Download or read book Scorpionates The Coordination Chemistry Of Polypyrazolylborate Ligands written by Swiatoslaw Trofimenko and published by World Scientific. This book was released on 1999-08-16 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966, but becoming rapidly popular with inorganic, organometallic and coordination chemists since 1986, because of their versatility and user-friendliness. They can be readily modified sterically and electronically through appropriate substitution on the pyrazole ring and on boron, and have led to a number of firsts in coordination chemistry (first stable CuCO complex, first monomeric MgR complex, and many other such firsts). Their denticity can range from two to four, their “Bite” can be adjusted, and additional coordinating sites can be added to the pyrazolyl rings. Over 170 different scorpionate ligands are known today, and some are published for the first time in this book.The author, Swiatoslaw Trofimenko, discovered and developed this ligand system and has written several reviews on the subject. The book is intended as a reference work, placing at the researcher's command practically all of the over 1500 references on the subject up, and into 1999, organized both according to the ligand type and according to the metal or metalloid being coordinated. It acquaints the reader with the special features of this ligand system and permits an assessment of what has been done in a given sub-area, and of which areas remain relatively unexplored. It presents procedures for ligand synthesis, and also covers their use in catalysis and in the modelling of biologically active substances.

Download or read book Catalysis by Metal Complexes and Nanomaterials written by Meng Zhou (Chemistry professor) and published by . This book was released on 2019 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: "Catalysis is truly an interdisciplinary field to which chemists, biologists, physicists, and engineers have made seminal contributions. This book aims to address the notably diverse topic of transition-metal catalysis in a single volume. The first half of the book is dedicated to the discrete and atomically precise metal complexes for homogeneous catalysis. Bimetallic, organometallic, and coordination complexes of early, late, and post-transition metals are described. Catalytic hydrogenation, oxidation, and coupling reactions are presented. The second half of the book focuses on three distinct types of nanomaterials: (1) zero- valent metallic nanoparticles, (2) titanium dioxide semiconductors, and (3) the porous coordination polymer known as the metal-organic framework. The chapters illustrate how deeply catalysis is influenced by other disciplines (e.g., coordination chemistry, bioinorganic chemistry, organometallic chemistry, computational chemistry, organic synthesis, photochemistry, materials science, environmental chemistry, green chemistry, and renewable energy). Advancements in these areas fuel the rapid growth of catalysis science. This book allows readers to reach a high-level of understanding in catalysis by learning from the perspectives of active practitioners. Unlike a textbook that provides a systematic, comprehensive, and historical education on the general topics of catalysis, this book offers critical case studies on select topics. Substantial emphasis is placed on the structural and fundamental properties that dictate catalyst performance, enabling readers to quickly understand and apply knowledge from cutting-edge studies and applications detailed within. This book can be utilized as a handbook, a textbook or textbook supplement, or a reference to guide future work"--

Download or read book Zinc Catalysis written by Stephan Enthaler and published by John Wiley & Sons. This book was released on 2015-04-27 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling the gap in the market for comprehensive coverage of this hot topic, this timely book covers a wide range of organic transformations, e. g. reductions of unsaturated compounds, oxidation reactions, Friedel-Crafts reactions, hydroamination reactions, depolymerizations, transformations of carbon dioxide, oxidative coupling reactions, as well as C-C, C-N, and C-O bond formation reactions. A chapter on the application of zinc catalysts in total synthesis is also included. With its aim of stimulating further research and discussion in the field, this is a valuable reference for professionals in academia and industry wishing to learn about the latest developments.

Download or read book Copper I Chemistry of Phosphines Functionalized Phosphines and Phosphorus Heterocycles written by Maravanji S. Balakrishna and published by Elsevier. This book was released on 2019-04-26 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Copper(I) Complexes of Phosphines, Functionalized Phosphines and Phosphorus Heterocycles is a comprehensive guide to one of the most widely used and extensively studied metals: copper. The numerous practical applications of copper compounds are discussed, including homogeneous and heterogeneous catalysis and their use as fungicides, pesticides, pigments for paints, resins and glasses, and in high-temperature superconductors. The remarkable structural flexibility of simple copper(I) complexes, such as cuprous halides is covered, including numerous structural motifs that, when combined with different ligand systems, exhibit linear, trigonal planar or tetrahedral geometries. This work is an essential reference for inorganic and coordination chemists, as well as researchers working on catalysis, anticancer reagents, luminescence, fluorescence and photophysical aspects.

Download or read book Catalysis of Organic Reactions written by Jr. Sowa and published by CRC Press. This book was released on 2005-03-30 with total page 586 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume compiles 63 peer-reviewed scientific papers documenting the latest developments in the application of homogeneous, heterogeneous, and immobilized homogenous catalysts used in organic synthesis. Catalysis of Organic Reactions consists of primary research articles accompanied by experimental sections that emphasize chemical processes with

Download or read book Molecular Catalysts written by Lutz H. Gade and published by John Wiley & Sons. This book was released on 2014-06-30 with total page 632 pages. Available in PDF, EPUB and Kindle. Book excerpt: Highlighting the key aspects and latest advances in the rapidly developing field of molecular catalysis, this book covers new strategies to investigate reaction mechanisms, the enhancement of the catalysts' selectivity and efficiency, as well as the rational design of well-defined molecular catalysts. The interdisciplinary author team with an excellent reputation within the community discusses experimental and theoretical studies, along with examples of improved catalysts, and their application in organic synthesis, biocatalysis, and supported organometallic catalysis. As a result, readers will gain a deeper understanding of the catalytic transformations, allowing them to adapt the knowledge to their own investigations. With its ideal combination of fundamental and applied research, this is an essential reference for researchers and graduate students both in academic institutions and in the chemical industry. With a foreword by Nobel laureate Roald Hoffmann.

Download or read book Organophosphorus Chemistry written by David W Allen and published by Royal Society of Chemistry. This book was released on 2020-04-15 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt: This annual review of the literature presents a comprehensive and critical survey of the vast field of study involving organophosphorus compounds, from phosphines and related P-C bonded compounds to phosphorus acids, phosphine chalcogenides and nucleotides. The Editors have added to the content with a timely chapter on the recent developments in green synthetic approaches in organophosphorus chemistry to reflect current interests in the area. With an emphasis on interdisciplinary content, this book is aimed at the worldwide organic chemistry and engineering research communities.

Download or read book Hydrogen Transfer Reactions written by Gabriela Guillena and published by Springer. This book was released on 2016-09-27 with total page 393 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Download or read book Sustainable Synthesis of Pharmaceuticals written by Mariette M. Pereira and published by Royal Society of Chemistry. This book was released on 2018-03-26 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Scorpionates II written by Claudio Pettinari and published by World Scientific. This book was released on 2008 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt: This resource continues where Trofimenko's original work left off. It not only includes discussions on all new ligands reported from 1999 to date, but also introduces new ligands, such as scorpionates based on S donors or P donors. As such, this volume is a 'must-have' for all researchers who use this family of molecules.

Download or read book CO2 as a Building Block in Organic Synthesis written by Shoubhik Das and published by John Wiley & Sons. This book was released on 2020-09-16 with total page 623 pages. Available in PDF, EPUB and Kindle. Book excerpt: A guide to the fascinating application of CO2 as a building block in organic synthesis This important book explores modern organic synthesis’ use of the cheap, non-toxic and abundant chemical CO2as an attractive C1 building block. With contributions from an international panel of experts, CO2 as a Building Block in Organic Synthesis offers a review of the most important reactions which use CO2 as a building block in organic synthesis. The contributors examine a wide-range of CO2 reactions including methylation reactions, CH bond functionalization, carboxylation, cyclic carbonate synthesis, multicomponent reactions, and many more. The book reviews the most recent developments in the field and also: Presents the most important reactions like CH-bond functionalization, carboxylation, carbonate synthesis and many more Contains contributions from an international panel of experts Offers a comprehensive resource for academics and professionals in the field Written for organic chemists, chemists working with or on organometallics, catalytic chemists, pharmaceutical chemists, and chemists in industry, CO2 as Building Block in Organic Synthesis contains an analysis of the most important reactions which use CO2 as an effective building block in organic synthesis.

Download or read book Homo and Heterobimetallic Complexes in Catalysis written by Philippe Kalck and published by Springer. This book was released on 2016-06-14 with total page 287 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal

Download or read book Strategic Applications of Named Reactions in Organic Synthesis written by Laszlo Kurti and published by Elsevier. This book was released on 2005-04-29 with total page 808 pages. Available in PDF, EPUB and Kindle. Book excerpt: Kurti and Czako have produced an indispensable tool for specialists and non-specialists in organic chemistry. This innovative reference work includes 250 organic reactions and their strategic use in the synthesis of complex natural and unnatural products. Reactions are thoroughly discussed in a convenient, two-page layout--using full color. Its comprehensive coverage, superb organization, quality of presentation, and wealth of references, make this a necessity for every organic chemist. - The first reference work on named reactions to present colored schemes for easier understanding - 250 frequently used named reactions are presented in a convenient two-page layout with numerous examples - An opening list of abbreviations includes both structures and chemical names - Contains more than 10,000 references grouped by seminal papers, reviews, modifications, and theoretical works - Appendices list reactions in order of discovery, group by contemporary usage, and provide additional study tools - Extensive index quickly locates information using words found in text and drawings

Download or read book Advanced Structural Chemistry written by Rong Cao and published by John Wiley & Sons. This book was released on 2021-06-28 with total page 1088 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Structural Chemistry Discover the relationships between inorganic chemical synthesis, structure, and property with these comprehensive and insightful volumes Advanced Structural Chemistry: Tailoring Properties of Inorganic Materials and their Applications (3 Volume Set) offers readers the opportunity to discover the relationship between the structure and function of matter, develop efficient and precise synthesis methodology, and to understand the theoretical tools for new functional substances. Advanced Structural Chemistry clarifies the relationships between synthesis and structure, as well as structure and property, both of which are central to the creation of new materials with unique functions. In addition to subjects like the syntheses of metal-oxide clusters, metal-organic cages, and metal-organic frameworks with tailored optical, electric, ferroelectric, magnetic, adsorption, separation, and catalytic properties, the accomplished editor Rong Cao provides readers with information on a wide variety of topics, such as: Coordination-assembled metal-organic macrocycles and cages, including metallacycles and metallacages The structural chemistry of metal-oxo clusters, including the oxo clusters of transition metal, main group metal, and lanthanides Synthetic approaches, structural diversities, and biological aspects of molybdenum-based heterometallic sulfide clusters and coordination polymers Group 11-15 metal chalcogenides, including discrete chalcogenide clusters synthesized in ionic liquids The structures of metal-organic frameworks, including one-, two-, and three-dimensional MOFs Perfect for inorganic chemists, structural chemists, solid state chemists, material scientists, and solid state physicists, Advanced Structural Chemistry also belongs on the bookshelves of catalytic and industrial chemists who seek to improve their understanding of the structure and functions of inorganic materials.

Download or read book Catalytic Asymmetric Synthesis written by Takahiko Akiyama and published by John Wiley & Sons. This book was released on 2022-05-27 with total page 798 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalytic Asymmetric Synthesis Seminal text presenting detailed accounts of the most important catalytic asymmetric reactions known today This book covers the preparation of enantiomerically pure or enriched chemical compounds by use of chiral catalyst molecules. While reviewing the most important catalytic methods for asymmetric organic synthesis, this book highlights the most important and recent developments in catalytic asymmetric synthesis. Edited by two well-qualified experts, sample topics covered in the work include: Metal catalysis, organocatalysis, photoredox catalysis, enzyme catalysis C–H bond functionalization reactions Carbon–carbon bond formation reactions, carbon–halogen bond formation reactions, hydrogenations, polymerizations, flow reactions Axially chiral compounds Retaining the best of its predecessors but now thoroughly up to date with the important and recent developments in catalytic asymmetric synthesis, the 4th edition of Catalytic Asymmetric Synthesis serves as an excellent desktop reference and text for researchers and students, from upper-level undergraduates all the way to experienced professionals in industry or academia.

Download or read book Applied Cross Coupling Reactions written by Yasushi Nishihara and published by Springer Science & Business Media. This book was released on 2012-12-14 with total page 247 pages. Available in PDF, EPUB and Kindle. Book excerpt: “Applied Cross-Coupling Reactions” provides students and teachers of advanced organic chemistry with an overview of the history, mechanisms and applications of cross-coupling reactions. Since the discovery of the transition-metal-catalyzed cross-coupling reactions in 1972, numerous synthetic uses and industrial applications have been developed. The mechanistic studies of the cross-coupling reactions have disclosed that three fundamental reactions: oxidative addition, transmetalation, and reductive elimination, are involved in a catalytic cycle. Cross-coupling reactions have allowed us to produce a variety of compounds for industrial purposes, such as natural products, pharmaceuticals, liquid crystals and conjugate polymers for use in electronic devices. Indeed, the Nobel Prize for Chemistry in 2010 was awarded for work on cross-coupling reactions. In this book, the recent trends in cross-coupling reactions are also introduced from the point of view of synthesis design and catalytic activities of transition-metal catalysts.

Download or read book Superbases for Organic Synthesis written by Tsutomu Ishikawa and published by John Wiley & Sons. This book was released on 2009-01-26 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: Guanidines, amidines and phosphazenes have been attracting attention in organic synthesis due to their potential functionality resulting from their extremely strong basicity. They are also promising catalysts because of their potential for easy molecular modification, possible recyclability, and reduced or zero toxicity. Importantly, these molecules can be derived as natural products – valuable as scientists move towards “sustainable chemistry”, where reagents and catalysts are derived from biomaterial sources. Superbases for Organic Synthesis is an essential guide to these important molecules for preparative organic synthesis. Topics covered include the following aspects: an introduction to organosuperbases physicochemical properties of organic superbases amidines and guanidines in organic synthesis phosphazene: preparation, reaction and catalytic role polymer-supported organosuperbases application of organosuperbases to total synthesis related organocatalysts: proton sponges and urea derivatives amidines and guanidines in natural products and medicines Superbases for Organic Synthesis is a comprehensive, authoritative and up-to-date guide to these important reagents for organic chemists, drug discovery researchers and those interested in the chemistry of natural products.