Download or read book Multicomponent Equilibrium Models for Testing Geothermometry Approaches written by and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Geothermometry is an important tool for estimating deep reservoir temperature from the geochemical composition of shallower and cooler waters. The underlying assumption of geothermometry is that the waters collected from shallow wells and seeps maintain a chemical signature that reflects equilibrium in the deeper reservoir. Many of the geothermometers used in practice are based on correlation between water temperatures and composition or using thermodynamic calculations based a subset (typically silica, cations or cation ratios) of the dissolved constituents. An alternative approach is to use complete water compositions and equilibrium geochemical modeling to calculate the degree of disequilibrium (saturation index) for large number of potential reservoir minerals as a function of temperature. We have constructed several "forward" geochemical models using The Geochemist's Workbench to simulate the change in chemical composition of reservoir fluids as they migrate toward the surface. These models explicitly account for the formation (mass and composition) of a steam phase and equilibrium partitioning of volatile components (e.g., CO2, H2S, and H2) into the steam as a result of pressure decreases associated with upward fluid migration from depth. We use the synthetic data generated from these simulations to determine the advantages and limitations of various geothermometry and optimization approaches for estimating the likely conditions (e.g., temperature, pCO2) to which the water was exposed in the deep subsurface. We demonstrate the magnitude of errors that can result from boiling, loss of volatiles, and analytical error from sampling and instrumental analysis. The estimated reservoir temperatures for these scenarios are also compared to conventional geothermometers. These results can help improve estimation of geothermal resource temperature during exploration and early development.
Download or read book A Thermodynamic Approach to Water Geothermometry written by Roberto Cioni and published by Springer Nature. This book was released on 2020-08-11 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book explores water geothermometry, a highly relevant topic in the exploration and exploitation of geothermal energy. Presenting theoretical geothermometers and indicators of CO2 fugacity, it describes a rigorous new approach entirely based on thermodynamics. The book will appeal to geothermal geoscientists, especially those working in research institutions and companies around the globe. It is also of interest to students on advanced courses in applied geochemistry, water–rock interaction and other related areas.
Download or read book Analysis of Some Modeling Equations Used in the Prediction of Multicomponent Equilibrium Data written by Frank C. Radice and published by . This book was released on 1974 with total page 738 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Thermodynamic Data Models and Phase Diagrams in Multicomponent Oxide Systems written by Olga Fabrichnaya and published by Springer. This book was released on 2010-12-09 with total page 198 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book involves application of the Calphad method for derivation of a self consistent thermodynamic database for the geologically important system Mg0- Fe0-Fe203-Alz03-Si02 at pressures and temperatures of Earth's upper mantle and the transition zone of that mantle for Earth. The created thermodynamic database reproduces phase relations at 1 bar and at pressures up to 30 GPa. The minerals are modelled by compound energy formalism, which gives realistic descriptions of their Gibbs energy and takes into account crystal structure data. It incorporates a detailed review of diverse types of experimental data which are used to derive the thermodynamic database: phase equilibria, calorimetric stud ies, and thermoelastic property measurements. The book also contains tables of thermodynamic properties at 1 bar (enthalpy and Gibbs energy of formation from the elements, entropy, and heat capacity, and equation of state data at pressures from 1 bar to 30 GPa. Mixing parameters of solid solutions are also provided by the book. Table of Contents Introduction to the Series . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . V Acknowledgments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . VII Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . IX Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XI Co-Authors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XIII Vitae of Co-Authors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XV CODATA Task Group on Geothermodynamic Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XXIII Chapter 1. Thermodynamics and Modeling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1. 1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1. 2 Thermodynamic Modeling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1. 3 Experimental Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 1. 4 Programs and Assessment. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 System and Phases . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 1. 5 Chapter 2. Experimental Phase Equilibrium Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 The Si02 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 2. 1 2. 2 The Fe-0 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 2. 3 The Fe-Si-0 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 2. 4 The Mg0-Si0 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Download or read book Crustal Magmatic System Evolution written by Matteo Masotta and published by John Wiley & Sons. This book was released on 2021-07-07 with total page 29 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive picture of the architecture of crustal magmatic systems The composition of igneous rocks – their minerals, melts, and fluids – reveals the physical and chemical conditions under which magmas form, evolve, interact, and move from the Earth’s mantle through the crust. These magma dynamics affect processes on the surface including crustal growth and eruptive behaviour of volcanoes. Crustal Magmatic System Evolution: Anatomy, Architecture, and Physico-Chemical Processes uses analytical, experimental, and numerical approaches to explore the diversity of crustal processes from magma differentiation and assimilation to eruption at the surface. Volume highlights include: Physical and chemical parameterization of crustal magmatic systems Experimental, theoretical and modelling approaches targeting crustal magmatic processes Timescales of crustal magmatic processes, including storage, recharge, and ascent through volcanic conduits The American Geophysical Union promotes discovery in Earth and space science for the benefit of humanity. Its publications disseminate scientific knowledge and provide resources for researchers, students, and professionals. Find out more about this book in a Q&A with the Editors.
Download or read book Thermal History of Sedimentary Basins written by Nancy D. Naeser and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 555 pages. Available in PDF, EPUB and Kindle. Book excerpt: The collection of papers in this volume is a direct result of the Society of Economic Paleontologists and Mineralogists Research Symposium on "Thermal History of Sedimentary Basins: Methods and Case Histories" held as part of the American Association of Petroleum Geologists Annual Convention in New Orleans in March 1985. The original goal of the sym posium was to provide a forum where specialists from a variety of dis ciplines could present their views of methods that can be used to study the thermal history of a sedimentary basin or an important portion of a basin. An explicit part of that goal was to illustrate each method by presentation of a case history application. The original goal is addressed by the chapters in this volume, each of which emphasizes a somewhat different approach and gives field data in one way or another to illustrate the practical useful ness ofthe method. The significance of our relative ignorance of the thermal conductivities of sedimentary rocks, especially shales, in efforts to understand or model sedimentary basin thermal histories and maturation levels is a major thrust of the chapter by Blackwell and Steele. Creaney focuses on variations in kerogen composition in source rocks of different depositional environments and the degree to which these chem- . ically distinct kerogens respond differently to progressive burial heating.
Download or read book Handbook of Crystal Growth written by Peter Rudolph and published by Elsevier. This book was released on 2014-11-04 with total page 1420 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vol 2A: Basic TechnologiesHandbook of Crystal Growth, Second Edition Volume IIA (Basic Technologies) presents basic growth technologies and modern crystal cutting methods. Particularly, the methodical fundamentals and development of technology in the field of bulk crystallization on both industrial and research scales are explored. After an introductory chapter on the formation of minerals, ruling historically the basic crystal formation parameters, advanced basic technologies from melt, solution, and vapour being applied for research and production of the today most important materials, like silicon, semiconductor compounds and oxides are presented in detail. The interdisciplinary and general importance of crystal growth for human live are illustrated.Vol 2B: Growth Mechanisms and DynamicsHandbook of Crystal Growth, Second Edition Volume IIB (Growth Mechanisms and Dynamics) deals with characteristic mechanisms and dynamics accompanying each bulk crystal growth method discussed in Volume IIA. Before the atoms or molecules pass over from a position in the fluid medium (gas, melt or solution) to their place in the crystalline face they must be transported in the fluid over macroscopic distances by diffusion, buoyancy-driven convection, surface-tension-driven convection, and forced convection (rotation, acceleration, vibration, magnetic mixing). Further, the heat of fusion and the part carried by the species on their way to the crystal by conductive and convective transport must be dissipated in the solid phase by well-organized thermal conduction and radiation to maintain a stable propagating interface. Additionally, segregation and capillary phenomena play a decisional role for chemical composition and crystal shaping, respectively. Today, the increase of high-quality crystal yield, its size enlargement and reproducibility are imperative conditions to match the strong economy. Volume 2A Presents the status and future of Czochralski and float zone growth of dislocation-free silicon Examines directional solidification of silicon ingots for photovoltaics, vertical gradient freeze of GaAs, CdTe for HF electronics and IR imaging as well as antiferromagnetic compounds and super alloys for turbine blades Focuses on growth of dielectric and conducting oxide crystals for lasers and non-linear optics Topics on hydrothermal, flux and vapour phase growth of III-nitrides, silicon carbide and diamond are explored Volume 2B Explores capillarity control of the crystal shape at the growth from the melt Highlights modeling of heat and mass transport dynamics Discusses control of convective melt processes by magnetic fields and vibration measures Includes imperative information on the segregation phenomenon and validation of compositional homogeneity Examines crystal defect generation mechanisms and their controllability Illustrates proper automation modes for ensuring constant crystal growth process Exhibits fundamentals of solution growth, gel growth of protein crystals, growth of superconductor materials and mass crystallization for food and pharmaceutical industries
Download or read book Geochemical and Biogeochemical Reaction Modeling written by Craig M. Bethke and published by Cambridge University Press. This book was released on 2010-12-09 with total page 564 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive overview of reaction processes in the Earth's crust and on its surface, both in the laboratory and in the field. A clear exposition of the underlying equations and calculation techniques is balanced by a large number of fully worked examples. The book uses The Geochemist's Workbench® modeling software, developed by the author and already installed at over 1000 universities and research facilities worldwide. Since publication of the first edition, the field of reaction modeling has continued to grow and find increasingly broad application. In particular, the description of microbial activity, surface chemistry, and redox chemistry within reaction models has become broader and more rigorous. These areas are covered in detail in this new edition, which was originally published in 2007. This text is written for graduate students and academic researchers in the fields of geochemistry, environmental engineering, contaminant hydrology, geomicrobiology, and numerical modeling.
Download or read book Geochemistry written by Harry Y. McSween and published by Columbia University Press. This book was released on 2003-11-19 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written expressly for undergraduate and graduate geologists, this book focuses on how geochemical principles can be used to solve practical problems. The attention to problem-solving reflects the authors'belief that showing how theory is useful in solving real-life problems is vital for learning. The book gives students a thorough grasp of the basic principles of the subject, balancing the traditional equilibrium perspective and the kinetic viewpoint. The first half of the book considers processes in which temperature and pressure are nearly constant. After introductions to the laws of thermodynamics, to fundamental equations for flow and diffusion, and to solution chemistry, these principles are used to investigate diagenesis, weathering, and natural waters. The second half of the book applies thermodynamics and kinetics to systems undergoing changes in temperature and pressure during magmatism and metamorphism. This revised edition incorporates new geochemical discoveries as examples of processes and pathways, with new chapters on mineral structure and bonding and on organic matter and biomarkers. Each chapter has worked problems, and the authors assume that the student has had a year of college-level chemistry and a year of calculus. Praise for the first edition "A truly modern geochemistry book.... Very well written and quite enjoyable to read.... An excellent basic text for graduate level instruction in geochemistry." —Journal of Geological Education "An up-to-date, broadly conceived introduction to geochemistry.... Given the recent flowering of geochemistry as an interdisciplinary science, and given the extent to which it now draws upon the fundamentals of thermodynamics and kinetics to understand earth and planetary processes, this timely and rigorous [book] is welcome indeed." —Geochimica et Cosmochimica Acta
Download or read book Transactions written by Geothermal Resources Council. Annual Meeting and published by . This book was released on 1991 with total page 520 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Electromagnetic Geothermometry written by Viacheslav V. Spichak and published by Elsevier. This book was released on 2015-01-14 with total page 194 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electromagnetic Geothermometry explores, presents and explains the new technique of temperature estimation within the Earth’s interior; the Electromagnetic technique will identify zones of geothermal anomalies and thus provides locations for deep drilling. This book includes many case studies from geothermal areas such as Travale (Italy), Soultz-sous-Forêts (France) and Hengill (Iceland), allowing the author and reader to draw conclusions regarding the dominating heat transfer mechanisms, location of its sources and to constrain the locations for drilling of the new boreholes. Covering a topic that so far has very little coverage (due to its newness) Electromagnetic Geothermometry presents ground breaking information on the interpretation of MT signals. And as such, is similar to the work that was done to develop new generations of seismic inversion methods that have since come to dominate the oil industry. Up until now geophysical methods have had difficulty resolving temperature differences which have been critical in the understanding of location and magnitude of geothermal resources Authored by the world’s foremost geothermometry experts who combined have more than 40 years of experience on the subject Presents case studies, allowing the author and reader to draw conclusions regarding the dominating heat transfer mechanisms, location of its sources and to constrain the locations for drilling of the new boreholes Provides important information on the constraints for drilling of new exploration boreholes Describes techniques that will dramatically decrease the costs associated with exploration drilling Includes information to help the reader improve the accuracy of the temperature estimations in the interwell space as well as far beneath boreholes
Download or read book Geochemistry written by William M. White and published by John Wiley & Sons. This book was released on 2013-01-22 with total page 1218 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive introduction to the field of geochemistry. The book first lays out the ‘geochemical toolbox’: the basic principles and techniques of modern geochemistry, beginning with a review of thermodynamics and kinetics as they apply to the Earth and its environs. These basic concepts are then applied to understanding processes in aqueous systems and the behavior of trace elements in magmatic systems. Subsequent chapters introduce radiogenic and stable isotope geochemistry and illustrate their application to such diverse topics as determining geologic time, ancient climates, and the diets of prehistoric peoples. The focus then broadens to the formation of the solar system, the Earth, and the elements themselves. Then the composition of the Earth itself becomes the topic, examining the composition of the core, the mantle, and the crust and exploring how this structure originated. A final chapter covers organic chemistry, including the origin of fossil fuels and the carbon cycle’s role in controlling Earth’s climate, both in the geologic past and the rapidly changing present. Geochemistry is essential reading for all earth science students, as well as for researchers and applied scientists who require an introduction to the essential theory of geochemistry, and a survey of its applications in the earth and environmental sciences. Additional resources can be found at: www.wiley.com/go/white/geochemistry
Download or read book Petrochronology written by Matthew J. Kohn and published by Walter de Gruyter GmbH & Co KG. This book was released on 2019-11-05 with total page 596 pages. Available in PDF, EPUB and Kindle. Book excerpt: Petrochronology is a rapidly emerging branch of Earth science that links time (ages or rates) with specific rock-forming processes and their physical conditions. It is founded in petrology and geochemistry, which define a petrogenetic context or delimit a specific process, to which chronometric data are then linked. This combination informs Earth’s petrogenetic processes better than petrology or geochronology alone. This volume and the accompanying short courses address three broad categories of inquiry. Conceptual approaches chapters include petrologic modeling of multi-component chemical and mineralogic systems, and development of methods that include diffusive alteration of mineral chemistry. Methods chapters address four main analytical techniques, specifically EPMA, LA-ICP-MS, SIMS and TIMS. Mineral-specific chapters explore applications to a wide range of minerals, including zircon (metamorphic, igneous, and detrital/Hadean), baddeleyite, REE minerals (monazite, allanite, xenotime and apatite), titanite, rutile, garnet, and major igneous minerals (olivine, plagioclase and pyroxenes). These applications mainly focus on metamorphic, igneous, or tectonic processes, but additionally elucidate fundamental transdisciplinary progress in addressing mechanisms of crystal growth, the chemical consequences of mineral growth kinetics, and how chemical transport and deformation affect chemically complex mineral composites. Most chapters further recommend areas of future research.
Download or read book Environmental Applications of Geochemical Modeling written by Chen Zhu and published by Cambridge University Press. This book was released on 2002-05-13 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt: An application of geochemical modeling to environmental problems, illustrated with case studies of real-world environmental investigations.
Download or read book Thermodynamics of Minerals and Melts written by R.C. Newton and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Today large numbers of geoscientists apply thermodynamic theory to solu tions of a variety of problems in earth and planetary sciences. For most problems in chemistry, the application of thermodynamics is direct and rewarding. Geoscientists, however, deal with complex inorganic and organic substances. The complexities in the nature of mineralogical substances arise due to their involved crystal structure and multicomponental character. As a result, thermochemical solutions of many geological-planetological problems should be attempted only with a clear understanding of the crystal-chemical and thermochemical character of each mineral. The subject of physical geochemistry deals with the elucidation and application of physico-chemical principles to geosciences. Thermodynamics of mineral phases and crystalline solutions form an integral part of it. Developments in mineralogic thermody namics in recent years have been very encouraging, but do not easily reach many geoscientists interested mainly in applications. This series is to provide geoscientists and planetary scientists with current information on the develop ments in thermodynamics of mineral systems, and also provide the active researcher in this rapidly developing field with a forum through which he can popularize the important conclusions of his work. In the first several volumes, we plan to publish original contributions (with an abundant supply of back ground material for the uninitiated reader) and thoughtful reviews from a number of researchers on mineralogic thermodynamics, on the application of thermochemistry to planetary phase equilibria (including meteorites), and on kinetics of geochemical reactions.
Download or read book Petrogenesis of Metamorphic Rocks written by Kurt Bucher and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 298 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metamorphic rocks are one of the three classes of rocks. Seen on a global scale they constitute the dominant material of the Earth. The understanding of the petrogenesis and significance of metamorphic of geological education. rocks is, therefore, a fundamental topic There are, of course, many different possible ways to lecture on this theme. This book addresses rock metamorphism from a relatively pragmatic view point. It has been written for the senior undergrad uate or graduate student who needs practical knowledge of how to interpret various groups of minerals found in metamorphic rocks. The book is also of interest for the non-specialist and non-petrolo gist professional who is interested in learning more about the geolo gical messages that metamorphic mineral assemblages are sending, as well as pressure and temperature conditions of formation. The book is organized into two parts. The first part introduces the different types of metamorphism, defines some names, terms and graphs used to describe metamorphic rocks, and discusses principal aspects of metamorphic processes. Part I introduces the causes of metamorphism on various scales in time and space, and some principles of chemical reactions in rocks that accompany metamorphism, but without treating these principles in detail, and presenting the thermodynamic basis for quantitative analysis of reactions and their equilibria in metamorphism. Part I also presents concepts of metamorphic grade or intensity of metamorphism, such as the metamorphic-facies concept.
Download or read book Geotitles written by and published by . This book was released on 1986 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt:
