Download or read book Metastable Systems under Pressure written by Sylwester Rzoska and published by Springer Science & Business Media. This book was released on 2009-11-19 with total page 435 pages. Available in PDF, EPUB and Kindle. Book excerpt: recently discovered advantages of amorphous forms of medicines/pharmaceutical products which focused a significant part of industry-related efforts on the GFA (Glass Forming Ability) and the glass temperature (T) versus pressure g dependences. 1 b ? 0 ? ? o ? P ? Pg P ? Pg 0 ? ? ? ? T (P ) = F (P )D (P ) =T 1 + exp ? g g ? 0 ? ? ? ? c + Pg ? ? ? ? 400 1 b 0 o ? ? ? ? P ? P P ? P g g 0 ? ? ? ? T (P ) = F (P )D (P ) =T 1 + exp ? g g 0 ? ? ? ? c ? + P max g ? ? ? ? T ~7 GPa g max P ~ 304 K Liquid g 300 1 HS glass 0 200 -1 mSG ?=0. 044 Liquid -2 100 -3 glass ?=0. 12 -1. 2 -0. 9 -0. 6 -0. 3 0. 0 log T 10 scaled -1 0 1 2 3 4 5 6 7 8 9 10 11 12 P (GPa) g 19 Figure 1. T he pressure evolution of the glass temperature in gl Th ye s cerol ol . id curve shows the parameterization of experimental data via the novel, modifie d Glat Sizm elon type equation, given in the Figure.
Download or read book Soft Matter Systems for Biomedical Applications written by Leonid Bulavin and published by Springer Nature. This book was released on 2021-09-27 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses new challenges in soft matter and colloids. It presents timely reports on colloidal self-assembly, soft matters from liquid crystals, nanoparticles in liquid crystals, hydrocolloids, hybrid nanosystems, nanosuspensions, and dispersion of nanoparticles in different media, soft matter processing and modern experiments related with soft matters.
Download or read book Transport and Reactivity of Solutions in Confined Hydrosystems written by Lionel Mercury and published by Springer. This book was released on 2013-11-12 with total page 271 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present work reflects a multi-disciplinary effort to address the topic of confined hydrosystems developed with a cross-fertilization panel of physics, chemists, biologists, soil and earth scientists. Confined hydrosystems include all situations in natural settings wherein the extent of the liquid phase is limited so that the solid-liquid and/or liquid-air interfaces may be critical to the properties of the whole system. Primarily, this so-called “residual” solution is occluded in pores/channels in such a way that decreases its tendency to evaporation, and makes it long-lasting in arid (Earth deserts) and hyper-arid (Mars soils) areas. The associated physics is available from domains like capillarity, adsorption and wetting, and surface forces. However, many processes are still to understand due to the close relationship between local structure and matter properties, the subtle interplay between the host and the guest, the complex intermingling among static reactivity and migration pathway. Expert contributors from Israel, Russia, Europe and US discuss the behaviour of water and aqueous solutes at different scale, from the nanometric range of carbon nanotubes and nanofluidics to the regional scale of aquifers reactive flow in sedimentary basins. This scientific scope allowed the group of participants with very different background to tackle the confinement topic at different scales. The book is organized according to four sections that include: i) flow, from nano- to mega-scale; ii) ions, hydration and transport; iii) in-pores/channels cavitation; iv) crystallization under confinement. Most of contributions relates to experimental works at different resolution, interpreted through classic thermodynamics and intermolecular forces. Simulation techniques are used to explore the atomic scale of interfaces and the migration in the thinnest angstrom-wide channels.
Download or read book Nanostructured Materials by High Pressure Severe Plastic Deformation written by Yuntian T. Zhu and published by Springer Science & Business Media. This book was released on 2006-01-20 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recently, it was reported that nanostructured materials processed under high pressure by HPT and ECAP have an extraordinary combination of both high strength and high ductility, which are two desirable, but rarely co-existing properties. These findings indicate that high-pressure is a critical factor that can be employed to process nanostructured materials with superior mechanical, and possibly also physical, properties. It is the objective of this workshop to review our current knowledge, identify issues for future research, and discuss future directions on the processing and properties of nanostructured materials via SPD techniques, with a special emphasis on high-pressure effects. The 42 peer-reviewed papers in this book cover areas of high pressure effect on the nanostructure and properties of SPD-processed materials, fundamentals of nanostructured materials, development of high-pressure SPD technologies for commercializations, recent advances of SPD technologies as well as applications and future markets of SPD-processed nanostructured materials.
Download or read book Geochemical Modeling of Groundwater Vadose and Geothermal Systems written by Jochen Bundschuh and published by CRC Press. This book was released on 2011-12-23 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt: Geochemical modeling is an important tool in environmental studies, and in the areas of subsurface and surface hydrology, pedology, water resources management, mining geology, geothermal resources, hydrocarbon geology, and related areas dealing with the exploration and extraction of natural resources. The book fills a gap in the literature through
Download or read book Properties of Water from Numerical and Experimental Perspectives written by Fausto Martelli and published by CRC Press. This book was released on 2022-10-20 with total page 211 pages. Available in PDF, EPUB and Kindle. Book excerpt: As the most important liquid in our life and one of the most abundant molecules in the universe, water is the least understood substance with a very rich phase diagram (at least 18 crystalline forms and two liquids) and more that 60 dynamical/thermodynamic anomalies whose origins are still under debate. Properties of Water from Numerical and Experimental Perspectives gathers together leading scientists and experts in the field of water. By merging the theoretical/computational point of view with experimental approaches, it presents a state-of-the-art description of the properties of water, enlightening the source of the anomalies of water and describing how such anomalies actively affect the functioning of biological substances.
Download or read book Crystallization as Studied by Broadband Dielectric Spectroscopy written by Tiberio A. Ezquerra and published by Springer Nature. This book was released on 2020-10-28 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents new approaches that offer a better characterization of the interrelationship between crystalline and amorphous phases. In recent years, the use of dielectric spectroscopy has significantly improved our understanding of crystallization. The combination of modern scattering methods, using either synchrotron light or neutrons and infrared spectroscopy with dielectrics, is now helping to reveal modifications of both crystalline and amorphous phases. In turn, this yields insights into the underlying physics of the crystallization process in various materials, e.g. polymers, liquid crystals and diverse liquids. The book offers an excellent introduction to a valuable application of dielectric spectroscopy, and a helpful guide for every scientist who wants to study crystallization processes by means of dielectric spectroscopy.
Download or read book The Vitreous State written by Ivan S. Gutzow and published by Springer Science & Business Media. This book was released on 2013-04-12 with total page 566 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book summarizes the experimental evidence and modern classical and theoretical approaches in understanding the vitreous state, from structural problems, over equilibrium and non-equilibrium thermodynamics, to statistical physics. Glasses, and especially silicate glasses, are only the best known representatives of this particular physical state of matter. Other typical representatives include organic polymer glasses, and many other easily vitrifying organic and inorganic substances, technically important materials, amidst them vitreous water and vitrified aqueous solutions, and also many metallic alloy systems. Some of these systems only form glasses under particular conditions, e.g. through ultra-rapid cooling. This book describes the properties and the formation of both every-day technical glasses and especially of such more exotic forms of vitreous matter. It is a unique source of knowledge and new ideas for materials scientists, engineers and researchers working on condensed matter. The new edition emphasizes latest experimental findings and modern theories, explaining the kinetics of glass formation, the relaxation and stabilization of glasses and their crystallization in terms of new models, derived from the framework of the thermodynamics of irreversible processes. It shows how the properties of common technical glasses, window glass, or the vitreous ice kernel of comets can be used to develop a new understanding of the existence of matter in various, unusual forms. The described theories can even find application for the description of lasers and interesting unusual processes in the universe.
Download or read book Sonochemistry Cavitation written by Margulis and published by CRC Press. This book was released on 1995-11-30 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sonochemistry and cavitation are rapidly increasing in importance in modern chemistry as a result of many significant achievements made in recent years. In this current and comprehensive text, the author clearly details and illustrates these developments as well as the fundamental concepts. Much attention is given to the fundamental problems, such as the general kinetics of sonochemical reactions: energetic yields; the principles of the cavitation diffusion theory; the place of acoustic energy among other physical methods of action on matter; and the new electrical theory of cavitation phenomena, sonochemical reactions and sonoluminescence initiation (the theory developed by Professor Margulis). Results of low-frequency acoustic fields investigations are also observed. Special attention is given to the influence of acoustic fields on chemical reactions in nonaqueous systems, catalytic processes and the initiation of oscillating reactions. This publication is designed to broaden the application of ultrasound in chemical technology and improve the efficiency of existing production processes. Its comprehensiveness makes it a practical handbook which will prove invaluable to a broad readership amongst chemistry, engineering and physics undergraduates, graduates, researchers, and industrialists working in the fields of sonochemistry, ultrasonic and chemical technology, high energy chemistry, acoustics and biology.
Download or read book Compounds and Alloys Under High Pressure written by E.Yu Tonkov and published by Taylor & Francis. This book was released on 2022 with total page 588 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the first book to classify and systematize the available data on the behavior of binary alloys under high pressure. Despite the fact that there is a strong correlation between temperature-composition (T-C) phase diagrams at normal pressure and three- dimensional temperature-composition-pressure (T-C-P) diagrams, many material scientists seldom refer to the (T-C-P) diagrams, just as many high pressure researchers often ignore the data obtained at normal pressure. This book aims to bridge the gap between data obtained at high pressure and that obtained at normal pressure. The most recent research covers not only elements and stoichiometric compounds, but also binary, ternary, and multicomponent alloys, and so this book covers an extended range of substances. The properties of 890 binary systems and a further 1153 pseudobinary and ternary systems are summarized, and accompanied by an extensive bibliography. The data includes information on the solubility of components in solid solutions, melting, and first- and second-order phase transformations in alloys and stoichiometric compounds.
Download or read book Proceedings of the Section of Sciences written by Koninklijke Nederlandse Akademie van Wetenschappen. Afdeling Natuurkunde and published by . This book was released on 1916 with total page 910 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Proceedings of the Section of Sciences written by Koninklijke Akademie van Wetenschappen (Netherlands). Afdeeling Natuurkunde and published by . This book was released on 1927 with total page 666 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Theory of Allotropy written by Andreas Smits and published by . This book was released on 1922 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Phase Rule and Its Applications written by Alexander Findlay and published by . This book was released on 1927 with total page 362 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Transformations of Lamarckism written by Snait B. Gissis and published by MIT Press. This book was released on 2011-04-22 with total page 474 pages. Available in PDF, EPUB and Kindle. Book excerpt: A reappraisal of Lamarckism—its historical impact and contemporary significance. In 1809—the year of Charles Darwin's birth—Jean-Baptiste Lamarck published Philosophie zoologique, the first comprehensive and systematic theory of biological evolution. The Lamarckian approach emphasizes the generation of developmental variations; Darwinism stresses selection. Lamarck's ideas were eventually eclipsed by Darwinian concepts, especially after the emergence of the Modern Synthesis in the twentieth century. The different approaches—which can be seen as complementary rather than mutually exclusive—have important implications for the kinds of questions biologists ask and for the type of research they conduct. Lamarckism has been evolving—or, in Lamarckian terminology, transforming—since Philosophie zoologique's description of biological processes mediated by "subtle fluids." Essays in this book focus on new developments in biology that make Lamarck's ideas relevant not only to modern empirical and theoretical research but also to problems in the philosophy of biology. Contributors discuss the historical transformations of Lamarckism from the 1820s to the 1940s, and the different understandings of Lamarck and Lamarckism; the Modern Synthesis and its emphasis on Mendelian genetics; theoretical and experimental research on such "Lamarckian" topics as plasticity, soft (epigenetic) inheritance, and individuality; and the importance of a developmental approach to evolution in the philosophy of biology. The book shows the advantages of a "Lamarckian" perspective on evolution. Indeed, the development-oriented approach it presents is becoming central to current evolutionary studies—as can be seen in the burgeoning field of Evo-Devo. Transformations of Lamarckism makes a unique contribution to this research.
Download or read book Journal of the Chemical Society written by Chemical Society (Great Britain) and published by . This book was released on 1926 with total page 1712 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Titles of chemical papers in British and foreign journals" included in Quarterly journal, v. 1-12
Download or read book Quarterly Journal of the Chemical Society of London written by Chemical Society (Great Britain) and published by . This book was released on 1926 with total page 1784 pages. Available in PDF, EPUB and Kindle. Book excerpt:
