Download or read book Modern Aspects of Diffusion Controlled Reactions written by E. Kotomin and published by Elsevier. This book was released on 1996-10-24 with total page 637 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph deals with the effects of reactant spatial correlations arising in the course of basic bimolecular reactions describing defect recombination, energy transfer and exciton annihilation in condensed matter. These effects lead to the kinetics considered abnormal from the standard chemical kinetics point of view. Numerous bimolecular reaction regimes and conditions are analysed in detail. Special attention is paid to the development and numerous applications of a novel, many-point density (MPD) formalism, which is based on Kirkwood's superposition approximation used for decoupling three-particle correlation functions.The book demonstrates that incorporation of the reaction-induced spatial correlations of similar reactants (e.g., vacancy-vacancy) leads to the development of an essentially non-Poisson spectrum of reactant density fluctuations. This can completely change the kinetics at longer times since it no longer obeys the law of mass action. The language of the correlation lengths and critical exponents similar to physics of critical phenomena is used instead. A relation between MPD theory and synergistics is discussed. The validity of the theorem giving a critical complexity for the two-step reactions exhibiting self-organization phenomena is questioned. Theoretical results are illustrated by numerous experimental data.
Download or read book Statistical Thermodynamics And Stochastic Theory Of Nonequilibrium Systems written by Werner Ebeling and published by World Scientific Publishing Company. This book was released on 2005-09-23 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents both the fundamentals and the major research topics in statistical physics of systems out of equilibrium. It summarizes different approaches to describe such systems on the thermodynamic and stochastic levels, and discusses a variety of areas including reactions, anomalous kinetics, and the behavior of self-propelling particles.
Download or read book Modern Aspects of Rare Earths and their Complexes written by Vinny R. Sastri and published by Elsevier. This book was released on 2003-12-09 with total page 1005 pages. Available in PDF, EPUB and Kindle. Book excerpt: In order to use rare earths successfully in various applications, a good understanding of the chemistry of these elements is of paramount importance. Nearly three to four decades have passed since titles such as The Rare Earths edited by F.H. Spedding and A.H. Daane, The chemistry of the Rare Earth Elements by N.E. Topp and Complexes of the Rare Earths by S.P. Sinha were published. There have been many international conferences and symposia on rare earths, as well as the series of volumes entitled Handbook of Physics and Chemistry of Rare Earths edited by K.A. Gschneidner and L. Eyring. Thus, there is a need for a new title covering modern aspects of rare earth complexes along with the applications. The present title consists of twelve chapters. 1. Introduction2. General aspects3. Stability of complexes4. Lanthanide complexes5. Structural chemistry of lanthanide compounds6. Organometallic complexes7. Kinetics and mechanisms of rare earths complexation8. Spectroscopy of lanthanide complexes9. Photoelectron spectroscopy of rare earths10. Lanthanide NMR shift reagents11. Environmental ecological biological aspects12. Applications The authors studied in schools headed by pioneers in rare earth chemistry, have a combined experience of one hundred and fifty years in inorganic chemistry, rare earth complex chemistry, nuclear and radiochemistry of rare earths and supramolecular chemistry. The present monograph is a product of this rich experience.
Download or read book Factorization Singular Operators and Related Problems written by Stefan Samko and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: These proceedings comprise a large part of the papers presented at the In ternational Conference Factorization, Singular Operators and related problems, which was held from January 28 to February 1, 2002, at the University of th Madeira, Funchal, Portugal, to mark Professor Georgii Litvinchuk's 70 birth day. Experts in a variety of fields came to this conference to pay tribute to the great achievements of Professor Georgii Litvinchuk in the development of vari ous areas of operator theory. The main themes of the conference were focussed around the theory of singular type operators and factorization problems, but other topics such as potential theory and fractional calculus, to name but a couple, were also presented. The goal of the conference was to bring together mathematicians from var ious fields within operator theory and function theory in order to highlight recent advances in problems many of which were originally studied by Profes sor Litvinchuk and his scientific school. A second aim was to stimulate in ternational collaboration even further and promote the interaction of different approaches in current research in these areas. The Proceedings will be of great interest to researchers in Operator The ory, Real and Complex Analysis, Functional and Harmonic Analysis, Potential Theory, Fractional Calculus and other areas, as well as to graduate students looking for the latest results.
Download or read book Modern Aspects of Electrochemistry written by John O'M. Bockris and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 565 pages. Available in PDF, EPUB and Kindle. Book excerpt: From reviews of previous volumes: 'This volume continues the valuable service that has been rendered by the Modern Aspects series.'-Journal of Electroanalytical Chemistry 'Extremely well referenced and very readable....Maintains the overall high standards of the series.'-Journal of the American Chemical Society
Download or read book Stochastic Methods for Boundary Value Problems written by Karl K. Sabelfeld and published by Walter de Gruyter GmbH & Co KG. This book was released on 2016-09-26 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph is devoted to random walk based stochastic algorithms for solving high-dimensional boundary value problems of mathematical physics and chemistry. It includes Monte Carlo methods where the random walks live not only on the boundary, but also inside the domain. A variety of examples from capacitance calculations to electron dynamics in semiconductors are discussed to illustrate the viability of the approach. The book is written for mathematicians who work in the field of partial differential and integral equations, physicists and engineers dealing with computational methods and applied probability, for students and postgraduates studying mathematical physics and numerical mathematics. Contents: Introduction Random walk algorithms for solving integral equations Random walk-on-boundary algorithms for the Laplace equation Walk-on-boundary algorithms for the heat equation Spatial problems of elasticity Variants of the random walk on boundary for solving stationary potential problems Splitting and survival probabilities in random walk methods and applications A random WOS-based KMC method for electron–hole recombinations Monte Carlo methods for computing macromolecules properties and solving related problems Bibliography
Download or read book Radiation Effects in Solids written by Kurt E. Sickafus and published by Springer Science & Business Media. This book was released on 2007-05-22 with total page 593 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is a comprehensive overview of fundamental principles and relevant technical issues associated with the behavior of solids exposed to high-energy radiation. These issues are important to the development of materials for existing fission reactors or future fusion and advanced reactors for energy production; to the development of electronic devices such as high-energy detectors; and to the development of novel materials for electronic and photonic applications.
Download or read book Silicon Dioxide and the Luminescence of Related Materials written by Anatoly Trukhin and published by Cambridge Scholars Publishing. This book was released on 2021-07-05 with total page 539 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is devoted to the study of the properties of materials that can be in a crystalline and glassy state. Its central focus is the physics of solids, whose structure is disordered, since the existing theories of solids are based on crystal structures. The approach adopted here is based on the comparison of data for crystals and glasses formed by the same atoms, paying particular attention to the under-explored glass-forming crystals. The book will be of interest to graduate students, solid states researchers, glass technologists, and young scientists beginning research in the field of experimental physics.
Download or read book Modern Aspects of Electrochemistry written by Brian E. Conway and published by Springer Science & Business Media. This book was released on 2005-11-21 with total page 435 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recognized experts present incisive analysis of both fundamental and applied problems in this continuation of a highly acclaimed series. Topics discussed include: A thorough and mathematical treatment of periodic phenomena, with consideration of new theories about the transition between `order' and `chaos'; Impedance spectroscopy as applied to the study of kinetics and mechanisms of electrode processes; The use of stoichiometric numbers in mechanism analysis; The electro-osmotic dewatering of clays with important implications for the processing of industrial waste and geotechnical; stabilization; Magnetic effects in electrolytic processes and the electrolytic Hall effect; and The computer analysis and modeling of mass transfer and fluid flow. These authoritative studies will be invaluable for researchers in engineering, electrochemistry, analytical chemistry, materials science, physical chemistry, and corrosion science.
Download or read book Materials Modification by Electronic Excitation written by Noriaki Itoh and published by Cambridge University Press. This book was released on 2001 with total page 658 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electronic excitation is a means to change materials properties. This book analyses the important features of the changes induced by electronic excitation, identifies what is critical, and provides a basis from which materials modification can be developed successfully. Electronic excitation by lasers or electron beams can change the properties of materials. In the last few years, there has been a mix of basic science, of new laser and electron beam tools, and of new needs from microelectronics, photonics and nanotechnology. This book extends and synthesises the science, addressing ideas like energy localisation and charge localisation, with detailed comparisons of experiment and theory. It also identifies the ways this understanding links to technological needs, like selective removal of material, controlled changes, altering the balance between process steps, and possibilities of quantum control. This book will be of particular interest to research workers in physics, chemistry, electronic engineering and materials science.
Download or read book Advances in Chemical Physics written by Ilya Prigogine and published by John Wiley & Sons. This book was released on 2003-04-14 with total page 696 pages. Available in PDF, EPUB and Kindle. Book excerpt: The latest edition of the leading forum in chemical physics Edited by Nobel Prize winner Ilya Prigogine and renowned authority Stuart A. Rice. The Advances in Chemical Physics series provides a forum for critical, authoritative evaluations in every area of the discipline. In a format that encourages the expression of individual points of view, experts in the field present comprehensive analyses of subjects of interest. This stand-alone, special topics volume reports recent advances in electron-transfer research, with significant, up-to-date chapters by internationally recognized researchers. Volume 123 collects innovative papers on "Transition Path Sampling," "Dynamics of Chemical Reactions and Chaos," "The Role of Self Similarity in Renormalization Group Theory," and several other related topics. Advances in Chemical Physics remains the premier venue for presentations of new findings in its field.
Download or read book Charged Particle and Photon Interactions with Matter written by Yoshihiko Hatano and published by CRC Press. This book was released on 2010-12-13 with total page 1068 pages. Available in PDF, EPUB and Kindle. Book excerpt: Building on Mozumder's and Hatano's Charged Particle and Photon Interactions with Matter: Chemical, Physicochemical, and Biological Consequences with Applications (CRC Press, 2004), Charged Particle and Photon Interactions with Matter: Recent Advances, Applications, and Interfaces expands upon the scientific contents of the previous volume by cover
Download or read book Modern Polyesters written by John Scheirs and published by John Wiley & Sons. This book was released on 2005-09-01 with total page 784 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides an overview of the family of polyester polymers which comprise an important group of plastics that span the range of commodity polymers to engineering resins. It describes the preparation, properties and applications of polyesters. Readers will also find details on polyester-based elastomers, biodegradable aliphatic polyester, liquid crystal polyesters and unsaturated polyesters for glass-reinforced composites. Presents an overview of the most recent developments. Explores synthesis, catalysts, processes, properties and applications. Looks at emerging polyester materials as well as existing ones. Written by foremost experts from both academia and industry, ensuring that both fundamentals and practical applications are covered.
Download or read book Fractional Dynamics written by Joseph Klafter and published by World Scientific. This book was released on 2012 with total page 530 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume provides the latest developments in the field of fractional dynamics, which covers fractional (anomalous) transport phenomena, fractional statistical mechanics, fractional quantum mechanics and fractional quantum field theory. The contributors are selected based on their active and important contributions to their respective topics. This volume is the first of its kind that covers such a comprehensive range of topics in fractional dynamics. It will point out to advanced undergraduate and graduate students, and young researchers the possible directions of research in this subject. In addition to those who intend to work in this field and those already in the field, this volume will also be useful for researchers not directly involved in the field, but want to know the current status and trends of development in this subject. This latter group includes theoretical chemists, mathematical biologists and engineers.
Download or read book Modern Aspects of Electrochemistry No 7 written by B. E. Conway and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: Despite reductions in the level of research activity in most fields which, for reasons of economic decline, have taken place in the U.S. during the last year or two, world progress in the fundamental aspects has continued actively. An important aspect of such recent work has been the use of nonaqueous solvents in studies on the constitution of the double-layer and electrochemical reactions. Interpretation of the behavior of electrode interfaces in such solvents demands more knowledge of the solvation properties of ions in nonaqueous media. Chapter 1 by Pad ova on "Ionic Solvation in Nonaqueous and Mixed Solvents" gives an up to date review of the present state of knowledge in this field, together with tabulations of data that are likely to be of quantitative value in further investigations of both homogeneous and heterogeneous electrochemistry in such media. Electrochemical studies of cathodic processes in nonaqueous solvents have, in recent years, revealed the role of solvated electrons. These are of interest in new approaches to reductive electro-organic synthesis. Similarly, the generation of hydrated electrons in photo cathodic processes is of great interest. In Chapter 2, by Conway, the conditions under which solvated electrons can arise in electrode processes are critically examined and the electro-organic reactions that hwe been investigated are reviewed. The supposed electro generation of hydrated electrons in the water solvent and as inter mediates in cathodic hydrogen evolution is shown to be unlikely.
Download or read book Dislocations in Solids written by Frank R.N. Nabarro and published by Elsevier. This book was released on 2002-12-05 with total page 687 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dislocations are lines of irregularity in the structure of a solid analogous to the bumps in a badly laid carpet. Like these bumps, they can be easily moved, and they provide the most important mechanism by which the solid can be deformed. They also have a strong influence on crystal growth and on the electronic properties of semiconductors.
Download or read book Contemporary Problems in Statistical Physics written by George H. Weiss and published by SIAM. This book was released on 1994-01-01 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt: This collection of independent articles describes some mathematical problems recently developed in statistical physics and theoretical chemistry. The book introduces and reviews current research on such topics as nonlinear systems and colored noise, stochastic resonance, percolation, the trapping problem in the theory of random walks, and diffusive models for chemical kinetics. Some of these topics have never before been presented in expository book form. Applied mathematicians will be introduced to some contemporary problems in statistical physics. In addition, a number of unsolved problems currently attracting intensive research efforts are described.
