economically viable and eco-friendly catalytic strategies for energy conversion In the two-volume Heterogeneous Nanocatalysis for Energy and Environmental Sustainability, a team of distinguished researchers deliver a comprehensive discussion of fundamental concepts in, and practical applications of, heterogeneous nanocatalysis for alternative energy production, biomass conversion, solar energy, green fuels, H2 production, fuel cells, electrochemical energy conversion processes, CO2 conversion, clean water, and environmental protection. The volumes cover the design and catalytic performance of various nanocatalysts, including nanosized metals and metal oxides, supported metal nanoparticles, inverse oxide-metal nanocatalysts, core-shell nanocatalysts, nanoporous zeolites, nanocarbon composites, and metal oxides in confined spaces. Each chapter contains a critical discussion of the opportunities and challenges posed by the use of nanosized catalysts for practical applications. Volume 1 – Energy Applications focuses on the conversion of renewable energy (biomass/solar) into green fuels and chemicals, ammonia synthesis, clean hydrogen production, and electrochemical energy conversion processes using a variety of nanosized catalysts. It also offers: A thorough introduction to heterogeneous catalysis and nanocatalysis, as well as a discussion of catalytic active sites at nano-scale range Comprehensive explorations of the methods for control and activation of nanosized catalysts Practical discussions of C3N4-based nanohybrid catalysts for solar hydrogen production via water splitting Nanosized catalysts in visible light photocatalysis for sustainable organic synthesis Applications of MXenes in electrocatalysis Perfect for researchers, postgraduate students, chemists, and engineers interested in heterogeneous catalysis and nanocatalysis, Heterogeneous Nanocatalysis for Energy and Environmental Sustainability will also earn a place in the libraries of professionals working in alternative energy production, biomass conversion, solar energy, green fuels, H2 production, fuel cells, electrochemical energy conversion processes, CO2 conversion, clean water, and environmental protection.

Download or read book Sustainable Catalytic Conversion of Biomass for the Production of Biofuels and Bioproducts written by Gabriel Morales and published by MDPI. This book was released on 2020-12-02 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biomass is widely considered as a potential alternative to dwindling fossil fuel reserves. There is a large variety of biomass sources (oleaginous, lignocellulosic, algae, etc.), with many possible conversion routes and products. Currently, biomass is not just viewed as a source of biofuels, but also as an interesting feedstock for the production of bio-based chemicals that could largely replace petrochemicals. In this context, the search for new sustainable and efficient alternatives to fossil sources is gaining increasing relevance within the chemical industry. There, the role of catalysis is often critical for the development of clean and sustainable processes, aiming to produce commodity chemicals or liquid fuels with a high efficiency and atom economy. This book gathers works at the cutting edge of investigation in the application of catalysis, for the sustainable conversion of biomass into biofuels and bio-based chemicals.

Download or read book Producing Fuels and Fine Chemicals from Biomass Using Nanomaterials written by Rafael Luque and published by CRC Press. This book was released on 2013-10-28 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: Scarcity of resources and increasing population and energy demands are important issues of the twenty-first century. A multidisciplinary approach is needed to produce suitable alternatives—such as renewable resources—for a more sustainable future. One of the most promising and widely available renewable feedstocks is biomass, which has significant potential for conversion to materials, fuels, and chemicals. In addition, nanomaterials can be designed for a range of applications including energy storage, fuel production, and nanocatalysis. Designing nanomaterials for the valorization of biomass and waste feedstocks is a major step in advancing the application of nanomaterials and helping to move us toward the goal of a sustainable economy. Producing Fuels and Fine Chemicals from Biomass Using Nanomaterials offers a wide-ranging approach to the development of innovative nanomaterials for biomass conversion and the production of energy and high-added-value chemicals, including biochemicals, biomaterials, and biofuels. The book is organized into three parts according to nanomaterial applications: Nanomaterials for Energy Storage and Conversion, Biofuels from Biomass Valorization Using Nanomaterials, and Production of High-Added-Value Chemicals from Biomass Using Nanomaterials. Providing a multidisciplinary perspective, this book covers the most important aspects of topics such as solar energy storage, design of carbonaceous nanomaterials as heterogeneous catalysts for producing biofuels, catalytic reforming of biogas into syngas using a range of nanoparticles, and biofuels production from waste oils and fats. It also describes the design and development of biocatalytic, solid acid, photocatalytic, and nanostructured materials for the conversion of various biomass feedstocks to valuable chemicals as intermediates to end products, such as biopolymers, bioplastics, biofuels, agrochemicals, and pharmaceutical products.

Download or read book A Study on Catalytic Conversion of Non Food Biomass into Chemicals written by Mizuho Yabushita and published by Springer. This book was released on 2016-01-13 with total page 171 pages. Available in PDF, EPUB and Kindle. Book excerpt: The topic of this thesis is catalytic conversion of non-food, abundant, and renewable biomass such as cellulose and chitin to chemicals. In biorefinery, chemical transformation of polymers to valuable compounds has attracted worldwide interest for building sustainable societies. First, the current situation of this hot research area has been summarized well in the general introduction of the thesis, which helps readers to become familiar with this topic. Next, the author explains high-yielding production of glucose from cellulose by using an alkali-activated carbon as a catalyst, resulting in a yield of glucose as high as 88%, which is one of the highest yields ever reported. The characterization of carbon materials has indicated that weak acid sites on the catalyst promote the reaction, which is markedly different from reported catalytic systems that require strong acids. In addition, the first catalytic transformation of chitin with retention of N-acetyl groups has been developed. The combination of mechanocatalytic hydrolysis and thermal solvolysis enables the production of N-acetylated monomers in good yields of up to 70%. The catalytic systems demonstrated in this thesis are unique in the fields of both chemistry and chemical engineering, and their high efficiencies can contribute to green and sustainable chemistry in the future. Meanwhile, mechanistic studies based on characterization, thermodynamics, kinetics, and model reactions have also been performed to reveal the roles of catalysts during the reactions. The results will be helpful for readers to design and develop new catalysts and reaction systems.